Environmental Science Reporting
Environmental Science Reporting
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WATER QUALITY
ASSESSING WATER
QUALITY
WATER QUALITY
STANDARDS
WATER SUPPLY
AND TREATMENT
Environmental Science BSCE - 1D
WATER
QUALITY
Measures of Water Quality
Group 2 | Presentation
Principal 1 Dissolved Oxygen
Indicators 3 Solids
4 Nitrogen
5 Bacteriological Measurements
Dissolved Oxygen
• measured with an oxygen probe
1 2 3
Theoretical Biochemical Chemical
Oxygen Demand Oxygen Demand Oxygen Demand
Theoretical Oxygen
1 Demand
• Oxygen demand for decomposition of pure materials
• Hydrocarbon compounds - only carbon and hydrogen, or
an alcohol containing oxygen
BOD = I - F
where, I = initial DO, mg/L
F = final DO, mg/L
Standard BOD Test
200mL
________ = 3.33mg/L
BOD seed= 5mg/L
300mL
Standard BOD Test
Standard BOD Test
Biochemical
Oxygen Demand
• measure of oxygen use
• "pounds of BOD"
lb BOD/day = [mg/L BOD] × [flow in mgd] × [8.34 lb/(mg/L)/(mil gal)]
• greater than the BOD unless the sample contains primarily easily
biodegradable wastes
• provides more consistent results because it is chemically, rather than
biologically based.
Solids
• anything other than water or gas in wastewater
• water-related illnesses are the leading cause of human sickness and death
world-wide
1 2
Membrane Filtration Most Probable
Number (MPN)
Membrane Filtration
• running a sample through a sterile filter
• filter is then placed in a petri dish containing a sterile agar that soaks into
the filter
LABORATORY
ANALYSIS
REMOTE SENSING
·Field tests are a common method used to assess
water quality. They involve using simple
instruments and kits to measure various water
quality parameter on site. For example, a T
thermometer can be used to measure water F E
temperature, a pH meter can be used to measure S
pH levels, and a dissolve oxygen meter can be I
used to measure oxygen levels in the water. Field E T
tests are convenient and relatively inexpensive, L I
but they may not be as accurate as laboratory N
analysis. D
G
·Laboratory Analysis involves collecting water L
samples and analyzing them in a laboratory A A
using specialized equipment and techniques.
Laboratory analysis can provide more accurate
B N
and precise results than field tests, but it is also O A
more expensive and time-consuming. Common R L
laboratory methods for water quality analysis
include spectrophotometry, chromatography, and
A Y
microbiological analysis. T S
O I
R S
Y
·Remote sensing is a method used to assess S
R
water quality from a distance, using satellite E
imagery or other types of remote sensors. E
N
Remote sensing can provide a broad overview of M
water quality over a large area, but it may not be
S
O
as accurate as field tests or laboratory analysis. I
T N
E G
The results of water quality assessments can provide
valuable information about the health of aquatic
ecosystems and safety of drinking water. For
example, high levels of nutrients such as nitrogen and
phosphorus can lead to the growth of harmful algal
blooms, which can have a negative impacts on water
quality and aquatic life. Elevated levels of bacteria or
other contaminants in drinking water sources can
pose health risks to human populations.
REMEMBER:
GROUP 2
WATER QUALITY
STANDARDS
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DRINKING WATER
STANDARDS
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DRINKING WATER STANDARDS
DRINKING WATER
STANDARDS
The list of chemical standards is quite long and includes the usual inorganics (lead, arsenic,
chromium, etc.) as well as some organics (e.g., DDT). Bacteriological standards for drinking water
are written in terms of the coliform indicators. The normal standard is presently less than 1 coliform
per 100 mL of treated drinking water.
One example of a physical standard is turbidity, or the interference with the passage of light. A
water that has high turbidity is cloudy, a condition caused by the presence of colloidal solids.
Turbidity does not in itself cause a health problem, but the colloidal solids may prove to be
convenient vehicles for pathogenic organisms.
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DRINKING WATER
STANDARDS
The standards listed in Table 9.2 are examples of primary standards. Primary
standards specify maximum contaminant levels (MCLs) or treatment techniques.
They are set to protect public health and so are enforceable.
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DRINKING WATER
STANDARDS
Secondary standards, on the other hand, are set to make the water more
palatable and usable, reducing, for example, unpleasant tastes and corrosivity
(Table 9.3). These standards are not enforceable.
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SECONDARY DRINKING WATER STANDARDS
TABLE 9.3
DRINKING WATER
STANDARDS
For example, the secondary standard for chloride is 250 mg/L, a point at which water has a distinct
salty taste. There is no primary standard for chloride because before the salt can become harmful it
will taste so bad that nobody would drink the water. Iron likewise is not a health problem (and, in
fact, is important for healthy blood), but high iron concentrations make water appear red and
discolor laundry. Manganese gives water a blue color and similarly can discolor laundry and
ceramic surfaces, such as bathtubs.
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DRINKING WATER
STANDARDS
Maximum contaminant level goals (MCLGs) are also not enforceable but apply to the primary
contaminants. These goals are set at levels that present no known or anticipated health effects.
Therefore, they may be lower than MCLs due to technological or economic issues. In other words,
it may be so expensive to reduce a contaminant to a concentration at which there are no known
effects that the decision is made to accept an increased health risk in order to reduce the cost of
compliance.
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DRINKING WATER
STANDARDS
Because science and technology evolve, the EPA continues to review data to determine whether
substances known or anticipated to occur in public water systems need to be regulated under the
SDWA. This review process results in a contaminant candidate list (CCL). CCL 1, published in
1998, had 60 contaminants. CCL 2, published in 2005, had 51 contaminants that were not removed
from CCL 1 through the regulatory determination process.
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DRINKING WATER
STANDARDS
The draft CCL 3, published in 2008, had 104 contaminants: 93 chemicals or chemical groups and
11 microbiological contaminants out of the approximately 7500 chemicals and microbes evaluated.
Contaminants on the CCL are studied to determine how to detect them, whether they occur in
drinking water, what health effects they have, and how to remove them. As of July 2008 the EPA
had determined that no regulatory action is appropriate or necessary for 9 contaminants on CCL 1
and 11 on CCL 2.
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STANDARDS
EFFLUENT
EFFLUENT STANDARDS
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STANDARDS
EFFLUENT STANDARDS
EFFLUENT
The Clean Water A ct (CWA) is use d to reduce th e flow of pollu ta nts into
natural wate rcourse s. A ll poin t source discharge rs to natural w atercourses are
requ ired to obta in a National P ollution Discharge Elimination Syste m (N PD ES)
perm it (40C FR122). (B usine sses discha rging to a sew er system rather tha n a
natural w atercourse are not re quire d to obtain an NPD ES permit; howe ver, they
must obta in permits from th e munic ipa l treatment pla nts re ceiving t he w aste. )
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STANDARDS
EFFLUENT
Alth ough some de tractors have la beled these “ permits to continue polluting, ”
the pe rmitting system h as nevertheless h ad a major bene ficial effe ct on the
quality o f surface waters. Typical efflue nt sta ndards fo r a domestic wastewater
trea tme nt plant ra nge from 5 to 20 mg/L B OD , for e xample . The intent is to
tigh te n these limits as required to e nhance wa ter quality.
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SURFACE WATER
STANDARDS
QUALITY
SURFACE WATER
QUALITY STANDARDS
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SURFACE WATER QUALITY STANDARDS
SURFACE WATER
STANDARDS
QUALITY
STANDARDS
QUALITY
The next highest classification includes waters that have had wastes
discharged into them but that nevertheless exhibit high levels of
q u a l i t y. T h e c a t e g o r i e s c o n t i n u e i n o r d e r o f d e c r e a s i n g q u a l i t y, w i t h
the lowest water quality useful only for irrigation and transport.
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SURFACE WATER
STANDARDS
QUALITY
STANDARDS
QUALITY
❑SOFTENING
❑COAGULATION AND FLOCCULATION
❑SETTLING
❑FILTRATION
❑DISINFECTION
❑OTHER TREATMENT PROCESSES
❑ SOFTENING
⮚ Water softening is achieved either by adding chemicals that form insoluble precipitates or by ion exchange. Chemicals
used for softening include ammonia, borax, calcium hydroxide, or trisodium phosphate , usually in conjunction with
sodium carbonate
⮚ Water softening is a process in which the ions of calcium and sometimes irons are removed. By doing this, the water
softening removes the offending minerals from the water.
⮚ Hardness is caused by multivalent cations that dissolve from soils and rocks. Some water (both surface water and
groundwater) need hardness removed to use them a potable water source.
⮚ TOTAL HARDNESS (TH) is defined as the sum of the multivalent cations in the water.
⮚ Typical units for hardness are mg/L as CaCO and meq/L. To convert a concentration in mg/L to meq/L, divide the
concentration by the substances equivalent weight (EW).
⮚ A substance’s equivalent weight is calculated by dividing its atomic weight(AW) or molecular
weight (MW) by its valence or ionic charge (n, which is always positive).
To convert to the standard unit mg/L CaCO, the meq/L concentration is multiplied by the equivalent
weight of CaCO, which is 50.0 mg/meq.
Sample Problem: The concentration of calcium in a water sample is 100mg/L. What is the concentration in (a)
meq/L and (b) mg/L as CaCO3.
Solution: The valence or ionic charge of calcium is +2, so n is 2 eq/mol. Calcium’s atomic weight is 40.1g/mol. Therefore, its
equivalent is:
(a) The concentration in meq/L is then simply obtained through unit conversion
(b) Again, the concentration in mg/L as CaCO3 is simply obtained through unit conversion
❑ COAGULATION AND FLOCCULATION
⮚ Coagulation is the chemical alteration of the colloidal particles to make them stick together to form larger particles
called flocs. Raw surface water entering a water treatment plant usually has significant turbidity caused by tiny
(colloidal) clay and silt particles. These particles have a natural electrostatic charge that keeps them continually in
motion and prevents them from colliding and sticking together. Chemicals known as coagulants, such as alum
(aluminum sulfate), and coagulant aids, such as lime and polymers, are added to the water, first to neutralize the charge
on the particles and then to aid in making the tiny particles “sticky” so they can coalesce and form large, quick-settling
particles. The purpose is to clear the water of the suspended colloidal solids by building larger particles that readily
settle.
Solution: Graph the dose versus the turbidity (Figure 10.25). While the lowest turbidity is obtained at a dose of 2
mg/L, this turbidity is not much lower than the turbidity obtained at half that dose. In addition, the minimum point on
the curve may be between 1 and 2 mg/L. If time permits, it may be useful to run another test. However, since the dose
chosen is an estimate, the operator may try 1 mg/L in the plant and adjust the dosage as needed.
Why does the turbidity increase at higher polymer doses in the previous example? The net effect of
coagulation is to destabilize the colloidal particles so they have the propensity to grow into larger
particles. But too high of a coagulant dose or a coagulant aid dose will restabilize the particles by
creating positive (rather than negative) particles or creating particles with large surface areas and low
densities.
As mentioned previously, a metal salt used as a coagulant can affect the alkalinity of the water.
The relationship is 1 meq/L coagulant consumes 1 meq/L of alkalinity and generates 1 meq/L of
chemical sludge (10.10) The total sludge generated can be calculated as
▪ Uniform flow occurs within the settling tank. (This is the same as saying that there is ideal plug flow
because uniform flow is defined as a condition wherein all water flows horizontally at the same
velocity.)
▪ All particles settling to the bottom are removed. That is, as the particles drop to the bottom of the
column as depicted in Figure 10.28, they are removed from the flow.
▪ Particles are evenly distributed in the flow as they enter the settling tank.
▪ All particles still suspended in the water when the column of water reaches the far side of the tank are
not removed and escape the tank.
▪ As noted above, t is V/Q, where V = HWL, or if the surface area of the settling tank is defined as As =
W L, then V = AsH. Substituting yields
Problem : A water treatment plant settling tank has an overflow rate of 600 gal/day-ft2 and a depth of 6 ft. What is its
retention time?
SOLUTION:
Problem : A water treatment plant settling tank has an overflow rate of 600 gal/day-ft2 and a depth of 6 ft. What is its
retention time?
SOLUTION:
❑FILTRATION
⮚ During filtration, the clear water passes through filters that have different pore sizes and are made of different
materials. These filters remove dissolved particles and germs, such as dust, chemicals, parasites, bacteria, and
viruses
⮚ The rapid sand filter or rapid gravity filter is a type of filter used in water purification and is commonly used in
municipal drinking water facilities as part of a multiple stage treatment system. The operation of a rapid sand
filter involves two phases: filtration and washing.
Solution: Chlorine demand is the dose required to reach the desired residual level. Therefore, the residual is the
difference between the chlorine applied and the chlorine demand.
Problem A: 4.5 mgd water treatment plant uses 21 lb/day of chlorine for disinfection. If the daily chlorine demand
is 0.5 mg/L, what is the daily chlorine residual?
Solution: Chlorine demand is the dose required to reach the desired residual level. Therefore, the residual is the
difference between the chlorine applied and the chlorine demand.
❑OTHER TREATMENT PROCESSES
▪ In addition to the treatment processes already discussed, there are other steps that may or may not have to be taken
before the water is distributed.
▪ Stable water is in chemical balance and will not cause corrosion or scaling in the distribution system. Two tests are
used to determine the stability of water—the Marble Test and the Langelier Index.
▪ Water is considered stable when it is saturated with calcium carbonate. Depending on the cause of the stability
problem, unstable water can be stabilized by using recarbonation, acid addition, phosphate addition, alkali addition, or
aeration. Unstable water from reactions in the distribution system can be prevented by providing a suitable chlorine
residual throughout the distribution system
▪ Taste, odor, and color complaints are the most common types of complaints received by water utilities.
▪ Prevention of T&O problems is the key to their control. Prevention takes the form of source water management and
plant and distribution system maintenance.
▪ Fluoridation of the water or fluoride removal may also be necessary. Fluoride prevents tooth decay, but at
concentrations above approximately 1.5 mg/L, it also stains teeth brown.
WATER QUALITY
ASSESSING WATER
QUALITY
WATER QUALITY
STANDARDS
WATER SUPPLY
AND TREATMENT
THE END OF THE SLIDE!
THANK YOU EVERYONE.
GODBLESS