Lecture 17
AIR POLLUTION
HRh
Ahh Fresh Clean Air
Air Pollution
Any undesirable changes in air that adversely affect the
health, survival, or activities of humans or other organisms
 Primary air pollutants
emitted directly into the
atmosphere
 Primary pollutants that
account for nearly all air
pollution problems are
carbon monoxide,
particulates, hydrocarbons,
nitrogen oxides, and sulfur
oxides
Secondary pollutants
Produced through
reactions between primary
pollutants and normal
atmospheric compounds,
e.g. ozone, peroxy-acyl
nitrate (PAN),
photochemical smog,
sulfur trioxide, acid rain
Tehran Air Pollution
Polluted Air/ Mexico City
Sources of Air Pollution
Stationary sources are those that have a fixed location
Emit most of the particulate matter, sulfur oxides, nitrogen oxides,
hydrocarbons, and carbon oxides
Include point sources, fugitive sources, and area sources
Point sources are stationary
sources that emit air pollutants
from one or more controllable sites,
e.g., smokestacks of power plants
Fugitive sources generate air
pollutants from open areas
exposed to wind processes, such
as dirt roads, construction sites,
farmlands, surface mines, etc
 Area sources are locations
from which air pollutants are
emitted from a well-defined
area having several sources,
e.g., agricultural areas sprayed
with herbicides and pesticides
 Mobile sources are emitters of air
pollutants that move from place to
place while yielding emissions,
include automobiles, trucks, buses,
aircraft, ships, trains
Sources of Air Pollution
 Combustion of fossil fuels release significant quantities of
nitrogen oxides, carbon oxides, particulate matter, and
hydrocarbons
 Each year over a billion tons of these pollutants enter the
atmosphere from human-related processes
 About half is carbon monoxide
Power plant Smokestacks
Tank farm
Smokestacks from (N) power plant
Factory chimneys, Cologne, Germany Mobile Source
Natural Sources of Air Pollution
 Volcanoes discharge ash, acid mist, and H2S
 Natural forest fires
 Trees and bushes emit millions of tons of volatile organic
compounds (terpenes & propenes), pollen, spores, virus,
bacteria in the air cause wide spread suffering from allergies
and airborne infections
 Dust storm
 Various chemicals used in buildings
 Both inside and outside pollutants create a high risk for the
human health
General Effects of Air Pollutants
 Affects many aspects of environment:
Visually aesthetic resources, vegetation, animals, soil, water
quality, structures, and human health
Affect visual resourcesAffect visual resources
by discoloring atmosphere,by discoloring atmosphere,
reducing visual range,reducing visual range,
atmospheric clarity, etcatmospheric clarity, etc
Effects on vegetationEffects on vegetation
Damage to leaf tissue, needles,Damage to leaf tissue, needles,
or fruitor fruit
Suppression of growthSuppression of growth
Increased susceptibility to aIncreased susceptibility to a
variety of diseasesvariety of diseases
Disruption of reproductiveDisruption of reproductive
processesprocesses
General Effects of Air Pollutants
Effects on human health
 Toxic poisoning causing
cancer
 Eye irritation
 Irritation of respiratory system
 Increased susceptibility to
viral infections
 Causing pneumonia &
bronchitis
 Heart disease
 Aggravation of chronic
diseases, such as asthma
Effect on vertebrate animals
 Impairment of respiratory
system
 Damage to eye, teeth bones
 Increased susceptibility to
disease, pests
 Decreased availability of food
sources
 Decreased ability to reproduce
Effects on Soil & Water
Degrades soil and water quality; may become toxic from
the deposition of various pollutants
Effects on structures include discoloration, erosion, and
decomposition of building materials
Potential for Urban Air Pollution Q
 The potential for air pollution in urban areas is determined by the
following factors:
 Population density
 The rate of emission of pollutants per unit area
 The distance downwind that a mass of air may move through an
urban area
 Temperature inversion
 The average speed of the wind
 The height to which pollutants may be thoroughly mixed in the
lower atmosphere
 Stronger the wind and the higher the mixing layer, the lower the
pollution
 Hills, mountains, tall buildings
 Rain helps clean the air pollutants
Acid rain
 Pure rainfall has a pH (a numeric value to describe the strength of
an acid) of about 5.6
 Acid rain is defined as the precipitation in which the pH is
below 5.6
 (Acid rain is rain consisting of water droplets that are unusually
acidic because of atmospheric pollution - most notably the
excessive amounts of sulfur and nitrogen released by cars and
industrial processes)
 Acidic deposition occurs in two ways: wet and dry
 Wet deposition refers to acidic rain, fog, and snow
 Dry deposition : In areas where the weather is dry, the acid
chemicals may become incorporated into dust or smoke and fall to
the ground through dry deposition, sticking to the ground, buildings,
homes, cars, and trees
 Dry deposited gases and particles can be washed from these
surfaces by rainstorms
Acid rain
 Causes (Q)
 Acid deposition can occur via natural sources like
volcanoes but it is mainly caused by the release of
sulfur dioxide and nitrogen oxide during fossil fuel
combustion
 When these gases are discharged into the atmosphere
they react with the water, oxygen, and other gases
already present there to form sulfuric acid and nitric
acid
 About 70% of the acidity of acid rain is due to sulfur
oxides emissions
 30% is due to nitrogen oxides emissions
 These acids may travel long distances with prevailing
winds to be deposited as acid precipitation
Emission from power plant in New Mexico
contained excessive amounts of SO2
Acid rain
Harmful effects on Terrestrial
ecosystems
1. Damages leaves and needles
2. Decrease ability of trees to tolerate
cold
3. Weakened trees either are killed or
become susceptible to diseases
5. Causes leaching of basic essential
elements
6. Causes dissolution of Fe, Al, Mn from
minerals
 Can cause human respiratory
diseases such as bronchitis and
asthma
Aquatic ecosystemsAquatic ecosystems
1.1. Loss of essentially all fishLoss of essentially all fish
populationspopulations below a pHbelow a pH
of 4.5of 4.5
2.2. Dissolution and release ofDissolution and release of
aluminum ions (aluminum ions (AlAl3+3+
) from) from
minerals can kill manyminerals can kill many
kinds of fishkinds of fish
3. Accumulation in fish of3. Accumulation in fish of
heavy metals pose healthheavy metals pose health
hazards to humans,hazards to humans,
mammals, and birdsmammals, and birds
Consequences of acid rain
Fish kill
Solution to Acid Rain Problem
 Liming periodically, though not satisfactory over a
long period
 Also expensive & requires continuing effort
 Long-term practical solution is to ensure that the
production of acid-forming components in the
atmosphere is minimized
 Best strategy
 Increasing energy efficiency and conservation
measures that result in burning less coal
 Alternative energy sources
 Pollution abatement technology to lower the emission
Solution to Acid Rain Problem
 The only way to fight acid rain is by curbing the release of the
pollutants that cause it
 This means burning fewer fossil fuels
 But even if acid rain could be stopped today, it would still take
many years for its harmful effects to disappear
 Individuals can also help prevent acid rain by conserving
energy
 The less electricity people use in their homes, the fewer
chemicals power plants will emit
 Vehicles are also major fossil fuel users, so emissions can be
reduced by using public transportation, carpooling, biking, or
simply walking wherever possible
Smog
Air pollution that is localized in urban areas, where it reduces visibility
Formation of smog depends on local climate, topography, population
density, industry, fuels used in industry, heating, and transportation
Two types
 Photochemical smog (brown air)
 Solar radiation is important
 Directly related to automobile use
 Involve both N- oxides & HCs
 Sulfurous smog (gray air/
Industrial smog )
 Produced primarily by
burning coal or oil at large
power plants
 Affects human health and comfort
 Damage to materials
 Affects atmosphere
 Toxic to plants
Smog over California
Looking from the Hollywood hills, air pollution is visible
in downtown Los Angeles
Smog in Cairo
Smog over a city
Pollution Control
 Most reasonable strategies are to reduce, collect, capture, or
retain the pollutants before they enter the atmosphere
 The reduction of emissions via energy efficiency and
conservation measures is the preferred strategy
 Particulates emitted from fugitive, point, or area stationary
sources are much easier to control than released from mobile
sources
 Settling chambers or collectors are may be used to control
emissions of coarse particulates from power plants and
industrial sites
 Particulates from fugitive sources (waste pile) must be controlled
on-site so that the wind does not blow them into the atmosphere
Pollution Control
 Control of pollutants such as carbon monoxide, nitrogen oxides,
and hydrocarbons in urban areas is best achieved through
control measures for automobiles
 Control of nitrogen oxides from automobile is accomplished by
recirculating exhaust gas
 Carbon monoxide and hydrocarbons from automobile is
reduced by using catalytic converter which converts carbon
monoxide to carbon dioxide, hydrocarbons to carbon dioxide
and water by passing exhaust gases over a catalyst
 Sulfur dioxide emission can be reduced by abatement
measures performed before, during, or after combustion
End of Slides
Thank You

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L 17 air pollution

  • 3. Air Pollution Any undesirable changes in air that adversely affect the health, survival, or activities of humans or other organisms  Primary air pollutants emitted directly into the atmosphere  Primary pollutants that account for nearly all air pollution problems are carbon monoxide, particulates, hydrocarbons, nitrogen oxides, and sulfur oxides Secondary pollutants Produced through reactions between primary pollutants and normal atmospheric compounds, e.g. ozone, peroxy-acyl nitrate (PAN), photochemical smog, sulfur trioxide, acid rain
  • 4. Tehran Air Pollution Polluted Air/ Mexico City
  • 5. Sources of Air Pollution Stationary sources are those that have a fixed location Emit most of the particulate matter, sulfur oxides, nitrogen oxides, hydrocarbons, and carbon oxides Include point sources, fugitive sources, and area sources Point sources are stationary sources that emit air pollutants from one or more controllable sites, e.g., smokestacks of power plants Fugitive sources generate air pollutants from open areas exposed to wind processes, such as dirt roads, construction sites, farmlands, surface mines, etc  Area sources are locations from which air pollutants are emitted from a well-defined area having several sources, e.g., agricultural areas sprayed with herbicides and pesticides  Mobile sources are emitters of air pollutants that move from place to place while yielding emissions, include automobiles, trucks, buses, aircraft, ships, trains
  • 6. Sources of Air Pollution  Combustion of fossil fuels release significant quantities of nitrogen oxides, carbon oxides, particulate matter, and hydrocarbons  Each year over a billion tons of these pollutants enter the atmosphere from human-related processes  About half is carbon monoxide Power plant Smokestacks
  • 7. Tank farm Smokestacks from (N) power plant
  • 8. Factory chimneys, Cologne, Germany Mobile Source
  • 9. Natural Sources of Air Pollution  Volcanoes discharge ash, acid mist, and H2S  Natural forest fires  Trees and bushes emit millions of tons of volatile organic compounds (terpenes & propenes), pollen, spores, virus, bacteria in the air cause wide spread suffering from allergies and airborne infections  Dust storm  Various chemicals used in buildings  Both inside and outside pollutants create a high risk for the human health
  • 10. General Effects of Air Pollutants  Affects many aspects of environment: Visually aesthetic resources, vegetation, animals, soil, water quality, structures, and human health Affect visual resourcesAffect visual resources by discoloring atmosphere,by discoloring atmosphere, reducing visual range,reducing visual range, atmospheric clarity, etcatmospheric clarity, etc Effects on vegetationEffects on vegetation Damage to leaf tissue, needles,Damage to leaf tissue, needles, or fruitor fruit Suppression of growthSuppression of growth Increased susceptibility to aIncreased susceptibility to a variety of diseasesvariety of diseases Disruption of reproductiveDisruption of reproductive processesprocesses
  • 11. General Effects of Air Pollutants Effects on human health  Toxic poisoning causing cancer  Eye irritation  Irritation of respiratory system  Increased susceptibility to viral infections  Causing pneumonia & bronchitis  Heart disease  Aggravation of chronic diseases, such as asthma Effect on vertebrate animals  Impairment of respiratory system  Damage to eye, teeth bones  Increased susceptibility to disease, pests  Decreased availability of food sources  Decreased ability to reproduce Effects on Soil & Water Degrades soil and water quality; may become toxic from the deposition of various pollutants Effects on structures include discoloration, erosion, and decomposition of building materials
  • 12. Potential for Urban Air Pollution Q  The potential for air pollution in urban areas is determined by the following factors:  Population density  The rate of emission of pollutants per unit area  The distance downwind that a mass of air may move through an urban area  Temperature inversion  The average speed of the wind  The height to which pollutants may be thoroughly mixed in the lower atmosphere  Stronger the wind and the higher the mixing layer, the lower the pollution  Hills, mountains, tall buildings  Rain helps clean the air pollutants
  • 13. Acid rain  Pure rainfall has a pH (a numeric value to describe the strength of an acid) of about 5.6  Acid rain is defined as the precipitation in which the pH is below 5.6  (Acid rain is rain consisting of water droplets that are unusually acidic because of atmospheric pollution - most notably the excessive amounts of sulfur and nitrogen released by cars and industrial processes)  Acidic deposition occurs in two ways: wet and dry  Wet deposition refers to acidic rain, fog, and snow  Dry deposition : In areas where the weather is dry, the acid chemicals may become incorporated into dust or smoke and fall to the ground through dry deposition, sticking to the ground, buildings, homes, cars, and trees  Dry deposited gases and particles can be washed from these surfaces by rainstorms
  • 14. Acid rain  Causes (Q)  Acid deposition can occur via natural sources like volcanoes but it is mainly caused by the release of sulfur dioxide and nitrogen oxide during fossil fuel combustion  When these gases are discharged into the atmosphere they react with the water, oxygen, and other gases already present there to form sulfuric acid and nitric acid  About 70% of the acidity of acid rain is due to sulfur oxides emissions  30% is due to nitrogen oxides emissions  These acids may travel long distances with prevailing winds to be deposited as acid precipitation
  • 15. Emission from power plant in New Mexico contained excessive amounts of SO2
  • 16. Acid rain Harmful effects on Terrestrial ecosystems 1. Damages leaves and needles 2. Decrease ability of trees to tolerate cold 3. Weakened trees either are killed or become susceptible to diseases 5. Causes leaching of basic essential elements 6. Causes dissolution of Fe, Al, Mn from minerals  Can cause human respiratory diseases such as bronchitis and asthma Aquatic ecosystemsAquatic ecosystems 1.1. Loss of essentially all fishLoss of essentially all fish populationspopulations below a pHbelow a pH of 4.5of 4.5 2.2. Dissolution and release ofDissolution and release of aluminum ions (aluminum ions (AlAl3+3+ ) from) from minerals can kill manyminerals can kill many kinds of fishkinds of fish 3. Accumulation in fish of3. Accumulation in fish of heavy metals pose healthheavy metals pose health hazards to humans,hazards to humans, mammals, and birdsmammals, and birds
  • 19. Solution to Acid Rain Problem  Liming periodically, though not satisfactory over a long period  Also expensive & requires continuing effort  Long-term practical solution is to ensure that the production of acid-forming components in the atmosphere is minimized  Best strategy  Increasing energy efficiency and conservation measures that result in burning less coal  Alternative energy sources  Pollution abatement technology to lower the emission
  • 20. Solution to Acid Rain Problem  The only way to fight acid rain is by curbing the release of the pollutants that cause it  This means burning fewer fossil fuels  But even if acid rain could be stopped today, it would still take many years for its harmful effects to disappear  Individuals can also help prevent acid rain by conserving energy  The less electricity people use in their homes, the fewer chemicals power plants will emit  Vehicles are also major fossil fuel users, so emissions can be reduced by using public transportation, carpooling, biking, or simply walking wherever possible
  • 21. Smog Air pollution that is localized in urban areas, where it reduces visibility Formation of smog depends on local climate, topography, population density, industry, fuels used in industry, heating, and transportation Two types  Photochemical smog (brown air)  Solar radiation is important  Directly related to automobile use  Involve both N- oxides & HCs  Sulfurous smog (gray air/ Industrial smog )  Produced primarily by burning coal or oil at large power plants  Affects human health and comfort  Damage to materials  Affects atmosphere  Toxic to plants
  • 22. Smog over California Looking from the Hollywood hills, air pollution is visible in downtown Los Angeles
  • 23. Smog in Cairo Smog over a city
  • 24. Pollution Control  Most reasonable strategies are to reduce, collect, capture, or retain the pollutants before they enter the atmosphere  The reduction of emissions via energy efficiency and conservation measures is the preferred strategy  Particulates emitted from fugitive, point, or area stationary sources are much easier to control than released from mobile sources  Settling chambers or collectors are may be used to control emissions of coarse particulates from power plants and industrial sites  Particulates from fugitive sources (waste pile) must be controlled on-site so that the wind does not blow them into the atmosphere
  • 25. Pollution Control  Control of pollutants such as carbon monoxide, nitrogen oxides, and hydrocarbons in urban areas is best achieved through control measures for automobiles  Control of nitrogen oxides from automobile is accomplished by recirculating exhaust gas  Carbon monoxide and hydrocarbons from automobile is reduced by using catalytic converter which converts carbon monoxide to carbon dioxide, hydrocarbons to carbon dioxide and water by passing exhaust gases over a catalyst  Sulfur dioxide emission can be reduced by abatement measures performed before, during, or after combustion