woodplc.com
Modelling Waxy Fluids in
Multiflash
Mehwish Manzoor and Jessy Zeng
18th June 2018
• Wax Management / Control
• Wax Deposition and Risks
• Modelling Waxy Fluids in Multiflash
• Case Study
– Fluid Characterisation
– Wax Content Tuning
– WAT and WDT Tuning
– Benchmarking
• Conclusion
Agenda
2 A presentation by Wood.
Wax Management / Control
3
General Approach to Control of Wax Issues
Wax Management / Control
4 A presentation by Wood.
Pigging < Insulation
Chemical
Operational
> Insulation
Heating
RISK
CAPEX / OPEX
Wax Deposition and Risks
5
• High molecular weight paraffins (typically n-C17+)
Wax in Fluids
6 A presentation by Wood.
Higher Molecular
Weight
Quickest
Precipitation
• Molecular Diffusion is the dominant wax deposition mechanism
• Radial diffusion of dissolved wax molecules in the oil
• Concentration gradient between dissolved wax in the turbulent
core and the wax in solution at the pipe wall
• Dissolved wax diffuses towards the wall where it precipitates
Wax Deposition (Molecular Diffusion)
7 A presentation by Wood.
Wax Deposition Risks
8 A presentation by Wood.
Reduction in Delivery
• Reduction in flow area
• Increased Pressure Drop
• Change in wall friction
• Change in fluid viscosity
Pipeline Integrity
• Trapped H2O may corrode
pipeline
Remediation Required
• Loss of production
• Risk of “stuck” pigs – long shutdowns
• Additional topsides equipment
required (i.e. chemicals plus
processing)
Wax Deposition Risks
9 A presentation by Wood.
Reduction in Delivery
• Reduction in flow area
• Increased Pressure Drop
• Change in wall friction
• Change in fluid viscosity
Pipeline Integrity
• Trapped H2O may corrode
pipeline
Remediation Required
• Loss of production
• Risk of “stuck” pigs – long shutdowns
• Additional topsides equipment
required (i.e. chemicals plus
processing)
Fluid characterisation and tuning
against lab data is crucial to
accurately predict the likely wax
deposition in field operation.
Modelling Waxy Fluids in Multiflash
10
Wax Model in Multiflash
11 A presentation by Wood.
Coutinho Wax Model
Solid wax phase treated as non-ideal mixture of n-paraffins
Equation of State
RKSA / CPA-InfoChem
Minimal difference in prediction of wax phase behaviour in crude oils
Viscosity
Default - SuperTRAPP
Oil Systems – Pedersen (Heavy Oils) is good
Input Data Required for Modelling Waxy Fluids
12 A presentation by Wood.
Compositional Analysis
Data
• Fluid Composition
• Calculated Sample Properties
(i.e. MW and Density)
N-Paraffin Distribution
• HTGC
• Wax Content
Wax Appearance
Temperature
Additional Data for Modelling Waxy Fluids
13 A presentation by Wood.
Wax Dissolution
Temperature
Saturates,
Aromatics, Resins
and Asphaltenes
Analysis
PVT Report
Density, Sat. Point,
GOR, Viscosity
Tuned
Thermodynamic
Fluid File
Steady State OLGA
Simulation
Wax Deposition Modelling Procedure
14 A presentation by Wood.
N-Paraffin
Distribution
Wax Content, WAT,
WDT, Viscosity
Tuned
N-Paraffin Fluid
File
Wax Deposition
OLGA Simulation
Case Study
North Sea Wax Deposition Study
15
North Sea Wax Deposition Study
Identification of a Suitable Wax Management Strategy
16 A presentation by Wood.
Scope
Benchmarking of Existing Pipeline
Future Operation of New Oil Export Route
Platform 3
Benchmarking Case
Future Operation
Platform 2Platform 1
Fluid Characterisation
17 A presentation by Wood. Real
ComponentsIso-ParaffinsN-Paraffins
• Lab Data = 5.0 wt%
• N-Alkane Distribution (n-C20+) = 3.99 wt%
• Predicted Wax Content @ -30 °C = 4.05 wt%
Wax Content Tuning
18 A presentation by Wood.
WAT and WDT Tuning Approach
19 A presentation by Wood.
Lab Test Methods
Cross Polar Microscopy
Differential Scanning Calorimetry
WAT and WDT Tuning
Client Request
Less Conservative
WAT Tuning Only
Preferred Method
Allows Prediction of WDT
Fluid Laboratory Results Model Prediction
WAT (°C) WDT (°C) WAT (°C) WDT (°C)
1 36.9 53.3 36.4 53.7
2 38.7 48.9 38.4 49.3
WAT and WDT Tuning
20 A presentation by Wood.
40.7
7.3
40.7
7.3
0
5
10
15
20
25
30
35
40
45
Export Temperature Arrival Temperature
Temperature(°C)
Benchmarking - Temperature
Operational Data Simulation Result
Benchmarking – Pressure and Temperature
21 A presentation by Wood.
22.5
18.76
22.4
18.76
16
17
18
19
20
21
22
23
Export Pressure Arrival Pressure
Pressure(barg)
Benchmarking - Pressure
Operational Data Simulation Result
• Steady state wax deposition simulation in OLGA;
• Wax content under-predicted in Multiflash – DCM tuned to match
pressure drop;
Conclusion
22 A presentation by Wood.
Wax Modelling in Multiflash is Reliable
Depending on:
Availability of Fluid Data
Availability of Wax Data
Accuracy of Lab Measurement Techniques
Tuning Approach
Questions?
woodplc.com

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Europe User Conference: Modelling-waxy-fluids

  • 1. woodplc.com Modelling Waxy Fluids in Multiflash Mehwish Manzoor and Jessy Zeng 18th June 2018
  • 2. • Wax Management / Control • Wax Deposition and Risks • Modelling Waxy Fluids in Multiflash • Case Study – Fluid Characterisation – Wax Content Tuning – WAT and WDT Tuning – Benchmarking • Conclusion Agenda 2 A presentation by Wood.
  • 3. Wax Management / Control 3
  • 4. General Approach to Control of Wax Issues Wax Management / Control 4 A presentation by Wood. Pigging < Insulation Chemical Operational > Insulation Heating RISK CAPEX / OPEX
  • 6. • High molecular weight paraffins (typically n-C17+) Wax in Fluids 6 A presentation by Wood. Higher Molecular Weight Quickest Precipitation
  • 7. • Molecular Diffusion is the dominant wax deposition mechanism • Radial diffusion of dissolved wax molecules in the oil • Concentration gradient between dissolved wax in the turbulent core and the wax in solution at the pipe wall • Dissolved wax diffuses towards the wall where it precipitates Wax Deposition (Molecular Diffusion) 7 A presentation by Wood.
  • 8. Wax Deposition Risks 8 A presentation by Wood. Reduction in Delivery • Reduction in flow area • Increased Pressure Drop • Change in wall friction • Change in fluid viscosity Pipeline Integrity • Trapped H2O may corrode pipeline Remediation Required • Loss of production • Risk of “stuck” pigs – long shutdowns • Additional topsides equipment required (i.e. chemicals plus processing)
  • 9. Wax Deposition Risks 9 A presentation by Wood. Reduction in Delivery • Reduction in flow area • Increased Pressure Drop • Change in wall friction • Change in fluid viscosity Pipeline Integrity • Trapped H2O may corrode pipeline Remediation Required • Loss of production • Risk of “stuck” pigs – long shutdowns • Additional topsides equipment required (i.e. chemicals plus processing) Fluid characterisation and tuning against lab data is crucial to accurately predict the likely wax deposition in field operation.
  • 10. Modelling Waxy Fluids in Multiflash 10
  • 11. Wax Model in Multiflash 11 A presentation by Wood. Coutinho Wax Model Solid wax phase treated as non-ideal mixture of n-paraffins Equation of State RKSA / CPA-InfoChem Minimal difference in prediction of wax phase behaviour in crude oils Viscosity Default - SuperTRAPP Oil Systems – Pedersen (Heavy Oils) is good
  • 12. Input Data Required for Modelling Waxy Fluids 12 A presentation by Wood. Compositional Analysis Data • Fluid Composition • Calculated Sample Properties (i.e. MW and Density) N-Paraffin Distribution • HTGC • Wax Content Wax Appearance Temperature
  • 13. Additional Data for Modelling Waxy Fluids 13 A presentation by Wood. Wax Dissolution Temperature Saturates, Aromatics, Resins and Asphaltenes Analysis
  • 14. PVT Report Density, Sat. Point, GOR, Viscosity Tuned Thermodynamic Fluid File Steady State OLGA Simulation Wax Deposition Modelling Procedure 14 A presentation by Wood. N-Paraffin Distribution Wax Content, WAT, WDT, Viscosity Tuned N-Paraffin Fluid File Wax Deposition OLGA Simulation
  • 15. Case Study North Sea Wax Deposition Study 15
  • 16. North Sea Wax Deposition Study Identification of a Suitable Wax Management Strategy 16 A presentation by Wood. Scope Benchmarking of Existing Pipeline Future Operation of New Oil Export Route Platform 3 Benchmarking Case Future Operation Platform 2Platform 1
  • 17. Fluid Characterisation 17 A presentation by Wood. Real ComponentsIso-ParaffinsN-Paraffins
  • 18. • Lab Data = 5.0 wt% • N-Alkane Distribution (n-C20+) = 3.99 wt% • Predicted Wax Content @ -30 °C = 4.05 wt% Wax Content Tuning 18 A presentation by Wood.
  • 19. WAT and WDT Tuning Approach 19 A presentation by Wood. Lab Test Methods Cross Polar Microscopy Differential Scanning Calorimetry WAT and WDT Tuning Client Request Less Conservative WAT Tuning Only Preferred Method Allows Prediction of WDT
  • 20. Fluid Laboratory Results Model Prediction WAT (°C) WDT (°C) WAT (°C) WDT (°C) 1 36.9 53.3 36.4 53.7 2 38.7 48.9 38.4 49.3 WAT and WDT Tuning 20 A presentation by Wood.
  • 21. 40.7 7.3 40.7 7.3 0 5 10 15 20 25 30 35 40 45 Export Temperature Arrival Temperature Temperature(°C) Benchmarking - Temperature Operational Data Simulation Result Benchmarking – Pressure and Temperature 21 A presentation by Wood. 22.5 18.76 22.4 18.76 16 17 18 19 20 21 22 23 Export Pressure Arrival Pressure Pressure(barg) Benchmarking - Pressure Operational Data Simulation Result • Steady state wax deposition simulation in OLGA; • Wax content under-predicted in Multiflash – DCM tuned to match pressure drop;
  • 22. Conclusion 22 A presentation by Wood. Wax Modelling in Multiflash is Reliable Depending on: Availability of Fluid Data Availability of Wax Data Accuracy of Lab Measurement Techniques Tuning Approach Questions?