IIT2014-MID-PHASE TEST -1-CPM(I)-17
F I I T J E E MID-PHASE TEST - I
(eso Batch)
liT - JEE 2014
ANSWERS
SECTION - I (Chemistry)
1. 0 2. B 3. B 4. B
5. 0 6. B 7. A 8 C
9. A 10. B 11. A 12. 0
13 C 14. B 15 A, B, 0
16. C, O
17 A, C, O
18. C 19. A, B, C, O 20. A, B, 0
SECTION -II (Physics)
1. A 2 B
3 0 4. 0
5. A 6. B 7 A
8 A
9 A 10. A 11. B 12. B
13 0 14. A 15 A, C
16 A, C
17. A, B 18 A, 0
19. C 20. A, B, C, 0
SECTION - III (Mathematics)
1. 0 2 C 3 0 4. A
5. C 6 C 7. A 8. 0
9. A 10 B 13. B 14. C
13. B 14. B 15. B, C 16. A, B
17. A, B, C, O
18. A, B, C
19. A, 0
20. A, O
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1IT2014-MID-PHASE TEST :1-CPM(I)-18
(enol form)
O-H
6
N
1.
Sol
2.
Sol
3
Sol
4.
Sol
5.
Sol
6.
Sol
7.
Sol
8
Sol
9
Sol
HINTS & SOLUTIONS
SECTION -I (Chemistry)
o
This structure is not permissible because it is not a valid lewis structure as nitrogen has give bonds
around it and a positive charge 'N' has 10 valance electrons around it
B
CO
cO ~
Li
H
(Keto form)
B
(B) is the most stable free radical as this is resonance stabilized by extended conjugation with the
phenyl ring.
B
The two compounds are constitutional isomers connectivity is different in both the compounds.
o
The two structures are diastereomers.
B
Plane of symmetry is present
A
Any reaction in which only one of a set of stereoisomers is formed exclusively or pre dominantly is
called stereoselectione reaction
C
80
Specific rotation = 12 x - =9.6
0
100
A
o
II
--O-C-CH
3
is ERG.
10. B
11. A
12. 0
13. C
14. B
15. A,B,O
16 C,O
17. A,C,O
18. C
Sol
19 A, B, C, 0
20. A, B, 0
Sol
-NHCOCH"
o
II
--O-C-CH
3
and ORare 'ERG' ORactivating groups.
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IIT20 14-MI D-PHASE TEST -I-CPM( 1)-19
SECTION - III (Mathematics)
1. 0
2. C
Sol. Give function is in the form of 1~
3. 0
Sol. lim I(x) = Iill\ I(x) =I( 4 )
x_4 .1"_4
4. A
Sol. For minimum value at x = 1,1'(1) =0
Now r(x ) =2x - .; :::>r(I) =2 - a =0 :::>a =2
x-
5
Sol.
6.
Sol.
7.
Sol.
8.
Sol.
9.
10.
13
14.
Sol.
C
If XE (2,4) then % E O (1,2) :::>[ % ] =[Link]>I (x) =x-I:::> x =I ( x) +I :::>r' (x) =x +1
C
[ x] ' - 2 [ x] + [ x] - 2 =0
:::>[x] =2, [ x] =-1 :::>XE [ 2,3) U [ -1,0)
A
r(O) =lim 1(0 +h) - 1(0)
11_0 h
3=/ (0) (l i m / (h) -I )
.11_0 h
( ( h ) - I ]
3=lim [.: /(0)=1
It_O h
Similarly ('(5) = ((5) lim I( h) -} =2x 3 =6
. . !I_O h
o
. x X x
7
sm x = x- - +- --+ .
LJ l2 11
A
8
8
C
If x <0, then I(x) =xe"
s o r(x) = e" (I +3 x)
1
So for f(xl to be increasing function. 3x >-I :::>x >- - &x <0
3
Now if x >0 then r(x) =1+6x - 3 x'
:::> ("(x) =6- 6x
So for f(x) to be increasing function, 6 - 6x >0where x> 0
:::>O<x<1
13 8
Sol. I(x) can be written in the form of ( % +~cos 4 X )
27[ 7[
cos4x is periodic with period - =-
4 2
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V'
IIT2014-MID-PHASE TEST-I-CPM(I)-20
14,
Sol.
15,
Sol.
16
Sol.
B
j(x+k)=-f(x)
f (x +2k) = -j (x +k) [replacing x by x +k]
j(x+2k)=((x)
B,C
dy y
-=--
dx x
(
d
Y
) 1
'. dx Hl = - "
.-. Slope of the normal is I'
, b
.-.'-=--
a
So either b >0 and a <0 or b <0 and a >0
A, B
y' =4ax,
=> 2yy'=4a
, 2a
=>y =-.
y
-rna
and y = e ' -
dy I -.rna
=>-=--e
dx 2a
1
=--.y
2a
17, A, B,C, 0
Sol. f(x) =cosXCOS(x +2) -cos' (x +I) =Hcos(2x +2) +cos2J -Hcos(2x +2) +IJ
1 1
=-cos2--
2 2
18 A, B, C
19 A, D
Sol. f( -x) =-((x) and f'(x) = ,4e", >O\fx
(e-'+lr
20 A, 0
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