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Masterfinish 202 Sds

This safety data sheet provides information on hazards and safe handling guidelines for MasterFinish 202. The product contains diesel fuel and is classified as combustible and toxic to aquatic life with long lasting effects. It may also be fatal if swallowed and cause cancer. Personal protective equipment should be worn and the product stored locked up away from heat and ignition sources. Spills should be contained and cleaned up with absorbent material.

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100% found this document useful (1 vote)
327 views10 pages

Masterfinish 202 Sds

This safety data sheet provides information on hazards and safe handling guidelines for MasterFinish 202. The product contains diesel fuel and is classified as combustible and toxic to aquatic life with long lasting effects. It may also be fatal if swallowed and cause cancer. Personal protective equipment should be worn and the product stored locked up away from heat and ignition sources. Spills should be contained and cleaned up with absorbent material.

Uploaded by

azer
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MasterFinish 202

Product code : 000000000050358228 000000000050358228

Manufacturer or supplier's details


Company : SAUDI BASF FOR BUILDING
MATERIALS CO. LTD

Address : Dammam 2nd Industrial Area


AL Khobar 31952

Telephone : +966966138121140

Emergency telephone : ChemTel: +1-813-248-0585

Telefax : +966966138121822

Recommended use of the chemical and restrictions on use


Recommended use : Product for construction chemicals

2. HAZARDS IDENTIFICATION

GHS Classification
Aspiration hazard : 1

Flammable liquids : 4

Carcinogenicity : 2

Hazardous to the aquatic : 2


environment - acute hazard

Hazardous to the aquatic : 2


environment - chronic hazard

GHS label elements


Hazard pictograms :

Signal Word : Danger

Hazard Statements : H227 Combustible liquid.


H304 May be fatal if swallowed and enters airways.
H351 Suspected of causing cancer.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

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SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Precautionary Statements :
Prevention:
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P202 Do not handle until all safety precautions have been read
and understood.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/ doctor/ .?.
P308 + P311 IF exposed or concerned: Call a POISON
CENTER/ doctor/ .?.
P391 Collect spillage.
P331 Do NOT induce vomiting.
P370 + P378 In case of fire: Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide to extinguish.
Storage:
P405 Store locked up.
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.

Other hazards which do not result in classification


If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Aliphatic hydrocarbons


Components
Chemical name CAS-No. Concentration (%
w/w)
diesel fuel 68476-34-6 >= 75 - < 100

4. FIRST AID MEASURES

General advice : Move out of dangerous area.


Show this material safety data sheet to the doctor in attend-
ance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.

If inhaled : If unconscious, place in recovery position and seek medical


advice.
If symptoms persist, call a physician.
In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Flush eyes with water as a precaution.

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SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Remove contact lenses.


Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Most important symptoms : None known.
and effects, both acute and
delayed
Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)


Unsuitable extinguishing : High volume water jet
media
Specific hazards during fire : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Specific extinguishing meth- : Collect contaminated fire extinguishing water separately. This
ods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for fire-fighters essary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.


tive equipment and emer- Ensure adequate ventilation.
gency procedures

Environmental precautions : Prevent product from entering drains.


Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Contain spillage, and then collect with non-combustible ab-
containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).
Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Advice on protection against : Product is not explosive.


fire and explosion

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SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Do not spray on a naked flame or any incandescent material.


Keep away from open flames, hot surfaces and sources of
ignition.

Advice on safe handling : Avoid formation of aerosol.


Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : no smoking
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Further information on stor- : Keep only in the original container in a cool, dry, well-
age conditions ventilated place away from ignition sources, heat or flame.
Protect from direct sunlight.

Materials to avoid : Observe VCI storage rules.

Further information on stor- : No decomposition if stored and applied as directed.


age stability

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters


Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Wear respiratory protection if ventilation is inadequate.
Combination filter for gases/vapours of organic, inorganic,
acid inorganic and alkaline compounds (e.g. EN 14387 Type
ABEK).
Hand protection

Remarks : Suitable chemical resistant safety gloves (EN 374) also with
prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5
mm), butyl rubber (0.7 mm) etc. Manufacturer's directions for
use should be observed because of great diversity of types.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Skin and body protection : Impervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
Protective measures : Do not inhale gases/vapours/aerosols.

4 / 10
SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Avoid contact with the skin, eyes and clothing.


Avoid exposure - obtain special instructions before use.
Handle in accordance with good building materials hygiene
and safety practice.
Wearing of closed work clothing is recommended.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : yellow

Odor : characteristic

pH : not applicable

Melting temperature : No data available

boiling temperature : approx. 170 - 390 °C

Flash point : 76 °C

Method: Flash-Point by Pensky-Martens Closed Cup Tester.


GLP: yes

Evaporation rate : not determined

Flammability (solid, gas) : not self-igniting

Self-ignition : not self-igniting

Upper explosion limit / Upper : not available


flammability limit

Lower explosion limit / Lower : not available


flammability limit

Relative vapor density : not determined

Density : 0,83 - 0,87 g/cm3 (20 °C)

Bulk density : not applicable

Solubility(ies)
Water solubility : insoluble

Autoignition temperature : No data available

Decomposition temperature : No decomposition if stored and handled as pre-


scribed/indicated.

Viscosity

5 / 10
SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Viscosity, dynamic : not determined

Explosive properties : Not explosive


Not explosive

Oxidizing properties : not fire-propagating

10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.


Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous reac- : No decomposition if stored and applied as directed.
tions Vapors may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.


Incompatible materials : Strong acids
Strong bases
Strong oxidizing agents
Strong reducing agents
Hazardous decomposition : No hazardous decomposition products if stored and handled
products as prescribed/indicated.

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Not classified based on available information.
Serious eye damage/eye irritation
Not classified based on available information.
Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Suspected of causing cancer.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.

6 / 10
SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Aspiration toxicity
May be fatal if swallowed and enters airways.
Components:

diesel fuel:
May also damage the lung at swallowing (aspiration hazard).

Further information

Product:
Remarks : Solvents may degrease the skin.

Components:

diesel fuel:
Remarks : Has a degreasing effect on skin.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Acute aquatic toxicity : Toxic to aquatic life.

Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Components:

diesel fuel:
Toxicity to fish : LL50 (Rainbow trout): 21 mg/l
Exposure time: 96 h
Method: Acute toxicity for fish

LL50 (Silverside, tidewater): 3,2 mg/l


Exposure time: 96 h

Toxicity to daphnia and other : LC50 (Daphnia magna): 5,3 mg/l


aquatic invertebrates Exposure time: 48 h
Method: Daphnia sp., Acute Immobilisation Test.

Toxicity to algae/aquatic : EL50 ( green algae): 2,9 mg/l


plants Exposure time: 72 h
Method: Algae, Growth Inhibition Test

Toxicity to daphnia and other : No observed effect concentration: 0,2 mg/l


aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Species: Daphnia magna
Method: Daphnia magna, Reproduction Test.

7 / 10
SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

Persistence and degradability


No data available
Bioaccumulative potential

Components:

diesel fuel:
Partition coefficient: n- : Remarks: not applicable for mixtures
octanol/water

Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Acutely toxic for aquatic organisms.
mation The product should not be allowed to reach either ground or
open waters.
The product has not been tested. The statement has been
derived from the properties of the individual components.

An environmental hazard cannot be excluded in the event of


unprofessional handling or disposal.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.

Components:

diesel fuel:
Additional ecological infor- : The product should not be allowed to reach either ground or
mation open waters.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

14. TRANSPORT INFORMATION

International Regulations

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SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

UNRTDG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(SOLVENT NAPHTHA)
Class : 9
Subsidiary risk : EHSM
Packing group : III
Labels : 9 (EHSM)
IATA-DGR
UN/ID No. : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(SOLVENT NAPHTHA)
Class : 9
Subsidiary risk : EHSM
Packing group : III
Labels : Miscellaneous, Environmentally hazardous
Packing instruction (cargo : 964
aircraft)
Packing instruction (passen- : 964
ger aircraft)
IMDG-Code
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(SOLVENT NAPHTHA)
Class : 9
Subsidiary risk : EHSM
Packing group : III
Labels : 9 (EHSM)
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

9 / 10
SAFETY DATA SHEET

MasterFinish 202

Version Revision Date: SDS Number: Date of last issue: 25.06.2020


1.1 29.06.2020 000000265367 Date of first issue: 25.06.2020

16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
formation System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

UN / EN

10 / 10

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