Physics Chemistry Math Exam Guide
Physics Chemistry Math Exam Guide
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
BATCHES –2123
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
(ii) Part-A (09-12) – This section contains Two (02) List-Match Sets, each List-Match set has Two (02) Multiple
Choice Questions. Each List-Match set has two lists: List-I and List-II. FOUR options ar e g i ven i n eac h
Multiple Choice Question based On List-I and List-II and ONLY ONE of these four o ptions s ati sfi es th e
condition asked in the Multiple Choice Question. Each question carries +3 Marks for correct c o mbi nation
chosen and -1 marks for wrong options chosen.
(iii) Part-B (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+3 marks for correct answer. There is no negative marking.
SECTION – I : PHYSICS
(PART – A)
(One or More Than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
(A) the smallest velocity v 0 for which the particle C will swing in a full circle about the
point B is 4g .
(B) the smallest velocity v 0 for which the particle C will swing in a full circle about the
point B is g .
(C) velocity of point C at the highest point of the circle (for the smallest value of v 0) is
zero.
(D) velocity of point C at the highest point of the circle (for the smallest value of v 0)
is g .
1. AC
Sol. Result: The minimum velocity at lowest point for a particle attached to a massless rod, to
compile vertical circle = 4g .
2. ACD
Sol. f1
f1 N3 We can see that N3 will be more than N2.
N2 N1
N2
m
m
f2
f3
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3. B
Sol. Apply virtual work method to get relation among velocities, then differentiate w.r.t. time.
force
4. A curve between force and displacement is drawn for a
particle moving in x axis only conservative forces are
acting
(A) At x 1 & x 3 particle in stable equilibrium. x1 x2 x3 x4
(B) At x 1 & x 3 particle in unstable equilibrium.
(C) At x 2 & x 4 particle in stable equilibrium.
(D) At x 2 & x 4 particle in unstable equilibrium.
4. BC
Sol. A stable equilibrium position n, F should be negative or n increases and vice versa.
5. For the system shown in the figure, the pulleys are light and
frictionless. Assume wedge to be fixed and smooth. The
m
tension in the string will be
2 3
(A) mg sin (B) mg sin m
3 4
1
(C) mg sin (D) mg sin
2
5. C
Sol. Simply apply Newton’s force equilibrium with a1 = a 2 .
Initially beads are at rest and angle between the springs is 60º at the fixed point O.
Normal length of each spring is 2R, where R is the radius of the ring. Beads are initially
symmetric w.r.t. the vertical diameter and now they are released, then the normal
reaction on one of the bead at initial moment due to the ring is
mg 3mg
(A) (B)
2 2
(C) mg (D) zero
6. C
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Sol. Each of the springs is already compression. A component of the spring force will be
balanced by the normal reaction.
7. BD
Sol. The pulley P1 will / should experience zero net force, so T = 0. Now apply constraint.
8. AC
Sol. One of the rods (BC) should be in compression while the other (AC) should be stretched
in tension. Now apply force balance along horizontal and along vertical.
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This section contains 2 List-Match Sets, each List-Match set has 2 Multiple Choice Questions. Each
List-Match set has two lists: List-I and List-II. Four options are given in each Multiple Choice Question
based On List-I and List-II and ONLY ONE of these f our options satisf ies the condition asked in the
Multiple Choice Question.
For Question 9 to 10
String 2 String 3
The system shown below is initially in
equilibrium C
mA = mB = 3kg Spring 1
String 4
mC = mD = mE = 2kg
Take g = 10 m/s2 B D
String 1 Spring 2
A E
List–I gives the four strings while List–II the value of the tension in the strings.
List – I List – II
(I) String 1 (P) 10 N
(II) String 2 (Q) 20 N
(III) String 3 (R) 30 N
(IV) String 4 (S) 40 N
(T) 60 N
(U) 0N
9. If the spring 1 is cut, match the correct for the tension in the strings just after the cutting.
(A) I → R, II → T, III → T, IV → P (B) I → U, II → T, III → T, IV → P
(C) I → U, II → U, III → U, IV → P (D) I → R, II → S, III → S, IV → P
9. C
Sol. Just after cutting force of cut spring will be zero whereas the force of other spring will be
unchanged.
10. If the spring 2 is cut, match the correct for the tension in the strings just after the cutting.
(A) I → R, II → T, III → T, IV → R (B) I → R, II → U, III → U, IV → R
(C) I → U, II → R, III → R, IV → P (D) I → P, II → Q, III → Q, IV → R
10. A
Sol. Just after cutting force of cut spring will be zero whereas the force of other spring will be
unchanged.
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For Question 11 to 12
A
m
k
Spring at its
Very high
natural length
table
B m
Block is released
from rest
After the above displayed event, consider the following two columns.
List-I List-II
(I) Maximum possible elongation in the (P) Either zero or (2 g)
spring.
(II) Maximum possible spring force (Q) mg
k
(III) Maximum acceleration of block A (R) 2mg
k
(IV) Maximum acceleration of block B (S) mg
(T) g
(U) 2 gm
11. D
Sol. At the maximum elongation, both the block will have same speed
12. C
Sol. Apply the result, maximum elongation in spring = 2mg/k, when the upper spring is
not moving.
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(PART – B)
(Integer Type)
Part-C (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks f or correct answer and there will be no negative marking.
2. A particle of mass m slides down from the vertex of hemisphere with initial tangential
velocity 7 m/s. At what height in m, form horizontal will the particle leave the sphere.
(Radius of sphere R = 10 m and g = 10 m/s2)
m
60°
5. In the given figure, the mass of block A is 40 kg and of block B is 20 kg. There is no
friction at any of the contact surface. Both the systems are held at rest initially. The ratio
of acceleration of block B in condition (i) to condition (ii) just at the moment system is
released, is
A A
B B
(i) (ii)
6. 4.00
Sol. The spring force will remain the same, before and just after the cutting of the string.
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SECTION – II : CHEMISTRY
(PART – A)
(One or More Than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. The first ionization enthalpies of two elements P and Q respectively are 8.1 and 10.2 eV.
The electron gain enthalpies of P and Q are respectively -3.1 and -6.6 eV respectively.
The percentage ionic character of the covalent bond P – Q is given as
% ionic character = 16(END) + 3.5(END) 2
Where END is the electronegativity difference in Pauling scale between P and Q.
Choose correct statements
(A) The electronegativity of P is 1.05
(B) Q is more electronegative than P
(C) percentage covalent character of P – Q bond is 80.5
(D) P – Q bond is purely covalent with 100% covalent character
1. BC
8.1 + 3.1
Sol. E.N of P = =2
5.6
10.2 + 6.6
E.N of Q = =3
5.6
% ionic character = 16(3 - 2) + 3.5(3 - 2)2 = 19.5
% covalent character = 100 – 19.5 = 80.5
2. ACD
Sol. Acid(HI) base(MgO, Mg(OH)2, MgCO3) reaction takes place.
3. In which of the following molecule(s) the bond containing H and the central atom
contains more than 25% s-orbital character?
H
(A) C (B) O
H Cl H H
Cl
F
N
(C) H H (D) C Cl
H
H H
3. AD
S
Sol. Cos =
S −1
Where = bond angle containing hydrogen and central atom
S = % s-orbital character.
In H2O, = 104.5o
S
Cos 104.5o = -0.25 =
S −1
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On solving S = 0.2, hence the O – H bond contain 20% s-orbital character and 80% p-
orbital character.
(B) is not correct similarly (C) will not be correct.
4. AD
Sol. (A) 4LiNO3 ⎯⎯ → 2Li2O + 4NO2 + O2
2NaNO3 ⎯⎯ → 2NaNO2 + O2
LiNO3 produces a colourfull gas(NO 2)
NaNO3 produces colourless gas
(B) Both compounds liberate CO 2 gas
(C) Both compounds liberate same gases
(D) 2KI ⎯⎯ → 2K + I2 ( violet )
KNO3 liberates no gas on heating.
5. ABC
Sol. Be (OH)2 ⎯⎯
→BeO + H2O
BeO + C + Cl2 ⎯⎯→ BeCl2 + CO
BeCl2 ⎯⎯⎯⎯⎯
Electrolysis
→ Be + Cl2
6. ABD
Sol. Ca or Mg (HCO3 )2 ⎯⎯
→ CaCO3 + CO2 + H2O
HCO3− + H2O ⎯⎯→ H2CO3 + OH−
Mg (HCO3 )2 + 2OH− ⎯⎯→ Mg ( OH)2 +2HCO3−
CaCO 3 is responsible for scale formation.
7. Which of the following statement(s) is/are correct regarding cyanate ion OCN – and
fulminate ion CNO –?
(A) OCN– ion has more stable resonating structures than CNO – ion.
(B) Protonation of cyanate ion forms two acids HNCO and HOCN whereas protonation
of fulminate ion forms one acid HCNO.
(C) Fulminic acid(HCNO) is linear in the vapour phase
(D) The dipole moment of HCNO is zero.
7. ABC
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O = C = N ⎯→ O − C N
2
O C −N
The resonating structures of fulminate ion CNO – are
2 3
C N − O ⎯→ C = N = O ⎯→ C − N O
In one resonating structure oxygen carries negative charge and in all three structure
carbon carries negative charge. Therefore H+ gets bonded to carbon forming
HCNO(fulminic acid).
8. ACD
Sol. Structure of PCl2Br3 is
Br Cl
P
Br Br
Cl
This section contains 2 List-Match Sets, each List-Match set has 2 Multiple Choice Questions. Each
List-Match set has two lists: List-I and List-II. Four options are given in each Multiple Choice Question
based On List-I and List-II and ONLY ONE of these f our options satisf ies the condition asked in the
Multiple Choice Question.
For Question 9 to 10
9. B
10. D
Sol. Cl
Ca ( OH)2 + Cl2 ⎯⎯→ Ca + H2O
OCl
Ba ( OH)2 + CO2 ⎯⎯→BaCO3 + H2O
For Question 11 to 12
11. B
12. C
(PART – B)
(Integer Type)
Part-C (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks f or correct answer and there will be no negative marking.
1. Barium ⎯⎯⎯2 N
→P ⎯⎯⎯
2
→Q + R
HO
Heat
⎯⎯⎯
CO
→S + T
Q + H2SO4
U + H2O
white
S + H2SO4
1. 189
Sol. P = Ba3N2, Q = Ba(OH)2, R = NH3, S = BaO, T = Ba(CN)2
2. The successive ionization enthalpies of the representative elements are given below in
eV unit.
Elements I.E1 I.E2 I.E3 I.E4
P 8.6 18.8 32.9 1830.4
Q 9.2 15.8 1021.8 2106.8
R 4.6 820.9 1926.5 3269.8
S 1296.2 1862.9 3589.6 7216.9
If the atomic mass of Q is 87.26 g mol what will be the molar mass of it’s oxide in g
–1
mol-1 unit?
2. 103.26
Sol. Q belongs to gr-2 as it contains two valence electrons.
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3. The dipole moment AgCl is 6.08D in gaseous state. The Ag-Cl distance is 228.1 pm. If
the percent ionic character in AgCl is x%, what is x?
4. The Cl – Cl distance in a BCl3 molecule in gaseous state is 303 pm. What is the bond
length(B – Cl distance) of BCl3 in pm unit?
30o
Cl Cl
D
303 pm
1
DCl ( Cl − Cl)
Cos30 =o
= 2
B − Cl B − Cl
1
( 303 ) 151.5
or, 0.866 = 2 =
B − Cl B − Cl
151.5
B − Cl = = 170.79 pm
0.866
⎯⎯ → Base + Acid + ( X )
(X) is a compound of beryllium, what is it’s molar mass in g mol-1 unit?
[At. mass Be = 9, N = 14, F = 19, O = 16]
5. 47
Sol. P = (NH4)2BeF4, Base = NH3, Acid = HF, X = BeF2
6. How many of the following substance(s) contain(s) more covalent character than NaBr?
NaCl, MgBr2, KCl, RbBr, LiI, NaI, BeI2, NaF, Cu2Br2, LiBr, AlBr3, KBr
6. 7
Sol. Apply Fajan’s rule.
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1. ABCD
Sol. x 2 + y 2 – 4x + 2y + 1 = 0
(x – 2)2 + (y + 1)2 = 4
(5, 3)
(x, y)
(2, -1)
[5 – 2, 5 + 2]
2. BD
Sol. Let the circle be x 2 + y 2 + 2gx + 2fy + c = 0
given : 2f − 2g + 9 = 0 2f = 2g − 9 and c − 4 = 0 c = 4
Circle is x2 + y2 + 2gx + ( 2g − 9) y + 4 = 0
( x2 + y2 − 9y + 4 ) + 2g ( y + x ) = 0
( )
Circle passes through points of intersection of x2 + y2 − 9y + 4 = 0 and
2g( y + x ) = 0
On solving : y = 4, 1
2
Points are (–4, 4) and − 1 , 1
2 2
3. A circle touches the y – axis at the point (0, 4) and passes through the point (2, 0).
Which of the following lines is a tangent to this circle?
(A) 3x − 4y − 24 = 0 (B) 3x + 4y − 6 = 0
(C) 4x − 3y + 17 = 0 (D) 4x + 3y − 8 = 0
3. ABC
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4. The point(s) on the locus of the mid – points of the perpendiculars drawn from points on
the line, x = 2y to the line x = y is/are:
(A) (7, 5) (B) (5, 7)
(C) (10, 14) (D) (14, 10)
4. AD
k− y=x
Sol. Slope AB = = −1
h − 2
k +k
= …….(1)
3
+ 2 + x
also = h, =k B (,) =y
2 2 2
= 2h − 2k …….(2) M (h, k)
From (1) and (2)
h+k
= 2h − 2k A ( 2, )
3
5h = 7k
5x = 7y
5. A point on the straight line, 3x + 5y = 15 which is equidistant from the coordinate, axes
will lie only in:
(A) 4th quadrant (B) 2nd quadrants
st
(C) 1 quadrant (D) 3rd quadrants
5. BC
15 − 3t
Sol. Now, = t
5
15 − 3t 15 − 3t
= t or = −t
5 5
15 −15
t= or t =
8 2
15 15 st
So, P , 1 quadrant
8 8
−15 15
or P , IInd Quadrant
2 2
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6. Let two points be A (1, –1) and B (0, 2). If a point P ( x',y' ) be such that the area of
PAB = 5 sq. units and it lies on the line, 3x + y − 4 = 0 , then a value of is:
(A) 3 (B) 4
(C) - 2 (D) –3
6. AC
0 2 1
1
Sol. D = 1 −1 1
2
x' y' 1
−2 (1− x' ) + ( y'+ x' ) = 10
−2 + 2x'+ y'+ x' = 10
3x'+ y' = 12 or 3x '+ y ' = −8
= 3, − 2
7. The points (–6, 1); (6, 0); (–3, –3) are the vertices of a parallelogram. If the area of the
a
portion of this parallelogram lying above the x – axis is ; find the value of a + b, given
b
a and b are co – primes.
(A) a = 225 (B) a =8
(C) b =10 (D) a + b = 233
7. AD
a
Sol. Given area of portion of parallelogram above x – axis =
b
= (area of parallelogram) – (area of PBC )
Y
D (3, 4)
1
M 0,
A (–6, 1) 2
X
C (6, 0)
B (–3, –3)
= (145 )
45 1
− (PC ) 3
145 2
1 21
= 45 − 6 + 3
2 4
45 45 3 45 4 − 45 3
= − =
1 8 8
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5 225
= 45 =
8 8
a = 225, b = 8
a + b = 233 .
8. AC
Sol. 3y 2 + 2xy − 8y − x 2 + 4 = 0 can be written as (3y − x − 2)( y + x − 2) = 0
The third line is passing through (–5, 1)
Let it be p ( x + 5) + q ( y − 1) = 0
−p
Slope of third line m =
q
−1
Now slope of the line joining (–5, 1) and (0, 0) is and slope of x + y − 2 = 0 is –1,
5
these two are the extreme possibilities
Y
(0, 2)
(–5, 1)
(2, 0)
X
Slop = –1/5
(–2, 0)
x+y=2
Slop = –1
Hence O (0, 0) will be interior point of the triangle when slope of the third line
−1
m −1,
5
−1
Comparing with interval (a, b), we get a = –1 and b =
5
1
a+ = −1 + 25 = 24
b2
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This section contains 2 List-Match Sets, each List-Match set has 2 Multiple Choice Questions. Each
List-Match set has two lists: List-I and List-II. Four options are given in each Multiple Choice Question
based On List-I and List-II and ONLY ONE of these f our options satisf ies the condition asked in the
Multiple Choice Question.
For Questions 9 to 10
x 2 + y 2 − x + 2y + c = 0 intersect orthogonally
(III) The circle x2 + y2 = 9 is contains the circle (R) If c =
1
x 2 + y 2 − 2x + 1 − c 2 = 0 2
(IV) The circle x2 + y2 = 9 is contains in the circle (S) If c > 8
c
x 2 + y 2 − 2x + 1 − = 0
2
(T) If c > 16
9. A
( )
2
The circles are S1 : ( x + 1) + y 2 =
2
(i) 1− c
( )
2
C1 ( −1,0) and r1 = 1− c and S2 :x 2 + ( y + 1) =
2
1− c
C2 ( 0, − 1) and r2 = r1; Now C1C2 = 2, as r1 = r2
The circles will touch externally only and C1C2 = r1 + r2
1 1
2 1 − c = 2; Hence 1 − c = c=
2 2
2
3 13
2
The circles are S1 = ( x + 1) + y + =
2
(ii) −c
2 4
3 13
C1 −1, − and r12 = −c
2 4
2
1 5
+ ( y + 1) = − c
2
Now, S2 : x −
2 4
1 5
C2 , − 1 and r22 = − c
2 4
For orthogonal intersection C1C22 = r12 + r22
2 2
3 1 18
+ = − 2c c = 1
2 2 4
( c)
2
C1 (0,0) and r1 = 3 and S2 : ( x − 1) + y2 =
2
C1 (1,0 ) and r2 = c
Now S1 will be contained in S 2 when r2 − r1 C1C2
c −3 1 c 16
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For Questions 11 to 12
Column-I Column-II
(P) 1
If ax + y=1 intersects the curve 5x − 15y + 3xy + 5 = 0
(I) 2 2
(III) The equation of three sides of a triangle are x = 2, y +1=0 and (R) 3
x+2y=4. If coordinate of circumcentre is ( , ) , then + is
equal to
11. D
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Column-I Column-II
(III) The equation of three sides of a triangle are x = 2, y +1=0 and (R) 3
x+2y=4. If coordinate of circumcentre is ( , ) , then + is
equal to
12. C
(PART – B)
(Integer Type)
Part-C (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks f or correct answer and there will be no negative marking.
1. 3 circles with radii r1,r2 ,r3 where (r1 r2 r3 ) touch each other externally. If they have a
r1 r
common tangent, then the value of + 1 is
r2 r3
1. 1
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0102 = r1 + r2 = 2 + (r1 − r2 )
2
0103 = r1 + r3 = 2 + (r1 − r3 )
2
2. 36
Sol. Two circles touches each other if C1 C2 = r1 r2
3. The length of the perpendicular from the origin, 0n the normal to the curve,
x 2 + 2xy − 3y 2 = 0 at the point (2, 2) is
then ‘k’ is
3. 8
Sol. x 2 + 2xy − 3y 2 = 0
x 2 + 3xy − xy − 3y 2 = 0
( x − y )( x + 3y ) = 0
x−y =0 x + 3y = 0
(2, 2) satisfy x − y = 0
Normal x + y =
=4
Hence x + y = 4
0+0−4
Perpendicular distance from origin = =2 2
2
0+0−4
= =2 2
2
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4. Let P ( ,) be a point in the first quadrant, circles are drawn through P touching the co
– ordinate axes such that the circles are orthogonal and 2 + 2 = k then find the
value of k.
4. 4
Let the circle is ( x − r ) + ( y − r ) = r 2
2 2
Sol.
x 2 + y 2 − 2rx − 2ry + r 2 = 0
Two circles are possible through ( ,) and touching coordinate axes and let r1 and r2
be their radii
So there equations are x2 + y2 − 2r1x − 2r1y + r12 = 0 ………….(1)
and x2 + y2 − 2r2x − 2r2y + r22 = 0 ………….(2)
where r1 and r2 are roots of r 2 − 2r ( + ) + 2 + 2 = 0
r1 + r2 = 2 ( + )
r1r2 = 2 + 2
For orthogonality of (1) and (2)
4r1r2 = r12 + r22
( )
4 2 + 2 = 4 ( + ) − 2 2 + 2
2
( )
6 ( 2
+ 2 ) = 4 ( 2
+ 2 + 2 )
2 2 + 22 − 8 = 0
2 + 2 = 4
3
5. Let A (1,0),B ( 6,2) and C ,6 be the vertices of a triangle ABC. If P is a point inside
2
the triangle ABC such that the triangles APC, APB and BPC have equal areas, then the
7 1
length of the line segment PQ, where Q is the point − , − is
6 3
5. 5
Sol. P will be centroid of ABC
2
17 8 24 9
P , PQ = + =5
6 3 6 3
6. The extremities of a diagonal of rectangle are (–4, 4) and (6, –1). A circle circumscribes
the rectangle and cuts an intercept AB on y – axis. If the area of the triangle formed by
k
AB and the tangents to the circle at A and B is , then the sum of digits of ‘k’ is
8
6. 8
Sol. Let P (–4, 4) and Q (6, –1) be the extremities of a diagonal then the circle is
x 2 + y 2 − 3y − 28 = 0 .
This circles will intersect y – axis at A and B, so y − 3y − 28 = 0
2
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A (0, 7)
R (–4, 4)
P
X
Q (6, –1)
B (0, 4)
3 3
x ( x1 − 1) + y y1 − − x1 − y1 − 28 = 0
2 2
3 9 −121
y1 = and x1 + + 28 = 0 x1 =
2 4 4
121 3
Hence M = − ,
4 2
121 11 1331
Now area MAB is A = = square units
4 2 8
k 1331
=
8 8
k = 1331