SET-1

Series AABB2/4 àíZ-nÌ H$moS>

Q.P. Code 56/4/1
amob Z§. narjmWu àíZ-nÌ H$moS> >H$mo CÎma-nwpñVH$m Ho$
Roll No. _wI-n¥ð >na Adí` {bIo§ &
Candidates must write the Q.P. Code
on the title page of the answer-book.

H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _o§ _w{ÐV n¥ð> 11 h¢ &

àíZ-nÌ _| Xm{hZo hmW H$s Amoa {XE JE àíZ-nÌ H$moS> H$mo narjmWu CÎma-nwpñVH$m Ho$ _wI-n¥ð>
na {bI| &
H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _| >12 àíZ h¢ &
H¥$n`m àíZ H$m CÎma {bIZm ewê$ H$aZo go nhbo, CÎma-nwpñVH$m _| àíZ H$m H«$_m§H$ Adí`
{bI| &
Bg àíZ-nÌ 15 {_ZQ >H$m g_` {X`m J`m h¡ & àíZ-
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db àíZ-
Am¡a Bg Ad{Y Ho$ Xm¡amZ do CÎma-nwpñVH$m na H$moB© CÎma Zht {bI|Jo &
Please check that this question paper contains 11 printed pages.
Q.P. Code given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 12 questions.
Please write down the serial number of the question in the
answer-book before attempting it.
15 minute time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (g¡ÕmpÝVH$)

CHEMISTRY (Theory)

:2 : 35
Time allowed : 2 hours Maximum Marks : 35

56/4/1 1 P.T.O.
 :

(i) 12
(ii)
(iii) 1 3 2

(iv) 4 11 3
(v) 12 5
(vi)
IÊS> H$
1. {ZåZ{b{IV hþE H«$_ _| ì`dpñWV
H$s{OE : (H$moB© ) 2 1=2
(i) EogrQ>¡pëS>hmBS>, ~oݵO¡pëS>hmBS>, EogrQ>moµ\$sZmoZ, EogrQ>moZ (HCN Ho$ à{V A{^{H«$`merbVm)
(ii) (CH3)2CHCOOH, CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH
(Aåbr` à~bVm)
(iii) CH3CH2OH, CH3CHO, CH3COOH

2. à~b Am¡a Xþ~b © AnKQ>çm| Ho$ {bE m Ho$ {dnarV gm§ÐVm Ho$ dJ©_yb (C1/2) Ho$ AmboI _|
Xþ~©b AnKQ>ç H$s gr_m§V _moba MmbH$Vm H$m _mZ AmboIr {d{Y Ûmam àmßV Zht {H$`m Om
gH$Vm h¡ & Bg _mZ H$mo àmßV H$aZo Ho$ {bE EH$ {d{Y gwPmBE & g§~§{YV {Z`_ ^r {b{IE,
`{X H$moB© h¡ & 2

3. {ZåZ{b{IV H$WZm| Ho$ {bE H$maU {b{IE : 2 1=2

(i) ~oݵOmoBH$ Aåb \«$sS>ob-H«$mâQ²>g A{^{H«$`m Zht XoVm h¡ &
(ii) H$sQ>moZm| H$s VwbZm _| EopëS>hmBS>m| H$m A
IÊS> I
4. (H$) {ZåZ{b{IV Ho$ {bE H$maU {b{IE : 3 1=3
(i) E{WbEo_rZ Ob _| {dbo` h¡ O~{H$ Eo{ZbrZ A{dbo` h¡ &
(ii) Q´>m°ZamJr à{VñWmnZ A{^{H«$`mAm| _| Eo_rZmo g_yh o- Am¡a
p-{ZX©oeH$ hmoVm h¡ {H$ÝVw Eo{ZbrZ Ho$ ZmBQ´>moH$aU go m-ZmBQ´>moEo{ZbrZ H$s
_hÎdnyU© _mÌm ~ZVr h¡ &
(iii) Eo_rZ Zm{^H$amJr H$s ^m±{V ì`dhma H$aVo h¢ &
AWdm
56/4/1 2
General Instructions :
Read the following instructions very carefully and strictly follow them :
(i) This question paper contains 12 questions. All questions are compulsory.
(ii) This question paper is divided into three Sections A, B and C.
(iii) Section A Questions no. 1 to 3 are very short answer type questions, carrying
2 marks each.
(iv) Section B Questions no. 4 to 11 are short answer type questions, carrying
3 marks each.
(v) Section C Question no. 12 is case based question, carrying 5 marks.
(vi) Use of log tables and calculators is not allowed.

SECTION A

1. Arrange the following compounds in the increasing order of their

property indicated : (Any two) 2 1=2
(i) Acetaldehyde, Benzaldehyde, Acetophenone, Acetone (Reactivity
towards HCN)
(ii) (CH3)2CHCOOH, CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH
(Acidic strength)
(iii) CH3CH2OH, CH3CHO, CH3COOH (Boiling point)
2. In a plot of m against the square root of concentration (C1/2) for strong
and weak electrolyte, the value of limiting molar conductivity of a weak
electrolyte cannot be obtained graphically. Suggest a way to obtain this
value. Also state the related law, if any. 2
3. Write reasons for the following statements : 2 1=2
(i) Benzoic acid does not undergo Friedel-Crafts reaction.
(ii) Oxidation of aldehydes is easier than that of ketones.

SECTION B
4. (a) Write reasons for the following : 3 1=3
(i) Ethylamine is soluble in water whereas aniline is insoluble.
(ii) Amino group is o- and p-directing in aromatic electrophilic
substitution reactions, but aniline on nitration gives a
substantial amount of m-nitroaniline.
(iii) Amines behave as nucleophiles.
OR

56/4/1 3 P.T.O.
 (I) Amn {ZåZ{b{IV n[adV©Z H¡$go H$a|Jo : 3 1=3
(i) ZmBQ´>mo~Ýo µOrZ go Eo{ZbrZ
(ii) EWoZm_mBS> go _oWoZo_rZ
(iii) EWoZZmBQ´>mBb go EWoZo_rZ

5. (H$) (i) d5 {dÝ`mg

{b{IE `{X o <P h¡ &
(ii) [Fe(CN)6]3 Xþ~©b AZwMwå~H$s` h¡ O~{H$ [Fe(CN)6]4 à{VMwå~H$s`
h¡ & Bg H$WZ H$s nwpîQ> Ho$ {bE H$maU Xr{OE &
[na_mUw H«$_m§H$ : Fe = 26]
(iii) g§Hw$b [Co(NH3)6]Cl2 Ho$ {db`Z _| CËnm{XV Am`Zm| H$s g§»`m
{b{IE & 3 1=3

AWdm
(I) (i) g§Hw$b [CoF6]3 H$m Ho$db àMH«$U Mwå~H$s` AmKyU© n[aH${bV H$s{OE &
(Co H$m na_mUw H«$_m§H$ = 27)
(ii) {XE JE g§Hw$b H$m IUPAC Zm_ {b{IE :
[CrCl2(H2O)4]Cl

(iii) {ZåZ Xmo g§Hw$bm| _| go H$m¡Z-gm ?

[Fe(H2O)6]3+, [Fe(C2O4)3]3 3 1=3

6. (i) {ZåZ{b{IV _| go H$m¡Z- ?

3+
Ti4+, Cr3+, V
(na_mUw H«$_m§H$ : Ti = 22, Cr = 24, V = 23)

(ii) Fe2+ H$s VwbZm _| Mn2+ ?

(iii) {H$gr YmVw H$s C AWdm

âbwAmoamBS> _| àX{e©V hmoVr h¡ ? Bg H$WZ H$s nwpîQ> H$s{OE & 3 1=3

56/4/1 4
 (b) How will you carry out the following conversions : 3 1=3

(i) Nitrobenzene to Aniline

(ii) Ethanamide to Methanamine

(iii) Ethanenitrile to Ethanamine

5. (a) (i) Write the electronic configuration of d5 on the basis of

crystal field splitting theory if o < P.

(ii) [Fe(CN)6]3 is weakly paramagnetic whereas [Fe(CN)6]4 is

diamagnetic. Give reason to support this statement.
[Atomic no. : Fe = 26]

(iii) Write the number of ions produced from the complex

[Co(NH3)6]Cl2 in solution. 3 1=3

OR

(b) (i) Calculate the spin only magnetic moment of the complex
[CoF6]3 . (Atomic no. of Co = 27)

(ii) Write the IUPAC name of the given complex :

[CrCl2(H2O)4]Cl

(iii) Which out of the two complexes is more stable and why ?

[Fe(H2O)6]3+, [Fe(C2O4)3]3 3 1=3

6. (i) Which ion amongst the following is colourless and why ?

3+
Ti4+, Cr3+, V
(Atomic number of Ti = 22, Cr = 24, V = 23)

(ii) Why is Mn2+ much more resistant than Fe2+ towards oxidation ?

(iii) Highest oxidation state of a metal is shown in its oxide or fluoride

only. Justify the statement. 3 1=3

56/4/1 5 P.T.O.
7. EH$ `m¡{JH$ 2H4O) 2H4O2) XoVm h¡ & Am`moS>mo\$m_©
A{^{H«$`m Ûmam nrbm Adjon XoVm h¡ VWm HCN go A{^{H«$`m H$aHo$ `m¡{JH$ ~ZmVm h¡ &
Ob-AnK{Q>V hmoH$a 2- Am¡a H$s
nhMmZ H$s{OE & g§~Õ A{^{H«$`mAm| Ho$ g_rH$aU {b{IE & 3

8. {XE JE {MÌ H$m AdbmoH$Z H$s{OE Am¡a {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE : 3 1=3

(i) R>mogm| na J¡gm| Ho$ A{YemofU Ho$ ì`§OH$ H$mo g_rH$aU ê$n _| {b{IE &

(ii) ?

(iii) ?

9. (H$) {ZåZ{b{IV A{^{H«$`mAm| go g§~Õ g_rH$aU {b{IE : 3 1=3

(i) EWoZo_rZ, Eo
(ii) H$j Vmn na Eo{ZbrZ, ~«mo_rZ Ob Ho$ gmW A{^{H«$`m H$aVm h¡ &
(iii) \ S> Ho$ gmW
A{^{H«$`m H$aVm h¡ &
AWdm
56/4/1 6
7. A com 2H4 2H4O2
Iodoform reaction to give yellow precipitate and reacts with HCN to form
-hydroxypropanoic acid.
equations for the
reactions involved. 3

8. Observe the given figure and answer the following questions : 3 1=3

(i) Write the expression for adsorption of gases on solids in the form of
an equation.

(ii) What is the slope of the graph ?

(iii) What does the intercept of the line represent ?

9. (a) Write equations involved in the following reactions : 3 1=3

(i) Ethanamine reacts with acetyl chloride.

(ii) Aniline reacts with bromine water at room temperature.

(iii) Aniline reacts with chloroform and ethanolic potassium

hydroxide.
OR

56/4/1 7 P.T.O.
 (I) (i) {ZåZ{b{IV H$m~©{ZH$ `m¡{JH$ H$m IUPAC Zm_ {b{IE :
(CH3CH2)2NCH3
(ii) {ZåZ{b{IV Ho$ {bE g_rH$aU {b{IE :
(I) J¡{~«Eb W¡{b_mBS> g§íbofU
(II) hm°\$_mZ ~«mo_m_mBS> {ZåZrH$aU 1+2=3
10. 298 K na {ZåZ{b{IV gob Ho$ {bE ZoÝñQ>© g_rH$aU {b{IE Am¡a {[Link].~b (emf)
n[aH${bV H$s{OE : 3
Cr|Cr3+ (0·1 M) || Fe2+ (0·01 M) | Fe
{X`m J`m h¡ : E = 0·75 V
Cr3 / Cr
E = 0·45 V
Fe2 / Fe
(log 10 = 1)
11. (H$) (i) _yb AdñWm _| {gëda na_mUw Ho$ d-H$jH$ nyÊm©V`m ^[aV hmoVo h¢, {\$a ^r
Bgo g§H«$_U VÎd _mZm OmVm h¡ & H$WZ H$s nwpîQ> H$s{OE &
(ii) Mn Am¡a Zn Ho$ E 2 _mZ Ano{
M /M
hmoVo h¢ ?
(iii) Vr h¢ ? 3 1=3
AWdm
(I) ZrMo {XE JE {MÌ Ho$ AmYma na {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE : 3 1=3

loUr 3

loUr 2

loUr 1

na_mUw H«$_m§H$
56/4/1 8
 (b) (i) Write the IUPAC name for the following organic compound :
(CH3CH2)2NCH3
(ii) Write the equations for the following :
(I) Gabriel phthalimide synthesis
(II) Hoffmann bromamide degradation 1+2=3
10. Write the Nernst equation and calculate emf of the following cell at
298 K : 3
Cr|Cr3+ (0·1 M)||Fe2+ (0·01 M)|Fe

Given : E = 0·75 V
Cr3 / Cr
E = 0·45 V
Fe 2 / Fe
(log 10 = 1)
11. (a) (i) Silver atom has completely filled d-orbitals in its ground
state, it is still considered to be a transition element. Justify
the statement.
(ii) Why are E values of Mn and Zn more negative than
M2 /M
expected ?
(iii) Why do transition metals form alloys ? 3 1=3
OR
(b) Answer the following questions on the basis of the figure given
below : 3 1=3

56/4/1 9 P.T.O.
 (i) 3d loUrHo$ {H$g VÎd H$s H$UZ EÝW¡ënr Ý`yZV_ hmoVr h¡ ?
(ii) {ÛVr` Am¡a V¥Vr` lo{U`m| Ho$ YmVwAm| H$s H$UZ EÝW¡ënr ~¥ hmoVr h¢ ?
(iii) ?

IÊS> J
12. ZrMo {XE JE {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE : 1+1+1+2=5
{H$gr amgm`{ZH$ A{^{H«$`m Ho$ {bE doJ {Z`_, A{^{H«$`m doJ H$mo A{^H$maH$m| H$s gm§ÐVm
AWdm Am§{eH$ Xm~ go g§~§{YV H$aVm h¡ & EH$ gm_mÝ` A{^{H«$`m aA + bB C
{Og_| BgH$s A{^{H«$`m H$m`©{d{Y _| H$moB© _Ü`dVu MaU Zht h¢, AWm©V² `h EH$ àmW{_H$
A{^{H«$`m h¡, doJ {Z`_ {X`m OmVm h¡ r = k[A]x [B]y Ohm± [A] Am¡a [B], A Am¡a B H$s
gm§ÐVmAm| H$mo _mob à{V brQ>a _| {Zê${nV H$aVo h¢ & KmVm§H$ x Am¡a y àË`oH$ A{^{H«$`m Ho$
{bE n[ad{V©V hmoVo h¢ {OÝh| à`moJ Ûmam {ZYm©[aV {H$`m OmVm h¡ & k Ho$ _mZ CZ n[apñW{V`m|
Ho$ gmW n[ad{V©V hmoVo h¢ Omo A{^{H«$`m doJ H$mo à^m{dV H$aVr h¢ O¡go Vmn, Xm~, n¥îR>r`
joÌ\$b, Am{X & BZ KmVm§H$m| H$m A{^{H«$`m H$s Hw$b H$mo{Q> Ho$ ê$n _| OmZm OmVm h¡ &
eyÝ` H$mo{Q> H$s A{^{H«$`m H$m doJ pñWa ahVm h¡ Am¡a `h A{^H$maH$m| H$s gm§ÐVm na {Z^©aVm
go ñdV§Ì hmoVm h¡ & àW_ H$mo{Q> H$s A{^{H«$`m Ho$db EH$ A{^H$maH$ H$s gm§ÐVm na {Z^©a
H$aVr h¡ & EH$ A{^{H«$`m {ÛVr` H$mo{Q> H$s H$hr OmVr h¡ O~ BgH$s Hw$b H$mo{Q> Xmo hmo & EH$
~ma `{X h_Zo A{^{H«$`m H$s H$mo{Q> {ZYm©[aV H$a br, Vmo h_ dmng OmH$a {H$gr ^r
k hb H$a gH$Vo h¢ &
(i) {ZåZ{b{IV doJ ì`§OH$ dmbr A{^{H«$`m H$s Hw$b H$mo{Q> n[aH${bV H$s{OE : 1
doJ = k[A]1/2 [B]3/2
(ii) hmoVm h¡ ? 1
(iii) {^àm` h¡ ? 1
(iv) (H$) EH$ àW_ H$mo{Q> H$s A{^{H«$`m H$mo 50% nyU© hmoZo _| 77·78 {_ZQ> bJVo
h¢ & Bg A{^{H«$`m Ho$ 30% nyU© hmoZo _| bJZo dmbo g_` H$m n[aH$bZ
H$s{OE & (log 10 = 1, log 7 = 0·8450) 2

AWdm
(I) EH$ àW_ H$mo{Q> H$s A{^{H«$`m H$m doJ pñWam§H$ 1 10 3 à{V goH$ÊS> h¡ &
Bg A{^{H«$`m _| A{^H$maH$ H$s _mÌm 5 g go KQ>H$a 3 g hmoZo _| {H$VZm
g_` bJoJm ? (log 3 = 0·4771, log 5 = 0·6990) 2
56/4/1 10
 (i) Which element in 3d series has lowest enthalpy of atomisation ?
(ii) Why do metals of the second and third series have greater
enthalpies of atomisation ?
(iii) Why are enthalpies of atomisation of transition metals quite high ?

SECTION C

12. Read the passage given below and answer the questions that
follow : 1+1+1+2=5
The rate law for a chemical reaction relates the reaction rate with the
concentrations or partial pressures of the reactants. For a general
reaction aA + bB C with no intermediate steps in its reaction
mechanism, meaning that it is an elementary reaction, the rate law is
given by r = k[A]x[B]y, where [A] and [B] express the concentrations of A
and B in moles per litre. Exponents x and y vary for each reaction and
are determined experimentally. The value of k varies with conditions
that affect reaction rate, such as temperature, pressure, surface area, etc.
The sum of these exponents is known as overall reaction order. A zero
order reaction has a constant rate that is independent of the
concentration of the reactants. A first order reaction depends on the
concentration of only one reactant. A reaction is said to be second order
when the overall order is two. Once we have determined the order of the
reaction, we can go back and plug in one set of our initial values and
solve for k.
(i) Calculate the overall order of a reaction which has the following
rate expression : 1
Rate = k[A]1/2 [B]3/2
(ii) What is the effect of temperature on rate of reaction ? 1
(iii) What is meant by rate of a reaction ? 1
(iv) (a) A first order reaction takes 77·78 minutes for 50%
completion. Calculate the time required for 30% completion
of this reaction. (log 10 = 1, log 7 = 0·8450) 2
OR
(b) A first order reaction has a rate constant 1 10 3 per sec.
How long will 5 g of this reactant take to reduce to 3 g ?
(log 3 = 0·4771; log 5 = 0·6990) 2

56/4/1 11 P.T.O.