GB/T 6892-2006 (English Version) Wrought aluminium and aluminium alloys extruded profiles for general engineering
GB/T 6892-2006 (English Version) Wrought aluminium and aluminium alloys extruded profiles for general engineering
net
ICS 77.150.10
H 61 GB
NATIONAL STANDARD OF
THE PEOPLE'S REPUBLIC OF CHINA
中华人民共和国国家标准
GB/T 6892-2006
Replace GB/T 6892-2000, GB/T 19347-2003, GB/T 19347.2-2005
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Contents
Foreword .................................................................................................................................... I
1 Scope ...................................................................................................................................... 1
2 Normative References ............................................................................................................ 1
3 Requirements.......................................................................................................................... 2
3.1 Product Classification .................................................................................................. 2
3.2 Chemical Compositions............................................................................................... 2
3.3 Permissible Dimension Variation................................................................................. 3
3.4 Mechanical Property .................................................................................................... 4
3.5 Conductivity................................................................................................................. 7
3.6 Ultrasonic Test Result .................................................................................................. 8
3.7 Stress Corrosion Resistance ......................................................................................... 8
3.8 Exfoliation Corrosion Property.................................................................................... 8
3.9 Anti-fatigue Corrosion Property .................................................................................. 9
3.10 Macrostructure ........................................................................................................... 9
3.11 Microstructure............................................................................................................ 9
3.12 Appearance quality .................................................................................................... 9
4 Test Methods ........................................................................................................................ 10
4.1 Chemical Composition Analysis Method .................................................................. 10
4.2 Dimension Test Method ............................................................................................. 10
4.3 Mechanical Property Test Method ............................................................................. 10
4.4 Conductivity Testing.................................................................................................. 10
4.5 Ultrasonic Test Method.............................................................................................. 10
4.6 Stress Corrosion Test Method .................................................................................... 10
4.7 Exfoliation Corrosion Test Method............................................................................ 10
4.8 Anti-fatigue Corrosion Test Method .......................................................................... 10
4.9 Inspection Method of Macrostructure........................................................................ 10
4.10 Inspection Method of Microstructure .......................................................................11
4.11 Inspection of Appearance Quality.............................................................................11
5 Heat Treatment System..........................................................................................................11
6 Test Rules ..............................................................................................................................11
6.1 Test and Acceptance....................................................................................................11
6.2 Group ..........................................................................................................................11
6.3 Test Item......................................................................................................................11
6.4 Sampling .................................................................................................................... 12
6.5 Judgment of Test Result............................................................................................. 13
7 Marking, Packing, Transportation and Storage .................................................................... 14
7.1 Marking...................................................................................................................... 14
7.2 Packing, Transportation and Storage ......................................................................... 14
7.3 Quality Certificate...................................................................................................... 15
8 Contract Contents ................................................................................................................. 15
Annex A (Normative) Test Method for Stress Corrosion of the Ring Samples of Wrought
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Foreword
This standard is the combined revision of GB/T 6892-2000 "Wrought Aluminium and
Aluminium Alloys--Extruded profiles for Commercial Usage", GB/T 19347-2003 "Wrought
Aluminum Alloy Extruded Profiles for Railroad Vehicle Structures" and GB/T 19347.2-2005
"Wrought Aluminium Alloy Extruded Profiles for Railroad Vehicle Structures for Special
Environment", and the major amendments are as follows:This standard shall replace GB/T
6892-2000, GB/T 19347-2003 and GB/T 19347.2-2005.
- 1050A, 1200, 1350, 3103, 2014, 2014A, 2017A, 5005, 5005A, 5051A, 5251, 5019 (original
5056A), 5154A, 5454, 5754, 5083, 5086, 6101A, 6101B, 6005A, 6106, 6351, 6261, 6463,
6081, 7003, 7005, 7020, 7022 and 7049A alloys specified in EN 775.2-1997 "Aluminium
and Aluminium Alloy Bars, Pipes and Profiles--Mechanical Properties", 7178 alloy specified
in ASTMB221M-2005 "Wrought Aluminium and Aluminium Alloy Extruded Pipes, Bars
and Profiles" and 6463A alloy with mature domestic process also were all included.
- Annex A "Test Method for Stress Corrosion of the Ring Samples of Wrought Aluminium
Alloy Products" was formulated by making reference to ASTMG 47-1990 "Stress
Corrosion Test Method for High-strength Wrought Aluminum Alloy Products" and
ASTMG 64-1985 "Stress Corrosion Test Method for High-strength Aluminum Alloys".
Annexes A, B and C of this standard are normative.
This standard was proposed by the China Nonferrous Metals Industry Association.
This standard is under the jurisdiction of and is explained by Standardization
Administration of Nonferrous Metals the Peoples Republic of China.
Chief Drafting Organizations of this standard: Southwest Aluminum (Group) Co., Ltd.,
Guangdong Xingfa Aluminium Co., Ltd., Fujian Minfa Aluminum Co., Ltd., Guangdong JMA
Aluminium Profile Factory Co Ltd., and China National Non-ferrous Metals-Industrial
Standard Metrological Quality Research Institute.
Participating Drafting Organizations of this standard: Lanzhou Aluminum Co., Ltd.
Northwest Aluminum Processing Branch, Northeast Light Alloy Co., Ltd., Hunan Jingge
Holding Group Co., Ltd., General Research Institute for Nonferrous Metals, and Huanan
Product Quality Supervision and Inspection Center of China Nonferrous Metal Industry
Chief Drafting Staffs: Li Ruishan, Wu Xikun, Chen Min, Lu Jiyan, Li Xiaofeng, Ge
Lixin, Yang Yaping, Jin Longbing, Chen Tieping, He Yaozu, and Zhou Renliang.
This standard replaces the following editions in turn:
——GB/T 6892-1986, GB/T 6892-2000;
——GB/T 19347-2003;
——GB/T 19347.2-2005.
NOTE: The English version hereof has been translated directly from the openly-published Chinese
standard GB/T 6892-2006. In the event of any discrepancy in the process of implementation, the
Chinese version shall prevail.
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1 Scope
This standard specifies the requirements, test methods, test rules and marking, packing,
transportation and storage as well as contract contents of the wrought aluminium and
aluminium alloy extruded profiles for general engineering.
This standard is applicable to the wrought aluminium and aluminium alloy extruded
profiles for general engineering.
2 Normative References
The following normative documents contain provisions which, through reference in this
standard, constitute provisions of this standard. For dated reference, subsequent amendments
to, or revisions of, any of these publications do not apply. However, all parties coming to an
agreement according to this code are encouraged to study whether the latest editions of these
documents are applicable. For undated references, the latest edition of the normative
document referred to applies.
GB/T 228 "Metallic Materials--Tensile Testing at Ambient Temperature"
GB/T 3190 "Wrought Aluminium and Aluminium Alloy-Chemical Composition"
GB/T 3199 "Wrought Aluminium and Aluminium Alloy Products-Packing, Marking,
Transporting and Storing"
GB/T 3246.1 "Wrought Aluminium and Aluminum Alloys Products Inspection Method
for Microstructure"
GB/T 3246.2 "Aluminum and Aluminum Alloys--Inspection Method of Microstructure
for Wrought Products"
GB/T 6519 "Process for Ultrasonic Inspection of Wrought Aluminum Alloy Products"
GB/T 6987 "Chemical Analysis Methods of Aluminium and Aluminium Alloys" (All the
Parts)
GB/T 7999 "Optical Emission Spectrometric Analysis Method of Aluminum and
Aluminum Alloys"
GB/T 12966 "The Method for Determining Aluminium Alloys Conductivity Using Eddy
Current"
GB/T 14846 "Aluminium and Aluminium Alloy Extruded Profiles-Tolerances on
Dimensions and Form"
GB/T 16865 "Test Pieces for Tensile Test for Wrought Aluminum and Magnesium Alloy
Products"
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3 Requirements
Profile for
5052, 5083, 6061, 6063, 6005A, 6082, 6106, 7003, 7005
vehicle a
1050A, 1060, 1100, 1200, 1350, 2A11, 2A12, 2017, 2017A, 2014, 2014A, 2024, 3A21, 3003, 3103, 5A02, 5A03,
Other 5A05, 5A06, 5005, 5005A, 5051A, 5251, 5052, 5154A, 5454, 5754, 5019, 5083, 5086, 6A02, 6101A, 6101B,
profiles 6005, 6005A, 6106, 6351, 6060, 6061, 6261, 6063, 6063A, 6463, 6463A, 6081, 6082, 7A04, 7003, 7005, 7020,
7022, 7049A, 7075, 7178
a
Profiles for vehicle refer to the profiles that are applicable to the railroad, subway and light rail vehicle structures as well as
other vehicle structures.
Other
Designation impurities a
Si Fe Cu Mn Mg Cr Zn Ti Alb
In
Single
total
5005A 0.30 0.45 0.05 0.45 0.7~1.1 0.10 0.20 0.05 0.15 Surplus
5051A 0.30 0.45 0.05 0.25 1.4~2.1 0.30 0.20 0.10 0.05 0.15 Surplus
6101B 0.30~0.6 0.10~0.30 0.05 0.05 0.35~0.6 0.10 0.03 0.10 Surplus
6106 0.30~0.6 0.35 0.25 0.05~0.20 0.40~0.8 0.20 0.10 0.05 0.10 Surplus
6261 0.40~0.7 0.40 0.15~0.40 0.20~0.35 0.7~1.0 0.10 0.20 0.10 0.05 0.15 Surplus
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6463 0.20~0.6 0.15 0.20 0.05 0.45~0.9 0.05 0.05 0.15 Surplus
6463A 0.20~0.6 0.15 0.25 0.05 0.30~0.9 0.05 0.05 0.15 Surplus
6081 0.7~1.1 0.50 0.10 0.10~0.45 0.6~1.0 0.10 0.20 0.15 0.05 0.15 Surplus
7049A 0.40 0.50 1.2~1.9 0.50 2.1~3.1 0.05~0.25 7.2~8.4 Ti+Zr:0.25 0.05 0.15 Surplus
7178 0.40 0.50 1.6~2.4 0.03 2.4~3.1 0.18~0.28 6.3~7.3 0.26 0.05 0.15 Surplus
Note: In this table, the single figures represent the maximum value of the percent content of element in mass.
a Other impurities refer to the metallic elements not included or not provided with amount in this table.
b The mass fraction of aluminium is the difference between 100% and the sum of all the metallic elements that are equal to or larger than
0.010%, and the values of every element shall be represented in 0.0X% before calculating the sum.
Tortuosity of such profile with length less than 4.5m is no larger than 1mm per meter per meter and no
Tortuosity of larger than 1×Lmm in the total length (L meters)
broadside Tortuosity of such profile with length no less than 4.5m is no larger than 1mm per meter per meter and
no larger than 10mm in the total length
Tortuosity of
No larger than 1 mm per 2m and no larger than 6 mm in total length
narrowside
3.3.3 Waviness
The waviness of profile shall be in accordance with the provisions on ordinary grade as
specified in GB/T 14846.
3.3.4 Twist
The twist of profiles for vehicle shall not be larger than 1mm per meter and shall not be
larger than 6mm in the total length. The twist of other profiles shall be in accordance with the
provisions on the ordinary grade as specified in GB/T 14846, and it shall be indicated in the
drawing or contract when the twist of high precision grade or super-high precision grade is
required.
3.3.5 Interplanar spacing
The interplanar spacing on the decorative surface of profile for vehicles shall not be
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larger than 1.8mm and that on the non-decorative surface shall not be larger than 2.4mm. The
interplanar spacing of other profiles shall be in accordance with the provisions on the ordinary
grade as specified in GB/T 14846, and it shall be indicated in the drawing or contract when
the interplanar spacing of high precision grade or super-high precisions grade is required.
3.3.6 Degree of cutting inclination
The degree of cutting inclination of vehicle profiles shall be in accordance with the
provisions on the high precision grade as specified in GB/T 14846, and the degree of cutting
inclination of other profiles shall be in accordance with the provisions on the ordinary grade
as specified in GB/T 14846, and it shall be indicated in the drawing or contract when the
degree of cutting inclination of high precision grade or super-high precision grade is required.
3.3.7 Length variation
The length variation of profiles shall be in accordance with those specified in GB/T
14846.
3.4 Mechanical Property
3.4.1 The longitudinal stretching mechanical property of profiles at room temperature shall be
in accordance with those specified in Table 4. As for those profiles not included in Table 4,
their mechanical properties shall be determined by the supplier and buyer and shall be
indicated in the contract. When the mechanical properties are not indicated in the contract, the
actual measurement results shall be attached.
Table 4
Percentage
Tensile strength Proof strength of non-proportional
Wall elongation/ %
Designation Condition Rm/Mpa extensionRp0.2/MPa
thickness/mm A5.05a A50mmb
No less than
1050A H112 — 60 20 25 23
0 — 60~95 15 22 20
1060
H112 — 60 15 22 20
0 — 75~105 20 22 20
1100
H112 — 75 20 22 20
1200 H112 — 75 25 20 18
1350 H112 — 60 — 25 23
0 — ≤245 — 12 10
0 — ≤245 — 12 10
≤5 390 295 — 8
2A12 >5~10 410 295 — 8
T4
>10~20 420 305 10 8
T4 — 390 245 15 13
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T4
2017A T4510 ≤30 380 250 10 8
T4511
0 — ≤250 ≤135 12 10
0 — ≤25 ≤150 12 10
T8
T8510 ≤50 455 38. 5 4
T8511
3003
H112 — 95 35 25 20
3103
5005
H112 — 100 40 18 16
5005A
5154A
H112 ≤25 200 85 16 14
5454
T4 — 180 — 12 10
6A02
T6 — 295 230 10 8
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0 — ≤160 ≤110 14 12
≤5 290 250 — 6
T6
>5~25 300 255 10 8
T4 ≤25 120 60 16 14
≤5 160 120 — 6
T5
606 >5~25 140 100 8 6
≤3 190 150 — 6
T6
>3~25 170 140 8 6
0 — ≤170 ≤120 14 12
≤5 270 230 — 7
T5 >5~25 260 220 9 8
6261 >25 250 210 9 —
T4 ≤25 130 65 14 12
≤3 175 130 — 6
T5
6063 >3~25 160 110 7 5
T4 ≤25 150 90 12 10
T4 ≤50 125 75 14 12
6463 T5 ≤50 150 110 8 6
T6 ≤3 205 170 — 6
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0 — ≤160 ≤110 14 12
≤5 290 250 — 6
T6
>5~25 310 260 10 8
0 — ≤245 — 10 8
T5 — 310 260 10 8
7003 ≤10 350 290 — 8
T6
>10~25 340 280 10 8
T6
7022 T6510 ≤30 490 420 7 5
T6511
T73
7075 T73510 ≤25 485 420 7 5
T73511
a A5.65 represents the percentage elongation of the profile with its original scale distance (L0) of 5.65 S0 .
b The elongation of profile with wall thickness no larger than 1.6mm will not be required, and when it is required by the buyers,
it will be determined by both the supplier and the buyer and shall be indicated in the contract.
3.5 Conductivity
The conductivity of such profiles with 7075 alloy supplied at condition of T73, T73510,
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T73511, T76, T76510 and T76511 as well as 7178 alloy supplied at condition of T76, T76510
and T76511 shall be in accordance with those specified in Table 5.
Table 5
Conductivity
Supply Acceptance
Designation index Mechanical property
condition judgment
MS/m(%IACS)
Height direction
75% of the
T73, T73510, T73511 (short transverse ≥20
longitudinal Rp0.2
direction)
7075
Height direction
T76, T76510, T76511 (short transverse 170 ≥20
direction) No crack
Height direction
7178 T76, T76510, T76511 (short transverse 170 ≥20
direction)
75% of the
6005A T5, T6 Any one ≥20
longitudinal Rp0.2
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T73510, T73511, T76, T76510 and T76511 supply condition and 5083 alloy at H112 supply
condition, when significant changes exist in the first batch of supplying or process or the
requirement on testing the exfoliation corrosion property is indicated in the contract, the
product shall not appear with the exfoliation corrosion of level EB~ED.
3.9 Anti-fatigue Corrosion Property
As for the 6005A alloy profile for vehicles at T5 and T6 conditions, when significant
changes exist in the first batch of supply or process or the requirement on testing the fatigue
resistance is indicated in the contract, the result of the fatigue corrosion test of Level B stress
level shall be carried out according to those specified in Annex C. In addition, the result shall
meet the acceptance requirements.
3.10 Macrostructure
3.10.1 The low power test piece of profile shall have no crack or shrinkage cavity in tail.
3.10.2 The spot defects such as bright grains, non-metallics, exterior metallics, white spots
and compounds on the low power test piece of profile shall not be more than 2, and the
diameter of every spot shall not be larger than 0.5 mm.
3.10.3 The oxidic coating over the low power test piece of profile shall be in accordance with
those specified in Table 7.
Table 7
When length of every defect is within the following scope
Defect name Inspected area
≤0.3 mm >0.3 mm~2.0 mm >2.0 mm
3.10.4 The depth of stratification around the low power test piece of vehicle profile shall not
exceed the negative deviation of profile, and that of the other profiles shall not exceed 0.5
mm.
3.10.5 The welds of hollow profile are allowed to have the welding marks.
3.11 Microstructure
The microstructure of profile is disallowed to have any overburning.
3.12 Appearance quality
3.12.1 The surface of profile shall be clean and free from cracks or corrosion spots.
3.12.2 The surface of the vehicle profile shall have no peeling or bubbling. It is allowed to
have such partial and slight defects as bruise, scuff, pit and scratch, however, the depth of
these defects in the decorative surface shall not be larger than 0.1 mm.
3.12.3 The surface of the profile not for vehicles is allowed to have peeling, bubble, surface
asperity and partial mechanical damages in depth not exceeding 8% of the nominal wall
thickness of the profile at where the defect exists. However, in the decorative surface, the
extreme depth of all the defects shall not exceed 0.2 mm, and the total area of defects shall
not exceed 2% of the surface area of profile. In the decorative surface, the extreme depth of
all the defects shall not exceed 0.5 mm, and the total area of defects shall not exceed 5% of
the surface area of profile.
3.12.4 At positions of profile under finishing, the depth of the surface defect shall not exceed
the finishing allowance (the difference between the measured thickness and allowable
minimum thickness of this point).
3.12.5 The surface of such profile not for vehicles is allowed to be glazed to smooth surface
along the longitudinal direction of profile by the supplier.
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4 Test Methods
>2.50~12.50 Measuring at the surface of profile after 10% of wall thickness is processed off
Measuring at the plane that is approximate to the center of the section thickness of profile and is parallel
>12.50~40.00
to the direction of extrusion
Measuring at the plane that is about 10mm away from the center of the section thickness of profile and is
>40.00
parallel to the direction of extrusion
10
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The method for the macrostructure inspection on profiles shall be in accordance with
those specified in GB/T 3246.2.
4.10 Inspection Method of Microstructure
The method for microstructural inspection of profiles shall be in accordance with those
specified in GB/T 3246.1.
4.11 Inspection of Appearance Quality
The surface quality of profiles shall be examined visually, when the defect depth is
difficult to be determined, the profile surface may be polished to determine the defect depth.
The heat treatment system may be carried out by making reference to YS/T 591.
6 Test Rules
11
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6.3.5 As for the profiles in thickness larger than or equal to 20mm and of 70% alloy at T73,
T73510, T73511, T76, T76510 and T76511 conditions and those of 7178 alloy at T76,
T76510 and T76511 conditions, as well as the profiles for vehicles of 6005A alloy at T5 and
T6 conditions, when significant changes exist in the first batch of supplying or in process or
requirement on inspecting the exfoliation corrosion property is indicated in the contract, the
exfoliation corrosion property of products shall be inspected.
6.3.6 As for the profiles of 7075 or 7178 alloy at T76, T76510 and T76511 conditions as well
as the profiles for vehicles of 7005 and 6005A alloys at T5 and T6 conditions and of 5083
alloy at H112 condition, when significant changes exist in the first batch of supplying or in
process or requirement on inspecting the exfoliation corrosion property is indicated in the
contract, the exfoliation corrosion property of products shall be inspected.
6.3.7 As for the profiles for vehicles of 6005A alloy at T5 or T6 condition, when significant
changes exist in the first batch of supplying or in process or requirement on inspecting the
antifatigue corrosion property is indicated in the contract, the products shall be inspected on
their antifatigue corrosion property.
6.4 Sampling
The product sampling shall be in accordance with those specified in Table 9.
Table 9
Serial number Serial number of
of required the chapter and
Test item Sampling specification
chapter an article on test
article methods
Chemical
Testing according to those specified in GB/T 17432 3.2 4.1
Compositions
Permissible
The sampling quantity shall not be less than those specified in
dimension 3.3 4.2
Table 10 and the product shall be inspected one by one
variation
Cutting off the test coupon from the front extruded end. The
Mechanical sample preparation shall meet those specified in GB/T 16865
3.4 4.3
property and the sampling quantity shall be in accordance with those
specified in Table 10
Cutting off the test coupon from the front extruded end. The
Conductivity sampling quantity shall be in accordance with those specified in 3.5 4.4
Table 10
Ultrasonic test
According to the agreement between the two parties 3.6 4.5
result
Stress corrosion Cutting off three test coupons and cutting off 3 adjacent same
3.7 4.6
property samples from every test coupon
Exfoliation Cutting off five test coupons and cutting off 1 sample from every
3.8 4.7
corrosion property test coupon
Antifatigue Cutting off three test coupons and cutting off 1 sample from
3.9 4.8
corrosion property every test coupon
Cutting off test coupon (as for the test weld of hollow profile,
Macrostructure 3.10 4.9
the macrostructure shall be cut from the front extruded end)
12
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Cutting off two test coupons and cutting off 1 sample from every
Microstructure 3.11 4.10
test coupon
Appearance
Inspecting one by one 3.12 4.11
quality
Note: To test the mechanical property, conductivity, stress corrosion property, exfoliation corrosion property, antifatigue corrosion
property and microstructure of the asquenched products, the manufacturing plant shall sample according to the number of heat
treating furnace and also shall sample in batches during the arbitration.
Table 10
Amount of every batch or every furnace /stick Sampling quantity /stick
≤50 2
>50~90 3
>90~150 5
>150~280 8
>280~500 13
>500~1200 20
13
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7.1 Marking
7.1.1 Those accepted products shall be printed with the following marks (or stuck with
labels):
a) Inspection stamp of the technical supervision department of supplier;
b) Designation;
c) Supply condition;
d) Lot identification mark.
7.1.2 The marks on the packing boxes of products shall be in accordance with those specified
in GB/T 3199.
7.2 Packing, Transportation and Storage
The profiles shall not be lubricated, and the packing manner and method shall be
14
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determined through negotiation between the two parties. Other requirements shall be in
accordance with those specified in GB/T 3199.
7.3 Quality Certificate
Each batch of profiles shall be accompanied by the product quality certificate, which
including:
a) Name, address, telephone and fax of suppliers;
b) Product name;
c) Designation, supply condition and configuration;
d) Batch number;
e) Net weight or number of packages;
f) Check result of every analytical items as well as the stamp of technical supervision
department;
g) Serial number of this standard;
h) Packing date (or release date).
8 Contract Contents
The procurement contracts (purchase order) of the products listed in this standard shall
include the following contents:
a) Product name;
b) Designation of alloy;
c) Supply condition;
d) Dimensions or type;
e) High precision grade or super-high precision grade of certain dimension indexes;
f) Requirements on ultrasonic wave;
g) Requirements on stress corrosion property;
h) Requirements on exfoliation corrosion property;
i) Requirements on antifatigue corrosion property;
j) Weight (or number of packages);
k) Serial number of this standard.
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A.1 Scope
This appendix specifies the stress corrosion test method for ring samples of wrought
aluminium alloy products of 2××× (copper content of 1.8%~7.0%) series, 7×××(copper
content 0.4%~2.8%) and 6×××.
This annex is applicable to the such wrought aluminium alloy products of 2×××(copper
content of 1.8%~7.0%) series, 7××× (copper content 0.4%~2.8%) and 6××× as aluminium
alloy panels, belts, pipes, bars, profiles and forgings.
A.2 Method Principle
This method is to apply constant varying stress on the C-type ring samples, periodically
dip the samples into the test solution and inspect whether the material is eroded and cracks
within the stipulated time so as to assess the stress corrosion sensibility and stress corrosion
ability of the material.
A.3 Reagents
A.3.1 Sodium chloride (Nacl, ρ=2.16 g/cm3).
A.3.2 Distilled water or deionized water.
A.3.3 Sodium hydroxide (NaOH, ρ=2.13 g/cm3).
A.3.4 Hydrochloric acid (HCl, ρ=1.10 g/mL).
A.4 Test Solution
Sodium chloride water solution (ρ=35 g/L, pH=6.4~7.2): This water solution shall be
prepared with sodium chloride (A.3.1) and distilled water or deionized water (A.3.2) and shall
be adjusted with sodium hydroxide (A.3.3) or hydrochloric acid (A.3.4).
A.5 Test Equipments
Various ring sample stress corrosion testers that meet those specified in the national or
professional standards shall be adopted.
A.6 Sample Preparation
A.6.1 Sampling
A.6.1.1 The sampling shall be in accordance with those specified in the product standard,
when it is not provided in the product standard, it shall be implemented according to this
method.
A.6.1.2 The C-ring samples of the extruded pipes, bars and profiles are shown as in Figure
A.1. The C-ring samples of rolled plates are shown as in Figure A.2. The C-ring samples of
forged products are shown as in Figure A.3.
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Height direction
Longitudinal elevation
(direction of extrusion)
Transverse direction
Figure A.1 C-ring Sampling Diagram of Extruded Products
Rolling direction
Thickness direction
Width direction
Transverse direction
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B minimum
1 from very
Rolled plates 3 blocks 3 9
block
2 from every
Forged products 1 piece 3 6
piece
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75% of longitudinal
6005A T5, T6 Any one ≥20
Rp0.2
A.7.4 The materials of the same series of the experimental alloy shall be adopted as bolts and
nuts. The stress bolt shall be screwed, which means the surface at C ring is under the action of
tension stress. The radial compression amount of the C ring shall be calculated according to
Formula (A.1). The outside diameter of C ring after being applied with stress shall be
calculated according to Formula (A.2).
fπD 2
Δ= (A.1)
4 EtZ
Where:
Δ——the radial compression amount of C ring in the unit of millimeter (mm);
f——the proof stress in unit of megapascal (MPa);
D——the pitch diameter of c ring (D=OD-t), the unit is millimeter (mm);
E——the elastic modulus of material in unit of megapascal (MPa);
t——the wall thickness of C ring, and the unit is millimeter (mm);
Z——the correction coefficient of bent beam (see Figure A.5).
ODf=OD-Δ (A.2)
Where:
ODf——the outside diameter of C ring after being applied with stress, the unit is
millimeter (mm);
OD——the outside diameter of C ring before applying stress (measured in the direction
of stressing bolt, the accuracy shall reach±0.01mm), and the unit is millimeter (mm);
Δ——the radial compression amount of C ring, the unit is millimeter (mm).
A.7.5 After applying stress onto the samples, the bolts, nuts and the small part of sample
surface adjacent to them shall be coated with water resistant paints.
A.7.6 The sample shall be fixed onto the test equipment with plastic wires so as to make the
sample be immersed in the test solution entirely or alternately.
A.7.7 The test shall be started as soon as possible after applying stress on samples, and the
maximum interval before starting the test after applying stress shall not exceed 4h generally.
A.7.8 The entire or alternate immersion test adopted in the test shall be in accordance with
those specified in the product standard. If not provided in the product standard, the alternate
immersion test shall be carried out according to the cycle period, the cycle period is to
immerge the sample in the test solution for 10min and then expose it in the air for 50 min per
hour.
A.7.9 Within the periodic immersion period, the samples shall not contact mutually or contact
with any other uncovered metal. The materials of the same chemical compositions may be
placed on one same tank.
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A.7.10 The moisture lost by evaporation must be supplemented every day in order to keep the
concentration of solution. And the test solution shall be replaced once every two weeks.
A.7.11 The test may be interrupted temporarily when replacing the solution or inspecting the
samples.
A.7.12 The samples shall be observed with naked eyes or with magnifier, and the corrosion
cracking time of the samples shall be recorded.
A.7.13 At the end of the test, the samples may be cleaned with any one kind of the detergents
as listed in Table A.3 for the convenience of observing.
Table A.3
Detergent composition
Type Temperature Time
CrO3 H3PO4(ρ=1.69g/mL) H2O HPNO3(ρ=1.42g/mL)
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B.1 Scope
This appendix specifies the test method for the constant immersion type exfoliation
corrosion of the wrought aluminium alloy products of 2×××, 5×××, 6××× and 7×××series.
This annex is applicable to the such wrought aluminium alloy products of 2×××, 5×××,
6××× and 7××× series as aluminium alloy panels, belts, pipes, bars, profiles and forgings.
B.2 Method Principle
This method is a kind of test method by accelerating the exfoliation corrosion, which is
to carry out a certain period of total immersion test on the test material in the corrosive
solution under certain conditions and to evaluate the exfoliation corrosion sensibility of
material by visual inspection or metallographical observation method.
B.3 Reagents
B.3.1 Reagents of 2×××, 6××× and 7×××series
B.3.1.1 Sodium chloride (NaCl, ρ=2.16 g/cm3)
B.3.1.2 Potassium nitrate (KNO3, ρ=2.10 g/cm3)
B.3.1.3 Distilled water or deionized water
B.3.1.4 Nitric acid (HNO3, 7+3)
B.3.2 Reagents of 5×××series
B.3.2.1 Ammonium chloride (NH4Cl, ρ=1.53 g/cm3)
B.3.2.2 Ammonium nitrate (NH4NO3, ρ=1.78 g/cm3)
B.3.2.3 Ammonium tartrate ([NH4]2C4H2O, ρ=1.66 g/cm3)
B.3.2.4 Hydrogen peroxide (H2O2, ρ=1.46 g/mL)
B.3.2.5 Distilled water or deionized water
B.4 Test Solutions
B.4.1 Aluminium alloy test solution of 2×××, 6××× and 7×××series
234g of sodium chloride (B.3.1.1) and 50g of potassium nitrate (B.3.1.2) shall be taken
and dissolved in distilled water (B.3.1.3), and then 6.3mL of nitric acid (B.3.1.4) shall be
added, and the solution shall be diluted up to 1000mL by adding distilled water (or deionized
water) (B.3.1.3). This kind of solution contains 4.0mol of sodium chloride, 0.5mol of
potassium nitrate and 0.1mol of nitric acid. And the pH value of this solution is about 0.4.
B.4.2 Aluminium alloy test solutions of 5×××series
53.5g of ammonium chloride (B.3.2.1), 20g of ammonium nitrate (B.3.2.2) and 1.84g of
ammonium tartrate (B.3.2.3) shall be taken and dissolved in a little distilled water or
deionized water, and then 10mL of hydrogen peroxide (B.3.2.4) will be added into the
solution, finally, the solution shall be diluted up to 1000mL by adding distilled water or
deionized water (B.3.2.5). This kind of solution contains 1mol of ammonium chloride,
0.25mol of ammonium nitrate, 0.01mol of ammonium tartrate and 0.09mol of hydrogen
peroxide, and its pH value is about 5.2~5.4.
B.5 Test Equipments
Appropriate containers made up of glass, plastic or other inert materials all can be used
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to contain the test solution and samples. According to the shapes and dimensions of the
samples, bars or brackets of glass, or other inert materials can be made at the bottom of the
container to support the samples. The container shall be covered with removable cover in
order to reduce the evaporation of solution.
B.6 Samples
B.6.1 The dimensions of the sample shall be in accordance with those specified in the product
standard, if they are not provided in the product standard, the width of the sample shall be
30mm~50mm; the length of the sample shall be 100mm, as for the extruded products, the
length of sample shall be parallel with the direction of extrusion; as for the rolled product, this
length shall be parallel with the final rolling direction, and as for the forgings, the length shall
be parallel with the final direction of flow. The thickness of the sample shall be the original
thickness of products, which generally shall not be less than 2.5 mm; as for the products with
coating layer, a surface layer of about 10% of the original thickness shall be machined off so
that the coating layer will be removed.
B.6.2 The edges of the samples sawed off may not be machined. The primary test surface of
the sample shall be exposed, and the other surfaces may be protected with paint or protective
layer. The surface perpendicular to the primary test surface may not be protected.
B.6.3 The same batch of samples for test shall be taken from one same batch or one same heat
treating furnace.
B.6.4 The prepared samples shall be stored and protected against deformation, superficial
degradation and corrosion.
B.7 Test Procedures
B.7.1 Before the test, the samples shall be inspected on their appearance and dimensions,
however, no damages can be made to the samples during the inspection.
B.7.2 The test solution shall be made and prepared. Unless otherwise specifically provided,
the temperature of the test solution for the alloys of 2×××, 6××× and 7××× series shall be
27℃±1℃, the temperature for alloys of 5××× series shall be 65℃±1℃, and the relative
humidity in the test space shall be controlled within (45±6)% as much as possible.
B.7.3 All the samples shall be cleaned thoroughly off the oil stain, dust and grease and shall
be tested as soon as they are cleaned or be stored in drier temporarily.
B.7.4 The non-primary test surfaces of the samples shall be protected by adopting with paints
or protective layer, and the surface perpendicular to the primary test surface shall not be
protected. The paints maintain or protective layer must have nice adhesive force for fear that
crevice corrosion happens at the lower edge of the paints or protective layer, in addition, the
paints or protective layer shall not have such ions or preservative oil that can seep out.
B.7.5 Fresh solution shall be adopted in every test, the solution shall be kept static during the
test, and the solution shall not be replaced during the test period.
B.7.6 Adequate amount of solution shall be used in the test, and the ratio between the solution
volume and the immersed area of the sample surface shall be 10 mL/cm2~30 mL/cm2.
B.7.7 The samples shall be immersed in the solution and placed on the bar or bracket of inert
materials at the container bottom. The primary test surfaces of the samples of 2×××, 6××× and
7×××series shall be upward at the horizontal position to prevent the surface corrosion
substances from losing, and the samples of 5×××series shall be placed in the solution
vertically with their top ends under the solution surface by at least 25 mm.
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B.7.8 The samples shall be observed when it the immersed by 6h~24h and then shall be
continued to be immersed. As for the alloys of 6××× and 7×××series, the total immersion time
shall be 48h; as for the alloys of 2×××series, the total immersion time shall be 96h; and as for
the alloys of 5×××series, the total immersion time shall be 24h.
B.8 Test Result and Assessment
B.8.1 Result assessment
B.8.1.1 Assessment grade
B.8.1.1.1 The immersed samples shall be inspected directly at the moist state, and the grade
shall be assessed. The samples shall be washed with water after the inspection and assessment,
and then they shall be immersed in concentrated nitric acid for another 30 min and be washed
with water again, and they shall be dried by blowing finally.
B.8.1.1.2 According to Table B.1, the test result code and the corrosion grade of the samples
shall be assessed by visual observation.
Table B.1
Code number Grade Explanation to grade
No visible
N —
corrosion
Spot
P Discontinuous small pits or small spotted bubbles appear in the surface
corrosion
The metal forms into visible laminated in various modes. And the corrosion can be divided
E(EA~ED)
into four grades including EA~ED according to the varying degrees
EA Tiny scars, cracks, flakes or powders with only slight separation appear on the surface
EB Exfoliation Obvious delamination appears on the surface and also penetrates into the metal
corrosion The surface delaminates severely and the delamination penetrates into the metal by quite a
EC
large depth
The surface delaminates very seriously and the delamination also penetrates into the metal,
ED
metal loss happens
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Aluminium Alloys
C.1 Scope
This annex specifies the test method for the fatigue corrosion of the profiles for vehicle
structures of 6005A aluminium alloy at T5 and T6 conditions.
This annex is applicable to the profiles for vehicle structures of 6005A aluminium alloy
at T5 and T6 conditions.
C.2 Method Principle
This method is to place the samples in the etching solution, multiply the proof strength
of non-proportional extension of this material by a certain percentage and take it as the stress
level of this material, take this stress value as the ultimate load of the corrosion fatigue test,
and obtain the minimum load of the test by determining the stress ratio and determine the
cracking frequency of this material by applying loads on the material sample with fatigue
corrosion tester till it cracked, and thereby to assess the corrosion fatigue property of this
material.
C.3 Reagents
C.3.1 Sodium chloride (NaCl, ρ=2.16 g/cm3).
C.3.2 Sodium chromate (Na2CrO4, ρ=2.72 g/cm3).
C.3.3 Distilled water or deionized water.
C.4 Test Solution
(20±1)g of sodium chloride (C.3.1) and (5±0.5)g of sodium chromate (C.3.2) shall be
respectively dissolved in a little distilled water or deionized water (C.3.3), the solutions shall
be transferred into 1000mL measuring flasks and diluted up to 1000mL by adding water, and
the solution shall be respectively blended.
C.5 Test Equipments
C.5.1 Different types of fatigue testers with axial loading function may be adopted for the test.
The relative error in the indicating value of the dead load of tester shall not be larger than
±1% of the indicating value and the relative variation in the indicating value shall not be
larger than 1% of the indicating value.
C.5.2 The relative error in the indicating value of the dynamic load of the tester shall not be
larger than ±3% of the ultimate load in every cycle, and the relative variation in the indicating
value of the dynamic load through the whole testing process shall not be larger than 3% of the
indicating value.
C.5.3 Within the applied spatial dimension, the stressing axiality of the upper and lower jigs
of the tester shall not be larger than 10%.
C.5.4 The tester shall be certified once every 1000h of operating or every year, and the
frequency shall be subjected to the one with shorter calibration interval. For all the shift
positions that may influence the accuracy of the tester, the tester shall be certificated
immediately after it is maintained or adjusted.
C.6 Samples
C.6.1 Longitudinal rectangular samples shall be sawed off from the representative positions
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of the profile and shall be milled at their edges with milling machine. During the processing
process of the samples, it shall be ensured that the sample surface shall not be overheated.
C.6.2 The thickness of the sample shall be the original thickness of profile, the length and
width of the sample may be determined by making reference to the relevant national or
professional standards and shall be in accordance with the requirements of the tester so that
the maximum absolute value of the loads on the sample can be ensured no less than 25% of
the full range of the load level of the tester or no larger than 90% of the full range of the
adopted load level. The ratio between the bed cross-sectional area at the gripped end of the
sample and the working section area depends upon the gripping mode of the sample, which
generally shall not be less than 1.5.
C.6.3 When selecting the sample size, the resonance caused by the approximate natural
frequency of the sample and the test frequency shall be avoided.
C.6.4 The sample surface shall be free from any abrasion, and the surface roughness of the
smooth and notched bar test section of the finished sample shall not be larger than 0.4μm.
C.6.5 The measurement accuracy of the sample shall be ±0.01 mm.
C.7 Test Procedures
C.7.1 Before the test, the samples shall be inspected on their appearance and dimensions,
however, no damages can be made to the samples during the inspection.
C.7.2 The oil stain, grime and grease on the sample surface shall be cleaned off with gasoline
and alcohol, and the sample shall be tested immediately or be stored in drier temporarily.
C.7.3 The test loading stress shall be determined. The ultimate loading stress in the test shall
be determined according to the stress level of the material; the stress level of the material is
related to the proof strength of non-proportional extension of the material, which is shown as
in Table C.1.
Table C.1
Stress level Ultimate loading stress
A ≥75% Rp0.2
B ≥50% Rp0.2
C ≥25% Rp0.2
C.7.4 After determining the ultimate loading stress, the stress ratio (the ratio between the
maximum and minimum stresses), the load waveform and the test frequency shall be
determined. Generally, the stress ratio is 0.1, the load waveform is of sine wave, and the test
frequency is less than 10Hz.
C.7.5 The test solution shall be added to immerse the entire samples (at least 6 parallel
samples) in the test solution, and then the samples shall be loaded immediately. The ratio
between the solution volume and the immersed surface area of the sample shall not be less
than 20 mL/cm2.
C.7.6 During the test, loads shall be applied stably and precisely and shall not be oversized.
During the test, the solution shall be kept static and will not be replaced within the required
test period. The temperature of the solution shall be controlled at 24℃±3℃.
C.7.7 Testers shall install the samples by wearing with gloves and shall not contact with the
samples by hands directly. The sample shall be installed carefully to make the sample be
coaxial with the upper and lower grip holders of the tester, and the other stresses except for
the axial stress of the sample shall be reduced.
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