Material Safety Data Sheet

Alpha-Pinene MSDS

Section 1: Chemical Product and Company Identification

Product Name: Alpha-Pinene Contact Information:

Catalog Codes: SLP3301

PERUM PERHUTANI
CAS#: 80-56-8 GEDUNG MANGGALA WANABAKTI, BLOK VII LT.8-11
JALAN GATOT SUBROTO, SENAYAN,
RTECS: DT7000000 JAKARTA, INDONESIA

TSCA: TSCA 8(b) inventory: Alpha-Pinene (24HR Emergency Telephone), call:

+628159385142
CI#: Not available.

Synonym: 2,6,6-Trimethylbicyclo[3,1,1]hept-2-ene For non-emergency assistance, call: +62 4216864

Chemical Name: Not available.

Chemical Formula: C10H16

Section 2: Composition and Information on Ingredients

Composition:
Name CAS # % by Weight
{Alpha-}Pinene 80-56-8 100

Toxicological Data on Ingredients: Alpha-Pinene: ORAL (LD50): Acute: 3700 mg/kg [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:
Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact
(irritant).

Potential Chronic Health Effects:

Hazardous in case of eye contact (irritant), of ingestion, of inhalation.
Slightly hazardous in case of skin contact (irritant).
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Section 4: First Aid Measures

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Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated
clothing before reusing.

Serious Skin Contact: Not available.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.

Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 255°C (491°F)

Flash Points: CLOSED CUP: 33°C (91.4°F).

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances: Highly flammable in presence of open flames and sparks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions:

Flammable liquid, insoluble in water.
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to prevent pressure
build-up, autoignition or explosion.

Special Remarks on Fire Hazards: Explosive in the form of vapor when exposed to heat or flame.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:
Flammable liquid, insoluble in water.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Prevent

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entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance
on disposal.

Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
ingest. Do not breathe gas/fumes/ vapour/spray. Avoid contact with eyes Wear suitable protective clothing In
case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately
and show the container or the label.

Storage:
Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep
away from sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all
equipment containing material. A refrigerated room would be preferable for materials with a flash point lower than
37.8°C (100°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.

Personal Protection: Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or
equivalent.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Strong.

Taste: Not available.

Molecular Weight: 136.23 g/mole

Color: Colorless.

pH (1% soln/water): Not applicable.

Boiling Point: 156°C (312.8°F)

Melting Point: -55°C (-67°F)

Critical Temperature: Not available.

Specific Gravity: 0.8592 (Water = 1)

Vapor Pressure: Not available.

Vapor Density: 4.7 (Air = 1)

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Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water, methanol, diethyl ether.

Solubility:
Soluble in methanol, diethyl ether.
Insoluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Not available.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 3700 mg/kg [Rat].

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans:

Hazardous in case of ingestion, of inhalation.
Slightly hazardous in case of skin contact (irritant).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may

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arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Class 3: Flammable liquid.

Identification: : alpha-Pinene : UN2368 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:
Pennsylvania RTK: Alpha-Pinene
Massachusetts RTK: Alpha-Pinene
TSCA 8(b) inventory: Alpha-Pinene

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada): CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).

DSCL (EEC):
R10- Flammable.
R36- Irritating to eyes.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 3

Reactivity: 0

Personal Protection: j

National Fire Protection Association (U.S.A.):

Health: 1

Flammability: 3

Reactivity: 0

Specific hazard:

Protective Equipment:
Not applicable.
Lab coat.
Vapor respirator. Be sure to use an

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approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 11:28 AM

Last Updated: 11/06/2008 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we
assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall PT NAVAL OVERSEAS be liable for any claims, losses, or damages
of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if PT NAVAL OVERSEAS has been advised of the possibility of such damages.

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