Heat Exchanger
Catastrophic Failure
Tesoro Anacortes Refinery, WA April 2010
June 24th, 2023
© 2020 Chevron
Incident Description
What went wrong?
Business Unit / Site
• Tesoro Anacortes Refinery, WA April 2010
Facility/Process Unit
• Naphtha Hydrotreater heat exchanger shell rupture
• Heat exchanger - hot liquid introduction after maintenance
Consequences
• Release of hydrogen and hydrocarbon
• Hydrocarbon autoignition and explosion
• 7 fatalities
• 6-month downtime
• 90 minutes to put out the fire
©2019 Chevron. 2
Incident Description
What went wrong?
Gap Analysis
• API-941 standards provide guidance on operating limits
for steels in hydrogen service
• Investigation outcomes
Inadequate Controls and Safeguards were in place to
ensure that the exchangers were operating within safe
operating limits, i.e., below the Nelson Curve • Previous analysis indicated potential for High
Temperature Hydrogen Attack (HTHA) within the
exchangers and outlet piping.
• Lack of instruments (TI/PI) and Process Data on piping
between the exchangers
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TC&S
Technical Codes and Standards
• HTHA: H2 permeates the steel and reduces iron
carbide (Fe3C) in the steel to form methane (CH4),
causing fissuring between grains
• Fissuring: the ductility of the metal is significantly
and permanently reduced. The severity of hydrogen
attack increases with increasing temperature and
hydrogen partial pressure.
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Prevention Safeguards
Failure Analysis
!
Hazard
Ha
z ar d Ina
no De de
- Hydrocarbon
t re s ig qu
- High Temperature co nr ate Initial event
gn ev in
ize iew
RM FD&C De
TC&S sig
n
Failures in Preventive Safeguards: Wrong Material Selection
• Risk Assessment: Hazard not recognize
• Technical Codes and Standards: Insufficient application of
• HTHA not identified as potential failure mechanism Safety in Design
for the ‘B’ and ‘E’ exchangers
• Not provide Instrument to detect process operating data
• FD&C: Insufficient in HEX Engineering Design (TC&S)
(Process & Mechanic)
• Not provide Control and Safeguard (TC&S)
©2019 Chevron. 5