Sec: XII PASS IIT_IC Date:21-08-2023
Time: 3 Hrs. FTM – 03 Max.Marks:300
JEE MAIN 2022 Model
KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
C C A D A D B D D C
11 12 13 14 15 16 17 18 19 20
C A C C C A D C B A
21 22 23 24 25 26 27 28 29 30
2 9 6 2 5 2 4 5 1 3
CHEMISTRY
31 32 33 34 35 36 37 38 39 40
A C C D A D A D B D
41 42 43 44 45 46 47 48 49 50
B D D D B B B C C B
51 52 53 54 55 56 57 58 59 60
100 17 4 6 200 300 1200 3 2 2
MATHEMATICS
61 62 63 64 65 66 67 68 69 70
D A D A B D C B B B
71 72 73 74 75 76 77 78 79 80
A B B D B D A C D B
81 82 83 84 85 86 87 88 89 90
2 1 1 2 4 8 4 4 2 2
Solutions
PHYSICS
1. C)
From free body diagram of the wedge, we have
Normal reaction between wedge and ground
N 0 mw g mb g cos 450 sin 450 mb g cos 450 sin 450
in vertical direction
1 1
300 200 0.6 200 460 N
2 2
And in horizontal direction,
mb g cos 2 450 f mb g cos2 450 or f 40
But f s N0 or 40 s 460
40 2
s min
460 23
2. C)
Let coefficient of friction be , then retardation will be g . From equation of motion, v u at
0 6 g 10
6
or 0.06
100
3. A)
A block of mass m is placed on a surface with a vertical cross-section then
x3
d
x2
dy 6
tan
dx dx 2
At limiting equilibrium, we get
tan , 0.5 x 2 / 2
x 2 1 x 1
Now, putting the value of x in y x3 / 6 , we get,
When x= 1 when x = -1
2
1 1 1
3 3
1
y y
6 6 6 6
So, the maximum height above the ground at which the block can be placed without slipping is.
4. D)
The acceleration of block B is a0 g sin along the inclined plane. From free body diagram of the
baby in the frame triangular block B.
ma0 cos f
and N ma0 sin mg
or N mg sin 2 mg
Or N mg cos 2
Thus, ma0 cos f s N
Or ma0 cos s mg cos2
or sin cos s mg cos2
a0 g sin
s tan
s min tan 600
s min 3
5. A)
Free body diagram of block,
Pseudo force acting on the block Fp ma0 1 4 4 N
f max s mg 0.3 110 3N
As FP f max the block slides towards right as the truck will accelerate towards left ( see figure) this
means the kinetic friction will act on the block. Let a be the acceleration of the block in the frame of
ground.
2
k mg ma
a k g 0.2 10 2m / s 2
1
using , s ut at 2 u 0
2
1
s 2 1 1m
2
6. D)
Here, F 10 8a ( where, a is the acceleration of the system)
20 5
Or 30 10 8a or a m / s2
8 2
Since, blocks are moving together,
Free body diagram of A.
For block A, F f 4a
5
or 30 4 f tmax or 20 30
2
or 30 20
2 2
min
3 3
7. B)
A1 area of complete circle a 2
a 2
2
A2 area of removed part
a
2 4
Coordinates of COM of original uncut lamina x1 , y1 0,0
a
Coordinates of COM of removed portion x2 , y2 , 0
2
For the residual part,
a 2 a
a 2 0
A x A2 x2 4 2 a
X COM 1 1
A1 A2 a 2
6
a 2
4
Similarly, you will get
YCOM 0
a
Hence, coordinates of COM of the uniform lamina ,0
6
8. D)
1 0 2 90
Assuming origin at origin at A, YCOM i 60 m from A,
1 2
m a m2 a2 1 10 2 10
a COM 1 1
m1 m2 1 2
10ms 2 or 10ms 2 downwards
3
m1 u1 m2 u2
u COM
m1 m2
1 200 2 55
30 ms 1
1 2
2
vCOM uCOM 2aCOM SCOM
2
0 30 2 10 SCOM
2
or SCOM 45m
So, maximum height attained by COM from the ground is
hmax 60 45 105 m
9. D)
Let x = 0 is located at the left end. As there is no external force acting on the system, position of
COM does not change.
X i COM X i COM
m 0 M 5 m 10 x M 5 x
mM mM
Or 20 5 60 10 x 20 5 x
Or x 7.5 m
10. C)
v1 2 gh
v2 e 2 gh
v3 ev2 e 2 2 gh
v22
h1 e2 h
2g
v2
h2 3 e4 h
2g
Similarly, h3 e6 h
Total distance travelled, s h 2h1 2h2 2h3 .....
h e2 h 2e4 h 2e6 h .....
4
h 2e 2 h 1 e 2 e 4 ....
1 2e2
Or s h 2e 2 h h
1 e2
1
1 e
2
1 e 2
h 2
1 e
11. C)
Let us assume that the smaller ball is slightly separated from M just before M colloids the floor.
m2 m1 2m1 mM 2M
v2 . u2 . u1 u u
m2 m1 m1 m2 mM mM
m
0
M
v2 u 2u 3u
But, u 2 gh , so v2 3 2 gh
v 2 9 2 gh
H 2 9h
2g 2g
12. A)
X CM
xdm
dm
If n 0,
L
Then, xCM
2
L
As n increases, the centre of mass shift away from x towards x L which only option (a) is
2
satisfying.
13. C)
To keep the centre of mass at the same position, velocity of centre of mass is zero, so,
m1v1 m2 v2
0
m1 m2
Where, v1 and v2 are the velocities of particles 1 and 2 respectively.
dr dr dr1 dr
m1 1 m2 2 0 v1 and v2 2
dt dt dt dt
5
Where dr1 and dr2 represent the change on displacement of particles.
Let 2nd particle has been displaced by distance x .
m1 d m2 x 0
m1d
Or x
m2
14. C)
For pure translatory motion, net torque about centre of mass should be zero.
Thus, F is applied at centre of mass of system,
m 0 m2 l
OP 1
m1 m2
Where, m1 and m2 are masses of horizontal and vertical section of the object. Assuming object is
uniform,
2l
OP
3
2 l
PC l l
3
2l 4l
2l
3 3
15. C)
Let mass of each body be m . Their motion is represent as shown in figure.
m1v1 m2 v2
From VCM
m1 m2
m 2v mv v
VCM
mm 2
(the direction of motion of first particle is taken as positive).
v
So, velocity of centre of mass of the system is in the direction of motion of particle having larger
2
speed.
16. A)
Angular momentum, L l ……………..(i)
1 2 1
Kinetic energy, K l L [from eq.(i)]
2 2
K
L2
6
K
2
L' L'
2 L
Now,
2 4
17. D)
As, r F
is perpendicular to both r and F, so r . as well as F . has to be zero.
18. C)
Conservation of angular momentum gives
1 1
MR 21 MR 2 2MR 2 2
2 2
1 1
MR21 R2 M 4m 2
2 2
M
or 2 1
M 4m
19. B)
Angular momentum of particle about O.
L m r v
L mrv sin mv r sin mvl
20. A)
Moment of inertia of circular wire about its axis is MR 2 .
Consider two diameters ZZ ' and YY ' .
Moment of inertia about of these two diameters is same, say l .
From perpendicular axes theorem,
l l MR 2
MR 2
l
2
21. 2
Since the wall is smooth, the vertical component of velocity remains unaltered.
7
As collision is elastic, e 1
speed of separation = speed of approach
u ' u cos u '
after compact, horizontal component of velocity relative to the ground.
u 'cos u ' u ' u cos 2u '
Time of flight depends on the vertical component of velocity, which is unchanged.
2u cos
T
g
Distance covered in the horizontal direction before and after impact are same.
u cos t u cos 2u 'T t t u cos u cos u '
2u sin
u cos u '
g
1 2u sin
t . u cos 2u '
2 u cos u ' g
or t
u cos 2u ' u sin k 2
g u cos u '
22. 9
Using law of conservation of momentum between B and C
mu mv1 2mv2 ………… (i)
Collision between B and C is elastic.
Note : friction between A and B will non-impulsive, therefore we ignore it.
So, e 1
u v2 v1 …………..(ii)
From eq. (i) and (ii), we get
2u
v2
3
For centre of mass of (A+B) system,
2m 3m v1
2u
3
4u
vf
9
2 2
1 2u 1 4u 4
E 2m 3m mu 2 9
2 3 2 9 27
23. 6
About the axis given
m 2R
2
mL2
IA m 2R m 2R
2 2
12 12
8
1 13
4 mR 2 mR 2
3 3
I B mR 2
mR 2
lhoop
2
13 1
I net 1 mR 2
3 2
36
mR2 6mR2 K 6
6
24. 2
In the frame of rod, the force on sleeve along the rod is only centrifugal force.
Thus, the acceleration of the sleeve in the frame of rod is
mr 2
arel r 2
m
dv vrel 1
or vrel rel r 2 or vrel dvrel r 2 dr
dr 0 r0
v2 2 2 2
or rel
2 2
l r0
vrel l 2 r02
The speed of the sleeve in the frame of ground is
v vrel l 2 l 2 r02 l 2 2
2 2
2l 2 2 2 r02
n 2
25. 5
mv 2
Centripetal acceleration is provided by normal contact force thus, we can write , N
R
Also,
dv mv 2 dv
N m or m
dt R dt
v
dv
v v 21
or 2 or t
R v0 v R 2 1 v 0
t t 1 1
v
1
or or
R v v0 R v v0
1 1 t
or
v v0 R
v0 R 10 1
or v 5m / s
R tv0 1 0.1110
26. 2
As shown in figure,
The time of flight in air is
2v sin 600 3v
T
g g
9
The block must travel the horizontal distance AB 2R sin 600 in the time T with constant horizontal
velocity v cos 600
v cos 600 T 3R here, R 0.2
V 2m / s
According to mechanical energy consecutive principle,
U C TC U A TA
or 0 mv02 mg R R sin 300 mv 2
1 1
2 2
2
v 3 1
or 0 10 0.2 4
2 2 2
1
v0 10 m / s 10 x
x 2
27. 4
At point B
N=0
mv 2
mg sin
R
2
v
or g sin
R
v 2 gR sin
Also, v 2 v02 2 gh
22 Rg
or v 2 2 g R R sin
5
or 5v 2 22 gR 10 gR 10 gR sin
or 5 gR sin 10 gR sin 12 gR
or 15 gR sin 12 gR
12 4 x
sin
15 5 5
x 4
28. 5
If the block completes its turn on vertical track, at the lowest point of track, then speed of block will
be
10
U min 5g R r ............. i
According to conservation principle of mechanical energy,
1
mg rmin cos R rmin mu 2
2
3R 3 23
rmin
2 cos 3 2 4 3
5
3 5 23
15m 3n
23
n5
29. 1
If the car brakes with deceleration a0 , then in the frame of car, a pseudo force of magnitude ma0 in
the direction of car’s motions will appear to act on the ball. If pseudo force acted continuously, then
ball could certainly not reach at the highest point of path because work done by pseudo force is
zero. Thus, the string will be horizontal when the car stop.
In the frame of car, let velocity of ball is v.
Work done by pseudo force + Work done by gravity = change in kinetic energy of ball.
1
or ma0l mg 2l mv 2 0
2
mv 2
But at top point, T mg
l
2
mvmin
0 mg
l
mvmin mgl
2
From eqs (i) and (ii) we get
mgl
ma0min l 2mgl
2
5
a0min g
2
maximum stopping distance of car is
u2 50
Smax 1m
2a0min 2 5 g
2
30. 3
When slipping stops, both will move with common velocity v(say).
From conservation of momentum,
mu 2m 0 m 2m v
u
v
3
1 1
Work done by friction, W f K f Ki 3m v2 mu 2
2 2
2
mu 2 mu 2 mu 2
1 u 1 1
2 9 2 3
k 3
11
31. (A)
E1 = 25 eV, E2 = 50 eV
150
1 = √ 25 Å
150 𝜆
2 = √ 50 Å 𝜆1 = √2 1 = √22
2
32. (C)
1
For hydrogen r = 0.529Å × 1
1
For Li2+ r1 = 0.529 × 3
𝑟 𝑟
=3 r1 = 3
𝑟1
33. (C)
Given t1/2 15 minutes
Total time (T) = 1hr =60min
From T n t1/2
T 60
L 4
t1/2 15
34. (D)
So, equivalent wt, of Cu2S = M/8
35. (A)
nf = 2 nf = 8
Number of eq. of Cl2
= moles × n factor = 0.15 × 2 = 0.30
Number of eq. of S2O3–2 = 0.010 × 8 = 0.08
Number of eq. of OH– = 0.30 × 1 = 0.30
𝑆2 𝑂3−2 has minimum equivalents hence 𝑆2 𝑂3−2 is limiting reagent.
Number of eq. of Cl2 remaining = 0.3 – 0.08 = 0.22
0.22
Number of moles of Cl2 remaining = = 0.11
2
12
36. (D)
r = k[N2O5]1
2.4 × 10–5 = 3 × 10–5 [N2O5]1
[N2O5]=0.8M
37. (A)
AB2
∆Tf = i.Kf × m
1 1000
2.3 = 5.4 × (𝐴+2𝐵) × (1)
20
AB4
1 1000
1.3 = 5.4 × (𝐴+4𝐵) × (2)
20
From (1) and(2) we get,
B = 45 A = 27
38. (D)
1
II < I < III (increasing order of Bond angle) ∝ 𝜃
III < I < II (Increasing order of dipole moment ).
39. (B)
Bond angle directly proportional to the size of surrounding atom.
40.
xy c
z
v 2.18 108 cm / s
n
41. (B)
Wsolute = A;
Vsolvent = 200 ml; = 1.25 g/ml
∆Tb = Kb × molality
13
𝐴 1000 4𝐴
Molality = 𝑀 × 200×1.25 = 𝑀
4𝐾𝑏 𝐴
So, ∆Tb = 𝑀
42. (D)
For KNO3
(∆Tf)1 = 2 × 0.1 × Kf = 0.2 Kf
For Na3PO4
(∆Tf)2 = (0.2) × (4) × Kf = 0.8 Kf
For FeCl3
(∆Tf)3 = (0.25) × 4× Kf =1Kf
For Na2SO4
(∆Tf)4 = (0.01) × 3× Kf = 0.03 Kf
Hence, maximum depression in freezing point is for FeCl3, and least for Na2SO4
Hence, F.P. is highest for Na2SO4 solution.
43. (D)
ℎ𝑐
E=
𝜆
E = hv
20
= × 10–34 × 3 × 1015
3
E = 20 × 10–19
20×10−19
E(eV) = 1.6×10−19
E(eV) = 12.5
E > work function
Hence photoelectron will eject
1
E = w + 2mv2
E = w + eV
12.5 = 4 + eV
eV = 8.5 eV
V = 8.5 V
44. (D)
O– will repel electron, hence, addition of electron in O– in endothermic
Ar Ar+ + e–, process is ionization, hence, endothermic
Ar + e– Ar–, Ar has noble gas configuration, hence, addition of e– is not favored hence we have to
give some energy, therefore, process is endothermic
14
, H– is getting noble gas configuration hence it will favors addition of e–. When H is
converted to H–, it gains stability hence loses energy.
45. (B)
Element Electron gain enthalpy Electron affinity
O –144 144
S –200 200
Se –195 195
S > Se > O
46. (B) (For same element)
Anions are larger than the neutral atom, while cations are smaller than the neutral atom.
47. (B)
mx = 0.2 g Vx = 0.44 L
𝑚𝐶𝑂2 = 0.1 g 𝑉𝐶𝑂2 = 0.32 L
P and T are constant
𝑉1 𝑉 𝑉1 ⇒ 𝑉𝑥
∴ = 𝑛2 [𝑉 ⇒ 𝑉 ]
𝑛1 2 2 𝐶𝑂2
0.44×𝑀𝑥 0.32×44
=
0.2 0.1
Mx = 64
Molecular mass of SO2 is also equal to 64.
48. (C)
dA = 2dB
𝑀𝐵
MA = [T1 = T2]
2
PA : P B = ?
PV = nRT
PAMA = dART …(i)
and PBMB = dBRT …(ii)
(i) ÷ (ii)
𝑃 𝑀 𝑑
𝑃𝐴 𝑀𝐴 = 𝑑𝐴
𝐵 𝐵 𝐵
PA/PB = 2 × 2
PA : P B = 4 : 1
49. (C)
At high pressure,
𝑎 𝑎
(𝑃 + 𝑉 2 ) ≅ 𝑃 (𝑃 + 𝑉 2 )(Vm – b) = RT
𝑚 𝑚
(Vm – b)P = RT
15
PVm – Pb = RT
𝑃𝑉𝑚 𝑃𝑏
or PVm = RT + Pb or − 𝑅𝑇 = 1
𝑅𝑇
𝑃𝑏
z - 𝑅𝑇 = 1
𝑃𝑏
z = 1 + 𝑅𝑇
50. (B)
x 1
Na 2 Fe CN 5 NO
2 x 5 1 0
x2
51.
𝑘 1 𝐸𝑎2 𝐸𝑎1
In ( 2 ) = − ( − )
𝑘1 𝑅 𝑇2 𝑇1
1 𝐸𝑎1 −20 𝐸𝑎
In (1) = – 𝑅 ( − 5001 )
40
Ea1 = 100 kJ/mol
52.
Ca NO3 2
1
Ca 2 2NO3
Initial 1 0 0
At eq 1 2
i 1 2
164
i 1 2 16.6%
123
53.
Each P is attached to 4 oxygen atoms.
54.
16
55.
11.2 volume H2O2 means
1 vol H2O2 gives 11.2 vol O2
11.2 ml O2 obtained from 1 ml H2O2
2240×1
2240 ml O2 obtained from = = 200 ml
11.2
56.
W(CH2OH.CH2OH) = 62 g
W (H2O) = 500 g and ∆Tf = 9.3
62×1000×1.86
(9.3) = 62×𝑊𝑠𝑜𝑙𝑣𝑒𝑛𝑡
62×1000×1.86
Wsolvent = = 200 g
62×9.3
Ice separated = 500 – 200 = 300 g
57.
8RT
uav =
M
uav1 T1
[ U av2 2U av1 ]
uav2 T2
1 T T1 1
1
2 T2 T2 4
T2 = 300 × 4
T2 = 1200 K
T2 = 927°C
T2 = 927+27=1200K
58.
The reaction given is
Cr2O72– + Fe2+ + C2O42– Cr3+ + Fe3+ + CO2
6
C r2O72 2Cr 3
On balancing
14H Cr2O7 2 6e 2Cr 3 7H2O ……..(i)
Fe2 Fe3 e ……………………………(ii)
C2O42 2CO2 2e ………………………(iii)
On balancing all three equations, we get
17
Cr2O7 2 Fe2 C2O42 14H 3e
2Cr 3 Fe3 2CO2 7H2O
Hence the total no. of electrons involved in the reaction =3
59.
MnO4 Mn 2 ;n.f. 5
2 ( 3) ( 4)
Fe C 2 O 4 Fe3 CO 2 ;
n.f 3 2 2 4 3 3
3
x 5 1 3 x
5
3 4
Fe2 ( C 2 O4 )3 CO2 ;
n.f. 6(4 3) 6
6
y 5 1 6 y
5
( 2)
Fe SO 4 Fe3 ;
n.f . 1;
1
z 5 1 1 z
5
Fe 2 SO 4 3 can not be oxidised.
Hence, number of moles of KMnO4 required
3 6 1
2
5 5 5
60.
(i) NO(g) + Br2(g) ⇌ NOBr2(g)
(ii) NOBr2(g) + NO(g) 2NOBr(g)
Rate law equation = k[NOBr2][NO]
But NOBr2 is intermediate and must not appear in the rate law equation.
𝑁𝑂𝐵𝑟
From Ist step, Kc = [𝑁𝑂][𝐵𝑟2 ]
2
[NOBr2] = Kc[NO][Br2]
Rate law equation = k Kc [NO]2[Br2]
Hence, order of reaction w.r.t. NO is 2.
18
61. The given numbers are in A.P. Therefore,
21
62. We have sin sin ... i
65
27
cos cos .... ii
65
Squaring Eq. i , we get
2
21
sin 2 sin 2 2sin sin .... iii
65
63. We have sin3 10° + sin3 50° - sin3 70°
19
64.
2cos y 1
65. cos x
2 cos y
66. First inequality gives
2sin x 1 sin x 2 0
1
sin x 0
2
5
x
6 6
Second inequality gives
(x + 1) (x – 2) < 0
-1 < x < 2
Common part is x 2
6
67. We have 4 x 2
2 x 2 4
0 | x 2 | 4
3 | x 2 | 3 1
0 | x 2 | 3 | 3
68. We have
20
69. We have
70.
71. 2sin 2 5sin 2 0
72. The set of lines is 4ax + 3by + c = 0, where a + b + c = 0
Eliminating c, we get
21
4ax + 3by – (a + b) = 0
or a(4x – 1) + b(3y – 1) = 0
This passes through the intersection of the lines 4x – 1 = 0 and 3y – 1 = 0, i.e., x = 1/4, y = 1/3, i.e.,
(1/4, 1/3).
73. The line passing through (2, 3) and perpendicular to –y + 3x + 4 = 0 is
y 3 1
x2 3
or 3y + x – 11 = 0
Therefore, the foot is x = -1/10, y = 37/10.
74. The point Q is (-b, -a) and the point R is (-a, -b). Therefore, the midpoint of PR is (0, 0).
75. Clearly, from the figure, the origin is contained in the acute angle. Writing the equations of the lines as
2x – y + 4 = 0 and - x + 2y + 1 = 0, the required bisector is
2x y 4 x 2y 1
5 5
76. S is the midpoint of Q and R. Therefore,
7 6 3 1 13
S , ,1
2 2 2
2 1 2
Now, the slope of PS is m
2 13/ 2 9
Then the equation of the line passing through (1, -1) and parallel to PS is
2
y 1 x 1
9
or 2x 9y 7 0
77. Any point on the line x y 25 is P a, 25 a , a R.
The equation of chord AB is
T=0
i.e., xa + y(25 – a) = 9 …. (i)
If the midpoint of chord AB is C(h, k), then the equation of chord AB is
T = S1
i.e., xh + yk = h2 + k2 …. (ii)
Comparing the ratio of coefficients of (i) and (ii), we get
a 25 a 9
2
h k h k2
a 25 a 9
or 2
hk h k2
Thus, the locus of C is 25 (x y ) 9 x y
2 2
22
78. Let the midpoint of the chord be P(h, k).
Then CP = h 2 k 2 , where C is the center of the circle.
Since the chord subtends right angle at the center,
Radius = 2 h2 k2
2 2 h2 k2
Locus is x 2 y 2 2
79. The given equation is
2sin 2 3sin 2 0
2sin 1 sin 2 0
1
sin [ sin 2 0 is not possible]
2
sin sin / 6 sin 7 / 6
n 1 / 6
n
n [ 1 7 / 6]
n
Thus, n 1 7 / 6, n Z
n
80. Let the orthocenter be H(5, 8).
Hence, CMH and BMD congruent. Therefore, HM = MD
D is the image of H in the line x – y = 0, which is D (8, 5).
Thus, the equation of the circumcrircle is
x 2 y 3 8 2 5 3
2 2 2 2
i.e., x 2 y 2 4x 6y 27 0
81. The given equation is
tan x sec x 2cos x
But for x = 3 /2, tan x and sec x are not defined. Therefore, there are only two solution
23
82.
83. Given tan
84.
85. The given expression is
24
86. We know that
Considering only integral values, which means k can take eight integral values.
87. We have tan 9° - tan 27° - tan 63° + tan 81°
88. Any point on the line x + y = 4 is (t, 4 – t), where t R. Now, the distance of this point from the line 4x
+ 3y – 10 = 0 is 1. Therefore,
| 4t 3 4 t 10 |
1
5
or | t 2 | 5
i.e., t 3 or t 7
Therefore, the sum of values is –4
89. Lines 2a b x a 3b y b 3a 0 or a 2x y 3 b x 3y 1 0 are concurrent at the
point of intersection of lines 2x + y – 3 = 0 and x + 3y + 1 = 0, which is (2, –1). Now, line mx + 2y + 6
= 0 must pass through this point.
Therefore, 2m – 2 + 6 = 0 or m = –2.
90. sin 7 + sin = sin 4
2 sin 4 cos 3 = sin 4
2 sin 4 cos 3 - sin 4 = 0
sin 4 [2 cos 3 - 1] = 0
1
sin 4 = 0 or cos 3
2
25
or
4 9
26