AMALORPAVAM LOURDS ACADEMY, PUDUCHERRY

REVISION WORKSHEET (12/12/2024)

STD. : XI SUB : CHEMISTRY
IONIC EQUILIBRIUM
I. Choose the best answer
1. Which of the given statements does not explain the equilibrium state precisely?
(a) The equilibrium can be approached from either direction.
(b) The equilibrium can be attained only if the system is an isolated system.
(c) The free energy change at constant pressure and temperature is zero.
(d) It is dynamic in nature.
2 Assertion (A): At equilibrium, the mass of each of the reactants and products remains constant.
Reason (R): At equilibrium, the rate of forward reaction is equal to the rate of backward reaction.
(a) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of
the Assertion (A).
(b) Both Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of the
Assertion (A).
(c) Assertion (A) is true and Reason (R) is false.
(d) Assertion (A) is false and Reason (R) is true.
3. For the reaction, A + B ⇌ C + D, initially equal moles of A and B were taken. At equilibrium, the
moles of C were found to be twice that of A. The equilibrium constant will be:
(a) 4 (b) 2 (c) ½ (d) ¼
4. The extent of dissociation of PCl5 at a certain temperature is 20% at one atm pressure. Calculate the
pressure at which this substance is half dissociated at the same temperature.
(a) 0.125 (b) 0.246 (c) 0.826 (d) 0.111
5. Statement-I: If HI (g) is 30% dissociated at 2 atm, its degree of dissociation at 5 atm would be 0.3.
Statement II: The degree of dissociation of HI would be independent of pressure.
(1) Statement-I and Statement-II both are correct.
(2) Statement I is correct but Statement II is incorrect.
(3) Statement I is incorrect but Statement II is correct.
(4) Statement-I and Statement-II both are incorrect.
II. Answer the following
6. How does the degree of ionization (assuming 1litre) of a weak electrolyte vary with concentration?
Give its relationship.
7. What happen to the PH if a few drops of acetic acid are added to the acetic acid solution?
8. The ionization of HCl in water is given below
HCI (aq) + H2O (l) ⇋ H3O+ (aq) + CI– (aq)
Label two conjugate acid-base pairs in this ionization
9. BF3 does not have protons but still acts as an acid and reacts with NH3. Why is it so? What type of
bond is formed between the two?
10. Conjugate acid of a weak base is always stronger. The decreasing order of basic strength of the
following conjugate bases will be? OH–, RO–, CH3COO–, CI–
11. What is meant by conjugate acid-base pair? Find the conjugate acid/base for the following
species: HNO2, CH–, HClO4 , OH–, CO32-, S2-
12. Classify the following species into Lewis acids and Lewis bases and show how these act as Lewis
acid/base: (a) OH–, (b) F–, (c) H+, (d) BCl3.
13. Arrange the following in increasing order of PH.
KNO3 (aq), CH3COONa (aq), NH4Cl (aq), C6H5COONH4 (aq)
14. The species H2O, HCOO3-, HSOO4-, NH3 can act both as bronsted acids and bases. For each case write
the corresponding conjugate acid.
15. Which of the following are Lewis Acids?
H2O, BF3, H+ and NH4+,
III. Answer the followings
16. Calculate the pH of a solution formed by mixing equal volumes of two solutions A and B of a strong
acid having pH = 6 and pH = 4 respectively.
17. The pH of a sample of vinegar is 3.76. Calculate the concentration of hydrogen ion in it.
18. (a).What will be the conjugate bases for the Bronsted acids?HF, H2S04 and H2C03?
(b).Write the conjugate acids for the following Bronsted bases: NH2, NH3 and HCOO–
19. The species H20, HCO3–, HSO4– and NH3 can act both as Bronsted acid and base. For each case, give
the corresponding conjugate acid and base.
20. Classify the following species into Lewis acids and Lewis bases and show how these can act as Lewis
acid/Lewis base? (a) OH– ions (b) F– (c) H+ (d) BCl3
21. Calculate the pH of the following solutions:
(a) 2g of TlOH dissolved in water to give 2 litre of the solution
(b) 0.3 g of Ca(OH)2 dissolved in water to give 500 mL of the solution
(c) 0.3 g of NaOH dissolved in water to give 200 mL of the solution
22. Assuming complete dissociation, calculate the pH of the following solutions:
(a) 0.003 M HCl (b) 0.005 M NaOH (c) 0.002 M HBr
23. (a) State Ostwald’s dilution law.
(b)What is basic buffer?
(c) S032-is Bronsted base or acid and why?
24. The degree of ionization of a 0.1 M bromoacetic acid solution is 0.132. Calculate the pH of the
solution and the PKa of bromoacetic acid.
25. Predict if the solutions of the following salts are neutral, acidic or basic: NaCl, KBr, NaCN, NH4NO3,
NaNO2 and KF
IV. Answer the followings
26. The ionization constant of HF, HCOOH and HCN at 298 K are is 6.8 x 10-4, 1.8 x 10-4 and 4.8 x 10-
9
respectively, calculate the ionization constant of the corresponding conjugate base.
27. The ionization constant of phenol is 1.0 x 10-10. What is the concentration of phenolate ion in 0.05 M
solution of phenol? What will be its degree of ionization if the solution is also 0.01 M in sodium
phenolate?
28. The ionization constant of acetic acid is 1.74 x 10-5. Calculate the degree of dissociation of acetic acid
in its 0.05 M solution. Calculate the concentration of acetate ions in the solution and its pH.
29. The following concentration were obtained for the formation of NH3 from N2 and H2 at equilibrium at
500 K.[N2(g)] = 1.5 x 10-2 M [H2 (g)] = 3.0 x 10-2 M [NH3] = 1.2 x 10-2 M. Calculate equilibrium
constant.
30. Calculate the degree of ionization of 0.05M acetic acid if its pKa value is 4.74. How is the degree of
dissociation affected when its solution also contains (a) 0.01 M (b) 0.1 M in HCl?

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