0% found this document useful (0 votes)
52 views16 pages

Soot Sticks MSDS

SOOT STICKS, produced by Drew Marine, is an environmentally hazardous solid containing zinc oxide and copper(II) oxide, classified as a skin and eye irritant and a respiratory tract irritant. The product requires careful handling and storage to prevent dust generation and potential fire hazards, with specific first-aid measures outlined for exposure. Emergency contact information and precautions for safe handling, storage, and disposal are also provided in the Safety Data Sheet.

Uploaded by

Roman Penkovskii
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
52 views16 pages

Soot Sticks MSDS

SOOT STICKS, produced by Drew Marine, is an environmentally hazardous solid containing zinc oxide and copper(II) oxide, classified as a skin and eye irritant and a respiratory tract irritant. The product requires careful handling and storage to prevent dust generation and potential fire hazards, with specific first-aid measures outlined for exposure. Emergency contact information and precautions for safe handling, storage, and disposal are also provided in the Safety Data Sheet.

Uploaded by

Roman Penkovskii
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 16

SOOT STICKS

Drew Marine Chemwatch Hazard Alert Code: 2


Chemwatch: 24-0215 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
Safety Data Sheet according to OSHA HazCom Standard (2024) requirements S.GHS.USA.EN

SECTION 1 Identification

Product Identifier
Product name SOOT STICKS

Chemical Name Not Applicable


Proper shipping name Environmentally hazardous substance, solid, n.o.s. (contains zinc oxide and copper(II) oxide)

Chemical formula Not Applicable


Other means of
UFI: 9DNP-T3P3-3009-9PGK
identification

Recommended use of the chemical and restrictions on use


Relevant identified uses Use according to manufacturer's directions.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name Drew Marine
Address 400 Captain Neville Drive, Waterbury CT 06705 United States

Telephone +1-973-526-5700
Fax Not Available

Website www.drew-marine.com
Email [email protected]

Emergency phone number


Association / Organisation Drew Marine CHEMWATCH EMERGENCY RESPONSE (24/7)

Emergency telephone The numbers below are for EMERGENCY USE ONLY. Use
+1 855-237-5573
number(s) the corporate number above for all other calls.
Other emergency
CHEMWATCH: +613 9573 3188 +61 3 9573 3188
telephone number(s)

SECTION 2 Hazard(s) identification

Classification of the substance or mixture

Skin Corrosion/Irritation Category 2, Serious Eye Damage/Eye Irritation Category 2A, Specific Target Organ Toxicity - Single
Classification
Exposure (Respiratory Tract Irritation) Category 3, Specific Target Organ Toxicity - Repeated Exposure Category 2

Label elements

Hazard pictogram(s)

Signal word Warning

Page 1 continued...
Chemwatch: 24-0215 Page 2 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.

Hazard(s) not otherwise classified


Not Applicable

Supplementary statement(s)
Not Applicable

Precautionary statement(s) Prevention


P260 Do not breathe dust/fume.
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fumes.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P264 Wash all exposed external body areas thoroughly after handling.

Precautionary statement(s) Response


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Precautionary statement(s) Storage


P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal


P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
7647-14-5 80-88 sodium chloride
1314-13-2 10-15 zinc oxide
1317-38-0 1-5 copper(II) oxide
Not Available Note: Manufacturer has supplied full ingredient
Not Available information to allow CHEMWATCH assessment.

The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.

SECTION 4 First-aid measures

Description of first aid measures


Eye Contact If this product comes in contact with the eyes:
Wash out immediately with fresh running water.

Continued...
Chemwatch: 24-0215 Page 3 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
Inhalation procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Ingestion Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

Most important symptoms and effects, both acute and delayed


See Section 11

Indication of any immediate medical attention and special treatment needed


Treat symptomatically.

SECTION 5 Fire-fighting measures

Extinguishing media
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture


Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
Fire Incompatibility
result

Special protective equipment and precautions for fire-fighters


Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water courses.
Use water delivered as a fine spray to control fire and cool adjacent area.
Fire Fighting
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
Fire/Explosion Hazard Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible
(circa 70%) - according to the circumstances under which the combustion process occurs, such materials may cause fires
and / or dust explosions.
Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended
in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including
secondary explosions).
Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture
with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the fine grinding
of the solid are a particular hazard; accumulations of fine dust (420 micron or less) may burn rapidly and fiercely if ignited -
particles exceeding this limit will generally not form flammable dust clouds; once initiated, however, larger particles up to
1400 microns diameter will contribute to the propagation of an explosion.
In the same way as gases and vapours, dusts in the form of a cloud are only ignitable over a range of concentrations; in
principle, the concepts of lower explosive limit (LEL) and upper explosive limit (UEL) are applicable to dust clouds but only
the LEL is of practical use; - this is because of the inherent difficulty of achieving homogeneous dust clouds at high
temperatures (for dusts the LEL is often called the "Minimum Explosible Concentration", MEC).
When processed with flammable liquids/vapors/mists,ignitable (hybrid) mixtures may be formed with combustible dusts.
Ignitable mixtures will increase the rate of explosion pressure rise and the Minimum Ignition Energy (the minimum amount of
energy required to ignite dust clouds - MIE) will be lower than the pure dust in air mixture. The Lower Explosive Limit (LEL) of
the vapour/dust mixture will be lower than the individual LELs for the vapors/mists or dusts.

Continued...
Chemwatch: 24-0215 Page 4 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

A dust explosion may release of large quantities of gaseous products; this in turn creates a subsequent pressure rise of
explosive force capable of damaging plant and buildings and injuring people.
Usually the initial or primary explosion takes place in a confined space such as plant or machinery, and can be of sufficient
force to damage or rupture the plant. If the shock wave from the primary explosion enters the surrounding area, it will disturb
any settled dust layers, forming a second dust cloud, and often initiate a much larger secondary explosion. All large scale
explosions have resulted from chain reactions of this type.
Dry dust can be charged electrostatically by turbulence, pneumatic transport, pouring, in exhaust ducts and during transport.
Build-up of electrostatic charge may be prevented by bonding and grounding.
Powder handling equipment such as dust collectors, dryers and mills may require additional protection measures such as
explosion venting.
All movable parts coming in contact with this material should have a speed of less than 1-meter/sec.
A sudden release of statically charged materials from storage or process equipment, particularly at elevated temperatures
and/ or pressure, may result in ignition especially in the absence of an apparent ignition source.
One important effect of the particulate nature of powders is that the surface area and surface structure (and often moisture
content) can vary widely from sample to sample, depending of how the powder was manufactured and handled; this means
that it is virtually impossible to use flammability data published in the literature for dusts (in contrast to that published for
gases and vapours).
Autoignition temperatures are often quoted for dust clouds (minimum ignition temperature (MIT)) and dust layers (layer
ignition temperature (LIT)); LIT generally falls as the thickness of the layer increases.
Combustion products include:
carbon monoxide (CO)
carbon dioxide (CO2)
hydrogen chloride
phosgene
other pyrolysis products typical of burning organic material.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures


See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up


Remove all ignition sources.
Clean up all spills immediately.
Avoid contact with skin and eyes.
Minor Spills Control personal contact with the substance, by using protective equipment.
Use dry clean up procedures and avoid generating dust.
Place in a suitable, labelled container for waste disposal.
Environmental hazard - contain spillage.

Environmental hazard - contain spillage.


Moderate hazard.
CAUTION: Advise personnel in area.
Alert Emergency Services and tell them location and nature of hazard.
Control personal contact by wearing protective clothing.
Major Spills Prevent, by any means available, spillage from entering drains or water courses.
Recover product wherever possible.
IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other
containers for disposal. IF WET: Vacuum/shovel up and place in labelled containers for disposal.
ALWAYS: Wash area down with large amounts of water and prevent runoff into drains.
If contamination of drains or waterways occurs, advise Emergency Services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling


Safe handling Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
DO NOT allow material to contact humans, exposed food or food utensils.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately. Launder contaminated clothing before re-use.
Use good occupational work practice.

Continued...
Chemwatch: 24-0215 Page 5 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Observe manufacturer's storage and handling recommendations contained within this SDS.
Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are
maintained.
Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended
in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including
secondary explosions)
Minimise airborne dust and eliminate all ignition sources. Keep away from heat, hot surfaces, sparks, and flame.
Establish good housekeeping practices.
Remove dust accumulations on a regular basis by vacuuming or gentle sweeping to avoid creating dust clouds.
Use continuous suction at points of dust generation to capture and minimise the accumulation of dusts. Particular attention
should be given to overhead and hidden horizontal surfaces to minimise the probability of a "secondary" explosion. According
to NFPA Standard 654, dust layers 1/32 in.(0.8 mm) thick can be sufficient to warrant immediate cleaning of the area.
Do not use air hoses for cleaning.
Minimise dry sweeping to avoid generation of dust clouds. Vacuum dust-accumulating surfaces and remove to a chemical
disposal area. Vacuums with explosion-proof motors should be used.
Control sources of static electricity. Dusts or their packages may accumulate static charges, and static discharge can be a
source of ignition.
Solids handling systems must be designed in accordance with applicable standards (e.g. NFPA including 654 and 77) and
other national guidance.
Do not empty directly into flammable solvents or in the presence of flammable vapors.
The operator, the packaging container and all equipment must be grounded with electrical bonding and grounding systems.
Plastic bags and plastics cannot be grounded, and antistatic bags do not completely protect against development of static
charges.
Empty containers may contain residual dust which has the potential to accumulate following settling. Such dusts may explode in
the presence of an appropriate ignition source.
Do NOT cut, drill, grind or weld such containers.
In addition ensure such activity is not performed near full, partially empty or empty containers without appropriate workplace
safety authorisation or permit.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry area protected from environmental extremes.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Other information Observe manufacturer's storage and handling recommendations contained within this SDS.
For major quantities:
Consider storage in bunded areas - ensure storage areas are isolated from sources of community water (including
stormwater, ground water, lakes and streams}.
Ensure that accidental discharge to air or water is the subject of a contingency disaster management plan; this may require
consultation with local authorities.

Conditions for safe storage, including any incompatibilities


Polyethylene or polypropylene container.
Suitable container
Check all containers are clearly labelled and free from leaks.

Zinc oxide:
slowly absorbs carbon dioxide from the air.
may react, explosively with magnesium and chlorinated rubber when heated
Storage incompatibility
is incompatible with linseed oil (may cause ignition)
Food grade materials must be protected from all possible contaminants
Avoid reaction with oxidising agents

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

US OSHA Permissible
Not Not Not
Exposure Limits (PELs) zinc oxide Zinc oxide fume 5 mg/m3
Available Available Available
Table Z-1

US OSHA Permissible
Not Not Not
Exposure Limits (PELs) zinc oxide Zinc oxide- Respirable fraction 5 mg/m3
Available Available Available
Table Z-1

US OSHA Permissible
Not Not Not
Exposure Limits (PELs) zinc oxide Zinc oxide- Total dust 15 mg/m3
Available Available Available
Table Z-1
US OSHA Permissible
5 mg/m3 / 15 Not Not Not
Exposure Limits (PELs) zinc oxide Inert or Nuisance Dust: Respirable fraction
mppcf Available Available Available
Table Z-3
US OSHA Permissible zinc oxide Inert or Nuisance Dust: Total Dust 15 mg/m3 / 50 Not Not Not
Exposure Limits (PELs) mppcf Available Available Available

Continued...
Chemwatch: 24-0215 Page 6 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Source Ingredient Material name TWA STEL Peak Notes


Table Z-3
US NIOSH Recommended Not Not
zinc oxide Zinc oxide - Dust 5 mg/m3 15 mg/m3
Exposure Limits (RELs) Available Available
US NIOSH Recommended Not Not
zinc oxide Zinc oxide - Fume 5 mg/m3 10 mg/m3
Exposure Limits (RELs) Available Available

US OSHA Permissible
copper(II) Particulates Not Otherwise Regulated Not Not Not
Exposure Limits (PELs) 15 mg/m3
oxide (PNOR)- Total dust Available Available Available
Table Z-1
US OSHA Permissible
copper(II) Particulates Not Otherwise Regulated Not Not Not
Exposure Limits (PELs) 5 mg/m3
oxide (PNOR)- Respirable fraction Available Available Available
Table Z-1
US OSHA Permissible
copper(II) 5 mg/m3 / 15 Not Not Not
Exposure Limits (PELs) Inert or Nuisance Dust: Respirable fraction
oxide mppcf Available Available Available
Table Z-3
US OSHA Permissible
copper(II) 15 mg/m3 / 50 Not Not Not
Exposure Limits (PELs) Inert or Nuisance Dust: Total Dust
oxide mppcf Available Available Available
Table Z-3

US NIOSH Recommended copper(II) Not Not Not


Copper fume (as Cu) 0.1 mg/m3
Exposure Limits (RELs) oxide Available Available Available

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

sodium chloride 0.5 ppm 2 ppm 20 ppm


zinc oxide 10 mg/m3 15 mg/m3 2,500 mg/m3

copper(II) oxide 0.75 mg/m3 11 mg/m3 93 mg/m3

Ingredient Original IDLH Revised IDLH


sodium chloride Not Available Not Available

zinc oxide 500 mg/m3 Not Available

copper(II) oxide 100 mg/m3 Not Available

Exposure controls
Appropriate engineering Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
controls engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively
large, a certain proportion will be powdered by mutual friction.
Exhaust ventilation should be designed to prevent accumulation and recirculation of particulates in the workplace.
If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be
considered. Such protection might consist of:
(a): particle dust respirators, if necessary, combined with an absorption cartridge;
(b): filter respirators with absorption cartridge or canister of the right type;
(c): fresh-air hoods or masks
Build-up of electrostatic charge on the dust particle, may be prevented by bonding and grounding.
Powder handling equipment such as dust collectors, dryers and mills may require additional protection measures such as
explosion venting.
Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture
velocities" of fresh circulating air required to efficiently remove the contaminant.

Type of Contaminant: Air Speed:

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas 1-2.5 m/s (200-500
discharge (active generation into zone of rapid air motion) ft/min)

grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial 2.5-10 m/s (500-
velocity into zone of very high rapid air motion). 2000 ft/min)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range


1: Room air currents minimal or favourable to capture 1: Disturbing room air currents

2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity

3: Intermittent, low production. 3: High production, heavy use

Continued...
Chemwatch: 24-0215 Page 7 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity
generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the
extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 4-10 m/s (800-2000 ft/min) for extraction of crusher dusts generated 2
metres distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction
apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are
installed or used.

Individual protection
measures, such as
personal protective
equipment

Safety glasses with side shields.


Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
Eye and face protection include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should
be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

Skin protection See Hand protection below

NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and
other protective equipment, to avoid all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).
· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time
greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes
according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for
long-term use.
· Contaminated gloves should be replaced.
As defined in ASTM F-739-96 in any application, gloves are rated as:
Hands/feet protection
· Excellent when breakthrough time > 480 min
· Good when breakthrough time > 20 min
· Fair when breakthrough time < 20 min
· Poor when glove material degrades
For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.
It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection
should also be based on consideration of the task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the
manufacturers technical data should always be taken into account to ensure selection of the most appropriate glove for the task.
Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:
· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these
gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of.
· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there
is abrasion or puncture potential
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a
non-perfumed moisturiser is recommended.
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids,
where abrasive particles are not present.
polychloroprene.
nitrile rubber.
butyl rubber.
fluorocaoutchouc.
polyvinyl chloride.
Gloves should be examined for wear and/ or degradation constantly.
Body protection See Other protection below

Continued...
Chemwatch: 24-0215 Page 8 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Recommended material(s) Respiratory protection


GLOVE SELECTION INDEX Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
Glove selection is based on a modified presentation of the: 149:2001, ANSI Z88 or national equivalent)
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the Required Minimum Half-Face Full-Face Powered Air
computer-generated selection: Protection Factor Respirator Respirator Respirator
SOOT STICKS P1 - PAPR-P1
up to 10 x ES
Air-line* - -
Material CPI
up to 50 x ES Air-line** P2 PAPR-P2
NATURAL RUBBER A
up to 100 x ES - P3 -
NATURAL+NEOPRENE A
Air-line* -
NITRILE A
100+ x ES - Air-line** PAPR-P3
* CPI - Chemwatch Performance Index
A: Best Selection * - Negative pressure demand ** - Continuous flow
B: Satisfactory; may degrade after 4 hours continuous immersion A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
C: Poor to Dangerous Choice for other than short term immersion hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
NOTE: As a series of factors will influence the actual performance of the glove, dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
a final selection must be based on detailed observation. - NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
* Where the glove is to be used on a short term, casual or infrequent basis, compounds(below 65 degC)
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
· Respirators may be necessary when engineering and administrative controls
of gloves which might otherwise be unsuitable following long-term or frequent
do not adequately prevent exposures.
use. A qualified practitioner should be consulted.
· The decision to use respiratory protection should be based on professional
judgment that takes into account toxicity information, exposure measurement
Ansell Glove Selection data, and frequency and likelihood of the worker's exposure - ensure users are
not subject to high thermal loads which may result in heat stress or distress
Glove — In order of recommendation
due to personal protective equipment (powered, positive flow, full face
AlphaTec 02-100 apparatus may be an option).
AlphaTec® 15-554 · Published occupational exposure limits, where they exist, will assist in
determining the adequacy of the selected respiratory protection. These may be
AlphaTec® Solvex® 37-185
government mandated or vendor recommended.
MICROFLEX® 63-864 · Certified respirators will be useful for protecting workers from inhalation of
AlphaTec® 38-612 particulates when properly selected and fit tested as part of a complete
respiratory protection program.
AlphaTec® 58-008
· Where protection from nuisance levels of dusts are desired, use type N95
AlphaTec® 58-530B (US) or type P1 (EN143) dust masks. Use respirators and components tested
AlphaTec® 58-530W and approved under appropriate government standards such as NIOSH (US)
or CEN (EU)
AlphaTec® 58-735
· Use approved positive flow mask if significant quantities of dust becomes
AlphaTec® 79-700 airborne.
· Try to avoid creating dust conditions.
The suggested gloves for use should be confirmed with the glove supplier.

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties


Appearance Black colour powder.

Relative density (Water =


Physical state Divided Solid Not Available
1)

Partition coefficient n-
Odour Not Available Not Available
octanol / water

Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)

Decomposition
pH (as supplied) Not Available Not Available
temperature (°C)

Melting point / freezing


Not Available Viscosity (cSt) Not Available
point (°C)

Initial boiling point and


1026 Molecular weight (g/mol) Not Applicable
boiling range (°C)

Flash point (°C) Not Available Taste Not Available

Continued...
Chemwatch: 24-0215 Page 9 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Surface Tension (dyn/cm


Upper Explosive Limit (%) Not Available Not Applicable
or mN/m)

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) 2.51 Gas group Not Available

Solubility in water Not Available pH as a solution (1%) Not Available


Vapour density (Air = 1) Not Available VOC g/L Not Available

Heat of Combustion (kJ/g) Not Available Ignition Distance (cm) Not Available

Flame Height (cm) Not Available Flame Duration (s) Not Available

Enclosed Space Ignition


Enclosed Space Ignition
Not Available Deflagration Density Not Available
Time Equivalent (s/m3)
(g/m3)

Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics

Particle Size Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Unstable in the presence of incompatible materials.


Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects


a) Acute Toxicity Based on available data, the classification criteria are not met.

b) Skin Irritation/Corrosion There is sufficient evidence to classify this material as skin corrosive or irritating.

c) Serious Eye
There is sufficient evidence to classify this material as eye damaging or irritating
Damage/Irritation

d) Respiratory or Skin
Based on available data, the classification criteria are not met.
sensitisation

e) Mutagenicity Based on available data, the classification criteria are not met.

f) Carcinogenicity Based on available data, the classification criteria are not met.
g) Reproductivity Based on available data, the classification criteria are not met.

h) STOT - Single Exposure There is sufficient evidence to classify this material as toxic to specific organs through single exposure

i) STOT - Repeated
There is sufficient evidence to classify this material as toxic to specific organs through repeated exposure
Exposure

j) Aspiration Hazard Based on available data, the classification criteria are not met.

Inhalation of dusts, generated by the material during the course of normal handling, may be damaging to the health of the
individual.
There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to
such irritation can cause further lung damage.
Inhaled Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur
further disability if excessive concentrations of particulate are inhaled.
If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, proper screenings
should be conducted on individuals who may be exposed to further risk if handling and use of the material result in excessive
exposures.

Ingestion Accidental ingestion of the material may be damaging to the health of the individual.

There is some evidence to suggest that the material may cause mild but significant inflammation of the skin either following direct
contact or after a delay of some time. Repeated exposure can cause contact dermatitis which is characterised by redness,
swelling and blistering.
Skin Contact
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Continued...
Chemwatch: 24-0215 Page 10 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

There is some evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more
Eye
after instillation. Moderate inflammation may be expected with redness; conjunctivitis may occur with prolonged exposure.

Overexposure to the breathable dust may cause coughing, wheezing, difficulty in breathing and impaired lung function. Chronic
symptoms may include decreased vital lung capacity and chest infections. Repeated exposures in the workplace to high levels of
fine-divided dusts may produce a condition known as pneumoconiosis, which is the lodgement of any inhaled dusts in the lung,
irrespective of the effect. This is particularly true when a significant number of particles less than 0.5 microns (1/50000 inch) are
present. Lung shadows are seen in the X-ray. Symptoms of pneumoconiosis may include a progressive dry cough, shortness of
breath on exertion, increased chest expansion, weakness and weight loss. As the disease progresses, the cough produces
stringy phlegm, vital capacity decreases further, and shortness of breath becomes more severe. Other signs or symptoms
include changed breath sounds, reduced oxygen uptake during exercise, emphysema and rarely, pneumothorax (air in the lung
cavity).
Removing workers from the possibility of further exposure to dust generally stops the progress of lung abnormalities. When there
is high potential for worker exposure, examinations at regular period with emphasis on lung function should be performed.
Inhaling dust over an extended number of years may cause pneumoconiosis, which is the accumulation of dusts in the lungs and
Chronic the subsequent tissue reaction. This may or may not be reversible.
For copper and its compounds (typically copper chloride):
Acute toxicity: There are no reliable acute oral toxicity results available. Animal testing shows that skin in exposure to copper
may lead to hardness of the skin, scar formation, exudation and reddish changes. Inflammation, irritation and injury of the skin
were noted.
Repeat dose toxicity: Animal testing shows that very high levels of copper monochloride may cause anaemia.
Genetic toxicity: Copper monochloride does not appear to cause mutations in vivo, although chromosomal aberrations were seen
at very high concentrations in vitro.
Cancer-causing potential: There was insufficient information to evaluate the cancer-causing activity of copper monochloride.
Welding or flame cutting of metals with zinc or zinc dust coatings may result in inhalation of zinc oxide fume; high concentrations
of zinc oxide fume may result in "metal fume fever"; also known as "brass chills", an industrial disease of short duration. [I.L.O]
Symptoms include malaise, fever, weakness, nausea and may appear quickly if operations occur in enclosed or poorly ventilated
areas.

TOXICITY IRRITATION
SOOT STICKS
Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: >10000 mg/kg[1] Eye (Rodent - rabbit): 100mg/24H - Moderate

Inhalation (Rat) LC50: >10.5 mg/l4h[1] Eye (Rodent - rabbit): 10mg - Moderate
sodium chloride
Oral (Rat) LD50: 3000 mg/kg[2] Eye: adverse effect observed (irritating)[1]

Skin (Rodent - rabbit): 500mg/24H - Mild

Skin: no adverse effect observed (not irritating)[1]

TOXICITY IRRITATION

dermal (rat) LD50: >2000 mg/kg[1] Eye (Rodent - rabbit): 500mg/24H - Mild

Inhalation (Rat) LC50: >1.79 mg/l4h[1] Eye: no adverse effect observed (not irritating)[1]
zinc oxide
Oral (Rat) LD50: >5000 mg/kg[1] Skin (Human): 300ug/3D (intermittent) - Mild

Skin (Rodent - rabbit): 500mg/24H - Mild

Skin: no adverse effect observed (not irritating)[1]

TOXICITY IRRITATION

copper(II) oxide dermal (rat) LD50: >2000 mg/kg[1] Not Available

Oral (Rat) LD50: >2500 mg/kg[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may
SODIUM CHLORIDE
produce conjunctivitis.

COPPER(II) OXIDE No significant acute toxicological data identified in literature search.

SODIUM CHLORIDE & Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-
COPPER(II) OXIDE allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe
bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without
eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of
and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a result

Continued...
Chemwatch: 24-0215 Page 11 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure
ceases. The disorder is characterized by difficulty breathing, cough and mucus production.

SODIUM CHLORIDE & The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling,
ZINC OXIDE the production of vesicles, scaling and thickening of the skin.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation

Respiratory or Skin
STOT - Repeated Exposure
sensitisation

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 Ecological information

Toxicity

Endpoint Test Duration (hr) Species Value Source


SOOT STICKS Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source


0.004-
EC50 48h Crustacea 4
0.006mg/L
NOEC(ECx) 6h Fish 0.001mg/L 4
sodium chloride
20.76-
EC50 72h Algae or other aquatic plants 4
36.17mg/L
EC50 96h Algae or other aquatic plants 1110.36mg/L 4

LC50 96h Fish 1000mg/L 4

Endpoint Test Duration (hr) Species Value Source


BCF 1344h Fish 19-110 7

EC50 48h Crustacea 0.105mg/L 2

EC50 72h Algae or other aquatic plants 0.022mg/L 2


zinc oxide
ErC50 72h Algae or other aquatic plants 0.62mg/l 2
EC50 96h Algae or other aquatic plants 0.042mg/L 2

EC10(ECx) 168h Algae or other aquatic plants 0.003mg/L 2

LC50 96h Fish 0.102mg/L 2

Endpoint Test Duration (hr) Species Value Source


EC50 48h Crustacea 0.001mg/L 2

EC50 72h Algae or other aquatic plants 0.014mg/l 4


copper(II) oxide
EC50 96h Algae or other aquatic plants 0.047mg/l 2

EC50(ECx) 48h Crustacea 0.001mg/L 2


LC50 96h Fish 0.003mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
DO NOT discharge into sewer or waterways.

Persistence and degradability


Ingredient Persistence: Water/Soil Persistence: Air

sodium chloride LOW LOW


copper(II) oxide HIGH HIGH

Continued...
Chemwatch: 24-0215 Page 12 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Bioaccumulative potential
Ingredient Bioaccumulation
sodium chloride LOW (LogKOW = 0.54)

zinc oxide LOW (BCF = 217)

copper(II) oxide LOW (BCF = 2.514)

Mobility in soil
Ingredient Mobility

sodium chloride LOW (Log KOC = 14.3)

copper(II) oxide LOW (Log KOC = 14.3)

Other adverse effects


No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

Waste treatment methods


Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. Shelf
life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use,
Product / Packaging and recycling or reuse may not always be appropriate. In most instances the supplier of the material should be consulted.
disposal DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a
licensed apparatus (after admixture with suitable combustible material)
Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

SECTION 14 Transport information

Labels Required

Marine Pollutant

Shipping container, transport vehicle placarding, and labeling may vary from the below information. This depends on the quantity shipped, the applicability of
excepted quantity requirements, limited quantity requirements, and/or special provisions according to US DOT, IATA and IMDG regulations. In case of reshipment,
it is the responsibility of the shipper to determine the appropriate labels and markings in accordance with applicable transport regulations.

Land transport (DOT)


14.1. UN number or ID
3077
number
14.2. UN proper shipping
Environmentally hazardous substance, solid, n.o.s. (contains zinc oxide and copper(II) oxide)
name

14.3. Transport hazard Class 9


class(es) Subsidiary Hazard Not Applicable

Continued...
Chemwatch: 24-0215 Page 13 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

14.4. Packing group III

14.5. Environmental
Environmentally hazardous
hazard

14.6. Special precautions Hazard Label 9


for user Special provisions 8, 146, 335, 384, 441, A112, B54, B120, IB8, IP3, N20, N91, T1, TP33

For Individual Packages of Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 that contain LESS THAN the reportable
quantity - Not Regulated.
For Individual Packages of Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 that contain EQUAL OR MORE THAN the
reportable quantity - Regulated.

Air transport (ICAO-IATA / DGR)


14.1. UN number 3077

14.2. UN proper shipping


Environmentally hazardous substance, solid, n.o.s. (contains zinc oxide and copper(II) oxide)
name

ICAO/IATA Class 9
14.3. Transport hazard
ICAO / IATA Subsidiary Hazard Not Applicable
class(es)
ERG Code 9L

14.4. Packing group III

14.5. Environmental
Environmentally hazardous
hazard

Special provisions A97 A158 A179 A197 A215

Cargo Only Packing Instructions 956


Cargo Only Maximum Qty / Pack 400 kg
14.6. Special precautions
Passenger and Cargo Packing Instructions 956
for user
Passenger and Cargo Maximum Qty / Pack 400 kg

Passenger and Cargo Limited Quantity Packing Instructions Y956

Passenger and Cargo Limited Maximum Qty / Pack 30 kg G

Sea transport (IMDG-Code / GGVSee)


14.1. UN number 3077

14.2. UN proper shipping


ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains zinc oxide and copper(II) oxide)
name

14.3. Transport hazard IMDG Class 9


class(es) IMDG Subsidiary Hazard Not Applicable

14.4. Packing group III

14.5 Environmental hazard Marine Pollutant

EMS Number F-A , S-F


14.6. Special precautions
Special provisions 274 335 966 967 969
for user
Limited Quantities 5 kg

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group

sodium chloride Not Available

zinc oxide Not Available


copper(II) oxide Not Available

14.7.3. Transport in bulk in accordance with the IGC Code


Product name Ship Type

sodium chloride Not Available

Continued...
Chemwatch: 24-0215 Page 14 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Product name Ship Type

zinc oxide Not Available

copper(II) oxide Not Available

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

sodium chloride is found on the following regulatory lists

US DOE Temporary Emergency Exposure Limits (TEELs)


US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

zinc oxide is found on the following regulatory lists

International WHO List of Proposed Occupational Exposure Limit (OEL) Values for Manufactured Nanomaterials (MNMS)
US - Alaska Air Quality Control - Concentrations Triggering an Air Quality Episode for Air Pollutants Other Than PM-2.5
US - Massachusetts - Right To Know Listed Chemicals
US - New Jersey Right to Know Hazardous Substances
US - Pennsylvania - Hazardous Substance List
US CWA (Clean Water Act) - Priority Pollutants
US CWA (Clean Water Act) - Toxic Pollutants
US DOE Temporary Emergency Exposure Limits (TEELs)
US EPA Integrated Risk Information System (IRIS)
US EPCRA Section 313 Chemical List
US New York City Community Right-to-Know: List of Hazardous Substances
US NIOSH Recommended Exposure Limits (RELs)
US OSHA Permissible Exposure Limits (PELs) Table Z-1
US OSHA Permissible Exposure Limits (PELs) Table Z-3
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

copper(II) oxide is found on the following regulatory lists

International WHO List of Proposed Occupational Exposure Limit (OEL) Values for Manufactured Nanomaterials (MNMS)
US - Alaska Air Quality Control - Concentrations Triggering an Air Quality Episode for Air Pollutants Other Than PM-2.5
US CWA (Clean Water Act) - Priority Pollutants
US CWA (Clean Water Act) - Toxic Pollutants
US DOE Temporary Emergency Exposure Limits (TEELs)
US EPCRA Section 313 Chemical List
US New York City Community Right-to-Know: List of Hazardous Substances
US NIOSH Recommended Exposure Limits (RELs)
US OSHA Permissible Exposure Limits (PELs) Table Z-1
US OSHA Permissible Exposure Limits (PELs) Table Z-3
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

Additional Regulatory Information


Not Applicable

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312 hazard categories

Flammable (Gases, Aerosols, Liquids, or Solids) No

Gas under pressure No

Explosive No

Self-heating No
Pyrophoric (Liquid or Solid) No

Pyrophoric Gas No

Corrosive to metal No

Oxidizer (Liquid, Solid or Gas) No

Organic Peroxide No

Self-reactive No

In contact with water emits flammable gas No

Combustible Dust No

Continued...
Chemwatch: 24-0215 Page 15 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Carcinogenicity No
Acute toxicity (any route of exposure) No

Reproductive toxicity No

Skin Corrosion or Irritation Yes

Respiratory or Skin Sensitization No

Serious eye damage or eye irritation Yes

Specific target organ toxicity (single or repeated exposure) Yes

Aspiration Hazard No

Germ cell mutagenicity No


Simple Asphyxiant No

Hazards Not Otherwise Classified No

US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)
None Reported

US. EPCRA Section 313 Toxic Release Inventory (TRI) (40 CFR 372)
This product contains the following EPCRA section 313 chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community
Right-To-Know-Act of 1986 (40 CFR 372):

CAS No %[weight] Name

1314-13-2 10-15 zinc oxide

1317-38-0 1-5 copper(II) oxide

This information must be included in all SDSs that are copied and distributed for this material.

Additional Federal Regulatory Information


Not Applicable

State Regulations

US. California Proposition 65


None Reported

Additional State Regulatory Information


Not Applicable

National Inventory Status


National Inventory Status

Australia - AIIC / Australia


Yes
Non-Industrial Use

Canada - DSL Yes

Canada - NDSL No (sodium chloride; copper(II) oxide)

China - IECSC Yes


Europe - EINEC / ELINCS /
Yes
NLP

Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA All chemical substances in this product have been designated as TSCA Inventory ‘Active'
Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH Yes

Yes = All CAS declared ingredients are on the inventory


Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 10/12/2021

Continued...
Chemwatch: 24-0215 Page 16 of 16 Issue Date: 10/12/2021
Version No: 6.1 Print Date: 02/04/2025
SOOT STICKS

Initial Date 26/07/2010

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

Definitions and abbreviations


PC TWA: Permissible Concentration-Time Weighted Average
PC STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL: No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
DNEL: Derived No-Effect Level
PNEC: Predicted no-effect concentration
MARPOL: International Convention for the Prevention of Pollution from Ships
IMSBC: International Maritime Solid Bulk Cargoes Code
IGC: International Gas Carrier Code
IBC: International Bulk Chemical Code

AIIC: Australian Inventory of Industrial Chemicals


DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

end of SDS

You might also like