CARBON COMPOUNDS
Made By:- Shivansh Singh
Class:- 10th ‘E’
CARBON COMPOUNDS
Carbon Compounds are compounds that contain
Carbon as one of their constituent elements
Carbon Compound
Organic Compound
-Carbon containing compounds
except oxides of carbon, carbonates,
syanides and metallic carbides
Hydrocarbon
-contain Carbon and
Hydrogen only
Alkanes
(saturated
hydrocarbons)
-contain only single
bond
Alkenes
(unsaturated
hydrocarbons)
-contain at least one
multiple bond
Non-hydrocarbon
-contain C,H and
O,N,P,S,F,Cl,Br,I
Alcohols
Carboxylic
acids
Esters
Inorganic Compound
-non-carbon
containing
compounds
Organic compound
Inorganic Carbon
compound
Similarity
Both contain carbon atoms
Diffenrences
Examples
Origin
Effect of heat
Solubility
Protein, fats, cellulose, natural
rubber, petroleum
Formed from living thing
Have low boiling points and
low melting point
Dissolve in organic solvents
such as ether, petrol, alcohol
and chloroform
Carbon dioxide, carbon
monoxide
Formed from minerals
Have high boiling points and
high melting point
Dissolve in inorganic solvents
such as ether, water, acids and
alkalis
Hydrocarbons
Hydrocarbons are organic compound that
contain only Carbon and Hydrogen
Natural sources of hydrocarbons:
• Petroleum
• Coal
• Natural gas
• Rubber trees
B: ALKANES
General Formula : CnH2n+2 , n=1,2,3…
Naming alkanes:
Number
of
Carbon
atoms
1 2 3 4 5 6 7 8 9 10
Root
name
Meth- Eth- Prop- But- Pent- Hex- Hept- Oct- Non- Dec-
Final
name
Methane Ethane Propane Butane Pentane Hexane Heptane Octane Nonane Decane
Structural Formula shows how the atoms in a
molecule are bonded together and by what types
of bonds
Example :
Ethane
C2H6
molecular formula structural formula
Physical
properties
of alkanes
Cannot
conduct
electricity
Insoluble in
water
Low melting
and boiling
points-
dissolve in
organic
solvents
Less dense
than water
because the molecules are held
together by weak intermolecular
forces which can be overcome by
small amount of energy
Chemical properties of alkanes
a) Combustion
1. Complete combustion
Alkanes burn in air to form carbon dioxide and water
CH4 (g) + 2O2(g) CO2 (g) + 2H2O(l)
More soot is given off when a higher alkane is burnt.
For example, the burning of heptane produce more
soot than the burning of ethane
2. Incomplete combustion
If insufficient oxygen available, carbon monoxide or even
carbon may be formed
2CH4 (g) + 3O2(g) 2CO (g) + 4H2O(l)
CH4 (g) + O2(g) C (s) + 2H2O(l)
b) Halogenation
-Reaction of alkanes with halogens.
-readily takes place in sunlight (not occur in the dark)
-carbon-hydrogen bonds are broken and new
carbon-halogens bonds are formed
-is a substitution reaction
occurs when one atom or a group of atoms in a
molecule is replaced by another atom or group of
atoms
-Example:
when a mixture of CH4 and chlorine is exposed to
ultraviolet light, 4 different products are formed
• CH4 (g) + Cl2(g) CH3Cl (g) + HCl(l)
Chloromethane hydrogen chloride
C: ALKENES
is a hydrocarbons containing at least one carbon-carbon double
bond
General Formula : CnH2n , n=2,3,4…
Naming alkenes:
Number
of
Carbon
atoms
2 3 4 5 6 7 8 9 10
Root
name
Eth- Prop- But- Pent- Hex- Hept- Oct- Non- Dec-
Final
name
Ethene Propene But-1-ene Pent-1-ene Hex-1-ene Hept-1-ene Oct-1-ene Non-1-ene Dec-1-ene
Structural formula of alkenes
Ethene: C2H4
Propene : C3H6
Physical
properties
of alkenes
Low melting
and boiling
point
Soluble in
organic
solvents
Insoluble in
water
Less dense than
water
Cannot conduct
electricity at
any state
Chemical
properties
of alkenes
(a)Combustion
reaction
(b)Addition
reaction
(c)
Polymerization
reaction
(i)Addition of hydrogen
(ii)Addition of halogens(halogenation)
(iii) Addition of hydrogen halides
(HCl, HBr, HI)
(iv) Addition of water (hydration)
(v) Addition of hydroxyl groups
Chemical properties of alkenes
a) Combustion reaction
Alkenes burn in excess oxygen to form carbon
dioxide and water
C2H4 (g) + 3O2(g) 2CO2 (g) + 2H2O(l)
Alkenes burn with sootier flames as compared to
alkanes because alkenes have a higher percentage
of carbon in their molecules than alkanes
b) Addition reaction
(i) Addition of hydrogen
This process is called catalytic hydrogenation
(ii) Addition of halogens (halogenation)
Observation: reddish-brown bomine is decolourised
and colourless liquid is formed
This reaction is used as a test for the presence of
a carbon-carbon double bond in organic molecules
(iii) Addition of hydrogen halides(HCl, HBr, HI)
• (iv) Addition of water (hydration)
(v) Addition of hydroxyl groups
Observation: purple solution of potassium
manganate (VII) is decolourized
c) Poymerization reaction
Homologous Series
A group or family of organic compounds that has the following
characteristics:
a) Members of the series can be represented by a general formula
b) Successive members differ from each other by –CH2
c) Members can be prepared by similar methods
d) Physical properties change regularly with increasing number of
carbon atoms
e) Members have similar chemical properties because they have the
same functional group
functional group :
-a special group of atoms attached to an organic mlecule
-determines the chemical properties of the molecule
-chemical reactions occur at the functional group
5 homologous series learnt in this
chapter:
Homologous
series
General formula Functional Group
Alkane CnH2n+2 , n=1,2,3… Carbon-carbon single
bond, C-C
Alkene CnH2n , n=2,3,4… Carbon-carbon double
bond, C=C
Alcohol CnH2n+1OH ,n=1,2,3… Hydroxyl group, -OH
Carboxylic Acid CnH2n+1 COOH ,n=0,1,2,… Carboxyl group, -COOH
Ester CnH2n+1 COOCmH2m+1,
n=0,1,2,…
m=1,2,3…
Carboxylate group, -COO-
First member
Second member
Third member
…..
…..
…..
As the number of
carbon atoms per
molecule increases:
•Melting point
increases
•Boiling point increases
•Volatility decreases
•Density increases
Descending
homologous series
D: ISOMERISM
Isomerism is a phenomenon whereby 2 or more
molecules are found to have same molecular
formula but different structural formula
Isomers: molecules with the same molecular
formula but with different structural
formula
• Example: C4H10
Steps to draw structural formula of isomers of
alkanes
Draw all the possible straight- chain and branched-chain carbon
skeletons
Place single bonds around every carbon atom. Ensure that each
carbon atom has 4 bonds
Place a hydrogen atom at each of the single bonds
Naming carboxylic acids
Find the longest continuous carbon chain containing the carboxyl
group
Name this longest chain by replacing the ending –e of the
corresponding alkane with –oic acid
Number the carbon atoms in this longest chain beginning at the
carboxyl group
Locate and name the attached alkyl group
Complete the name for the carboxylic acid molecule by combining
the 2 component parts together
Carbon compound

Carbon compound

  • 1.
    CARBON COMPOUNDS Made By:-Shivansh Singh Class:- 10th ‘E’
  • 2.
    CARBON COMPOUNDS Carbon Compoundsare compounds that contain Carbon as one of their constituent elements
  • 3.
    Carbon Compound Organic Compound -Carboncontaining compounds except oxides of carbon, carbonates, syanides and metallic carbides Hydrocarbon -contain Carbon and Hydrogen only Alkanes (saturated hydrocarbons) -contain only single bond Alkenes (unsaturated hydrocarbons) -contain at least one multiple bond Non-hydrocarbon -contain C,H and O,N,P,S,F,Cl,Br,I Alcohols Carboxylic acids Esters Inorganic Compound -non-carbon containing compounds
  • 4.
    Organic compound Inorganic Carbon compound Similarity Bothcontain carbon atoms Diffenrences Examples Origin Effect of heat Solubility Protein, fats, cellulose, natural rubber, petroleum Formed from living thing Have low boiling points and low melting point Dissolve in organic solvents such as ether, petrol, alcohol and chloroform Carbon dioxide, carbon monoxide Formed from minerals Have high boiling points and high melting point Dissolve in inorganic solvents such as ether, water, acids and alkalis
  • 5.
    Hydrocarbons Hydrocarbons are organiccompound that contain only Carbon and Hydrogen Natural sources of hydrocarbons: • Petroleum • Coal • Natural gas • Rubber trees
  • 6.
    B: ALKANES General Formula: CnH2n+2 , n=1,2,3… Naming alkanes: Number of Carbon atoms 1 2 3 4 5 6 7 8 9 10 Root name Meth- Eth- Prop- But- Pent- Hex- Hept- Oct- Non- Dec- Final name Methane Ethane Propane Butane Pentane Hexane Heptane Octane Nonane Decane
  • 7.
    Structural Formula showshow the atoms in a molecule are bonded together and by what types of bonds Example : Ethane C2H6 molecular formula structural formula
  • 8.
    Physical properties of alkanes Cannot conduct electricity Insoluble in water Lowmelting and boiling points- dissolve in organic solvents Less dense than water because the molecules are held together by weak intermolecular forces which can be overcome by small amount of energy
  • 9.
    Chemical properties ofalkanes a) Combustion 1. Complete combustion Alkanes burn in air to form carbon dioxide and water CH4 (g) + 2O2(g) CO2 (g) + 2H2O(l) More soot is given off when a higher alkane is burnt. For example, the burning of heptane produce more soot than the burning of ethane 2. Incomplete combustion If insufficient oxygen available, carbon monoxide or even carbon may be formed 2CH4 (g) + 3O2(g) 2CO (g) + 4H2O(l) CH4 (g) + O2(g) C (s) + 2H2O(l)
  • 10.
    b) Halogenation -Reaction ofalkanes with halogens. -readily takes place in sunlight (not occur in the dark) -carbon-hydrogen bonds are broken and new carbon-halogens bonds are formed -is a substitution reaction occurs when one atom or a group of atoms in a molecule is replaced by another atom or group of atoms
  • 11.
    -Example: when a mixtureof CH4 and chlorine is exposed to ultraviolet light, 4 different products are formed • CH4 (g) + Cl2(g) CH3Cl (g) + HCl(l) Chloromethane hydrogen chloride
  • 13.
    C: ALKENES is ahydrocarbons containing at least one carbon-carbon double bond General Formula : CnH2n , n=2,3,4… Naming alkenes: Number of Carbon atoms 2 3 4 5 6 7 8 9 10 Root name Eth- Prop- But- Pent- Hex- Hept- Oct- Non- Dec- Final name Ethene Propene But-1-ene Pent-1-ene Hex-1-ene Hept-1-ene Oct-1-ene Non-1-ene Dec-1-ene
  • 14.
    Structural formula ofalkenes Ethene: C2H4 Propene : C3H6
  • 15.
    Physical properties of alkenes Low melting andboiling point Soluble in organic solvents Insoluble in water Less dense than water Cannot conduct electricity at any state
  • 16.
    Chemical properties of alkenes (a)Combustion reaction (b)Addition reaction (c) Polymerization reaction (i)Addition ofhydrogen (ii)Addition of halogens(halogenation) (iii) Addition of hydrogen halides (HCl, HBr, HI) (iv) Addition of water (hydration) (v) Addition of hydroxyl groups
  • 17.
    Chemical properties ofalkenes a) Combustion reaction Alkenes burn in excess oxygen to form carbon dioxide and water C2H4 (g) + 3O2(g) 2CO2 (g) + 2H2O(l) Alkenes burn with sootier flames as compared to alkanes because alkenes have a higher percentage of carbon in their molecules than alkanes
  • 18.
    b) Addition reaction (i)Addition of hydrogen This process is called catalytic hydrogenation
  • 19.
    (ii) Addition ofhalogens (halogenation) Observation: reddish-brown bomine is decolourised and colourless liquid is formed This reaction is used as a test for the presence of a carbon-carbon double bond in organic molecules
  • 20.
    (iii) Addition ofhydrogen halides(HCl, HBr, HI)
  • 21.
    • (iv) Additionof water (hydration)
  • 22.
    (v) Addition ofhydroxyl groups Observation: purple solution of potassium manganate (VII) is decolourized
  • 23.
  • 24.
    Homologous Series A groupor family of organic compounds that has the following characteristics: a) Members of the series can be represented by a general formula b) Successive members differ from each other by –CH2 c) Members can be prepared by similar methods d) Physical properties change regularly with increasing number of carbon atoms e) Members have similar chemical properties because they have the same functional group functional group : -a special group of atoms attached to an organic mlecule -determines the chemical properties of the molecule -chemical reactions occur at the functional group
  • 25.
    5 homologous serieslearnt in this chapter: Homologous series General formula Functional Group Alkane CnH2n+2 , n=1,2,3… Carbon-carbon single bond, C-C Alkene CnH2n , n=2,3,4… Carbon-carbon double bond, C=C Alcohol CnH2n+1OH ,n=1,2,3… Hydroxyl group, -OH Carboxylic Acid CnH2n+1 COOH ,n=0,1,2,… Carboxyl group, -COOH Ester CnH2n+1 COOCmH2m+1, n=0,1,2,… m=1,2,3… Carboxylate group, -COO-
  • 26.
    First member Second member Thirdmember ….. ….. ….. As the number of carbon atoms per molecule increases: •Melting point increases •Boiling point increases •Volatility decreases •Density increases Descending homologous series
  • 27.
    D: ISOMERISM Isomerism isa phenomenon whereby 2 or more molecules are found to have same molecular formula but different structural formula Isomers: molecules with the same molecular formula but with different structural formula
  • 28.
  • 29.
    Steps to drawstructural formula of isomers of alkanes Draw all the possible straight- chain and branched-chain carbon skeletons Place single bonds around every carbon atom. Ensure that each carbon atom has 4 bonds Place a hydrogen atom at each of the single bonds
  • 30.
    Naming carboxylic acids Findthe longest continuous carbon chain containing the carboxyl group Name this longest chain by replacing the ending –e of the corresponding alkane with –oic acid Number the carbon atoms in this longest chain beginning at the carboxyl group Locate and name the attached alkyl group Complete the name for the carboxylic acid molecule by combining the 2 component parts together