AQUEOUS
SOLUTION
Formation of ions
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Dissociation
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NATURE OF AQUEOUS SOLUTIONS
Strong Weak
nonelectrolytes
electrolytes electrolytes
• Soluble salts • Weak acid • Pure water
• Strong acids • Weak base • Substance
• Strong base does not
produce ions
TYPES OF AQUEOUS CHEMICAL REACTION
Precipitation Reaction
Acid Bases Reaction
Oxidation Reaction
Imagination is more important
than knowledge. Knowledge is
limited. Imagination encircles the
world.
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PRECIPITATION
REACTION
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Objectives
To apply the general form of metathesis
reaction
To write the complete ionic equation
To eliminate the spectator ions
To write the net ionic equation
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DISSOCIATION AND SOLUBILITY
Solubility is defined as the maximum amount of a
substance that will dissolve in a given amount of solvent at
a specified temperature.
Dissociation occurs when an ionic compound is dissolved in
water due to interactions between the charges and the polarity
of atoms in the water molecule.
NaCl Na+ + Cl-
Ba(NO3)2 Ba2+ + NO3-
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Metathesis Reaction
AB + CD AD + CB
Double displacement Reaction
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PRECIPITATION REACTIONS
• Formation of a
solid from two
aqueous solutions
• Produce insoluble
ionic compounds,
called precipitate.
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Mixing Solutions of Pb(NO3)2 and NaI
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Predicting Reaction Products
1. KNO3 + BaCl2 Ba(NO3)2 + KCl
NaNO3 + PbSO4
2. Na2SO4 + Pb(NO3)2
KNO3 + Fe(OH)3
3. KOH + Fe(NO3)3
Write the equation
Pb(NO3)2 (aq) + 2NaI(aq) → 2NaNO3 (aq) + PbI2(s)
(s) = insoluble
(aq) = soluble
(l) = liquid
(g)= gases
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Molecular equation: shows all compounds
represented by their chemical formulas
Complete Ionic equation: shows all strong
electrolytes as ions and all other substances
(non- electrolytes, weak electrolytes, gases) by
their chemical formulas
+
+
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Net Ionic equation: shows only the reacting
species in the chemical equation
– Eliminates spectator ions
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STEPS IN WRITING A NET IONIC EQUATION
1. Predict products by exchanging cations
and anions in reactants.
2. Write the balanced molecular equation.
3. Separate strong electrolytes into ions.
(Complete Ionic Equation)
4. Cancel spectator ions.
5. Use the remaining species to write the net
ionic equation.
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Aqueous solutions of silver nitrate and
sodium sulfate are mixed. Write the net
ionic reaction.
2AgNO3(aq)+Na2SO4(aq) → 2NaNO3( )+Ag2SO4( )
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Step 2: Use solubility table; all nitrates
are soluble but silver sulfate is insoluble
2Ag+(aq) + 2NO3−(aq) + 2Na+(aq) + SO42−(aq)
→ 2Na+(aq) + 2NO3−(aq) + Ag2SO4(s)
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Step 3: Cancel spectators
2Ag+(aq) + 2NO3−(aq) + 2Na+(aq) + SO42−(aq)
→ 2Na+(aq) + 2NO3−(aq) + Ag2SO4(s)
Step 4: Write the net ionic reaction
2Ag+(aq) + SO42−(aq) → Ag2SO4(s)
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Aqueous Cobalt chloride and aqueous sodium
sulphate
Molecular equation
CoCl2(aq)+Na2SO4(aq)→CoSO4(aq)+2NaCl(aq)
Complete ionic equation
Co2- (aq) + 2Cl-(aq) + 2Na+ (aq) + SO42-(aq)
→ Co2- (aq) + SO42-(aq) + 2Na+ (aq) + 2Cl-(aq)
Net ionic equation
No reaction
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