Module 1 Thermal (4)
Module 1 Thermal (4)
Module 1: Thermodynamics -
Fundamental Concepts & Definitions
Thermodynamics: definition and scope
• Thermodynamics can be defined as the
science of energy.
• One of the most fundamental laws of nature is
the conservation of energy principle.
• The second law of thermodynamics asserts
that energy has quality as well as quantity
• All activities in nature involve some interaction
between energy and matter; thus, it is hard to
imagine an area that does not relate to
thermodynamics in some manner.
• Other applications of thermodynamics are
right where one lives.
Microscopic and Macroscopic approaches
SYSTEMS AND CONTROL VOLUMES
• A system is defined as a quantity of matter or a
region in space chosen for study. The mass or
region outside the system is called the
surroundings. The real or imaginary surface that
separates the system from its surroundings is
called the boundary.
• Systems may considered to be closed or open,
depending on whether a fixed mass or a fixed
volume in space is chosen for study.
Thermodynamic properties
• Every system has certain characteristics by which its
physical condition may described. Such
characteristics are called properties of the system.
These properties are measurable characteristics of a
system that is in equilibrium.
• Properties may be intensive or extensive. Intensive –
Are independent of the amount of mass: e.g:
Temperature, Pressure, and Density,
Extensive – varies directly with the mass. e.g: mass,
volume, energy, enthalpy.
Specific properties
• The ratio of any extensive property of a
system to that of the mass of the system is
called an average specific value of that
property (also known as intensives property)
State, Equilibrium and Process
• State – a set of properties that describes the conditions
of a system. Eg. Mass m, Temperature T, volume V
• Thermodynamic equilibrium - system that maintains
thermal, mechanical, phase and chemical equilibriums.
• The number of properties required to fix the state of a
system is given by the state postulate:
The state of a simple compressible
system is completely specified
by two independent,
intensive properties.
Cont.
• Process – change from one equilibrium state
to another.
• When a process proceeds in such a manner
that the system remains infinitesimally close
to an equilibrium state at all times, it is called
a quasistatic, or quasi-equilibrium, process.
Types of Thermodynamics Processes
• Cyclic process - when a system
in a given initial state
goes through various processes
and finally return
to its initial state, the system
has undergone a cyclic
process or cycle.
• Reversible process - it is defined as a process that, once having
take place it can be reversed. In doing so, it leaves no change in
the system or boundary.
• Irreversible process - a process that cannot return both the system
and surrounding to their original conditions
• Adiabatic process - a process that has no heat transfer
into or out of the system. It can be considered to be
perfectly insulated.
• Isentropic process - a process where the entropy of the
fluid remains constant.
• Polytropic process - when a gas undergoes a reversible
process in which there is heat transfer, it is represented
with a straight line, PV^n = constant.
• Throttling process - a process in which there is no
change in enthalpy, no work is done and the process is
adiabatic.
Zeroth Law of Thermodynamics
• “ If two bodies are in thermal equilibrium with
a third body, they are also in thermal
equilibrium with each other.”
Work and Heat
Thermodynamic definition of work
Work, like heat, is an energy interaction between
a system and its surroundings.