Spark ignition engine cycle calculations
V
P
E
op
E
oR
E
T
Reactants
Products
C
B
D
A
A
D
B
C
Pressure/volume diagram
Internal energy /temperature diagram
Cycle calculations
The basic equations are used to solve the cycle:
the basic stochiometric equation for hydrocarbon-air reaction is:
The stoichiometric fuel/air ratio is :
For the mixture of equivalence ,we have:
Then the total number of moles M
A
of the mixture is :
(1)
The magnitude of w is obtained from the ideal gas equation for the mixture :
(2)
2 2 2 2 2
( ) 3.76( ) 3.76( )
4 4 2 4
n m
m m m m
C H n O n N nCO H O n N + + + + = + + +
2 2
( ) 3.76( )
4 4
n m
C H
m m
n O n N + + +
2 2
1 1
( ) 3.76( )
4 4
n m
m m
C H n O n N
o o
+ + + +
1
(1 4.76( ) )
4
A
m
M w n
o
= + +
A A A mol A
P V M R T =
Adiabatic Compression:
Consider a small change in volume V
1
to V
2
, the first low for the change is :
Since the process is adiabatic , dQ=0 , we have :
(3)
For change in pressure from p1 to p2 the work dW is approximately :
(4)
The internal energy change is dE ,which is given by:
(5)
If E
R
is the internal energy of the reactants ,then:
E
R
=E
OR
+E
R
(T)
and the internal energy for the reactants at absolute zero E
OR
is :
dQ dW dE =
0 dE dW + =
1 2
2
( )( )
2
P P
dw pdV V V
+
= =
2 1
dE E E =
2 2
1 1
( ) ( ) ( ) 3.76( ) ( )
4 4
OR O n m O O
m m
E w e C H n e O n e N
o o
= + + + +
Then E
R
(T) for mixture is given by :
(6)
The internal energy change E
2
-E
1
is then :
(7)
composition constant Since for a mixture of
For a change in state from V
1
to V
2
,the first law (3) is thus :
(8)
substituting for E
2
-E
1
and dW ,we obtain:
(9)
We can get the magnitude of P
2
from :
(10)
2 2
1 1
( ) ( ) ( ) ( ) 3.76( ) ( )
4 4
n m
R C H O N
m m
E T w e T n e T n e T
o o
= + + + +
2 1 2 1
( ) ( )
R R
E E E T E T =
| | | |
2 1
OR OR
E E =
2 1
0 E E dW + =
| |
2 1
2 1 2 1
( ) ( ) 0
2
R R
P P
E T E T V V
+
+ =
1 2
2 1
2 1
V T
P P
V T
=