Lecture 2
Fossil Fuels
What are Fossil fuels
Fossil Fuels are the energy rich substances formed
from the remains of once-living organisms.
The three major fossil fuels are
- coal
- oil
- natural gas.
How Fossil Fuels Are Formed
As fossil fuels are all derived from the remains of animals and plants, in
terms of chemical composition,
Principal constituents are carbon (C)and hydrogen (H).
other important constituents are nitrogen (N), oxygen (O) and sulfur
(S).
The global carbon cycle
We have a finite (limited) amount that is being depleted
Therefore,
Fossil fuels are
nonrenewable resources
Coal
Coal is a solid fossil fuel
It’s easy to transport
Types of coal:
- Lignite-soft coal; low in sulfur and produces less heat
- Sub-bituminous; intermediate grade coal between lignite and
bituminous. Low hear value and sulfur content.
- Bituminous- “soft coal” , high in sulfur and produces lots of heat
- Anthracite- “hard coal” that is low in sulfur and produces the most
heat and less pollution
Coal Ultimate Analysis
(elemental composition)
Carbon 60 - 96%
Hydrogen 2 - 6%
Nitrogen 1-2%
Sulfur 0.5 - 5%
Oxygen 1 - 30%
Oil
Oil is a thick, liquid fossil fuel, it is formed from remains of small
animals, algae and protists.
Petroleum is another name for oil.
When oil is first pumped out of the ground, it is called crude oil.
A factory where crude oil is separated into fuels and other products by
heating is called a refinery.
A very complicated liquid mixture of hydrocarbons
Liquid HCs start at C4-C5
Oil distillation
Some of the world’s most productive
sedimentary basins
Saudi Arabia
Kuwait
Alaska – north slope
Texas – Louisiana Gulf Coast
Iraq and Iran
Mexico
Venezuela
Natural gas
The third major fossil fuel is natural gas.
It is a mixture of methane and other gases.
oMostly methane, CH4 (60-80%)
oOthers: C2 HCs (5-9%), C3 HCs (3-18%), C4 HCs(2-14%)
Advantages:
o Provides lots of energy
o Lower levels of air pollutants than coal and oil
Disadvantage:
oHighly flammable
Fuel Calorific values
The calorific value of a fuel is the quantity of heat produced by
its combustion – at constant pressure and under normal”
(standard) conditions (i.e. to 0oC and under a pressure of 1,013
mbar). Unit kcal/kg
Fuel Calorific Values
Natural gas 12500 kcal/kg
Propane-butane 11950 kcal/kg
Disel 10000 kcal/kg
Fuel oil 9520 kcal/kg
Brown coal 3500 kcal/kg
Woods 2500 kcal/kg
Example: Calculate the calorific value of the gas mixture 90%
methane and 10% butane by weight. Also calculate how much
CO2 produced by burning 1 kg of this gas mixture.