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Physics Chemistry Math Exam Guide

The document provides instructions for a physics, chemistry, and mathematics test. It outlines that the test has three sections, with Section I focusing on physics. It provides instructions on marking answers, time limits, prohibited items, and details on the test format including multiple choice and numerical questions. The summary highlights that the document outlines instructions and formatting for a STEM test covering physics, chemistry, and math.

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0% found this document useful (0 votes)
811 views25 pages

Physics Chemistry Math Exam Guide

The document provides instructions for a physics, chemistry, and mathematics test. It outlines that the test has three sections, with Section I focusing on physics. It provides instructions on marking answers, time limits, prohibited items, and details on the test format including multiple choice and numerical questions. The summary highlights that the document outlines instructions and formatting for a STEM test covering physics, chemistry, and math.

Uploaded by

Yoyo
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

FIITJEE – CM Monthly Test-2

PHYSICS, CHEMISTRY & MATHEMATICS


Pattern -2 QP Code:

Time Allotted: 3 Hours Maximum Marks: 186

▪ Pl e a se re ad th e i n structio ns ca reful ly. Yo u a re a l lo tted 5 m i nute s sp e ci ficall y f o r


th i s p u rp ose.
▪ Yo u a re n o t a l l o wed to l e ave th e Exami nati on H a ll b efo re t h e e n d o f th e te st.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
BATCHES –2123

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Part.


(i) Part-A (01-08) – Contains eight (08) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provi ded NO i ncor re ct
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: −1 In all other cases.

(ii) Part-A (09-12) – This section contains Two (02) List-Match Sets, each List-Match set has Two (02) Multiple
Choice Questions. Each List-Match set has two lists: List-I and List-II. FOUR options ar e g i ven i n eac h
Multiple Choice Question based On List-I and List-II and ONLY ONE of these four o ptions s ati sfi es th e
condition asked in the Multiple Choice Question. Each question carries +3 Marks for correct c o mbi nation
chosen and -1 marks for wrong options chosen.
(iii) Part-B (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+3 marks for correct answer. There is no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________


2
CM Test-II-(C-XI)-PCM-IITJEE/23

SECTION – I : PHYSICS
(PART – A)
(One or More Than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. A Block A is placed on a smooth horizontal surface and a particle C


is suspended with the help of light rod from point B of the block as v0
shown. Now both the block A and the particle C are given velocity v 0
A
towards left. The block A strikes a fixed wall and suddenly stops. B
Then, (The rod BC is free to rotate about B) 
C

(A) the smallest velocity v 0 for which the particle C will swing in a full circle about the
point B is 4g .
(B) the smallest velocity v 0 for which the particle C will swing in a full circle about the
point B is g .
(C) velocity of point C at the highest point of the circle (for the smallest value of v 0) is
zero.
(D) velocity of point C at the highest point of the circle (for the smallest value of v 0)
is g .

1. AC
Sol. Result: The minimum velocity at lowest point for a particle attached to a massless rod, to
compile vertical circle = 4g .

2. A book leans against a crate on a table (both having equal


masses m each). All the surfaces are identically rough
(friction coefficient = µ). Now when released from rest,
which of the following may be correct? (assume
magnitudes of each force only)
(A) The force by the ground on the book is less than that on crate by the ground.
(B) The force by the ground on the book is more than that on crate by the ground.
(C) The force by the ground on the book is equal that on crate by the ground.
(D) Reaction force on the book by the ground, is not parallel to the table’s surface.

2. ACD
Sol. f1
f1 N3 We can see that N3 will be more than N2.
N2 N1
N2
m
m

f2
f3
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CM Test-II-(C-XI)-PCM-IITJEE/23

3. A bob of mass m 1 hangs by a light inextensible string a2


v2
which passes over a fixed smooth pulley P and
connects a ring of mass m 2. The ring is constrained 
m2
to move along a smooth rigid horizontal rod. The
instantaneous velocities and acceleration of the
P
bodies are v1,a1 and v2 ,a2 respectively then:
(A) a1 = a2 cos 
(B) v 1 = v 2 cos 
(C) a1 = a2 sin  a1
m1
v1
(D) v 1 = v 2 sin 

3. B
Sol. Apply virtual work method to get relation among velocities, then differentiate w.r.t. time.
force
4. A curve between force and displacement is drawn for a
particle moving in x axis only conservative forces are
acting
(A) At x 1 & x 3 particle in stable equilibrium. x1 x2 x3 x4
(B) At x 1 & x 3 particle in unstable equilibrium.
(C) At x 2 & x 4 particle in stable equilibrium.
(D) At x 2 & x 4 particle in unstable equilibrium.

4. BC
Sol. A stable equilibrium position n, F should be negative or n increases and vice versa.

5. For the system shown in the figure, the pulleys are light and
frictionless. Assume wedge to be fixed and smooth. The
m
tension in the string will be
2 3 
(A) mg sin  (B) mg sin  m
3 4
1
(C) mg sin  (D) mg sin 
2

5. C
Sol. Simply apply Newton’s force equilibrium with a1 = a 2 .

6. In the adjacent figure, two identical beads of mass m free to slide on O


a fixed smooth vertical ring are attached to the free ends of two
(2 + 3)mg
identical light springs of spring constant k= . The other
3R
ends of the springs are fixed to the highest point O on the ring.

Initially beads are at rest and angle between the springs is 60º at the fixed point O.
Normal length of each spring is 2R, where R is the radius of the ring. Beads are initially
symmetric w.r.t. the vertical diameter and now they are released, then the normal
reaction on one of the bead at initial moment due to the ring is
mg 3mg
(A) (B)
2 2
(C) mg (D) zero

6. C
4
CM Test-II-(C-XI)-PCM-IITJEE/23

Sol. Each of the springs is already compression. A component of the spring force will be
balanced by the normal reaction.

7. As situations shown in figure all pulleys and strings are P3


massless and frictionless. The system is released from rest.
Take g is the acceleration due to gravity in vertically g
downward direction.
P1
(A) The acceleration of pulley P1 will be g downward
(B) The acceleration of pulley P1 will be 3g downward
P2
(C) The acceleration of pulley P2 will be zero
(D) The acceleration of pulley P2 will be g downward
m1 m2

7. BD
Sol. The pulley P1 will / should experience zero net force, so T = 0. Now apply constraint.

8. Find the forces in the hinged rods BC and AC, if AB = 60


cm, AC = 1.2 m, BC = 1.6 m (see figure). Hanging mass
has a mass of 50 kg, the mass of the rods can be
neglected. C is hinge.
(A) AC is in tension with force of 1000 N.
(B) AC is in tension with force of 4000/3 N.
(C) BC is in compression with force of 4000/3 N.
(D) BC is in compression with force of 400 N.

8. AC
Sol. One of the rods (BC) should be in compression while the other (AC) should be stretched
in tension. Now apply force balance along horizontal and along vertical.
5
CM Test-II-(C-XI)-PCM-IITJEE/23

This section contains 2 List-Match Sets, each List-Match set has 2 Multiple Choice Questions. Each
List-Match set has two lists: List-I and List-II. Four options are given in each Multiple Choice Question
based On List-I and List-II and ONLY ONE of these f our options satisf ies the condition asked in the
Multiple Choice Question.

For Question 9 to 10

String 2 String 3
The system shown below is initially in
equilibrium C
mA = mB = 3kg Spring 1
String 4
mC = mD = mE = 2kg
Take g = 10 m/s2 B D

String 1 Spring 2

A E

List–I gives the four strings while List–II the value of the tension in the strings.

List – I List – II
(I) String 1 (P) 10 N
(II) String 2 (Q) 20 N
(III) String 3 (R) 30 N
(IV) String 4 (S) 40 N
(T) 60 N
(U) 0N

9. If the spring 1 is cut, match the correct for the tension in the strings just after the cutting.
(A) I → R, II → T, III → T, IV → P (B) I → U, II → T, III → T, IV → P
(C) I → U, II → U, III → U, IV → P (D) I → R, II → S, III → S, IV → P

9. C
Sol. Just after cutting force of cut spring will be zero whereas the force of other spring will be
unchanged.

10. If the spring 2 is cut, match the correct for the tension in the strings just after the cutting.
(A) I → R, II → T, III → T, IV → R (B) I → R, II → U, III → U, IV → R
(C) I → U, II → R, III → R, IV → P (D) I → P, II → Q, III → Q, IV → R

10. A
Sol. Just after cutting force of cut spring will be zero whereas the force of other spring will be
unchanged.
6
CM Test-II-(C-XI)-PCM-IITJEE/23

For Question 11 to 12

A
m

 k
Spring at its
Very high
natural length
table

B m
Block is released
from rest

After the above displayed event, consider the following two columns.

List-I List-II
(I) Maximum possible elongation in the (P) Either zero or (2 g)
spring.
(II) Maximum possible spring force (Q) mg
k
(III) Maximum acceleration of block A (R) 2mg
k
(IV) Maximum acceleration of block B (S) mg
(T) g
(U) 2 gm

11. If  = 0, then correct match is:


(A) I → Q, II → U, III → P, IV → T (B) I → R, II → U, III → P, IV → T
(C) I → Q, II → S, III → P, IV → T (D) I → Q, II → S, III → T, IV → T

11. D
Sol. At the maximum elongation, both the block will have same speed

12. If  = 1, then correct match is:


(A) I → R, II → U, III → P, IV → P (B) I → Q, II → S, III → P, IV → R
(C) I → R, II → U, III → P, IV → T (D) I → Q, II → S, III → P, IV → T

12. C
Sol. Apply the result, maximum elongation in spring = 2mg/k, when the upper spring is
not moving.
7
CM Test-II-(C-XI)-PCM-IITJEE/23

(PART – B)
(Integer Type)
Part-C (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks f or correct answer and there will be no negative marking.

1. A rod of mass 2kg is constrained to move perpendicular to


1m/s
inclined plane of wedge which is placed on rough horizontal
surface having friction coefficient  = 0.1. Fixed wall
A constant force F0 is applied on the wedge of mass 4 kg in
such a way that the rod moves with constant velocity 1 m/s 2kg
along the wall. The power delivered by F0 (in watts) is
F0
4kg
600 =0.1

1. 15.19 (Range: 15.10 to 15.25)


Sol. Apply contact constraint to get velocity of the rod and then apply P = F  V.

2. A particle of mass m slides down from the vertex of hemisphere with initial tangential
velocity 7 m/s. At what height in m, form horizontal will the particle leave the sphere.
(Radius of sphere R = 10 m and g = 10 m/s2)

2. 8.30 (Range: 8.20 to 8.40)


Sol. Apply energy (Total mechanical) conservation theorem, centripetal force = (mass) ×
(centripetal acceleration). Now put N = 0.

3. Figure shows a bob hanging from a point “O” through a O


string of length “ = 1 m”. The bob is given a velocity uo
= 2 g as shown. The maximum height ( in m) raised
by bob above lowest point will be ?
uo = 2 g

3. 1.85 (Range: 1.80 to 1.90)


Sol. The particle given speed u = 4g which is less than 5g , hence the string will slack
at some height and then further the practice will follow projection motion.

4. What is the magnitude of acceleration of each m


m
block as shown in figure ) (Assume pulleys & 30°
strings are ideal) m
(take g = 10 m/s2) 45°

m
60°

4. 5.18 (Range: 5.10 to 5.30)


Sol. All blocks move with same magnitude of acceleration, so, a = component of each weight
along incline.
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CM Test-II-(C-XI)-PCM-IITJEE/23

5. In the given figure, the mass of block A is 40 kg and of block B is 20 kg. There is no
friction at any of the contact surface. Both the systems are held at rest initially. The ratio
of acceleration of block B in condition (i) to condition (ii) just at the moment system is
released, is

A A
B B

(i) (ii)

5. 1.06 (Range: 1.01 to 1.10)


Sol. In case (I) A & B will have same horizontal acceleration while in case (II), only A will
move along horizontal initially.

6. The block shown in the figure is in equilibrium. The


ng
acceleration of the block just after the string burns is . 53
3
Find the value of ‘n’.

6. 4.00
Sol. The spring force will remain the same, before and just after the cutting of the string.
9
CM Test-II-(C-XI)-PCM-IITJEE/23

SECTION – II : CHEMISTRY
(PART – A)
(One or More Than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. The first ionization enthalpies of two elements P and Q respectively are 8.1 and 10.2 eV.
The electron gain enthalpies of P and Q are respectively -3.1 and -6.6 eV respectively.
The percentage ionic character of the covalent bond P – Q is given as
% ionic character = 16(END) + 3.5(END) 2
Where END is the electronegativity difference in Pauling scale between P and Q.
Choose correct statements
(A) The electronegativity of P is 1.05
(B) Q is more electronegative than P
(C) percentage covalent character of P – Q bond is 80.5
(D) P – Q bond is purely covalent with 100% covalent character

1. BC
8.1 + 3.1
Sol. E.N of P = =2
5.6
10.2 + 6.6
E.N of Q = =3
5.6
% ionic character = 16(3 - 2) + 3.5(3 - 2)2 = 19.5
% covalent character = 100 – 19.5 = 80.5

2. The hydrated compound MgI2.xH2O is formed when HI is treated with


(A) MgO (B) Mg(NO3)2
(C) Mg(OH)2 (D) MgCO 3

2. ACD
Sol. Acid(HI) base(MgO, Mg(OH)2, MgCO3) reaction takes place.

3. In which of the following molecule(s) the bond containing H and the central atom
contains more than 25% s-orbital character?
H
(A) C (B) O
H Cl H H
Cl
F
N
(C) H H (D) C Cl
H
H H

3. AD
S
Sol. Cos =
S −1
Where  = bond angle containing hydrogen and central atom
S = % s-orbital character.
In H2O,  = 104.5o
S
Cos 104.5o = -0.25 =
S −1
10
CM Test-II-(C-XI)-PCM-IITJEE/23

On solving S = 0.2, hence the O – H bond contain 20% s-orbital character and 80% p-
orbital character.
 (B) is not correct similarly (C) will not be correct.

4. Which of the following two compound(s) is/are distinguished by heating?


(A) LiNO 3 and NaNO 3 (B) CaCO 3 and SrCO3
(C) Mg(NO3)2 and Ca(NO 3)2 (D) KI and KNO 3

4. AD

Sol. (A) 4LiNO3 ⎯⎯ → 2Li2O + 4NO2 + O2

2NaNO3 ⎯⎯ → 2NaNO2 + O2
LiNO3 produces a colourfull gas(NO 2)
NaNO3 produces colourless gas
(B) Both compounds liberate CO 2 gas
(C) Both compounds liberate same gases
(D) 2KI ⎯⎯ → 2K + I2 ( violet )
KNO3 liberates no gas on heating.

5. Beryllium can be prepared by electrolysis of fused BeCl 2. Which of the following


substance(s) do you need to prepare BeCl2?
(A) Cl2 (B) Be(OH)2
(C) Carbon (D) HCl

5. ABC
Sol. Be (OH)2 ⎯⎯

→BeO + H2O
BeO + C + Cl2 ⎯⎯→ BeCl2 + CO
BeCl2 ⎯⎯⎯⎯⎯
Electrolysis
→ Be + Cl2

6. Heating of hard water in a boiler results in the


(A) formation of scales inside the boiler
(B) removal of temporary hardness
(C) evolution of H2 and O2 from the boiler
(D) formation of Mg(OH)2

6. ABD
Sol. Ca or Mg (HCO3 )2 ⎯⎯

→ CaCO3  + CO2 + H2O
HCO3− + H2O ⎯⎯→ H2CO3 + OH−
Mg (HCO3 )2 + 2OH− ⎯⎯→ Mg ( OH)2  +2HCO3−
CaCO 3 is responsible for scale formation.

7. Which of the following statement(s) is/are correct regarding cyanate ion OCN – and
fulminate ion CNO –?
(A) OCN– ion has more stable resonating structures than CNO – ion.
(B) Protonation of cyanate ion forms two acids HNCO and HOCN whereas protonation
of fulminate ion forms one acid HCNO.
(C) Fulminic acid(HCNO) is linear in the vapour phase
(D) The dipole moment of HCNO is zero.

7. ABC
11
CM Test-II-(C-XI)-PCM-IITJEE/23

Sol. The resonating structures of cyanate ion are

O = C = N ⎯→ O − C  N

2
O  C −N
The resonating structures of fulminate ion CNO – are
2 3

C  N − O ⎯→ C = N = O ⎯→ C − N  O
In one resonating structure oxygen carries negative charge and in all three structure
carbon carries negative charge. Therefore H+ gets bonded to carbon forming
HCNO(fulminic acid).

Structure of HCNO is H − C  N → O . It is linear in vapuor phase.

8. The correct statement(s) regarding PCl2Br3 molecule is/are


(A) the formal charge on phosphorus is zero.
(B) the electronegativity of phosphorus in PCl2Br3 is higher than that in PF2Cl3.
(C) the ClPCl bond angle is the largest bond angle observed in the molecule.
(D) the bond pair electrons are more nearer to Cl in P – Cl bond than the bonds pairs
towards bromine in P – Br bond.

8. ACD
Sol. Structure of PCl2Br3 is
Br Cl

P
Br Br
Cl

This section contains 2 List-Match Sets, each List-Match set has 2 Multiple Choice Questions. Each
List-Match set has two lists: List-I and List-II. Four options are given in each Multiple Choice Question
based On List-I and List-II and ONLY ONE of these f our options satisf ies the condition asked in the
Multiple Choice Question.

For Question 9 to 10

Match the following & answer accordingly:


List – I List– II
(I) NaOH (P) Used as a component in antacid
syrup
(II) Ca(OH)2 (Q) Forms white turbidity when CO 2 is
passed through their aqueous
solution
(III) Mg(OH)2 (R) Dissolves metal as well as non-
metals
(IV) Ba(OH)2 (S) Forms a disinfectant when reacts
with Cl2
(T) Obtained as a white precipitate
when Ca(OH)2 reacts with sea-
water
(U) Neutralisation with H2SO4 become
difficult due to formation of
protective layer
12
CM Test-II-(C-XI)-PCM-IITJEE/23

9. Choose the correct matching?


(A) I → T (B) II → S
(C) III → U (D) IV → P

9. B

Match the following & answer accordingly:


List – I List– II
(I) NaOH (P) Used as a component in antacid
syrup
(II) Ca(OH)2 (Q) Forms white turbidity when CO 2 is
passed through their aqueous
solution
(III) Mg(OH)2 (R) Dissolves metal as well as non-
metals
(IV) Ba(OH)2 (S) Forms a disinfectant when reacts
with Cl2
(T) Obtained as a white precipitate
when Ca(OH)2 reacts with sea-
water
(U) Neutralisation with H2SO4 become
difficult due to formation of
protective layer

10. Choose the correct matching?


(A) I → P (B) II → R
(C) III → S (D) IV → Q

10. D
Sol. Cl
Ca ( OH)2 + Cl2 ⎯⎯→ Ca + H2O
OCl
Ba ( OH)2 + CO2 ⎯⎯→BaCO3  + H2O

For Question 11 to 12

Match the following & answer accordingly:


List – I List– II
(I) NO2BF4 (P) p - p back bond is observed
(II) (SiH3)2O (Q) Bond angle HSiH is greater than
109.5o
(III) BF2Cl (R) Nitrogen undergoes sp-
hybridization
(IV) :N(SiH3)3 (S) Electron deficient compound with
non-zero dipole moment
(T) Boron undergoes sp3-
hybridization
(U) Has angular shape

11. Choose the correct matching?


(A) I → P (B) II → U
(C) III → T (D) IV → S
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CM Test-II-(C-XI)-PCM-IITJEE/23

11. B

Match the following & answer accordingly:


List – I List– II
(I) NO2BF4 (P) p - p back bond is observed
(II) (SiH3)2O (Q) Bond angle HSiH is greater than
109.5o
(III) BF2Cl (R) Nitrogen undergoes sp-
hybridization
(IV) :N(SiH3)3 (S) Electron deficient compound with
non-zero dipole moment
(T) Boron undergoes sp3-
hybridization
(U) Has angular shape

12. Choose the correct matching?


(A) I → U (B) II → P
(C) III → S (D) IV → R

12. C

(PART – B)
(Integer Type)
Part-C (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks f or correct answer and there will be no negative marking.

1. Barium ⎯⎯⎯2 N
→P ⎯⎯⎯
2
→Q + R 
HO
Heat

⎯⎯⎯
CO
→S + T

Q + H2SO4
U  + H2O
white
S + H2SO4

What is the molar mass of T in g mol–1 unit? [At. mass of Ba = 137]

1. 189
Sol. P = Ba3N2, Q = Ba(OH)2, R = NH3, S = BaO, T = Ba(CN)2

2. The successive ionization enthalpies of the representative elements are given below in
eV unit.
Elements I.E1 I.E2 I.E3 I.E4
P 8.6 18.8 32.9 1830.4
Q 9.2 15.8 1021.8 2106.8
R 4.6 820.9 1926.5 3269.8
S 1296.2 1862.9 3589.6 7216.9
If the atomic mass of Q is 87.26 g mol what will be the molar mass of it’s oxide in g
–1

mol-1 unit?

2. 103.26
Sol. Q belongs to gr-2 as it contains two valence electrons.
14
CM Test-II-(C-XI)-PCM-IITJEE/23

3. The dipole moment AgCl is 6.08D in gaseous state. The Ag-Cl distance is 228.1 pm. If
the percent ionic character in AgCl is x%, what is x?

3. 55.5 (Range 55.47 to 55.56)


Sol.  = 6.08D
r = 228.1 pm
 6.08  3.3356  10−30
 Charge(q) = = −12
= 0.0889  10−18 C
r 228.1 10
0.0889  10−18
% ionic character = −19
 100 = 0.05548  103 = 55.48%
1.6022  10

4. The Cl – Cl distance in a BCl3 molecule in gaseous state is 303 pm. What is the bond
length(B – Cl distance) of BCl3 in pm unit?

4. 174.93 [Range: 174.92 to 175.02]


Sol. Cl

30o
Cl Cl
D
303 pm

1
DCl ( Cl − Cl)
Cos30 =o
= 2
B − Cl B − Cl
1
( 303 ) 151.5
or, 0.866 = 2 =
B − Cl B − Cl
151.5
B − Cl = = 170.79 pm
0.866

5. Be ( OH)2 + NH4HF2 ⎯⎯→ P + H2O


⎯⎯ → Base + Acid + ( X )
(X) is a compound of beryllium, what is it’s molar mass in g mol-1 unit?
[At. mass Be = 9, N = 14, F = 19, O = 16]

5. 47
Sol. P = (NH4)2BeF4, Base = NH3, Acid = HF, X = BeF2

6. How many of the following substance(s) contain(s) more covalent character than NaBr?
NaCl, MgBr2, KCl, RbBr, LiI, NaI, BeI2, NaF, Cu2Br2, LiBr, AlBr3, KBr

6. 7
Sol. Apply Fajan’s rule.
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SECTION – III : MATHEMATICS


(PART – A)
(One or More Than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. If (x, y) satisfies x 2 + y 2 – 4x + 2y + 1 = 0 then the complete set of values, then integer


values of the expression x 2 + y 2 − 10x − 6y + 34 can take, is
(A) 4 (B) 5
(C) 6 (D) 7

1. ABCD
Sol. x 2 + y 2 – 4x + 2y + 1 = 0
(x – 2)2 + (y + 1)2 = 4
(5, 3)

(x, y)

(2, -1)

[5 – 2, 5 + 2]

2. The centre of a circle S = 0 lies on 2x − 2y + 9 = 0 and S = 0 cuts orthogonally the circle


x 2 + y 2 = 4 . Then the circle must pass through the point:
(A) (1, 1) (B) (–1/2, 1/2)
(C) (5, 5) (D) (–4, 4)

2. BD
Sol. Let the circle be x 2 + y 2 + 2gx + 2fy + c = 0
given : 2f − 2g + 9 = 0  2f = 2g − 9 and c − 4 = 0  c = 4
 Circle is x2 + y2 + 2gx + ( 2g − 9) y + 4 = 0
 ( x2 + y2 − 9y + 4 ) + 2g ( y + x ) = 0

( )
 Circle passes through points of intersection of x2 + y2 − 9y + 4 = 0 and
2g( y + x ) = 0
On solving : y = 4, 1
2
 Points are (–4, 4) and  − 1 , 1 

2 2 

3. A circle touches the y – axis at the point (0, 4) and passes through the point (2, 0).
Which of the following lines is a tangent to this circle?
(A) 3x − 4y − 24 = 0 (B) 3x + 4y − 6 = 0
(C) 4x − 3y + 17 = 0 (D) 4x + 3y − 8 = 0

3. ABC
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Sol. Equation of family of circle


( x − 0 )2 + ( y − 4 )2 + x = 0
 passes (2, 0)
4 + 16 + 2 = 0   = −10
x 2 + y 2 − 10x − 8y + 16 = 0
centre (5, 4). R = 25 + 16 − 16 = 5
Check the options.

4. The point(s) on the locus of the mid – points of the perpendiculars drawn from points on
the line, x = 2y to the line x = y is/are:
(A) (7, 5) (B) (5, 7)
(C) (10, 14) (D) (14, 10)

4. AD
k− y=x
Sol. Slope AB = = −1
h − 2
k +k
= …….(1)
3
 + 2 + x
also = h, =k B (,) =y
2 2 2
 = 2h − 2k …….(2) M (h, k)
From (1) and (2)
h+k
= 2h − 2k A ( 2,  )
3
 5h = 7k
 5x = 7y

5. A point on the straight line, 3x + 5y = 15 which is equidistant from the coordinate, axes
will lie only in:
(A) 4th quadrant (B) 2nd quadrants
st
(C) 1 quadrant (D) 3rd quadrants

5. BC
15 − 3t
Sol. Now, = t
5
15 − 3t 15 − 3t
 = t or = −t
5 5
15 −15
 t= or t =
8 2
 15 15  st
So, P  ,  1 quadrant
 8 8 
 −15 15 
or P  ,  IInd Quadrant
 2 2 
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6. Let two points be A (1, –1) and B (0, 2). If a point P ( x',y' ) be such that the area of
PAB = 5 sq. units and it lies on the line, 3x + y − 4 = 0 , then a value of  is:
(A) 3 (B) 4
(C) - 2 (D) –3

6. AC
0 2 1
1
Sol. D = 1 −1 1
2
x' y' 1
−2 (1− x' ) + ( y'+ x' ) = 10
−2 + 2x'+ y'+ x' = 10
3x'+ y' = 12 or 3x '+ y ' = −8
 = 3, − 2

7. The points (–6, 1); (6, 0); (–3, –3) are the vertices of a parallelogram. If the area of the
a
portion of this parallelogram lying above the x – axis is ; find the value of a + b, given
b
a and b are co – primes.
(A) a = 225 (B) a =8
(C) b =10 (D) a + b = 233

7. AD
a
Sol. Given area of portion of parallelogram above x – axis =
b
= (area of parallelogram) – (area of PBC )
Y
D (3, 4)

 1
M  0, 
A (–6, 1)  2
X
C (6, 0)

B (–3, –3)

= (145 )
 45  1
 − (PC )  3
 145  2
1 21 
= 45 −  6 +   3
2 4
45 45  3 45  4 − 45  3
= − =
1 8 8
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 5  225
= 45   =
8 8
 a = 225, b = 8
 a + b = 233 .

8. Two sides of a triangle have the combined equation x 2 − 3y 2 − 2xy + 8y − 4 = 0 . The


third side, which is variable always passes through the point (–5, 1). If the range of
values of the slope of the third line so that the origin is an interior point of triangle is the
interval (a, b), then
(A) a = -1 (B) a =0
 1  1
(C)  a +  =24 (D)  a +  = 25
 b2   b2 

8. AC
Sol. 3y 2 + 2xy − 8y − x 2 + 4 = 0 can be written as (3y − x − 2)( y + x − 2) = 0
The third line is passing through (–5, 1)
Let it be p ( x + 5) + q ( y − 1) = 0
−p
Slope of third line m =
q
−1
Now slope of the line joining (–5, 1) and (0, 0) is and slope of x + y − 2 = 0 is –1,
5
these two are the extreme possibilities
Y

(0, 2)
(–5, 1)
(2, 0)
X

Slop = –1/5

(–2, 0)
x+y=2

Slop = –1
Hence O (0, 0) will be interior point of the triangle when slope of the third line
 −1 
m   −1, 
 5 
−1
Comparing with interval (a, b), we get a = –1 and b =
5
1
a+ = −1 + 25 = 24
b2
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This section contains 2 List-Match Sets, each List-Match set has 2 Multiple Choice Questions. Each
List-Match set has two lists: List-I and List-II. Four options are given in each Multiple Choice Question
based On List-I and List-II and ONLY ONE of these f our options satisf ies the condition asked in the
Multiple Choice Question.

For Questions 9 to 10

Match the following


Column-I Column-II
(I) The circle x + y + 2x + c = 0 (where c > 0) and (P)
2 2 If c = 1

x 2 + y 2 + 2y + c = 0 touch each other


(II) The circle x 2 + y 2 + 2x + 3y + c = 0 and (Q) If c  2

x 2 + y 2 − x + 2y + c = 0 intersect orthogonally
(III) The circle x2 + y2 = 9 is contains the circle (R) If c =
1
x 2 + y 2 − 2x + 1 − c 2 = 0 2
(IV) The circle x2 + y2 = 9 is contains in the circle (S) If c > 8
c
x 2 + y 2 − 2x + 1 − = 0
2
(T) If c > 16

9. Which is correct option?


(A) I→R (B) III→Q, R,S
(C) II→P, S (D) IV →P, R, S

9. A

Match the following


Column-I Column-II
(I) The circle x + y + 2x + c = 0 (where c > 0) and (P)
2 2 If c = 1
x 2 + y 2 + 2y + c = 0 touch each other
(II) The circle x 2 + y 2 + 2x + 3y + c = 0 and (Q) If c  2
x 2 + y 2 − x + 2y + c = 0 intersect orthogonally
(III) The circle x2 + y2 = 9 is contains the circle (R) If c =
1
x 2 + y 2 − 2x + 1 − c 2 = 0 2
(IV) The circle x2 + y2 = 9 is contains in the circle (S) If c > 8
c
x 2 + y 2 − 2x + 1 − = 0
2
(T) If c > 16

10. Which is correct option?


(A) I→Q, R (B) III→ Q, R, S
(C) II→P (D) IV →S
10. C
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Solutions 9 & 10.

( )
2
The circles are S1 : ( x + 1) + y 2 =
2
(i) 1− c

( )
2
 C1 ( −1,0) and r1 = 1− c and S2 :x 2 + ( y + 1) =
2
1− c
 C2 ( 0, − 1) and r2 = r1; Now C1C2 = 2, as r1 = r2
 The circles will touch externally only and C1C2 = r1 + r2
1 1
 2 1 − c = 2; Hence 1 − c = c=
2 2
2
3   13 
2

The circles are S1 = ( x + 1) +  y +  = 
2
(ii) −c 
 2   4 

 3 13
 C1  −1, −  and r12 = −c
 2 4
2
 1 5
+ ( y + 1) = − c
2
Now, S2 :  x −
 2 4
1  5
 C2  , − 1 and r22 = − c
2  4
For orthogonal intersection C1C22 = r12 + r22
2 2
 3   1 18
  +  = − 2c  c = 1
2  2 4

(iii) The circle S1 :x2 + y2 = 9


c2
 C1 (0,0),r1 = 3 and S2 : ( x − 1) + y 2 =
2
4
c
 C2 (1,0 ) ,r2 =
2
The circle S 2 will be contained in S1 when C1C2  r1 − r2
 r3  3 − 1 = 2  c2

(iv) The circle S1 :x2 + y2 = 9

( c)
2
 C1 (0,0) and r1 = 3 and S2 : ( x − 1) + y2 =
2

 C1 (1,0 ) and r2 = c
Now S1 will be contained in S 2 when r2 − r1  C1C2
 c −3 1  c  16
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For Questions 11 to 12

Match the following

Column-I Column-II

(P) 1
If ax + y=1 intersects the curve 5x − 15y + 3xy + 5 = 0
(I) 2 2

in A and B and AB subtends 90 at origin then a2 is equal to

(II) A ray of light coming along the line 3x + 2y − 5 = 0 gets (Q) 2


reflected from the line ax+by=1 and goes along the
line 2x + 3y = 5 , then 2a+4b is equal to

(III) The equation of three sides of a triangle are x = 2, y +1=0 and (R) 3
x+2y=4. If coordinate of circumcentre is ( ,  ) , then  +  is
equal to

(IV) The member of family of lines (S) 4


(  +  ) x + ( 2 +  ) y =  + 2 where   0,   0 and are
parameter pass through a fixed point ( ,  ) , then  +  is
equal to
(T) 5

11. Which is correct option?


(A) I→R (B) III→Q
(C) II→P (D) IV →Q

11. D
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Match the following

Column-I Column-II

(I) If ax + y=1 intersects the curve 5x − 15y + 3xy + 5 = 0


2 2 (P) 1

in A and B and AB subtends 90 at origin then a2 is equal to

(II) A ray of light coming along the line 3x + 2y − 5 = 0 gets (Q) 2


reflected from the line ax+by=1 and goes along the
line 2x + 3y = 5 , then 2a+4b is equal to

(III) The equation of three sides of a triangle are x = 2, y +1=0 and (R) 3
x+2y=4. If coordinate of circumcentre is ( ,  ) , then  +  is
equal to

(IV) The member of family of lines (S) 4


(  +  ) x + ( 2 +  ) y =  + 2 where   0,   0 and are
parameter pass through a fixed point ( ,  ) , then  +  is
equal to
(T) 5

12. Which is correct option?


(A) I→ R (B) III→Q
(C) II→R (D) IV →P

12. C

(PART – B)
(Integer Type)
Part-C (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks f or correct answer and there will be no negative marking.

1. 3 circles with radii r1,r2 ,r3 where (r1  r2  r3 ) touch each other externally. If they have a
r1 r
common tangent, then the value of + 1 is
r2 r3

1. 1
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Sol. Let O1 (0,r1 ), O2 ( ,r2 ) and


O3 (, r3 ) are the centers

0102 = r1 + r2 = 2 + (r1 − r2 )
2

0103 = r1 + r3 = 2 + (r1 − r3 )
2

0203 = r2 + r3 = (  − )2 + (r2 − r3 )2


(  −  )2 = 4r2r3
( )
2
4 r1r2 + r1r3 = 4r2r3
r1 r
+ 1 =1
r2 r3

2. If the curves, x 2 − 6x + y 2 + 8 = 0 and x2 − 8y + y2 + 16 − k = 0, (k  0 ) touch each


other at a point, then the largest value of k is

2. 36
Sol. Two circles touches each other if C1 C2 = r1  r2

Distance between C2 ( 3,0) and C1 ( 0,4 ) is either k + 1 = 5 or k −1 = 5


 k = 16 or k = 36
 maximum value of k is 36

3. The length of the perpendicular from the origin, 0n the normal to the curve,
x 2 + 2xy − 3y 2 = 0 at the point (2, 2) is
then ‘k’ is

3. 8
Sol. x 2 + 2xy − 3y 2 = 0
x 2 + 3xy − xy − 3y 2 = 0
( x − y )( x + 3y ) = 0
x−y =0 x + 3y = 0
(2, 2) satisfy x − y = 0
Normal x + y = 
=4
Hence x + y = 4
0+0−4
Perpendicular distance from origin = =2 2
2
0+0−4
= =2 2
2
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4. Let P ( ,) be a point in the first quadrant, circles are drawn through P touching the co
– ordinate axes such that the circles are orthogonal and  2 + 2 = k then find the
value of k.

4. 4
Let the circle is ( x − r ) + ( y − r ) = r 2
2 2
Sol.
 x 2 + y 2 − 2rx − 2ry + r 2 = 0
Two circles are possible through ( ,) and touching coordinate axes and let r1 and r2
be their radii
So there equations are x2 + y2 − 2r1x − 2r1y + r12 = 0 ………….(1)
and x2 + y2 − 2r2x − 2r2y + r22 = 0 ………….(2)
where r1 and r2 are roots of r 2 − 2r (  + ) + 2 + 2 = 0
r1 + r2 = 2 (  + )
r1r2 = 2 + 2
For orthogonality of (1) and (2)
4r1r2 = r12 + r22
( )
4  2 + 2 = 4 (  +  ) − 2  2 +  2
2
( )
6 ( 2
+ 2 ) = 4 ( 2
+ 2 + 2 )
2 2 + 22 − 8 = 0
 2 + 2 = 4

3 
5. Let A (1,0),B ( 6,2) and C  ,6  be the vertices of a triangle ABC. If P is a point inside
2 
the triangle ABC such that the triangles APC, APB and BPC have equal areas, then the
 7 1
length of the line segment PQ, where Q is the point  − , −  is
 6 3

5. 5
Sol. P will be centroid of ABC
2
 17 8   24   9 
P  ,   PQ =   +  =5
 6 3  6  3

6. The extremities of a diagonal of rectangle are (–4, 4) and (6, –1). A circle circumscribes
the rectangle and cuts an intercept AB on y – axis. If the area of the triangle formed by
k
AB and the tangents to the circle at A and B is , then the sum of digits of ‘k’ is
8

6. 8

Sol. Let P (–4, 4) and Q (6, –1) be the extremities of a diagonal then the circle is
x 2 + y 2 − 3y − 28 = 0 .
This circles will intersect y – axis at A and B, so y − 3y − 28 = 0
2
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CM Test-II-(C-XI)-PCM-IITJEE/23

 ( y − 7)( y + 4) = 0, i.e. A ( 0,7) and B (0, − 4) .


Let the point of intersection of tangent from A and B be at M( x1,y1 ), then chord of
3 3
contact of tangents is x1x + y1y − x − x1 − y − y1 − 28 = 0 (i.e. x = 0 )
2 2
Y

A (0, 7)

R (–4, 4)

P
X

Q (6, –1)
B (0, 4)

 3 3
 x ( x1 − 1) + y  y1 −  − x1 − y1 − 28 = 0
 2 2
3 9 −121
 y1 = and x1 + + 28 = 0  x1 =
2 4 4
 121 3 
Hence M =  − , 
 4 2
121 11 1331
Now area MAB is A =  = square units
4 2 8
k 1331
 =
8 8
 k = 1331

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