Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_STERLING BT JEE-MAIN Date: 28-06-2025
Time: 09:00AM to 12:00PM WTM-36 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point
Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on
the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.@
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:

Candidate’s Signature:________________ Invigilator’s Signature: ________________

 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P
28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Test Syllabus

MATHEMATICS : TOTAL PERMUTATIONS

PHYSICS : REFRACTION AT PLANE SURFACES: Laws of refraction, Relation
between real depth and apparent depth, Refraction through a slab
with parallel sides: Lateral displacement of a ray, Atmosphere
refraction, Total internal reflection: TIR, Mirage, Refraction at
spherical surfaces,
Prisms and dispersion (Deleted pertaining to JEE MAIN but still in JE
E ADV Syllabus)
CHEMISTRY : Reaction of glycol & glycerol with oxalic acid, conc.HI, PI3, HIO4
Oxidation of polyhydric alcohols,ETHERS: Preparation by
Williamson's synthesis, from alkenes, from alcohols and phenols, C-
O bond cleavage reactions,Electrophilic substitution reactions of
anisole, ring opening reactions of oxiranes,HENOLS: Prepartion,
properties & Reactions,Physical properties; Preparation, Electrophilic
substitution reactions of phenol (halogenation, nitration,
sulphonation); Reimer-Tiemann reaction, Kolbe
reaction;Esterification; Etherification; Aspirin synthesis; Oxidation
and reduction reactions of phenol, Bakelite formation,
phenolphthalein formation, Azo-dye formation, Tests for phenols

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 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Match the following from column-I to Column-II
Column-I Column-II
A) If n be the number of numbers between 500 and 4000 can be p) 2
formed with the digits 2,3,4,5,6 when repetition is not
allowed, then n is divisible by
B) If n be the number of even numbers between 200 and 3000 q) 3
can be formed with the digits 0,1,2,3,4 when repetition is not
allowed, then n is divisible by
C) If n be the number of words that can be made by arranging the r) 5
letters of the word ROORKEE that neither begin with R nor
end with E, then n is divisible by
D) If P  n(n2  12 )(n 2  22 )....(n2  r 2 ), n  r n, r  N and s) 11
P is always divisible by 11! then r 
1) A  p,r; B  q ; C  p,q; D  s 2) A  p,s; B  q,p ; C  p; D  r
3) A  p,q; B  q ; C  p,q,r; D  r 4) A  p,s; B  q ; C  p,r; D  s
2. Statement I : The number of ways of arranging the letters of the word ASSOCIATION
such that the two S’s come together and two I’s are not together is 8!  9 P2
2!2!
Statement II: If in the given ‘n’ things ‘p’ things are alike of one kind and ‘q’ things are
n!
alike of second kind, then the number of ways of arranging all the ‘n’ things is
p!q!
1) Both Statement – I and statement –II are true
2) Both Statement – I and statement –II are false
3) Statement –I is true, statement –II is false
4) Statement-I is false , statement-II is true
3. The number of different words that can be formed using all the letters of the word
‘SHASHANK’ such that in any word the vowels are separated by atleast two
consonants, is
1) 2700 2) 1800 3) 900 4) 600
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4. The number of 5-digit numbers which are divisible by 3 that can be formed by using the
digits 1,2,3,4,5,6,7,8 and 9, when repetition of digits is allowed, is
1) 95 2) 39 3) 4.38 4) 7.38
5. Let y  2sin x  cos 2 x,0  x  2 . All the points at which y is extremum are arranged in
a row such that the points of maximum and minimum come alternately the number of
such arrangements is
1) 16 2) 8 3) 12 4)24
6. 20 Persons are to be seated around a circular table. out of these 20, two are brothers. Then
the number of arrangements in which there will be atleast three persons between the
brothers is
1) 15  20! 2) 36  18! 3) 13  18! 4) 13!18!
7. There are 2010 chairs round the table numbered from 1 to 2010. The number of ways in
which 5 persons can be seated in any five of these chairs so that the number of empty
chairs between any two consecutive persons must be same is
1) 201  5! 2) 402  5! 3) 804  5! 4) 0
8. The number of different permutations of all the letters of the word ‘PERMUTATION’
such that any two consecutive letters in the arrangement are neither both vowels nor both
identical is
1) 63  6! 5! 2) 57  5! 5! 3) 33  6! 5! 4) 7  7! 5!
9. 60 words can be made using all the letters of the word BHBJO, with or without meaning.
If these words are written as in a dictionary, then 45th word is
1) JBBOH 2) OBBJH 3) OBBHJ 4) JHOBB
10. There are thirty volumes of magazine on the book shelf. The number of ways in which
they can be arranged, so that two particular volumes are kept side by side and another
two volumes are not side by side, is
1) 57  27! 2) 56  27! 3) 56  28! 4) 54  28!
11. The number of ways in which 6 boys and 6 girls can be seated at a round table so that no
two girls sit together and two particular girls do not sit next to a particular boy is
1) 6!4! 2) 2.5!4! 3) 2.6!4! 4) 5!4!
12. The number of 4-digit numbers that can be formed by using the digits 1,2,3,4,5,6,7,8
and 9 such that the least digit used is 4, when repetition of digits is allowed is
1) 617 2) 671 3) 716 4) 761
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13. Five digit numbers are formed by using the numbers 0,1,2,3,4 and 5 with repetition of the
same digit in any number, then the number of numbers that are divisible by 3 is
1) 1080 2) 2160 3) 540 4) 4320
14. The number of three digit numbers with three distinct digits such that one of the digits is
the arithmetic mean of the other two is
1) 120 2) 180 3) 112 4) 104

195   P3
n3
15. The number of positive terms in the sequence xn   , n  N is
4(n!) (n  1)!
1) 2 2) 3 3) 4 4) 5
16. The remainder when x  1! 2! 3! ...  100! is divided by 240 is
1) 153 2) 33 3) 73 4) 187
17. How many different 5 letter sequences can be made using the letters A,B,C,D with
repetition such that the sequence does not include the word BAD ?
1) 48 2) 550 3) 976 4) 1024
18. A six digit number is formed using all the six digits 2,3,4,5,7,8 then number of such
digits that are divisible by 11 is
1) 36 2) 720 3) 180 4) 72
19. The number of 3  3 matrices having trace ‘0’ by using the elements -3,-2,-1,0,1,2,3 is

1) 79 2) 30  76 3) 37  76 4) 36  76

20. The letters of the word ‘ARRANGE’ are arranged in all possible ways. Let ‘m’ be the

number of arrangements in which the two A’s are together and the two R’s are not

together and ‘n’ be the number of arrangements in which neither the two A’s nor the two

R’s are together then m  n 

1) 900 2) 1260 3) 780 4) 420

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SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. If the number of arrangements of letters of the word ‘DHARAMSHALA’ taken all at a

time so that no two alike letters appear together is 4a5b6c7d where a,b,c, d  N , then the
value of a  b  c  d  _____
22. All the arrangements, with or without meaning, of the word FORMER are written
excluding any word that has two R’s appearing together. The arrangements are listed
serially in the alphabetical order as in the English dictionary. Then the serial number of
the word FORMER in the list is ________
23. Five digit numbers are formed using the digits 1,2,3,5,7 with repetition and are written in
ascending order with serial numbers for example, the number 11111 has serial number 1
then the serial number of 35331 is _________
24. In a group of 3 girls and 4 boys, there are two boys B1 and B2 .The number of ways, in
which these girls and boys can stand in a queue such that all the girls stand together, all
the boys stand together, but B1 and B2 are not adjacent to each other is ________
25. The number of different 5 digit numbers greater than 50000 that can be formed using the
digits 0,1,2,3,4,5,6,7, such that the sum of their first and last digits should not be
more than 8, is_________

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 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P
PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. A beam of white light is incident on a hollow prism of glass. Then

1) The light emerging from prism gives no spectrum.

2) The light emerging from prism gives spectrum but the bending of all colours is away
from base.
3) The light emerging from prism gives spectrum, all the colours bend towards base, the
violet most and red the least.
4) The light emerging from prism gives spectrum, all the colours bend towards base, the
violet the least and red the most.
27. The angle of minimum deviation equals to one fourth of the angle of prism (A/4) of an
equilateral glass prism. The angle of incidence at which minimum deviation will be
obtained is
 2
1) sin 1   2) 37.50 3) 60.5 4) 45
 3 
3
28. A ray of light travelling inside a rectangular glass block of refractive index is incident
2
on the glass air surface at an angle of incidence of 45 . The refractive index of air is 1.
The ray will
1) Emerge into air without any deviation.
2) Be reflected back into glass.
3) Emerge into air with an angle of refraction equal to 60
4) Emerge into air with an angle of refraction equal to 90
29. Two transparent slabs have the same thickness as shown in figure. One is made of
material A of refractive index 1.5. The other is made of two materials B and C having
thicknesses in the ratio 1:3. The refractive index of C is 1.6. If a monochoromatic parallel
beam passing through the slabs has the same number of wavelengths inside both, the
refractive index of B is

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 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P

1) 1.1 2) 1.2 3) 1.3 4) 1.4

30. A small rod ABC is put in water making an angle 9 with vertical. If it is viewed
paraxially from above, it will look like bent shaped ABC’. The angle of bending
 4
(CBC ') will be in degree is  nw  
 3

1) 6 2) 3 3) 4 4) 4.5
 4
31. In the situation shown in figure, water   w   is filled in a beaker upto a height of
 3
10cm.A plane mirror is fixed at a height of 10cm from the surface of water. Distance of
image from the mirror after reflection from it of an object O at the bottom of the beaker is

1) 7.5cm 2) 10 cm 3)12.5 cm 4)17.5cm

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 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P
32. A plane mirror is placed at the bottom of a tank containing a liquid of refractive index  .
A small object P lies at a height h above the mirror. An observer O , vertically above P ,
outside the liquid, observe P and its image in the mirror. The apparent distance between
these two will be

 1 2h 2h
1) h 1   2) 3) 2h 4)
   1 
33. A parallel glass slab of refractive index 2 is placed in contact with an equilateral prism
of refractive index 3 . A ray is incident on left surface of slab as shown. The slab and
prism combination is surrounded by air. The magnitude of minimum possible deviation
of this ray by slab-prism combination is

2
1) 30 2) 45 3) 60 4) 60  sin 1
3
34. Statement-1: A parallel beam of light traveling in air can be displaced laterally by a
parallel transparent slab by distance more than the thickness of the plate.
Statement-2: The lateral displacement of light traveling in air increases with rise in value
of refractive index of slab.
1) Both statements are TRUE and STATEMENT 2 is the correct explanation of
STATEMENT 1.
2) Both statements are TRUE and STATEMENT 2 is not the correct explanation of
STATEMENT 1.
3) STATEMENT 1 is TRUE and STATEMENT 2 is FALSE.
4) STATEMENT 1 is FALSE but STATEMENT 2 is TRUE.
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35. A bird in air is diving vertically over a tank with a speed of 6cms 1 . The base of the
tank is silvered. A fish in the tank is rising upward along the same line with a speed of
4
8cms 1 . Taking  water  , match the quantities in COLUMN-I with their respective
3
values in COLUMN-II

Column-I Column-II
A Speed of the image of fish, in cms 1 as seen by the bird p) 16
directly
B) Speed of the image of fish, in cms 1 formed after q) 0
reflection from the mirror as seen by the bird
C) Speed of image of bird, in cms 1 relative to the fish r) 12
looking upwards
D) Speed of image of bird, in cms 1 relative to the fish s) 8
looking downwards in the mirror
1) A-r, B-q, C-p, D-q 2) A-q, B-p, C-r, D-s
3) A-s, B-p, C-r, D-s 4) A-r, B-p, C-q, D-q
36. A hemispherical glass body of radius 10cm and refractive index 1.5 is silvered on its
curved surface. A small air bubble is 6 cm below the flat surface inside it along the axis.
The position of the image of the air bubble made by
the mirror is seen

1) 14 cm below flat surface 2) 20 cm below flat surface

3) 16 cm below flat surface 4) 30 cm below flat surface
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37. A concave mirror has radius of curvature of 40 cm. It is at the bottom of a glass that has
water filled up to 10cm (see figure). If a small particle is floating on the surface of water,
its image as seen, from directly above the glass, is at a distance d from the surface of
water. The value of d is close to : (Refractive index of water = 1.33)

1) 11.7 cm 2) 6.7 cm 3) 22.5 cm 4) 8.8cm

38. A transparent cube of side d , made of a material of refractive index  2 , is immersed in a
liquid of refractive index 1 (1   2 ) / A ray is incident on the face AB at an angle 
(shown in the figure). Total internal reflection takes place at point E on the face BC.

Then  must satisfy

 2 
1  1  1 
1)   sin   2)   sin 2 1
  2 
 2  1 
 2 
1  1  1   2
3)   sin   4)   sin 1
  2 
 2  1 
39. A green light is incident from the water to the air-water interface at the critical angle
(  ).Select the correct statement.
1) The entire spectrum of visible light will come out of the water at various angles to the
normal
2) The entire spectrum of visible light will come out of the water at an angle of 90 to the
normal
3) The spectrum of visible light whose frequency is less than that of green light will come
out to the air medium
4) The spectrum of visible light whose frequency is more than that of green light will
come out to the air medium
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 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P
40. Assertion (A): Refractive index of glass is less than that of air.
Reason ( R): Optical density of a medium is directly proportionate to its mass density
which results in a proportionate refractive index.
In the light of the above statements, choose the most appropriate answer from the options
given below:
1) Both (A) and (R) are correct and (R) is the correct explanation of (A)
2) (A) is correct and (R) is not correct
3) Both A and R are not correct
4) Both A and R are correct but R is not the correct explanation of A
41. An ice cube has a bubble inside. When viewed from one side the apparent distance the
bubble is 14cm when viewed from the opposite side, the apparent distance of the bubble
is observed as 4cm . If the side of the ice cube is 24cm, the refractive index of the ice
cube is
3 4 2 6
1) 2) 3) 4)
2 3 3 5
42. Two thin slabs of refractive indices 1 and  2 are placed parallel to each other in the
x  z plane. If the direction of propagation of a ray in the two media are along the vectors
 
r1  aiˆ  bjˆ and r2  ciˆ  djˆ then we have

1a 2 c
1) 1a   2b 2) 
a 2  b2 c2  d 2
3) 1  a 2  b2    2  c 2  d 2  4) None of these
43. In the figure ABC is the cross section of a right angled prism and BCDE is the cross
section of a glass slab. The value of  such that light incident normally on the face AB
does not cross the face BC is (given sin 1 (3 / 5)  37 )

   
1)   37 2)   37 3)   53 4)   53
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44. A small source of light is 4m below the surface of a liquid of refractive index 5/3. In
order to cut off all the light coming out of liquid surface, minimum diameter of the disc
placed on the surface of liquid is:
1) 3m 2) 4m 3) 6m 4) 
45. STATEMENT-1: An air bubble in water shines.
STATEMENT-2: When light is incident from water to air, total internal reflection takes
outer surface of the bubble.
1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1
2) Statement – 1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement-1
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
r 1
46. Find the maximum value of  , so that the beam of light incident normally at the face
R x
A of a U shaped glass tube emerges through B as shown in the figure. The refractive
3
index of glass is   . Then x 
2

47. A 2 cm thick layer of liquid covers a 3 cm thick glass slab. A coin is placed at the bottom
of the slab and is being observed from the air side along the normal to the surface. Find
the apparent position of the coin from the surface approximately

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48. A vessel is filled with a non-homogeneous liquid whose refractive index varies with the
 y
depth y from the free surface of liquid as   1   . The apparent depth as seen by
 H
an observer from above, if H is the height to which the liquid is filled in the vessel
h  H nZ then Z =
49. A ray of light falls on a transparent sphere with centre at C as shown in the figure. The
ray emerges from the sphere parallel to the line AB. Find the refractive index of the
sphere x .Then x 

50. Face AC of a right angled prism (   1.5) is coated with a thin film of liquid as shown in
figure. Light is allowed to fall normally on the face AB of the prism. In order that the ray
3 3
of light gets totally reflected, the maximum refractive index of liquid   .Then x 
x

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 Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING BT_Jee-Main_WTM-36_Q.P
CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Match List I with List II
List-I List-II
(Reactants) (Products)
(A) NH 2 (I) OH

CHO

NaNO2+HCl (273K)

H2O, warm
.
(B) OH (II)
OH
Na2Cr2O7
H2SO4

(C) OH (III) OH

O2N NO2

(i) CHCl3+aq.NaOH
(ii) H+

NO2
(D) OH (IV) O

Con C. HNO3

O
Choose the correct answer from the options given below.
1) A-III, B-II, C-I, D-IV 2) A-IV, B-II, C-III, D-I
3) A-I, B-IV, C-II, D-III 4) A-II, B-IV, C-I, D-III
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52. Statement-1: Picric acid is 2, 4, 6- tri Bromo Phenol
Statement-2: Phenol-2, 4 disulphonic acid is treated with conc. HNO3 to get picric Acid
1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1
2) Statement – 1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement-1
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true
53.
OCH3

OCH3
HI (Excess)
Product

OCH3

Predict major product of the above reaction is :

I
OH CH3 OH

OH I O I

1) OH
2) I 3) 4) OH

54. For given compounds, correct order of increasing Pk a value:

OH

OH NO2 OH
A) B) C)
NO2

OCH3

NO2 OH

OH

D) E) NO2

1) E<B<D<A<C 2) D<E<C<B<A 3) E<D<B<A<C 4) B<D<A<C<E

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55.

Product (A) in above reaction is

Ph-CH2-CH-CH3 , (inversion) Ph-CH2-CH-CH3 , (retention)

1) OEt 2) OEt
Ph-CH2-CH-CH3 , (racemic)

3) OEt 4) Ph  CH 2  CH 2  CH 3
OH

Na
O OH

COO

56. Statement-1: CO2  rather than COO

Statement-2: Salicylate ion is a weaker base than para hydroxyl benzoate.

1) Both Statement-1 and Statement-2 are false.
2) Both Statement-1 and Statement-2 are true.
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true
57. Statement-1: Bond angle at oxygen in ethers is greater than ideal tetrahedral angle
Statement-2: Steric hindrance between alkyl group increases bond angle
1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1
2) Statement – 1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement-1
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true

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58. Assertion: Reaction of C2 H 5ONa with 2-chloro propane is a better method than reaction
of  CH 3 2 CHONa with chloro ethane in order to prepare ethyl-isopropyl ether
Reason: Here ether is formed by SN 2 reaction mechanism
1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1
2) Statement – 1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement-1
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true
59. Which of the following synthetic route may be employed to prepare the following aryl
ether
O

OH Br

Br + N aO H
OH
NaOH

1) 2)
OH

+ Br NaOH

3) 4) Both (1) and (2)

60. In following reaction most probable Product (P) is;
CH3
O2 /  H 3O 
P h -C H CH3 P + Q (C a rb o n y lc o m p o u n d )

OH
OH

1) PhOH 2) CH 3OH 3) CH3 4) CH3

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OH

C 2H 5O
C 2H 5I
a n h y d .C 2 H 5 O H
61.
Select the correct answer for the product formed is
1) PhOC2 H 5 2) Ph  O  Ph 3) PhI 4) C6 H 6

62.
Product of the above reaction is
CH3
CH3

CH3

1) CH3 2) O 3) O 4)

63. Glycerol reacts with an excess of HI to give

1) Allyl halide 2) 1, 2, 3-triiodo propane 3) Isopropyl Iodide 4) Acrolein

64.

Br2/Fe Conc.HBr
CH2-O Product is

CH2 Br + OH Br CH2 OH + Br Br
1) 2)

CH2 OBr HO CH2 Br

3) 4)
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65. Identify the end product of the following reaction
OH

D 2S O 4(ex c ess)
D 2O

OH
OH OD

D D D D
D
D D

1) 2) D 3) D 4) D

18
O
CH3 H+/H2O

CH3
66.
Products formed are
18 18
18 OH OH
OH OH

& &
CH3 CH3 CH3 CH3
1) 2)
18
OH 18 OH
O O

& &
3) 4)
67. Among the following which one cannot give any colour in pthalein dye test
OH

OH OH OH

CH3

1) 2) CH3 3) CH3
4) OH

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68. In given reaction scheme, P is a Phenyl alkyl ether, Q is an aromatic compound. R and S
are major products
(i) N a O H
(ii) C O 2 ( i) ( C H 3 C O ) 2 O
P HI Q R S
 ( iii) H 3 O + (ii) H +

Consider following statements, which of the following are correct statements

A) Pure compounds ‘Q’ is white crystalline solid
B) R is more acidic than Benzoic acid
C) Degree of unsaturation in S is six
D) (R) gives 2, 4, 6- tribromo phenol upon with bromine water
1) A, B, C only 2) B, C only 3) A, B, C, D only 4) B, C, D only
69. What is the product (B) of the following Reaction sequence?

OH
OH
O
OH

OH
1) 2) 3) 4) OH

70. Which of the following give characteristic colour reaction with neutral FeCl3 solution
OH OH

C H 2O H OCH3

1) 2) 3) CH3 4) CH3

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SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. Consider the following compounds and count number of compounds which can produce
tribromo derivative on reaction with Br2 / H 2O
OH OH

OH OH

(i) (ii) COOH (iii) OH (iv) SO3H

OH

OH CH3 OH

CH3

(v) (vi) COOH (vii)

72. A poly hydroxy aliphatic compound (A) (molar mass = 180) on acetylation give a
product (molar mass = 390) then find the number of hydroxyl groups present in
compound (A)

73. 1)

Degree of unsaturation of A + B =
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74. Total number of cyclic ethers (including stereo isomers) possible for molecular formula
C4 H 8O
75. How many of the given ethers can be synthesized by Williamson’s synthesis in good
yield (major)

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