IOSR Journal of Electronics and Communication Engineering (IOSR-JECE)
e-ISSN: 2278-2834,p- ISSN: 2278-8735.Volume 10, Issue 4, Ver. I (Jul - Aug .2015), PP 01-03
www.iosrjournals.org
DOI: 10.9790/2834-10410103 www.iosrjournals.org 1 | Page
Superconducting Behaviour of Carbon Nanotube (CNTS)
*Kanchan Kumar and **D.N. Singh
*Faculty; Dept.of Physics, MahilacollegeGodda (S.K.M.U.Dumka)
**Asst.Professor, Dept. of Physics, S.P.collegeDumka (S.K.M.U.Dumka)
Abstract: In our present article the concentration is given to the superconducting behaviour of CNTs. The
superconductivity of a material depends on transition temperature Tc. the impact of coulomb interaction is also
taken into account. A theory have been developed with resistivity and coherence length from the earlier
experimental curve between transition temperature and resistivity for a single wall nanotube.The curvature of
CNTs leads to the creation of new electron –phonon interaction can introduce superconductivity. In this part the
resistivity of carbon nanotube has been derived theoretically with relaxation time and Fermi velocity.
Keywords: 1transition temperature, 2coherance length, 3coulomb interaction, 4electron –phonon interaction
I. Introduction
In our recent development of nanotechnology CNTs are studied in different arena. The conductivity of
nanotubes have been determined by a number of workers. The superconductivity is to be discussed along that
way. It is familiar the superconductivity of a material depends on transition temperature Tc. it is the main task
before the workers how to decrease the temperature and to bring at transition point where the resistivity comes
to zero.
From the experiment between the transition temperature and resistivity, several curves appear in the
graph for a single wall nanotube [1].when the curvature of CNTs leads to the creation of new electron-phonon
scattering channels and consequent attractive electron phonon interactions [2] can induce superconductivity. It
means with rise in transition temperature, resistivity initially increases. However at a certain value of Tc,
resistivity comes down. The impact of coulomb interaction have been also introduced with resistivity.The
present article consists of introduction in section (I) a model (theory an technique) in section (II) result and
discussion in section (III), conclusion in section (IV), acknowledgement in section (V) and references in section
(VI).
(I) Model:
Let a nanotube of length ξ resistance R resistivity ρ for a certain range.
ρ ∝Tc (x≤a) ………………………………………..(1)
And ρ ∝
1
Tc
(x ≥ a)……………………………. .(2)
Where Tc is the transition temperature
Since resistivity, ρ=RA ξ……………………… .(3)
Where ξ is a coherence length
From Bardeen-cooper-schriffer (BCS) a coherence length with a superconducting gap, △ and Fermi velocity vf
is
ξ=
ℏvflmfp
△
Where lmfp=mean free path=λ (conveniencially)
ξ=
ℏvfλ
△
Superconducting behaviour of carbon nanotube (CNTs)
DOI: 10.9790/2834-10410103 www.iosrjournals.org 2 | Page
From eqn.(3) ρ=
RA
ℏvfλ
△
………………………………….(4)
If the coulomb interaction ie.interaction between electron-electron, a resistance may occur say Rc then eqn.(4) is
rewritten as
ρ=
(Rc +R)A
ℏvfλ
△
In superconducting state, coulomb interaction will be unaffected. So the resistance Rc is neglected i.e.
ρ=
RA
ℏvfλ
△
………………… (5)
If m is the mass of an electron, n, the number of electrons and τ is the relaxation time and A is the cross
sectional area of the nanotube.
A=πr2
= π [
2r
2
]2
== π [
dt
2
]2
= πdt
2
4
Where dt is the tube diameter,i.e.
dt==
□ 𝟑
□
(m2
+mn+n2
)12
here m and n are integers.
From eqn (5)
ρ =R
□ 𝟑
□
(m2+mn +n2)12
ℏvfλ
………………………(6)
In our general idea, the resistance with relaxation time τ is related to
R∝
1
τ
R=
k
τ
where k is a constant.
From eqn. (6)
ρ =
k
τ
□ 𝟑
□
(m2+mn +n2)12
ℏvfλ
………………….(7)
Where k is a constant
Fig. a graph between resistivity and temperature.
Superconducting behaviour of carbon nanotube (CNTs)
DOI: 10.9790/2834-10410103 www.iosrjournals.org 3 | Page
II. Result And Discussion
A Tc of~0.55k was measured [*]3 in ropes of SWNTs. Δ =1.76KBTc~85μev and a coherence length
ξ=300nm was inferred.
For a mean free path length, λ of 18nm and a Fermi velocity, vf of 8.0× 105
ms.
A higher Tc of 15k was reported [*4] in 04nm SWNTs embedded in a zeolite Matrix, accompanied by the
observation of an anisotropic Meissner effect, characteristic to one dimension.
Such an effect is very intriguing in that a strictly one-dimensional system is unstable to any fluctuations and true
superconducting behaviour can also be observed at T=0k.
It was also shown that [5] superconductivity could be induced in a metallic nanotube bundle in close
proximity with a superconducting electrode on a characteristic length scale, bounded by both the phase
coherence length and the thermal diffusion length. Induced superconductivity was inferred through the existence
of Josephson supercurrents, with a magnitude exceeding the theoretically predicted value of
π∆
eRN
RN is the
resistance of the junction. It is hypothesized that the superconducting state in the nanotube could have been
stabilized by the microscopic superconductivity of the contacts, tuned by varying a backside gate voltage Vg.
Contacts were varied between high and low transparency to incident electrons.
An incident electron at the contact is converted into a cooper pair with the concomitant introduction of
a reflected hole. In this case contacts are relatively opaque to the incident current.
In I-V characteristics with electron-electron interaction lead to non- superconducting state. The
superconducting behaviour shows at low temperature.
In our theoretically derived formula eqn.(7) consists of relaxation time, c is to be measured
experimentally. In earlier result relaxation time was not considered. It might be merged with some constant.
More- over, coulomb interaction have also been neglected.
III. Conclusion
When there is interaction between electro –electron, the relaxation time τ decreases.it tends to produce larger
resistivity. If weak interaction be managed so that the Fermi velocity increases. Through this way the resistivity
tends to decrease and leads to superconducting behaviour.
Acknowledgement
we would like to thankPh.D candidate Mr.Rajesh Kumar Yadav(Dept. of Physics, S.K.M.U,Dumka) a
research scholar (B.H.U. Varanasi) who inspired me for creative work and care of my supervisor Dr.D.N.
Singh(Dept. of Physics, S.K.M.U,Dumka)who gave the leading roles, have deeply affected me.
References
[1]. L.X.Benedict,V.H.Crespy.S.G.Louie, and M.L. Cohen, Phys.Rev.B 52, 14935(1995).
[2]. M.Tinkham, introduction to superconductivity, Dover Publications Inc.Mineola. NY(2004).
[3]. M.Kociak, A.Y.Kasumov.S.Gueron.B.Reulet.L.I.Khodos,Y.B.Gorbatov, V.T.Volkov.L.Vaccarini, and H.Bouchiat,
Phys.Rev.Lett.86.2416(2001).
[4]. Z.K.Tang.L.Zhang,N. Wang, X.X.Zhng. G.H. Wen, G.D.LiJ.N.Wang. C.T. chan, and P.sheng. science 292,2462 (2001).

A010410103

  • 1.
    IOSR Journal ofElectronics and Communication Engineering (IOSR-JECE) e-ISSN: 2278-2834,p- ISSN: 2278-8735.Volume 10, Issue 4, Ver. I (Jul - Aug .2015), PP 01-03 www.iosrjournals.org DOI: 10.9790/2834-10410103 www.iosrjournals.org 1 | Page Superconducting Behaviour of Carbon Nanotube (CNTS) *Kanchan Kumar and **D.N. Singh *Faculty; Dept.of Physics, MahilacollegeGodda (S.K.M.U.Dumka) **Asst.Professor, Dept. of Physics, S.P.collegeDumka (S.K.M.U.Dumka) Abstract: In our present article the concentration is given to the superconducting behaviour of CNTs. The superconductivity of a material depends on transition temperature Tc. the impact of coulomb interaction is also taken into account. A theory have been developed with resistivity and coherence length from the earlier experimental curve between transition temperature and resistivity for a single wall nanotube.The curvature of CNTs leads to the creation of new electron –phonon interaction can introduce superconductivity. In this part the resistivity of carbon nanotube has been derived theoretically with relaxation time and Fermi velocity. Keywords: 1transition temperature, 2coherance length, 3coulomb interaction, 4electron –phonon interaction I. Introduction In our recent development of nanotechnology CNTs are studied in different arena. The conductivity of nanotubes have been determined by a number of workers. The superconductivity is to be discussed along that way. It is familiar the superconductivity of a material depends on transition temperature Tc. it is the main task before the workers how to decrease the temperature and to bring at transition point where the resistivity comes to zero. From the experiment between the transition temperature and resistivity, several curves appear in the graph for a single wall nanotube [1].when the curvature of CNTs leads to the creation of new electron-phonon scattering channels and consequent attractive electron phonon interactions [2] can induce superconductivity. It means with rise in transition temperature, resistivity initially increases. However at a certain value of Tc, resistivity comes down. The impact of coulomb interaction have been also introduced with resistivity.The present article consists of introduction in section (I) a model (theory an technique) in section (II) result and discussion in section (III), conclusion in section (IV), acknowledgement in section (V) and references in section (VI). (I) Model: Let a nanotube of length ξ resistance R resistivity ρ for a certain range. ρ ∝Tc (x≤a) ………………………………………..(1) And ρ ∝ 1 Tc (x ≥ a)……………………………. .(2) Where Tc is the transition temperature Since resistivity, ρ=RA ξ……………………… .(3) Where ξ is a coherence length From Bardeen-cooper-schriffer (BCS) a coherence length with a superconducting gap, △ and Fermi velocity vf is ξ= ℏvflmfp △ Where lmfp=mean free path=λ (conveniencially) ξ= ℏvfλ △
  • 2.
    Superconducting behaviour ofcarbon nanotube (CNTs) DOI: 10.9790/2834-10410103 www.iosrjournals.org 2 | Page From eqn.(3) ρ= RA ℏvfλ △ ………………………………….(4) If the coulomb interaction ie.interaction between electron-electron, a resistance may occur say Rc then eqn.(4) is rewritten as ρ= (Rc +R)A ℏvfλ △ In superconducting state, coulomb interaction will be unaffected. So the resistance Rc is neglected i.e. ρ= RA ℏvfλ △ ………………… (5) If m is the mass of an electron, n, the number of electrons and τ is the relaxation time and A is the cross sectional area of the nanotube. A=πr2 = π [ 2r 2 ]2 == π [ dt 2 ]2 = πdt 2 4 Where dt is the tube diameter,i.e. dt== □ 𝟑 □ (m2 +mn+n2 )12 here m and n are integers. From eqn (5) ρ =R □ 𝟑 □ (m2+mn +n2)12 ℏvfλ ………………………(6) In our general idea, the resistance with relaxation time τ is related to R∝ 1 τ R= k τ where k is a constant. From eqn. (6) ρ = k τ □ 𝟑 □ (m2+mn +n2)12 ℏvfλ ………………….(7) Where k is a constant Fig. a graph between resistivity and temperature.
  • 3.
    Superconducting behaviour ofcarbon nanotube (CNTs) DOI: 10.9790/2834-10410103 www.iosrjournals.org 3 | Page II. Result And Discussion A Tc of~0.55k was measured [*]3 in ropes of SWNTs. Δ =1.76KBTc~85μev and a coherence length ξ=300nm was inferred. For a mean free path length, λ of 18nm and a Fermi velocity, vf of 8.0× 105 ms. A higher Tc of 15k was reported [*4] in 04nm SWNTs embedded in a zeolite Matrix, accompanied by the observation of an anisotropic Meissner effect, characteristic to one dimension. Such an effect is very intriguing in that a strictly one-dimensional system is unstable to any fluctuations and true superconducting behaviour can also be observed at T=0k. It was also shown that [5] superconductivity could be induced in a metallic nanotube bundle in close proximity with a superconducting electrode on a characteristic length scale, bounded by both the phase coherence length and the thermal diffusion length. Induced superconductivity was inferred through the existence of Josephson supercurrents, with a magnitude exceeding the theoretically predicted value of π∆ eRN RN is the resistance of the junction. It is hypothesized that the superconducting state in the nanotube could have been stabilized by the microscopic superconductivity of the contacts, tuned by varying a backside gate voltage Vg. Contacts were varied between high and low transparency to incident electrons. An incident electron at the contact is converted into a cooper pair with the concomitant introduction of a reflected hole. In this case contacts are relatively opaque to the incident current. In I-V characteristics with electron-electron interaction lead to non- superconducting state. The superconducting behaviour shows at low temperature. In our theoretically derived formula eqn.(7) consists of relaxation time, c is to be measured experimentally. In earlier result relaxation time was not considered. It might be merged with some constant. More- over, coulomb interaction have also been neglected. III. Conclusion When there is interaction between electro –electron, the relaxation time τ decreases.it tends to produce larger resistivity. If weak interaction be managed so that the Fermi velocity increases. Through this way the resistivity tends to decrease and leads to superconducting behaviour. Acknowledgement we would like to thankPh.D candidate Mr.Rajesh Kumar Yadav(Dept. of Physics, S.K.M.U,Dumka) a research scholar (B.H.U. Varanasi) who inspired me for creative work and care of my supervisor Dr.D.N. Singh(Dept. of Physics, S.K.M.U,Dumka)who gave the leading roles, have deeply affected me. References [1]. L.X.Benedict,V.H.Crespy.S.G.Louie, and M.L. Cohen, Phys.Rev.B 52, 14935(1995). [2]. M.Tinkham, introduction to superconductivity, Dover Publications Inc.Mineola. NY(2004). [3]. M.Kociak, A.Y.Kasumov.S.Gueron.B.Reulet.L.I.Khodos,Y.B.Gorbatov, V.T.Volkov.L.Vaccarini, and H.Bouchiat, Phys.Rev.Lett.86.2416(2001). [4]. Z.K.Tang.L.Zhang,N. Wang, X.X.Zhng. G.H. Wen, G.D.LiJ.N.Wang. C.T. chan, and P.sheng. science 292,2462 (2001).