Q no 1: UV spectroscopy is used to measure the
a) No of conjugate bonds b) Diffrentiate between conjugate & non conjugate bonds
c) Aromatic conjugation with molecules d) All
Ans: All
Q no 2: Units of absorbance are
a) dm³ mol⁻¹ cm⁻¹ b) Dimensionless c)mol dm⁻³ d)cm
Ans: Dimensionless
Q no 3: Beer‒Lambert law gives the relation between which of the following
a) Reflected radiation & concentration b) Scattered radiation & concentration
c) Energy absorption & concentration d) Energy absorption & reflected radiation
Ans: Energy absorption & concentration
Q no 4: Lambert’s law states that the intensity of light decreases with respect to
a) Concentration b) Volume c) Distance d) Composition
Ans: Distance
Q no 5: Which of the following is not true about absorption spectroscopy
a) It involves transmission b) Scattering is kept minimum
c) Reflection is kept maximum d) Intensity of radiation leaving the substance is an indication of
concentration
Ans: Reflection is kept maximum
Q no 6: Ordinary spectrometers cover a range of
a) 200‒400 nm b) 220‒800 nm c) 400‒800 nm d) 350‒700 nm
Ans: 220‒800 nm
Q no 7: Red shift is also called as
a) Bathochromic shift b) hypsochromic shift c) hypochromic shift d) Hyperchromic shift
Ans Bathochromic shift
Q no 8: R‒ Bands arise due to
a) n‒π* b) π‒π* c)σ ‒π* d) σ‒σ*
Ans: n‒π*
Q no 9: Which of the following is application of UV spectroscopy
a) Extent of conjugation b) determination of geometrical isomerism
c) Identification of unknown compound d) All
Ans: All
Q no 10: Quantitative analysis is based on
a) Beer’s law b) Lambert’s law c) Beer‒ lambert law d) None
Ans: Beer‒ lambert law
Q no 11: Spectroscopy used for the determination of structure of a compound using vibrational
transistions
a)IR b) UV c) Visible d) Microwave
Ans: IR
Qno 12: The IR region of electromagnetic radiation spectrum extends from
a) 0.3‒200μ b) 0.8 ‒200μ c) 0.4‒300μ d) 0.1‒100μ
Ans: 0.8‒200μ
Q no13: The order of energies for various transistions is
a) n‒σ* >π‒σ*>σ‒σ*>π‒π* b)σ‒σ*>n‒σ*>π‒π*>n‒π* c) σ‒σ*<n‒σ*<π‒π*<n‒π* d)
n‒π*<π‒π*<σ‒π*<n‒σ*
Ans: σ‒σ*>n‒σ*>π‒π*>n‒π*
No 14: Allowed transistions with values of extinction coefficient є max more than generally arise due
to
a) π‒π* transistions b)σ‒σ* transistions c) n‒π* transistions d) n‒σ* transistions
Ans: π‒π* transistions
Q no 15: Which of the following shows both types of transistions both allowed & forbidden
a) Benzophenone b) cyclopentonone cHexene d) None
Ans: benzophenone
Q no 16 : Groups which distort the geometry of molecules cause
a) bathochromic shift b)Hypsochromic shift c) Hypochrmic shift d) Hyperchromic shift
Ans: Bathochromic shift
Q no 17: molecular vibrations are detected & measured in
a) 2.5μ to 15μ b) 2.4μ to 20μ c) 4.2μ to 80μ d) 5.2 μ to 40μ
Ans: 2.5μ to 15μ
Q no 18: Which of the following provides finger print region
a) UV b) IR c) Microwave d) ALL
Ans: IR
Qno 19: In which of the following bond angle changes
a) Strecthing b) Bending c) twisting d) None
Ans: Twisting
QNo 20: Which of the following is IR inactive
a) H₂ b) N₂ c) O₂ d)All
Ans: All
Q no 21: Absorbed band of hexane comes in
a) 1713 cm⁻¹ b) 1709 cm⁻¹ c)1726 cm⁻¹ d) 1728 cm⁻¹
Ans: 1726 cm⁻¹
Q no 22: Prism used to obtain monochromatic light is made of
a) Glass b) NaCl c) CaCl ₂ d) None
Ans: Nacl
Q no 23: Solvents used for IR are
a) Chlorofom b) Carbontetrachloride c) Carbondisulphide d) All
Ans: All
Q no24: Position of IR bands of chelate compounds is
a) 2300‒3200 cm⁻¹ b) 2500‒3000 cm⁻¹ c) 2500‒ 3200 cm⁻¹ d) 2200‒3000 cm⁻¹
Ans: 2500‒3200 cm⁻¹
