Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 30-11-2024
Time: 09:00AM to 12:00PM WTM-20 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point
Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on
the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:

Candidate’s Signature:________________ Invigilator’s Signature: ________________

 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Test Syllabus

MATHEMATICS : Differentiation: from First Principle, Basic Rules of Differentiation, Logarithmic &
Parametric Differentiation, Differentiation of Implicit Functions, Differentiation of composite
functions, Differentiation using substitution, Derivative of a function w.r.t another function,
Summation of some Series using Derivative, derivative of inverse of a function, Higher
Order Derivative, solving Fucntional Equations using differentiation.
PHYSICS : Entropy, Second law of thermodynamics, Carnot engine(Deleted pertaining to JEE
MAINS but still in JEE ADV Syllabus), Different types of processes, Efficiency of a
cycle(Deleted pertaining to JEE MAINS but still in JEE ADV Syllabus), Thermal Properties of
Matter: Heat Transfer, Thermal Conduction, Coefficient of Thermal Conductivity, Physical
Idea of Flow of Heat at Microscopic Level, Thermal Properties of Matter : Radiation,
Distinction Between Conduction, Convection and Radiation, Good Absorbers and bad
reflectors and Vice-Versa, Emittance, Absorptance and Energy Density, Black Body,
Prevost's theory of heat exchange, Kirchoff's Law, Relative Emmitance or Emissivity,
Newtons Law of cooling, Radiation Inside a Hallow Enclosure, Stefans Law, Derivation of
Newtons Law of Cooling From Stefans Law(Deleted pertaining to JEE MAINS but still in JEE
ADV Syllabus), Distribution of Energy in Black Body Spectrum, Wiens Displacement Law,
Solar Constant and Surface Temperature of the Sun, The Green House Effect.
CHEMISTRY : Benzyne, carbenes, nitrenes and radical ions: Generation, Strutucture and Stability,
GOC III: Strength of acids and bases, Strength of acids and bases, Tautomerism.

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. If f  x   x3  x 2 f 1 1  xf 11  2  f 111  3 then f 1  ________
1) -6 2) 4 3) 6 4) 8
1 dy
If e x . e y  sin 1  x 2  y 2  
2 2
2.  5  0 then  ______
x y
2 2 dx

x y x y
1) 2) 3) 4)
y x y x

 dy 
3. If y  cos x.cos 2 x.cos 4 x.cos8 x.cos16 x then   is
 dx  x  
4
1
1) 0 2) 2 3) 4) 2 2
2
 1 x 
  x 2 x3  7 
4. If f  x   4e 2 
1 x   , g  x   f 1  x  then reciprocal of g 1   
2 3  6 
1 1
1) 2) 5 3) -5 4)
5 5

then  
dy
5. If y  Tan 1  4 sin 2 x 
 is equal to
 cos 2 x  6 sin
2
x  dx  x 0

1) 8 2) 7 3) 9 4) 6
d2 y
If x 2  xy  3 y 2  1 then  x  6 y 
3
6.  ______
dx 2
1) 22 2) 46 3) -46 4) -22
7. If x  cos  , y  sin 5 then 1  x 2  y2  xy1  _____

1) 25y 2) 36y 3) -25y 4) -36y

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
d y
2
8. If x  et sin t , y  et cos t then  2  is
 dx t 

   e 
1) 2e 2) 2e 3) e 4)
2
9. Match the following
Column-I Column-II
d  1  2   2
A)  sin  1   P)
dx   x  x  1  x2
 0  x  1
d  1  2 x   1
B)  cos    Q)
dx   1  x2   1  x2
 x  1
1 d  1  2 x  
C)  cos    R) 1
2 dx   1  x2  
 x  1
D)
d
dx

sin 1  cos x    S)
2
1  x2
 x   0,  
1) A  S , B  P, C  Q, D  R 2) A  S , B  Q, C  P, D  R
3) A  S , B  P, C  R, D  Q 4) A  S , B  Q, C  R, D  P

If f is any function defined on R and f  x   f  y    x  y  x, y  R, f  0   1

2
10.

then f  2024  
1
1) 0 2) 3) 1 4) 2
2
5

If cos    log e   y  2 and x 2 y11  xy1  ky  0 then k=_____

y
1 x
11.
2 5
1) 5 2) 25 3) -25 4) -5

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
1

x  1 y2   xy1   y  0 . Then    
1
12. If y  y
4 4
 2 x, 2

1) 15 2) 17 3) 6 4) -17
x 4  x 2  1 dy
13. Statement -I : If y  ,  ax  b then a+b= 2  3
x 2  3 x  1 dx

x4  x2  1 dy
Statement-II : If y  2 then  2x  1
x  x 1 dx
1) Both statement I and statement II are correct
2) Both statement I and statement II are incorrect
3) Statement I is incorrect but statement II is correct.
4) Statement I is correct but statement II is incorrect.
4
Let f : R  R, f  x    2 x  3   x  cos x and g  f 1 then g 11  2   ____
3
14.
3
1
1) 1 2) 3) 0 4) -1
2

 x  x 1  dy
15. if y  cos 1  1 
then  ____
 xx  dx

2 2 3 3
1) 2) 3) 4)
1  x 1  x2 1  x2 1  x2
16. If f  x  y  , f  x  f  y  , f  x  y  are in A.P. for all x, y  R , f  0  0 .Then which of the
following is correct ?
1) f  5  f  5  0 2) f  10   f 10   0

3) f  100   f 100  4) f 1  f  1  0

17. If f  x   x  2 2 x  4  x  2 2 x  4 then f 1  3  f 1  6   _____

1 1
1) 2) 2 3) 3 4)
2 3
cos 6 x  6cos 4 x  15cos 2 x  10 dy
18. If y  then  _____
cos 5 x  5cos 3x  10cos x dx
1) 2 sinx 2) 2 cossecx 3) -2 sinx 4) 2 cosx

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
d  3 d2y 
19. If y  p  x  , a polynomial of degree 3 .Then  y . 2   ______
2

dx  dx 

P  x  P111  x 
1) P  x  P111  x  2) P  x   P111  x  3) P11  x  P111  x  4)
2


If x  sec  cos , y  sec10   cos10  . Then    _____

dy
20.
 dx 

100  x 2  4  100  y 2  4  100  y 2  4  100  y 2  4 

1) 2) 3) 4)
y2  4 x2  4 x2  4 x2  4

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. Let f  x  be a polynomial of degree 3 such that f  3  1 , f 1  3  1 , f 11  3   0 ,
f 111  3  12 . Then the value of 2 f 1 1  ______

 x 2 1
3
log x 1
2 4 log
2 3 27  2x dy
22. If y  x
,&  ax  b . Then ab 
dx
7 4 log 49  x 1
23. If f  x    x  1 x  2      x  n  , n  N , f 1  n   5040 then n=_____

 dy 
24. If 4 xe xy  y  5sin 2 x . Then   is
 dx  x  0
f  x f 1  3
25. Let f  x  y   f  x   f  y   xy 2  x 2 y x, y  R, Lt  1 , then  ____
x 0 x 5

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. There are two identical vessels filled with equal amounts of ice. The vessels of different
metals. If the ice melts in the two vessels in 25 and 40 minutes respectively. The ratio of
the coefficients of thermal conductivity of the two metals is
1) 4 : 7 2) 8 : 5 3) 16 : 49 4) 49 : 16
27. When fluids are heated from the bottom, convection currents are produced because
1) molecular motion of fluid becomes aligned
2) Molecular collisions take place within the fluid
3) Heated fluid becomes more dense then the cold fluid above it
4) Heated fluid becomes less dense than the cold fluid above it
28. A diatomic gas    1.4  does 100J of work in an isobaric expansion. The heat given
to the gas is:
1) 350J 2) 490J 3) 150J 4) 250J
29. Heat is given to an ideal gas in an isothermal process.
A) Internal energy of the gas will decrease.
B) Internal energy of the gas will increase.
C) Internal energy of the gas will not change
D) The gas will do positive work.
E) The gas will do negative work
1) A and E only 2) B and D only 3) C and E only D) C and D only
30. Two identical metal rods of thermal conductivities K1 and K2 respectively are connected
in series. The effective thermal conductivity of the combination is:
K1  K 2 K1  K 2 2K1 K 2 K1 K 2
1) 2) 3) 4)
K1 K 2 2 K1 K 2 K1  K 2 K1  K 2

31. The relation between U, P and V for an ideal gas is U=2+3PV. The atomicity of
the gas is.
3 4 3 2
1) 2) 3) 4)
4 3 2 3
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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
32. The plots of intensity versus wavelength for three black bodies at temperatures
T1 , T2 and T3 respectively are as shown. Their temperature are such that

1) T1  T2  T3 2) T1  T3  T2 3) T2  T3  T1 4) T3  T2  T1
33. Assertion : A body that is a good radiator is also a good absorber of radiation at a given
wavelength
Reason : According to Kirchoff’s law the absorptivity of a body is equal to its
emissivity at a given wavelength
1) If both assertion and reason are true and the reason is the correct explanation of the
assertion
2) If both assertion and reason are true and the reason is not the correct explanation of the
assertion
3) If assertion is true but reason is false
4) If assertion is false but reason is ture
34. One mole of a monatomic gas is take through a cycle ABCDA as shown in the P-V
diagram. Colum-II give the characteristics involved in the cycle. Match them with each
of the processes given in Column-I

Column-I Column-II
(A) Process A→B (p) Internal energy decrease
(B) Process B→C (q) Internal energy increase
(C) Process C→D (r) Heat is lost
(D) Process D→A (s) Heat is gained
(t) Work is done on the gas
1) A  p, r , t; B  p , r ; C  q, s; D  r , t 2) A  p, t ; B  p , r ; C  q, s; D  p, r , t
3) A  p, r , t ; B  p , t ; C  q, s; D  p , r , t 4) A  q, t ; B  p, r , t ; C  q, r ; D  r , t
Sec: Jr.Super60_STERLING BT Page 8
 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
35. A certain mass of gas is taken from an initial thermodynamics state A to another state B
by process I and II. In process I for the gas does 5J of work and absorbs 4J of heat
energy. In process II, the gas absorbs 5 joules of heat. The work done by the gas in
process II is

1) +5 J 2) +6 J 3) -6 J 4) +4 J
36. One mole of diatomic ideal gas undergoes a cyclic process ABC as shown in figure. The
process BC is adiabatic. The temperatures at A, B and C are 400K, 800K and 600K
respectively. Choose the correct statement

1) The change in internal energy in whole cyclic process is 250 R

2) The change in internal energy in the process CA is 700 R
3) The change in internal energy in the process AB is – 350 R
4) The change in internal energy in the process BC is – 500 R
37. Which of the following graphs correctly represents the variation of     dV / dP  / V

with P for an ideal gas at constant temperature

1) 2) 3) 4)
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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
38. Tow rods A and B of identical dimensions are at temperature 300C. If A heated upto 1800
C and B upto T0C, then the new lengths are the same. if the ratio of the coefficients of
linear expansion of A and B is 4:3, then the value of T is
1) 2300C 2) 2700C 3) 2000C 4) 2500C
39. A 100g of iron nail is hit by a 1.5kg hammer striking at a velocity of 60ms-1. What will
be the rise in the temperature of the nail if one fourth of energy of the hammer goes into
heating the nail? [ Specific heat capacity of iron =0.42Jg-1-C-1]
1) 6750C 2) 16000C 3) 16.070C 4) 6.750C
40. The specific heat at constant pressure of a real gas obeying PV2=RT equation is:
R R
1) Cv  R 2)  C v 3) R 4) Cv 
3 2V
41. A cylinder of radius R made of a material of thermal conductivity K1 is surrounded by
cylindrical shell of inner radius R and outer radius 3R made of a material of thermal
conductivity K2 . The two ends of the combined system are maintained at two different
temperatures There is no loss of heat across the cylindrical surface and system is in
steady state. The effective thermal conductivity of the system is

3 K1  K 2 K1  K 2 K1  8 K 2 K1  3 K 2
1) 2) 3) 4)
4 2 9 4
42. The PV diagram shows four different possible paths of a reversible processes performed
on a monoatomic ideal gas. Path A is isobaric, path B is isothermal, path C is adiabatic
and path D is isochoric. For which process does the temperature of the gas decrease?
P
A

P0 B
D
1 C
P0
2
V
V0 2V0

1) process A only 2) Process C only 3) Processes C & D 4) Processes B, C & D

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
43. The thickness of ice in a lake is 5cm and the atmospheric temperature is -100 C .
The time (in hours) required for the thickness of ice to grow to 7cm is (Thermal
conductivity of ice  4 103 cal cm1 s 1 C 1 ; density of ice =0.92 g/cm3 and latent heat of
fusion of ice=-80 cal/g) (The rounded value of time is to be given)
1) 3 2) 4 3) 6 4) 5
44. A spherical shell of radius R is at a temperature T. Consider the black body radiations
inside the shell to be an ideal gas of photons with internal energy per unit volume (U/V)

proportional to T4 and pressure P    . The shell now undergoes an adiabatic

2 U
3 V  

compression. Find a relation between T and R.

1 3 1
1) T  2) T  R 2
3) T  R 2 4) T 
R R2
45. A cylinder consists of a movable piston and 2 moles of helium at STP is enclosed in it.
The walls of the cylinder are made of a heat insulator and piston is insulated by using a
pile of sand on it. If the gas is compressed to half its original volume, what will be its
5
final pressure in terms of initial pressure P? (Value of 2 3  3 )
1) 3 2) 4 3) 6 4) 5

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
46. Two rods of different materials having coefficients of thermal expansion 1 ,  2 and
Young’s moduli Y1 , Y2 respectively are fixed between two rigid walls. The rods are heated
such that they undergo the same increase in temperature. There is no bending of rods.
If 1 :  2  2 : 3 , thermal stress developed in the rods are equal provided Y1 : Y2 is equal to
X : Y then find X  Y

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
47. The two opposite faces of a cubical piece of iron (thermal conductivity=0.2 CGS units)
are at 1000C and 00C. If the area of a surface is 4 cm2, then the mass of ice melted in 10
minutes will be (in grams)
48. One gram molecules of a gas contained in a cylinder compressed adiabatically in such a
way that its temperature rises from 50 0C to 150 0C . What will be the heat produced in
the gas? (in Joule)    1.5 (R=8.3 S.I units)
49. One mole of an ideal diatomic gas is taken through a cyclic process ABCA, shown in the
P-T graph. During A→B, PT 2  constant. If T0  300 K , work done on the gas during
process AB is x  100 R . Find ' x '

50. n moles of an ideal gas undergoes a process A  B as shown in the adjoining PV

diagram. If the maximum temperature of the gas during the process is T, then find the
9PV
0 0
value of
nRT
P
A
2P0

P0 B

V0 2V0 V

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-20_Q.P
CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Which among the following is least basic :
NO2
O Cl

N N N

Me C H NMe Cl Cl
1) 2) 5 5 3) 4)
52. Which of the following indicated H-atom is most acidic in nature.
O O
Hb
Hc

Hd
Ha
1) Ha 2) Hb 3) Hc 4) Hd
53. Correct Acidic strength among the following compounds
OH OH OH
OH
I) II) III) IV)

NO2
NO2
1) I > II > III > IV 2) II > III > IV > I 3) II > III > I > IV 4) III > II > IV > I
54. Assertion : para chloro phenol is more acidic than para-fluoro phenol
Reason : (-I) effect of F is greater than Cl.
1) Assertion is True, Reason is true; Reason is a correct explanation for assertion
2) Assertion is True, Reason is true; Reason is not a correct explanation for assertion
3) Assertion is True, Reason is False
4) Assertion is False, Reason is true
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55. Which among the following is least basic:
CH 3  C  NH 2

1) CH 3 CH 2  NH 2 2) O 3) CH 3  NH 2 4) CH 3  NH  CH 3
56. Among the following ainons, the order of basic strength is
(-)
A) C 2 H 5 B) NH 2 C) OH  D) Cl(-)
1) A>B>C>D 2) B>A>C>D 3) C>B>A>D 4) C<A<B<D
NH 2
NH 2 NH 2

NH 2

NH 2 NH 2
57. Give the decreasing order of , and basic character with
NH 2

reference to
NH 2
NH 2 NH 2 NH 2
NH 2
  

NH 2 NH 2
1)
NH 2 NH 2 NH 2 NH 2
NH 2
  

NH 2
NH 2
2)
NH 2 NH 2 NH 2 NH 2
NH 2
  
NH 2
NH 2
3)
NH 2 NH 2 NH 2 NH 2
NH 2
  
NH 2
NH 2
4)
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58. Correct order of acidic strength of given compounds will be

1) IV > II >I >III 2) IV > III>I>II 3) IV>I>II>III 4) IV>I>III>II

59. Arrange in the order of increasing acidic strength
COOH
(Z)
HOOC
(X)

N H3
(Y)

1) Z>Y>X 2) Y>Z>X 3) X>Z>Y 4) X>Y>Z

60. Consider the following reactions
RONa  H 2O  ROH  NaOH
RONa  NaNH 2  RONa  NH 3
Predict, which of the following order regarding base strength is correct
1) (-) (-) (-)
OH < NH 2 < RO 2) (-) (-) (-)
NH 2 < OH < RO 3) (-) (-) (-)
OH < RO < NH 2 4) (-) (-) (-)
OH = RO < NH 2

61. Which statement is not correct?

1) Phenols are acidic than alchols
2) Formic acid is stronger acid than acetic acid
3) Fumaric acid is stronger acid than maleic acid
4) Picric acid is more acidic than phenol
62. Identify the correct statement?
1) p-nitro phenol is more acidic than ortho nitro phenol
2) Picric acid is less acidic than formic acid
3) Pka of maleic and fumaric acid is same
4) Dichloro acetic acid is stronger acid than tricholoro acidic acid
63. The correct order of basicity (in gas phase) of the following compound is

3) 4)
1) 2)
N N N N

H H CH 3
1) 1>2>3>4 2) 4>1>3>2 3) 1>3>4>2 4) 2>4>3>1
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64. Choose the strongest base among the following
NH 2

1) 2) 3) 4)
NH
N N
H
65. Amongst the following , the most basic compound is
1) Benzylamine 2) Aniline 3) Acetanilide 4) p-nitroaniline
66. Which statement is not correct?
1) Formic acid is stronger acid than benzoic acid
2) Formic acid is stronger acid than acetic acid
3) CH  CH  CH 2  CH 2  CH 3  CH 3 acidic character
4) Phenol is stronger acid than asprin
67. Assertion(A): Enol form of cyclohexane -1,3,5-trione is more stable-than its ketoform.
Reason (R) : Cyclohexane -1,3,5-trione contains  -hydrogen atoms
1) Both (A) and ( R ) are false
2) Both (A) and ( R ) are true
3) (A) is true but ( R ) is false
4) (A) is false but ( R ) is true
68. Assertion : Salicylic acid is stronger acid than p-hydroxy benzoic acid
Reason : Salicylate ion is stabilized by H-bonding (Intra molecular)
1) Assertion is True, Reason is true; Reason is a correct explanation for assertion
2) Assertion is True, Reason is true; Reason is not a correct explanation for assertion
3) Assertion is True, Reason is False
4) Assertion is False, Reason is true
69. Which carbon more acidic hydrogens
O O
CH 3  C  CH 2  C  CH 2  CH 3
a b c d e f
1) a 2) b 3) c 4) d
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70. The correct decreasing order of basic strength of the following species is _______
H 2O, NH 3 , OH  , NH 2
1) NH 2  OH   NH 3  H 2O 2) OH   NH 2  H 2O  NH 3
3) NH 3  H 2O  NH 2  OH  4) H 2O  NH 3  OH   NH 2
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. How many of the following compounds are capable to undergo tautomerism in base
catalysed medium
O O O

CH 3  C  CH 3
N  OH O
1  2  3  4
72. How many of the following will give aromatic products in Tautomerism

O O O
O

N
a c O d
H
b

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73. How many of the following are less stable than Allyl free radical.

74. In which case 1st compound is more acidic than 2nd compound
a) CF3COOH, HCOOH b) PhOH, CH  CH

F COOH , Cl OH

c) Me3CCOOH, CCl3COOH d)

NO2 OH , F OH

e)
COOH COOH

NH 2 ,
NH 3

f)

OH COOH H 3C COOH
O2 N OH
,
NO2 , CH 3
g) h)
75. How many of the following are correct?
1) :CH2 Triplet carbene is more stable than :CH2 Singlet carbene
2) :CF2 Singlet carbene > :CCl2 singlet carbene > :C Br2 singlet carbene
3) :CF2 singlet carbene more stable than :CF2 Triplet carbene
4) In acidic character Cl - CH2 – COOH > Cl2CH - COOH
5) In acidic character R-COOH>>RCONH2>>R-CO-CH3

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING& BT_Jee-Main_WTM-20_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 30-11-2024
Time: 09:00AM to 12:00PM WTM-20 Max. Marks: 300

KEY SHEET
MATHEMATICS

1) 2 2) 3 3) 2 4) 2 5) 1
6) 4 7) 3 8) 1 9) 1 10) 3
11) 2 12) 1 13) 4 14) 3 15) 2
16) 3 17) 1 18) 3 19) 4 20) 3
21) 46 22) 1 23) 8 24) 4 25) 2

PHYSICS

26) 2 27) 4 28) 1 29) 4 30) 3

31) 2 32) 2 33) 1 34) 1 35) 2
36) 4 37) 1 38) 1 39) 3 40) 4
41) 3 42) 3 43) 3 44) 1 45) 1
46) 5 47) 300 48) 1660 49) 9 50) 4

CHEMISTRY

51) 2 52) 1 53) 2 54) 2 55) 2

56) 1 57) 4 58) 4 59) 3 60) 3
61) 3 62) 1 63) 2 64) 4 65) 1
66) 4 67) 2 68) 1 69) 3 70) 1
71) 3 72) 4 73) 3 74) 5 75) 4

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING& BT_Jee-Main_WTM-20_Key & Sol’s

SOLUTIONS
MATHEMATICS
1. f 1  x   3x 2  2 xf 1 1  f 11  2 
f 1 1  3  2 f 1 1  f 11  2 
f 11  x   6 x  2 f 1 1
f 11  2   12  2 f 1 1
f 11  x   6  f 111  3  6

Given eq is f  x  y
x 2
 y2  dy dy  x
2. 2 2
0 d
dx
 0  2x  2 y
dx
0 
dx y
sin 32 x  dy 
3. y    0
32.sin x  dx  x 
4

4. g  f  x  x
g1  f  x   . f 1  x   1
x 1
 4.2sinx.cosx  1  8tan x  1  7 tan x  tan x 
5. y =Tan -1   =Tan    Tan  
 1  7 tan x   1  7.tan x.tan x 
2 2
 1-8sin x 
dy   2 x  y  d2y 22
6.  = 
dx x  6y dx 2
 x  6 y 3
dx 5cos5 5 1  y 2
7.  
dy  sin  1  x2
1  x  y
2 2
1  25 1  y 2   1  x 2  y2  xy1  25 y
dy dy / dt d 2 y dz dz / dt
8. z  ,  
dx dx / dt dx 2 dx dx / dt
9. Conceptual
10. Clearly f(x) is constant function
1 y1 5
11.   25 4  y 2  xy1  0
2 2 x
y
1
4
Differentiate on both sides
x 2 y11  xy1  25 y  0

 
4
12. y  x  x 2  1  x 2  1y1  4 y   x 2  1 y2  xy1  16 y  0

13. y  x 2  3x  1
dy
 2x  3
dx

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14. g  f  x  x
g1  f  x   . f 1  x   1
g 1  f  x   . f 11  x    f 1  x   g 11  f  x    0
2

3
x
2
15. x  tan 
16. f  x  is even function
17. f  x  x  2  2  x2  2
18. y  2 cos x
dy
 2sin x
dx
19. 2 yy1  p1  x 
p1  x 
y1 
2y
 11 p1  x  
 y. p  x   p 1
 x  
2y 
y11  2 
 y2 
 
 
Again Differentiate
dy dy / d  10sec10 tan   10cos9  sin  10  sec   cos  
10 10

20.   
dx dx / d  sec  tan   sin  sec   cos 
21. Let f  x   ax  bx  cx  d
3 2

f 1  x , x  3
f 11  x  , x  3
f 111  x  , x  3
By solving
22. y  x2  x  1
23. f 1  x    x  2  x  3 .. x  n    x  1 x  3 ..... x  n    x  1 x  2 ..... x   n  1 
dy df / dx
24. 
dx df / dy
f  x  h  f  x
25. f 1  x  lth0
h
lt f  h   xh  x h
2 2

h0  1  x2
h
x3
f  x  x 
3

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PHYSICS
Ka 1   2  K t 35 7
26. Q t  K1t1  K 2t2  1  2  
l K 2 t1 20 4
[As Q, I , A and 1   2  are same]
27. convection currents are produced because, heated fluid becomes less dense than the
cold fluid above it
28. (a) work done in the isobaric process,
w  Pv  nRT  100 J
Q  u  w
Q  nCv T  nRT

5   5 
  1100  350 J  As Cv  2 R 
2 
29. d) dQ=dU+dW  dU=nCvdT
dU=0( for isothermal)
U=constant
Also dQ>0(supplied)
Heance dW>0

30. Formula of thermal resistance,

1
R
KA

   1 1  2 2K1K 2
Req  R1  R2       K
K1 A K 2 A A  K1 K 2  KA K1  K 2

31. For an adiabatic process dQ=0=dU+dW or 0=dU+PdV ……..(1)

From the given equation dU=3(PdV+VdP)
Substituting dU from (1), -PdV=3(PdV+VdP) or 4P (dV)+3V (dP)=0

Or 4    3  
dV dP
 V   P 

On integrating, we get ln V 4   ln  P3   constant , ln V 4 P3  = constant  V 4 P3 =constant

or PV 4/3 =constant
4 1
i.e,   i.e., gas is polyatomic.32. According to Wien’s law m  and from the
3 T
figure  m 1   m 3   m 2 therefore T1  T3  T2

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 Sri Chaitanya IIT Academy, India 30-11-2024_Jr.Super60_STERLING& BT_Jee-Main_WTM-20_Key & Sol’s
e
33. According to Kirchhoff’s law  E4
a
If for a particular wave length E  1  e  a i.e., absorptivity of a body is equal to it’s
emissivity. This statement also reveals that a good radiator is also is good absorber and
vice versa.
34. A  B  V  P const  T  U   p  ,  r  ,  t 
B  C  d  0
PT 
d  du  d  p ,r 
C  D  V  T 
du   ve
d   ve q , s
D  A  d   ve
dq  ve
du  0  r  , t 
35. For process I : dQ  dU  dW  4  dU  5  dU  1
For process II : 5  dU  dW  5  1  dW  dW  6 J
f
36. U  nRT
2
For cyclic process U  0
For process CA
5
U  1 R  200   500 R
2
For process AB :
5
U  1 R   400   1000 R
2
For process BC :
5
U  1 R   200   500 R
2
37. For an isothermal process PV=constant
1  dV  1
 PdV  VdP  0   
V  dP  P
1
So,    graph will be rectangular hyperbola
p
38. (a) Change in length due to rise in temperature l  l T
l1  l2
l1T1  l 2 T2
1 T1

 2 T2
4 T  30

3 180  30
T  2300 C

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1
39. c) According to the equestion , Heating energy = th energy of the hammer
4
1 1 2 1 1
( mv )    1.5  60  60  675 J
4 2 4 2
 675  Heating energy =mcΔT
675  100  0.42T
675
T   16.070 C
42
40. b) Given PV2=RT
P(2VdV)=RdT  P  constant 

RdT
PdV 
2V
From first law of thermodynamic
dQ=dU+dW
CdT=CvdT+pdV
From equation (i) & (ii)
R
C  Cv 
2V
41. A1   R 2 , A2    4 R 2  R 2 
Two cylinders are in parallel,
 K eff  A1  A2   K1 A1  K 2 A2

K eff 
K1 R 2  K 2 8 R 2  K  8K 2 
; K eff  1
 R  8 R
2 2
9
42. In adiabatic and isochoric processes temperature decreases as P decreases.
L 92  102 80
43. t 
2 KT
 x22  x12   2  4  10 3
 0  7 2  52   22080 s  6.13hrs
10
U
44. Given, T4
V
and P     T 4
2 U
……(i)
3V 
Ideal gas equation is PV  nR0T
nR0T
……(ii)
P
V
nR T
Comparing (i) and (ii), we get 0  T 4
V
nR0 1
T3   T3
V V

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4 3
Or V  T 3   R  T 3
3
1 1
Or R 3  T 3  T 2  2  T 
R R
r
V 
45. P V  PV
2 2
r
1 1
r
= P2  P1  1 
 V2 
46. Thermal stress Y11t  Y2 2 t

47. Q  mL  KA
1   2  t
l
48. T1  50  273  323 K
T2  150  273  423K
R 8.3
As W T2  T1    423  323 =1660 J
1  1  1.5
49. The ideal gas equation is, PV=nRT
Differentiating, partially we get
PdV+VdP=nRdT …..(i)
2
In process AB, PT =constant
Differentiating this
2PTdT+TdP=0 … (ii)
2 PTdT 2 PdT
dP  
T2 T
2PVdT
Substituting this in (i), we get PdV   nRdT
T
2PVdT 2  nRT  dT
PdV  nRdT   nRdT   nRdT  2nRdT  PdV  3nRdT
T T
Work done by the gas in process A  B is
TB

WAB   PdV   3nRdT  3nR TB  TA   3  1 R  300  600   900 R

TA

Work done on the gas is 900 R. …..(iii)

P
50. P  2 P0  0 V  V0 
V0
 PV
P  0  3P0  1
V0
But PV  nRT
nRT
P   2
V
dT
Sub (2) in (1) do differentiation 0
dV
dT
 3PV
0 0  2 PV
0 0
dV
3V
V 0   3
2
9 PV 9 PV
Sub (3) and (2) in (1) find (T) T 0 0
; n  9; 0 0  4
4nR nRT

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CHEMISTRY
51. Nitrogen does not contain lone pair of electrons
52. Acid base theory concept of Bronsted theory
53. Resonance, steric effect
54. - para chloro phenol is more acidic than para-fluoro phenol
55. Amides are neutral
56. On the basis of experimental values
57. On the basis of Pka values
58. On the basis of experimental values
59. Acid base theory concept of Bronsted theory
60. On the basis of En concept
61. On the basis of Pka values
62. On the basis of En concept and resonance
63. On the basis of En concept and resonance
64. On the basis of En concept and resonance
65. Acids are more acidic than alcohols

 
CH 2Cl CH 2 F
66. is stabilized by resonance while is not because Cl can receive electrons
of -ve charge in its empty d orbital.
67. Carboxylic acid is more acidic than alkane, alkene and aromatic anions
68. Salicylate ion is stabilized by H-bonding (intra molecular)
O O
CH 3  C  CH 2  C  CH 2  CH 3
a b c d e
69. c is more acidic
70. Acid base theory concept of Bronsted theory
71. Alpha hydrogen concepts and resonance
72. Alpha hydrogen concepts and resonance
73. Stability of carbon free radicals
74. a, b, d, e, h are correct
75. Stability of carbeens

SEC: Jr.Super60_STERLING BT Page 8