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Specification for titanium and titanium alloy welding electrodes and rods 6th Edition Edition American Welding Society. Committee On Filler Metals And Allied Materials. ebook classic edition

The document is the 6th Edition of the Specification for Titanium and Titanium-Alloy Welding Electrodes and Rods by the American Welding Society. It outlines the requirements for classifying over 30 types of welding electrodes and rods based on chemical composition, including general requirements, testing, and application guidelines. The specification incorporates ISO 24034 and is intended for use in both U.S. Customary Units and the International System of Units (SI).

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AWS A5.16/A5.16M: 2013 (ISO 24034:2010 MOD)
An American National Standard
Approved by the
American National Standards Institute
February 19, 2013

Speciﬁcation for
Titanium and Titanium-Alloy
Welding Electrodes and Rods

6th Edition

Supersedes AWS A5.16/A5.16M:2007

Prepared by the
American Welding Society (AWS) A5 Committee on Filler Metals and Allied Materials

Under the Direction of the

AWS Technical Activities Committee

Approved by the
AWS Board of Directors

Abstract
This specification prescribes the requirements for the classification of over 30 titanium and titanium-alloy welding elec-
trodes and rods. Classification is based upon the chemical composition of the electrode. Major topics include general
requirements, testing, packaging, and application guidelines.
This specification makes use of both U.S. Customary Units and the International System of Units (SI). Since these are not
equivalent, each must be used independently of the other.
This specification adopts the requirements of ISO 24034 and incorporates the provisions of earlier versions of
A5.16/A5.16M, allowing for classifications under both specifications.
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

International Standard Book Number: 978-0-87171-834-1

American Welding Society
8669 Doral Blvd., Suite 130, Doral, FL 33166
© 2013 by American Welding Society
All rights reserved
Printed in the United States of America

Photocopy Rights. No portion of this standard may be reproduced, stored in a retrieval system, or transmitted in any
form, including mechanical, photocopying, recording, or otherwise, without the prior written permission of the copyright
owner.

Authorization to photocopy items for internal, personal, or educational classroom use only or the internal, personal, or
educational classroom use only of speciﬁc clients is granted by the American Welding Society provided that the appro-
priate fee is paid to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, tel: (978) 750-8400;
Internet: <www.copyright.com>.

ii
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

Foreword
This foreword is not part of AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD), Specification for
Titanium and Titanium – Alloy Welding Electrodes and Rods, but is included for informational purposes only.

This document is the first adoption of ISO 24034:2010: Welding consumables – Solid wires and rods for arc welding of
titanium and titanium-alloys – Classification. With its insertion of references and additional informative annexes it
replaces A5.16/A5.16M: 2007. The adoption of the modified ISO 24034, designated by MOD, is in accordance with
ISO/IEC Guide 21-2005, Clause 4.3. All changes are listed in Annex F. The modifications to ISO 24034:2010 are also
shown in Italic font.
Please note that ISO uses commas (,) and AWS uses periods (.) for decimals.
Document Development
The current specification is the sixth edition of the initial AWS/ASTM document issued in 1961 as shown below:
AWS A5.16-61T Tentative Specification for Titanium-Alloy Bare Welding Rods and Electrodes
ASTM B362-61T
AWS A5.16-70 Specification for Titanium and Titanium-Alloy Bare Welding Rods and Electrodes
ANSI W3.16-1973
ANSI/AWS A5.16-90 Specification for Titanium and Titanium-Alloy Bare Welding Rods and Electrodes
ANSI/AWS A5.16-90R Specification for Titanium and Titanium-Alloy Bare Welding Rods and Electrodes, reaffirmed in
1997
AWS A5.16/A5.16M:2004 Specification for Titanium and Titanium-Alloy Bare Welding Electrodes and Rods
AWS A5.16/A5.16M:2007 Specification for Titanium and Titanium-Alloy Bare Welding Electrodes and Rods
Attention is drawn to the possibility that some of the elements of this part of ISO 24034 may be the subject of patent
rights. AWS and ISO shall not be held responsible for identifying any or all such patent rights.
Comments and suggestions for the improvement of this standard are welcome. They should be sent to the Secretary,
AWS A5 Committee on Filler Metals and Allied Materials, American Welding Society, 8669 Doral Blvd., Suite 130,
Doral, FL 33166.

vii
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

Personnel

AWS A5 Committee on Filler Metals and Allied Materials

H. D. Wehr, Chair Arcos Industries, LLC
J. J. DeLoach Jr., 1st Vice Chair Naval Surface Warfare Center
R. D. Fuchs, 2nd Vice Chair Bohler Welding Group USA, Incorporated
R. K. Gupta, Secretary American Welding Society
T. Anderson ITW Welding North America
J. M. Blackburn Naval Sea Systems Command
J. C. Bundy Hobart Brothers Company
J. L. Caron Haynes International, Incorporated
D. D. Crockett Consultant
R. V. Decker Weldstar
D. A. DelSignore Consultant
H. W. Ebert Consultant
D. M. Fedor The Lincoln Electric Company
J. G. Feldstein Foster Wheeler North America
S. E. Ferree ESAB Welding and Cutting Products
D. A. Fink The Lincoln Electric Company
G. L. Franke Naval Surface Warfare Center
R. M. Henson Harris Products Group
S. D. Kiser Special Metals
P. J. Konkol Concurrent Technologies Corporation
D. J. Kotecki Damian Kotecki Welding Consultants
L. G. Kvidahl Ingalls Shipbuilding
A. Y. Lau Canadian Welding Bureau
J. S. Lee Chevron
T. Melfi The Lincoln Electric Company
M. T. Merlo RevWires, LLC
K. M. Merlo-Joseph EWI
B. Mosier Polymet Corporation
A. K. Mukherjee Siemens Energy, Inc.
T. C. Myers Oceaneering Intervention Engineering
C. L. Null Consultant
B. A. Pletcher Select-Arc
K. C. Pruden BP America
K. Roossinck Ingalls Shipbuilding
P. K. Salvesen Det Norske Veritas (DNV)
K. Sampath Consultant
W. S. Severance ESAB Welding and Cutting Products
M. F. Sinfield Naval Surface Warfare Center
M. J. Sullivan NASSCO-National Steel and Shipbuilding
R. C. Sutherlin ATI Wah Chang
M. D. Tumuluru US Steel Corporation
J. Zhang Indalco Alloys-Lincoln Electric

Advisors to the AWS A5 Committee on Filler Metals and Allied Materials

R. Bateman Soldaduras West Arco SAS
J. E. Beckham Chrysler Group, LLC
M. L. Caruso Special Metals Welding Products Company
R. A. Daemen Consultant

v
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

B. S. Dauble Carpenter Technology Corporation

T. A. Davenport PRL Industries
J. DeVito Consultant
C. E. Fuerstenau Lucas-Milhaupt, Incorporated
J. P. Hunt Consultant
S. Imaoka KOBE Steel, Ltd.
S. J. Knostman Hobart Brothers
W. A. Martilla WAMcom Consulting, LLC
R. Menon Stoody Company
M. P. Parekh Consultant
J. W. Price DMI Industries
M. A. Quintana The Lincoln Electric Company
E. S. Surian National University of Lomas de Zamora
H. J White Consultant

AWS A5K Subcommittee on Titanium and Zirconium Filler Metals

R.C. Sutherlin, Chair ATI Wah Chang
A. L. Diaz, Secretary American Welding Society
S. S. Delmore CK Worldwide, Incorporated
H. Kotaki Japan Titanium Society
B. Krueger Consultant
K. T. Tran Naval Surface Warfare Center
G. E. Trepus Boeing Research and Technology

Advisors to the AWS A5K Subcommittee on Titanium and Zirconium Filler Metals
J. A. McMaster MC Consulting
S. D. Sparkowich SABIC Innovative Plastics

vi
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Table of Contents

Page No.
Personnel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
Foreword . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
List of Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . x
1. General Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Units of Measure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.3 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
2. Normative References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
3. Classification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
4. Symbols and Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
4.1 Symbols for the Product Form . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
4.2 Symbol for the Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
4.3 Rounding-Off Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
5. Mechanical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
6. Chemical Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
7. Retest . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
8. Technical Delivery Conditions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
9. Designation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Annex A (Informative)—Explanation of Classification Symbols for Chemical Composition . . . . . . . . . . . . . . . . . . . 7
Annex B (Informative)—Corresponding National Classifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Annex C (Informative)—Informative References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
National Annexes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Annex D (Informative)—Guide to AWS Specification for Titanium and Titanium-Alloy
Welding Electrodes and Rods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Annex E (Informative)—Guidelines for the Preparation of Technical Inquiries . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Annex F (Informative)—List of Deviations from ISO 24034:2010 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
AWS Filler Metal Specifications by Material and Welding Process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
AWS Filler Metal Specifications and Related Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

ix
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

Specification for Titanium and

Titanium-Alloy Welding Electrodes and Rods

1. General Requirements
1.1 Scope. This standard specifies requirements for the classification of solid wire electrodes, solid wires and rods for
fusion welding of titanium and titanium-alloys. The classification of the solid wires and cut lengths and spools of wire is
based on their chemical composition.
For titanium welding consumables, the compositions of the wire electrodes for the gas metal arc welding (GMAW)
process are the same as for the gas tungsten arc welding (GTAW) process, the plasma arc welding (PAW) process, the
laser beam welding (LBW) process, and other fusion welding processes. Therefore, the use of the word “wires/rods” in
this classification refers to both “wire electrodes” and “wires and rods” in this standard.
NOTE: In this standard, the word “titanium” is used for “titanium and titanium-alloys.”
The classification of titanium wires/rods is based upon the chemical composition of the wires/rods.
1.2 Units of Measure. This standard makes use of both U.S. Customary Units and the International System of Units (SI). The
latter are shown within brackets ([ ]) or in appropriate columns in tables and figures. The measurements may not be exact
equivalents; therefore, each system must be used independently when referring to material properties. Standard dimensions
based on either system may be used for sizing of electrodes or packaging or both under A5.16 or A5.16M specifications.
1.3 Safety. Safety and health issues and concerns are beyond the scope of this standard; some safety and health
information is provided, but such issues are not fully addressed herein.
American Welding Society:
(1) ANSI Z49.1. Safety in Welding, Cutting, and Allied Processes
(2) AWS Safety and Health Fact Sheets
(3) Other safety and health information on the AWS website
Material or Equipment Manufacturers:
(1) Material Safety Data Sheets supplied by materials manufacturers
(2) Operating Manuals supplied by equipment manufacturers
Applicable Regulatory Agencies
Work performed in accordance with this standard may involve the use of materials that have been deemed hazardous,
and may involve operations or equipment that may cause injury or death. This standard does not purport to address all
safety and health risks that may be encountered. The user of this standard should establish an appropriate safety
program to address such risks as well as to meet applicable regulatory requirements. ANSI Z49.1 should be considered
when developing the safety program.

2. Normative References
The following referenced documents are indispensable for the application of this document. For dated references, only
the edition cited applies. For undated references, the latest edition of the referenced document (including any amend-
ments) applies.
2.1 The following AWS standards1 are referenced in the mandatory sections of this document:

1
AWS standards are published by the American Welding Society, 8669 Doral Blvd., Suite 130, Doral, FL 33166.

1
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

Specification for Titanium and

Titanium-Alloy Welding Electrodes and Rods

1
AWS standards are published by the American Welding Society, 8669 Doral Blvd., Suite 130, Doral, FL 33166.

1
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

AWS A3.0M/A3.0, Standard Welding Terms and Definitions

AWS A5.01M/A5.01 (ISO 14344 MOD), Procurement Guidelines for Consumables—Welding and Allied
Processes—Flux and Gas Shielded Electrical Welding Processes
AWS A5.02/A5.02M, Specification for Filler Metal Standard Sizes, Packaging, and Physical Attributes
2.2 The following ANSI standard2 is referenced in the mandatory sections of this document:
ANSI Z49.1, Safety in Welding, Cutting, and Allied Processes
2.3 The following ASTM standards3 are referenced in the mandatory sections of this document:
ASTM E29, Standard Practice for Using Significant Digits in Test Data to Determine Conformance with
Specifications
ASTM E539, Standard Test Method for Analysis of Titanium Alloys by X-Ray Fluorescence Spectrometry
ASTM E1409, Standard Test Method for Determination of Oxygen and Nitrogen in Titanium and Titanium Alloys by
the Inert Gas Fusion Technique
ASTM E1447, Standard Test Method for Determination of Hydrogen in Titanium and Titanium Alloys by the Inert
Gas Fusion Thermal Conductivity/Infrared Detection Method
ASTM E1941, Standard Test Method for Determination of Carbon in Refractory and Reactive Metals and Their
Alloys by Combustion Analysis
ASTM E2371, Standard Test Method for Analysis of Titanium and Titanium Alloys by Atomic Emission Plasma
Spectrometry
ASTM E2626, Standard Guide for Spectrometric Analysis of Reactive and Refractory Metals
2.4 The following ISO standards4 are referenced in the mandatory sections of this document:
ISO 544, Welding consumables — Technical delivery conditions for welding filler materials and fluxes-Type of
product, dimensions, tolerances and markings
ISO 14344, Welding consumables-Procurement of filler materials and fluxes
ISO 80000–1:2009, Quantities and units — Part 1: General

3. Classification
The welding consumables may be classified with a numerical and/or an AWS designation.
1. Numerical designation:
a. The first part indicates the product form as solid wires or rods, see 4.1.
b. The second part gives a numerical symbol indicating the chemical composition of the solid wire/rod, see Table 1.
2. AWS designation:
a. The AWS classification includes the product form as part of the classification designator.

4. Symbols and Requirements

4.1 Symbols for the Product Form
The symbol for the solid wire and rod shall be S. If numerical designations are used there is no additional symbol when
AWS classification is used.

2
This ANSI standard is published by the American Welding Society, 8669 Doral Blvd., Suite 130, Doral, FL 33166.
3
This ASTM standards is published by the American Society for Testing and Materials, 100 Barr Harbor Drive, West
Conshohocken, PA 19428–2959.
4
ISO standards are published by the International Organization for Standardization, 1, ch. de la Voie-Creuse, Case
postale 56 CH-1211 Geneva 20, Switzerland.

2
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

AWS A3.0M/A3.0, Standard Welding Terms and Definitions

4. Symbols and Requirements

4.1 Symbols for the Product Form
The symbol for the solid wire and rod shall be S. If numerical designations are used there is no additional symbol when
AWS classification is used.

2
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AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

AWS A3.0M/A3.0, Standard Welding Terms and Definitions

4. Symbols and Requirements

4.1 Symbols for the Product Form
The symbol for the solid wire and rod shall be S. If numerical designations are used there is no additional symbol when
AWS classification is used.

2
Table 1
Symbols for Chemical Composition and Composition Requirements
Alloy Symbols Chemical Composition Requirements, % (by mass)a, b, c, d
AWS
Numerical A5.16/A5.16M Chemical C O N H Fe Al V Pd Ru Ni Mo Other
Classification

Ti 0100 ERTi-1 Ti99,8 0.03 0.03 to 0.10 0.012 0.005 0.08 — — — — — — —

Ti 0120 ERTi-2 Ti99,6 0.03 0.08 to 0.16 0.015 0.008 0.12 — — — — — — —
Ti 0125 ERTi-3 Ti99,5 0.03 0.13 to 0.20 0.02 0.008 0.16 — — — — — — —
Ti 0130 ERTi-4 Ti99,3 0.03 0.18 to 0.32 0.025 0.008 0.25 — — — — — — —
Ti 2251 ERTi-11 TiPd0,2 0.03 0.03 to 0.10 0.012 0.005 0.08 — — 0.12 to 0.25 — — — —
Ti 2253 ERTi-17 TiPd0,06 0.03 0.03 to 0.10 0.012 0.005 0.08 — — 0.04 to 0.08 — — — —
Ti 2255 ERTi-27 TiRu0,1 0.03 0.03 to 0.10 0.012 0.005 0.08 — — — 0.08 to 0.14 — — —
Ti 2401 ERTi-7 TiPd0,2A 0.03 0.08 to 0.16 0.015 0.008 0.12 — — 0.12 to 0.25 — — — —
Ti 2403 ERTi-16 TiPd0,06A 0.03 0.08 to 0.16 0.015 0.008 0.12 — — 0.04 to 0.08 — — — —
Ti 2405 ERTi-26 TiRu0,1A 0.03 0.08 to 0.16 0.015 0.008 0.12 — — — 0.08 to 0.14 — — —
Ti 3401 ERTi-12 TiNi0,7Mo0,3 0.03 0.08 to 0.16 0.015 0.008 0.15 — — — — 0.6 to 0.9 0.2 to 0.4 —
Ti 3416 ERTi-15A TiRu0,05Ni0,5 0.03 0.13 to 0.20 0.02 0.008 0.16 — — — 0.04 to 0.06 0.4 to 0.6 — —
Ti 3423 ERTi-13 TiNi0,5 0.03 0.03 to 0.10 0.012 0.005 0.08 — — — 0.04 to 0.06 0.4 to 0.6 — —
3

Ti 3424 ERTi-14 TiNi0,5A 0.03 0.08 to 0.16 0.015 0.008 0.12 — — — 0.04 to 0.06 0.4 to 0.6 — —
Ti 3443 ERTi-33 TiNi0,45Cr0,15 0.03 0.08 to 0.16 0.015 0.008 0.12 — — 0.01 to 0.02 0.02 to 0.04 0.35 to 0.55 — Cr: 0.1 to 0.2
Ti 3444 ERTi-34 TiNi0,45Cr0,15A 0.03 0.13 to 0.20 0.02 0.008 0.16 — — 0.01 to 0.02 0.02 to 0.04 0.35 to 0.55 — Cr: 0.1 to 0.2
Ti 3531 ERTi-30 TiCo0,5 0.03 0.08 to 0.16 0.015 0.008 0.12 — — 0.04 to 0.08 — — — Co: 0.20 to 0.80
Ti 3533 ERTi-31 TiCo0,5A 0.03 0.13 to 0.20 0.02 0.008 0.16 — — 0.04 to 0.08 — Co: 0.20 to 0.80

AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

Ti 4251 ERTi-38 TiAl4V2Fe 0.05 0.20 to 0.27 0.02 0.010 1.2 to 1.8 3.5 to 4.5 2.0 to 3.0 — —
Sn: 0.6 to 1.4
Ti 5112 ERTi-32 TiAl5V1SnMo1Zr11 0.03 0.05 to 0.10 0.012 0.008 0.20 4.5 to 5.5 0.6 to 1.4 — — — 0.6 to 1.2 Zr: 0.6 to 1.4
Si: 0.06 to 0.14
Ti 6321 ERTi-9e TiAl3V2,5A 0.03 0.06 to 0.12 0.012 0.005 0.20 2.5 to 3.5 2.0 to 3.0 — — — — —
Ti 6324 ERTi-28 TiAl3V2,5Ru 0.03 0.06 to 0.12 0.012 0.005 0.20 2.5 to 3.5 2.0 to 3.0 — 0.08 to 0.14 — — —
Ti 6326 ERTi-18 TiAl3V2,5Pd 0.03 0.06 to 0.12 0.012 0.005 0.20 2.5 to 3.5 2.0 to 3.0 0.04 to 0.08 — — — —
Ti 6402 ERTi-5 TiAl6V4B 0.05 0.12 to 0.20 0.030 0.015 0.22 5.50 to 6.75 3.50 to 4.50 — — — — —
Ti 6408 ERTi-23 TiAl6V4A 0.03 0.03 to 0.11 0.012 0.005 0.20 5.5 to 6.5 3.5 to 4.5 — — — — —
Ti 6413 ERTi-25 TiAl6V4Ni0,5Pd 0.05 0.12 to 0.20 0.030 0.015 0.22 5.5 to 6.7 3.5 to 4.5 0.04 to 0.08 — 0.3 to 0.8 — —
Ti 6414 ERTi-29 TiAl6V4Ru 0.03 0.03 to 0.11 0.012 0.005 0.20 5.5 to 6.5 3.5 to 4.5 — 0.08 to 0.14 — — —
Ti 6415 ERTi-24 TiAl6V4Pd 0.05 0.12 to 0.20 0.030 0.015 0.22 5.5 to 6.7 3.5 to 4.5 0.04 to 0.08 — — — —
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)
Table 1 (Continued)
Symbols for Chemical Composition and Composition Requirements
Alloy Symbols Chemical Composition Requirements, % (by mass)a, b, c, d
AWS
Numerical A5.16/A5.16M Chemical C O N H Fe Al V Pd Ru Ni Mo Other
Classification

Ti 8211 ERTi-21 TiMo15Al3Nb3 0.03 0.10 to 0.15 0.012 0.005 0.20 to 0.40 2.5 to 3.5 — — — — 14.0 to 16.0 Nb: 2.2 to 3.2
Si: 0.15 to 0.25
Ti 8451 ERTi-36 TiNb45 0.03 0.06 to 0.12 0.02 0.0035 0.03 — — — — — — Nb: 42.0 to 47.0
Ti 8641 ERTi-19 TiV8Cr6Mo4Zr4Al3 0.03 0.06 to 0.10 0.015 0.015 0.20 3.0 to 4.0 7.5 to 8.5 — — — 3.5 to 4.5 Cr: 5.5 to 6.5
Zr: 3.5 to 4.5
Ti 8646 ERTi-20 TiV8Cr6Mo4Zr4Al3Pd 0.03 0.06 to 0.10 0.015 0.015 0.20 3.0 to 4.0 7.5 to 8.5 0.04 to 0.08 — — 3.5 to 4.5 Cr: 5.5 to 6.5
Zr: 3.5 to 4.5
a
Single values are maxima, unless otherwise noted.
b
The remainder of the alloy is titanium.
c
Analysis of Fe and the interstitial elements C, O, H, and N shall be conducted on samples of rod/wire taken after the rod/wire has been reduced to its final diameter and all processing operations have been completed.
Analysis of the other elements may be conducted on these same samples or it may have been conducted on samples taken from the ingot or the rod stock from which the rod/wire is made. In case of dispute, samples
from the finished rod/wire shall be the referee method.
d
Any element intentionally added (O, Fe, N, and C) shall be measured and reported. Residual elements, total, shall not exceed 0.20 percent, with no single element exceeding 0.05 percent, except for yttrium, which shall
4

not exceed 0.005 percent. Residual elements need not be reported unless specifically required by the purchaser. A residual element is any element present in the metal in small quantities that is inherent in the sponge
or scrap additions, but not intentionally added. In titanium these elements include, among others, aluminum, vanadium, tin, chromium, molybdenum, niobium, zirconium, hafnium, bismuth, ruthenium, palladium,
yttrium, copper, silicon, and cobalt.
e
Formerly ERTi-9 ELI
Note: Corresponding national classifications are shown in Annex B.
AWS A5.16/A5.16M:2013 (ISO 24034:2010 MOD)

4.2 Symbol for the Chemical Composition

The numerical symbols or AWS Classification in Table 1 indicates the chemical composition of the solid wire or rod,
determined under conditions given in Clause 6. The first two digits indicate the alloy group. See Annex A for an expla-
nation of the numerical symbols. The second column (AWS A5.16/A5.16M Classification) is for reference to previous
revisions of this specification.
4.3 Rounding-Off Procedure
For the purpose of determining compliance with the requirements of this standard, the actual test values obtained shall be
subjected to the rounding-off rules of ASTM E29, Standard Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications or Rule A in Clause B.3 of ISO 80000–1:2009 (the results are the same). If
the measured values are obtained by equipment calibrated in units other than those of this standard, the measured values
shall be converted to the units of this standard before rounding-off. If an average value is to be compared to the require-
ments of this standard, rounding-off shall be done only after calculating the average. In the case where the testing stan-
dard cited in the normative references of this standard contains instructions for rounding-off that conflict with the
instructions of this standard, the rounding-off requirements of the testing standard shall apply. The rounded-off results
shall fulfill the requirements of the appropriate table for the classification under test.

5. Mechanical Properties
Mechanical properties of weld metal or welded joints are not part of this classification.

6. Chemical Analysis
Chemical analysis shall be performed on specimens of the product or the stock from which it is made. See also footnote
c to Table 1. Many approved analytical techniques are applicable but, in case of a dispute, reference shall be made to
established published methods, agreed upon between the contracting parties.

7. Retest
If any test fails to meet the requirement, that test shall be repeated twice. The results of both retests shall meet the require-
ment. Specimens for the retest may be taken from the original test sample or from a new test sample. For chemical analy-
sis, retests need be only for those specific elements that failed to meet their test requirement. If the results of one or both
retests fail to meet the requirement, the material under test shall be considered as not meeting the requirements of this
specification for that classification.
In the event that, during preparation or after completion of any test, it is clearly determined that prescribed or proper pro-
cedures were not followed in preparing the weld test sample or test specimen(s), or in conducting the tests, the test shall
be considered invalid, without regard to whether the test was actually completed, or whether the test results met, or failed
to meet, the requirement. That test shall be repeated, following proper prescribed procedures. In this case, the requirement
for doubling the number of test specimens does not apply.

8. Technical Delivery Conditions

Technical delivery conditions shall meet the requirements in AWS A5.01M/A5.01(ISO 14344 MOD) and AWS
A5.02/A5.02M, or ISO 544 and ISO 14344.

5
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