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Safe Use Instructions for Glass Fibers

This document provides safe use instructions for continuous glass fiber products. It identifies the products and manufacturer, discusses potential hazards including mild skin and eye irritation, and provides first aid measures such as rinsing skin with water. Sections cover identification, hazards, composition, and first aid procedures.

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Olaniyan Samson
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0% found this document useful (0 votes)
947 views12 pages

Safe Use Instructions for Glass Fibers

This document provides safe use instructions for continuous glass fiber products. It identifies the products and manufacturer, discusses potential hazards including mild skin and eye irritation, and provides first aid measures such as rinsing skin with water. Sections cover identification, hazards, composition, and first aid procedures.

Uploaded by

Olaniyan Samson
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
  • Section 1 – Identifications of Products and Company
  • Introduction
  • Section 2 – Hazards Identification
  • Section 3 – Composition / Ingredients Information
  • Section 5 – Fire-Fighting Measures
  • Section 4 – First-Aid Measures
  • Section 8 – Exposure Controls / Personal Protection
  • Section 7 – Handling and Storage
  • Section 6 – Accidental Release Measures
  • Section 9 – Physical and Chemical Properties
  • Section 10 – Stability and Reactivity
  • Section 11 – Toxicological Information
  • Section 13 – Disposal Considerations
  • Section 12 – Ecological Information
  • Section 14 – Transport Information
  • Section 15 – Regulatory Information
  • Section 16 – Other Information

Number: Q/JS J0520-2014

Standard
Code
J125-01
Reolaced
Standard
Q/JS J0520—2013
Main Drafter Han Tao
Assessor Chupeigen
Modifi-c Implement Modify The Standardization
Version
ation
Release Date
Date Implement Date Censor
Chupeigen
NO.1 NO.2 07/03/2014 07/03/2014 28/09/2015 Ratifier Xiang Rubing Date 28/09

SAFE USE INSTRUCTIONS


For Continuous Glass Fiber Products

INTRODUCTION
According to the European Regulation(ER) on Chemicals No.1907/2006(REACH)
enforced from June 1st 2007, Material Safety Data Sheets (MSDS) are required only for
hazardous substances and preparations. Continuous glass fiber products of our
company are defined as “articles” under REACH and therefore MSDS are not required
for them.
In order to ensure our customers’ acquisition of information on proper handling and use
of glass fiber products, Jushi Group provides the customers with this Safe Use
Instructions.

SECTION 1 – IDENTIFICATIONS OF PRODUCTS AND COMPANY


PRODUCT IDENTIFICATION
Continuous Glass Fiber Products include Assembled Roving, Direct Roving, Dry
Chopped Strands, Wet Chopped Strands, Woven Roving, Stitch Chopped Strand Mat,
Powder Chopped Strand Mat, Emulsion Chopped Strand Mat, Stitch Combo Mat, Woven
Roving Combo Mat, Glass Filament Yarn, Marketable Cake, Cut Strands,Texturized
Roving and Milled Fiber.

MANUFACTURER INFORMATION:
JUSHI GROUP CO., LTD.
No.669 Wenhua Rd.(S.), Tongxiang Economic Development Zone, Zhejiang 314500,
China

Page 1 of 12
Number: Q/JS J0520-2014

FAX:
Customer Service: +86-573-88181388
International Sales: +86-573-88181058
Domestic Sales: +86-573-88136222
COMPANY EMERGENCY TELEPHONE : (8:30-16:40 In Beijng, from Monday to
Saturday )
Customer Service: +86-573-88136367
International Sales: +86-573-88181025
Domestic Sales: +86-573-88181016
E-mail: services@[Link]

Jushi(India) FRP Accessories Private Limited


310 CREATIVE INDUSTRIAL ESTATE N/M. JOSHI MARG MUMBAI 420011 India
PHONE: 0091 224 033 5375/ 224 033 5333
FAX: 0091 224 033 5334
E-mail: vishal@[Link]

Jushi Korea Co., Ltd


Rm No. 2003, Hyundai 41 Tower, 917-9, Mok-dong, Yangcheon-gu, Seoul, 158-723,
Korea
PHONE: 0082 2 21683288
FAX: 0082 2 21683286
Email: [Link]@[Link]

JUSHI SINGAPORE PTE. LTD


10 UBI CRESCENT, #05-70 (LOBBY D)UBI TECHPARK, SINGAPORE 408564
PHONE: 0065 67425118
FAX: 0065 6742 7108
E-mail: hsseng@[Link]

Jushi Japan Co.,Ltd


Eisen Blad, 5F1-6-3, Yurakucho Chiyoda Tokyo, Japan
PHONE: 0081 3 62688508

Page 2 of 12
Number: Q/JS J0520-2014

FAX: 0081 3 35028080


Email: m_hitomi@[Link]

Jushi Italy SRL


VIA ADIGE 10/12 21043 CASTIGLIONE OLONA (VA)
PHONE: 0039 0331857918
FAX: 0039 0331825521
E-mail: lydiazheng@[Link];essebi@[Link]

Jushi Spain, S.A.


Avd. de Barajas, 24. Planta 2. (Edificio Gamma, Parque Empresarial Omega). C.P
28108. Alcobendas (Madrid) Spain
PHONE: 0034 917678817
FAX: 0034 917678818
E-mail: [Link]@[Link]

JUSHI France SAS


65 RUE DU DAUPHINE 69800 SAINT-PRIEST France
PHONE: 0033 4 72 78 20 48/33 (0) 4 7278 20 62
FAX: 0033 4 72 78 20 41
E-mail: [Link]@[Link]

JUSHI USA
4982 4th Street Irwindale,CA 91706 U.S.A.
PHONE: 00626 960-2038
FAX: 00626 960-2037
E-mail: [Link]@[Link]

Jushi Canada Glass fiber Co., Ltd.


Markham, Toronto Canada
PHONE: 001 9054777628
FAX : 001 9054776047
E-mail: [Link]@[Link]

Jushi Group Sinosia SA Composite Materials


4/65 Nerl Hare Road,Atlantis Industrial7350,Capetown, South Africa

Page 3 of 12
Number: Q/JS J0520-2014

PHONE: 0027 21 5772747/00852 2541 1114


FAX: 0027 21 5772727
E-mail: w_w9@[Link] / info@[Link]

HELM AG Hamburg
Nordkanal Strasse 28 D-20097 Hamburg Germany
PHONE: 0049 40 2375 1330
FAX: 0049 40 2375 1845
E-mail: [Link]@[Link]

Cathay Composites Ltd


The orangery, Home Fram, Cams, Estate, Fareham, Hants, England P016 8UT
PHONE: 0040 1329 225200
FAX: 0040 1329 225222
E-mail: .[Link]@[Link]
If you are not able to reach the above phone numbers, please call the company
emergency number.
SECTION 2 – HAZARDS IDENTIFICATION
Classification of the substance or mixture:
GHS Classification
Hazard class Category
Skin irritation Category 3
Eye irritation Category 2B
Acute toxicity Category 5
GHS label elements:
Signal word Warning
Hazard statements H316- Causes mild skin irritation.
H320- Causes eye irritation.
H303-May be harmful if swallowed.
H333-May be harmful if inhaled.
Symbol No pictogram
Precautionary statements
Prevention:Wash skin thoroughly after handling
Wear protective eye/face protection

Page 4 of 12
Number: Q/JS J0520-2014

Response: IF ON SKIN: rinse with soap and water. Make sure to refrain from
rinsing with warm water since warm water will make the skin pores open to allow
fiberglass to penetrate more deeply. If fiberglass penetrates the skin, use a wash cloth to
help pull out the fiberglass.
IF IN EYE: Immediately flush eyes with clean water for at least 15
minutes. If irritation persists, get medical help.
If inhalation occurs: immediately remove the affected person to fresh
air. If irritation persists, get medical help.
If ingestion occurs: watch the person for several days to make sure
that gastrointestinal disturbance does not occur. Do not let the person vomit unless
required by medical personnel.
This product is no classified hazardous according to European RegulationNo.1272/2008.
This section identifies the potential hazards related to the article i.e. its shape, its
dimensions and other physical characteristics.

SECTION 3 – COMPOSITION / INGREDIENTS INFORMATION


Product Composition:
Product Name Glass, % Sizing, % Binder, % Water, %
Assembled Roving 98.75±0.75 1.05±0.75 / ≤0.20
Direct Roving 99.28±0.58 0.62±0.48 / 0.10±0.1
Dry Chopped Strands 99.08±0.82 0.82±0.75 / ≤0.10
Wet Chopped Strands 89.9±2.1 0.10±0.1 / 10.0±2.0
Flame Retardant Fiber Glass 99.08±0.82 0.82±0.75 / ≤0.10
Woven Roving 99.33±0.53 0.57±0.43 / 0.10±0.1
Power Chopped Strand Mat 95.4±2.95 0.85±0.5 3.65±2.35 0.10±0.1
Emulsion Chopped Strand Mat 94.85±1.8 0.85±0.5 4.2±1.2 0.10±0.1
Glass Filament Yarn 98.9±0.3 1.0±0.2 / 0.10±0.1
Cut Strands 88.5±3.5 / / 11.5±3.5
Marketable Cake 99.45±0.25 0.45±0.15 / 0.10±0.1
Texturized Roving 99.55±0.35 0.35±0.25 / 0.10±0.1
Milled Fiber 98.98±0.82 0.82±0.75 / ≤0.20
CAS No.:
Glass Fiber: 65997-17-3
Sizing: N/A

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Number: Q/JS J0520-2014

Sizing :
Sizing is a mixture of chemicals applied to the strand surface. It mainly consists of
high-molecular polymers of no reactivity (usually natural ingredients, such as starch)
which are not listed in the appendices of EINECS or ELINCS.
In some cases, sizing maybe also contain substances of organic-silane family or other
substances. The manufacturer considers this risk as negligible as, even though listed as
hazardous substance, their concentration is extremely low (under 0.1% of total weight)
and they are polymerised during the production of glass fibers.

SECTION 4 – FIRST-AID MEASURES


Skin Contact:
If irritation occurs to the skin, rinse with soap and water. Make sure to refrain from rinsing
with warm water since warm water will make the skin pores open to allow glass fiber to
penetrate deeper. If glass fiber penetrates the skin, use a wash cloth to help pull out the
glass fiber. Do not rub or scratch affected skin to any further any further deterioration.
Please go to a doctor if irritation increases. Make sure to refrain from using compressed
air to remove glass fiber from skin.
Eye Contact:
Immediately flush eyes with clean water for at least 15 minutes. Please go to a doctor if
irritation increases.
Inhalation:
Immediately move to fresh air. Please go to a doctor if irritation increases.
Ingestion:
Normally, ingestion is less than likely. If it does occur, keep the person under observation
for several days to make sure that no gastrointestinal disturbance occurs. Do not induce
vomiting unless required by medical staff. Please go to a doctor if irritation increases.

SECTION 5 – FIRE-FIGHTING MEASURES


Continuous glass fiber products are neither flammable nor incombustible.
Only the sizing and the packing materials are combustible and could release small
quantities of hazardous gas in case of major and prolonged heat or fire.

Page 6 of 12
Number: Q/JS J0520-2014

Hazardous Combustion Products :


Primary combustion products are carbon monoxide, hydrogen, carbon dioxide and water.
Other undetermined compounds can be released in small quantities.
Fire-Fighting Methods:
Use dry chemical, foam, carbon dioxide and water as extinguishing media.
Fire-Fighting Instructions:
Fire fighters should use self-contained breathing apparatus and wear full protective gear.

SECTION 6 – ACCIDENTAL RELEASE MEASURES


Personal precautions:
Avoid contact with the skin and the eyes
Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Methods for Clean-up:
• Pick up and transfer to properly labeled containers.
• Avoid dry sweeping.
• Shovel the major part of spilled material into a container.
• Use an industrial vacuum cleaner with a high efficiency filter to clean up dust and
residual spilled material.
• After vacuum cleaning, flush away with water.

SECTION 7 – HANDLING AND STORAGE


Handling:
Try to prevent the packing material from being damaged and keep the product inside the
packing material to minimize the generation of dusts. Maintain a clean work environment
and avoid generation of glass fiber fragments from improper handling.
Storage:
Keep the product in its packaging until use to minimize potential dust generation.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION


Continuous glass fibers are not respirable. However, certain mechanical processes

Page 7 of 12
Number: Q/JS J0520-2014

might generate airborne dust or fibers. The occupational exposure limits below
mentioned are applicable to airborne fiber exposure and/or to dust exposure.
Exposure limits:
NOTE: The user of continuous glass fibers products has to comply with the national
regulations on occupational health protection. Occupational exposure limit values in
some European countries are illustrated as below. (8-hour work day)
Respirable dust Total Dust Respirable Fiber
ACGIH 3 mg/m3 10 mg/m3 1 fiber/ml
Austria 6mg/m3 / 0.5 fiber/ml
Denmark 5 mg/m3 10 mg/m3 1 fiber/ml
Finland / 10 mg/m3 1 fiber/ml
France / 10 mg/m3 1 fiber/ml
Germany 3 mg/m3 4 mg/m3 0.25 fiber/ml
Irealand 5 mg/m3 / 2 fiber/ml
Italy 3 mg/m3 10 mg/m3 1 fiber/ml
Netherlands 2 mg/m3 10 mg/m3 1 fiber/ml
Norway 5 mg/m3 10 mg/m3 1 fiber/ml
Portugal / 4 mg/m3 1 fiber/ml
Spain 3 mg/m3 10 mg/m3 1 fiber/ml
United Kingdom 5 mg/m3 10 mg/m3 2 fiber/ml

Engineering Control:
Production areas are closed off and a required relative humidity is maintained.
Respiratory Protection:
Wear a suitable mask when working in an environment where dust concentration is high.
Eye Protection:
Wear safety glasses and face shield.
Body Protection:
Normal loose working clothing (long-sleeved shirts and long pants) is recommended.
Skin irritation occurs primarily at the contact areas such as around the neck and waist.
Hand Protection:

Page 8 of 12
Number: Q/JS J0520-2014

Wear gloves. Skin irritation occurs primarily at the contact areas such as wrists and
between the fingers.

SECTION 9 – PHYSICLAL AND CHEMICAL PROPERTIES


Product Appearance and Properties: White or off-white solid;No odor.
Flash Point: Not applicable
pH Value: Not applicable.
Ignition Temperature: Not applicable.
Melting Point: >800°C.
Explosion Upper Limit: Not applicable.
Boiling Point: Not applicable.
Explosion Lower Limit: Not applicable.
Relative Density: 2.6 Times that of water.
Solubility (in Water): Insoluble
Relative Vapor Density: Not applicable
Product Use:
Glass fiber is an inorganic nonmetal material and is used for plastic reinforcement,
acoustic absorption and insulation.

SECTION 10 – STABILITY AND REACTIVITY


Chemical Stability:
Stable under normal conditions.
Materials to Avoid:
None.
Conditions to Avoid:
None.
Possibility of Hazardous Reactions:
Hazardous reaction does not occur.

SECTION 11 – TOXICOLOGICAL INFORMATION


Acute Toxicity:

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Number: Q/JS J0520-2014

None.
Local Effects:
Dusts and fibers may cause irritation to eyes and skin. The irritation disappears when the
exposure ceases. Inhalation may cause coughing, nose and throat irritation and
sneezing. High exposures may cause difficult breathing, chest distress and congestion.
Mechanical irritation is not considered as a health hazard under the European directive
76/548/EC on hazardous substances. It is required to classify continuous glass fibers as
an irritant under the European directive 97/69/EC.

Long Term Health Effects:


The International Agency for Research on Cancer (IARC), agency of the World Health
Organization (WHO), has determined that glass fiber is a non-carcinogenic material
because the evidence is inadequate to prove that glass fiber can cause humans and
experimental animals to develop cancer.
Continuous glass fibers do not possess cleavage planes which would allow them to split
length-wise into fibers with smaller diameters, rather they break across the fiber,
resulting in fibers which are of the same diameter as the original fiber with a shorter
length and a small amount of dust.

Continuous glass fibers are not carcinogenic. (See section 15)

SECTION 12 – ECOLOGICAL INFORMATION


Glass fiber products are not listed as a material harmful to animals, plants and fish. No
specific data available for glass fiber products at present.

SECTION 13 – DISPOSAL CONSIDERATIONS


RCRA Hazard Class:
Non-Hazardous.
European code number for waste is 101103.
Disposal Instructions:
Dispose waste materials as per local environmental regulations.

Page 10 of 12
Number: Q/JS J0520-2014

DECTION 14 – TRANSPORT INFORMATION


IMDG/IM – RID – ADR – ICAO – IATA – DOT – TDG – MEX
Not regulated
Transport Instructions:
Rolling and moisture should be avoided in transit.

SECTION 15 – REGULATORY INFORMATION


This product is not hazardous according to European Directive 99/45/EC, 67/548/EEC
and their latest amendments.
Information on Non-carcinogenicity:
According to EU Directives, the continuous glass fibers in these products are not
classified as carcinogenic.
Continuous glass fibers are not within the scope of Amendment 97/69/EC of Directive
67/548/EEC since they are not “fibers with random orientation”.

The International Agency for Research on Cancer (IARC) categorized continuous glass
fiber as not classifiable with respect to human carcinogenicity (Group 3) in June1987 and
October 2001,. The evidence from human, as well as, animal studies was evaluated by
IARC as insufficient to classify continuous glass fiber as a confirmed, probable or even
possible cancer causing material.

National Chemicals Inventory


Based on the rules enforced with regards to the marketing and use of chemicals in
countries where our Jushi products are manufactured, each chemical ingredient of these
finished products has to be listed on the National Chemicals Inventory of the specific
country where the products are produced.
However, continuous glass fiber products are “articles” under the chemicals inventories
listed below and consequently are exempt from listing on these inventories:
- The European Inventory of Existing Chemical Substances: EINECS/ELINCS,
- The US EPA Toxic Substance Control Act: TSCA,
- The Canadian Chemical Registration Regulations: NDSL/DSL,
- The Japanese Chemical Substances Control Law under METI: CSCL,
- The Australian Inventory of Chemical Substances: AICS,
Page 11 of 12
Number: Q/JS J0520-2014

- The Philippine Inventory of Chemicals and Chemical Substances: PICCS,


- The Korean Existing Chemicals List: (K)ECL and
- The Chinese List on New Chemical Substances.

SECTION 16 – OTHER INFORMATION

Preparation Date:March 2014


Prepared by:QA&EHS Dept
Data Verified by:Vice President of Jushi Group
Modification Information:The First Version
This document has been issued to align with REACH Regulation.

Disclaimer
Reasonable care has been taken in the preparation of this information, but the
manufacturer makes no warranty of accuracy or any other warranty, expressed or
implied, with respect to this information. The manufacturer makes no representations
and assumes no liability for any direct, incidental or consequential damages resulting
form its use.

Page 12 of 12

Number: Q/JS J0520-2014 
Page 1 of 12 
 
Standard 
Code 
J125-01 
Reolaced 
Standard 
Q/JS J0520—2013 
Main Drafter 
Han Tao
Number: Q/JS J0520-2014 
Page 2 of 12 
FAX: 
Customer Service: +86-573-88181388 
International Sales: +86-573-88181058 
Domes
Number: Q/JS J0520-2014 
Page 3 of 12 
FAX: 0081 3 35028080 
Email: m_hitomi@Jushijapan.co.jp 
 
Jushi Italy SRL 
VIA ADIGE 1
Number: Q/JS J0520-2014 
Page 4 of 12 
PHONE: 0027 21 5772747/00852 2541 1114 
FAX: 0027 21 5772727 
E-mail: w_w9@mweb.co.za
Number: Q/JS J0520-2014 
Page 5 of 12 
Response: IF ON SKIN: rinse with soap and water.  Make sure to refrain from 
rinsing w
Number: Q/JS J0520-2014 
Page 6 of 12 
Sizing : 
Sizing is a mixture of chemicals applied to the strand surface. It mainly co
Number: Q/JS J0520-2014 
Page 7 of 12 
Hazardous Combustion Products : 
Primary combustion products are carbon monoxide, hydr
Number: Q/JS J0520-2014 
Page 8 of 12 
might generate airborne dust or fibers. The occupational exposure limits below 
mentio
Number: Q/JS J0520-2014 
Page 9 of 12 
Wear gloves. Skin irritation occurs primarily at the contact areas such as wrists and
Number: Q/JS J0520-2014 
Page 10 of 12 
None.  
Local Effects: 
Dusts and fibers may cause irritation to eyes and skin. The i

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