JEE
VARUN JEE ADVANCED 2025
CHEMISTRY
DPP: 1
CHEMICAL BONDING AND MOLECULAR STRUCTURE
Q1 Which option(s) is/are correct for PCl3 and Q5 Which of the following statement is/are correct?
POCl3 ? (A) In PCl3F2, the P – F bond length is greater
than P – Cl bond length.
(B) N – N bond length in N2H4 is greater than N –
N bond length in N2F4.
(C) In PCl5, the P – Cl axial bond length is greater
than P – Cl equatorial bond length.
(A) d1 > d2
(D) In SF6, all S – F bonds have equal bond
(B) θ1 > θ2
length.
(C) d1 < d2
(D) θ1 < θ2 Q6 Find total no. of polar molecules.
(a) PF3Cl2 (b) SF4
Q2 Which of the following is/are incorrect
(c) PCl5 (d) PCl3F2
statement(s):
(e) SF6 (f) XeF2
(A) CHCl3 is less acidic than CHF3
(g) NO2 (h) BF2Cl
+
(B) Dipole moment of chlorobenzene is more
(i) BF3
than chlorocyclohexane
(C) Dipole moment of fluoromethane is more Q7 Consider the following compounds
than chloromethane (i) IF5 (ii) ICl4
−
(D) NH2NH2.HCl show positive test for nitrogen in (iii) XeO2 F 2 (iv) NH−
2
lassaigne’s test (v) BCl3 (vi) BeCl2
(vii) AsCl4 (viii) B(OH)3
+
Q3 Select the correct statements
(ix) NO2 −
(x) ClO+
2
(A) The bond length in BF3 is shorter than that
Then, calculate value of x + y − z, here x, y ,
of BF−
4 and z are total number of compounds in given
(B) OCl2 has 2pπ − 3d π back bonding
compounds in which central atom used their all
(C) (AlCl3 )2 is not electron deficient but
three p-orbitals, only two p-orbitals and only one
(Al(Me)3 ) is electron deficient
2
p-orbital in hybridisation respectively
(D) In B2 H6 , all the hydrogens are not identical
Q8 Consider the following orbitals
Q4 Which of the following statements are correct?
(i) 3px (ii) 4dz 2
(A) The addition of an electron to NO forms
(iii) 3dx 2 2
−y
(iv) 3dyz
stable NO .
−
Then, calculate value of x + y − z, here x is total
(B) The removal of an electron from NO forms
number of gerade orbital and y is total number
stable NO .
+
of ungerade orbitals and z is total number of
(C) The bond length in NO is greater than that in
axial orbitals in given above orbitals
the NO ion.
+
(D) The bond order of NO+ is 3.0 . Q9 How many of the following species have bond
order less than two?
Android App | iOS App | PW Website
JEE
(a) N O−
3
(D) I→S, T; II→Q, T; III→Q, S; IV→P, R
(b) C O3
2−
Q12 Which pair will have same geometry?
(c) F2
(A) Carbon dioxide and sulphur dioxide
(d) C l2
(B) Carbonate and sulphate ion
(e) Br2
(C) Ammonia and BH3
(f) O2
2−
(D) Sulphate and perchlorate ion
(g) O−
2
(h) N2− Q13 Given the species N2 , CO, NO+ , and CN−
(i) O2
2+
which of the following statements are true for
(j) Li+
2 this:
(k) H e+
2 (I) All the species are diamagnetic
(II) All the species are isostructural
Q10 Match the LIST-I with LIST-II
(III) All the species have identical bond order
(IV) More than one species have zero dipole
moment
(A) I, II, and III
(B) I, II, III, and IV
(C) III and IV
(D) I and II only
Q14 The melting point of RbBr is 682∘ C while that
of NaF is 988 . The principal reason for higher
∘
C
melting point of NaF is:
Choose the correct answer from the options (A) The two crystals are not isomorphous
given below (B) The molar mass of NaF is less than the molar
(A) A-IV, B-II, C-I , D-III mass of RbBr .
(B) A-IV, B-I, C-III , D-II (C) The bond in RbBr is covalent
(C) A-III, B-II, C-I , D-IV (D) The internal distance (rc + ra ) is higher for
(D) A-II, B-IV, C-III , D-I RbBr than for NaF
Q11 Match the species given in List-I with the bond Q15 During the formation of a molecular orbital from
order and magnetic nature given in List-II. atomic orbitals of the same atom, the probability
of electron density is
(A) Non-zero in the nodal plane
(B) Maximum in the nodal plane
(C) Zero in the nodal plane
(D) Zero on the surface of the lobe
(A) I→R, S; II→P, T; III→P, T; IV→Q, S
(B) I→R, T; II→Q, S; III→Q, R; IV→P, Q
(C) I→R, T; II→Q, T; III→Q, T; IV→P, S
Android App | iOS App | PW Website
JEE
Answer Key
Q1 (A, D) Q9 9
Q2 (A, B, C, D) Q10 (A)
Q3 (A, B, C, D) Q11 (C)
Q4 (B, C, D) Q12 (D)
Q5 (B, C, D) Q13 (A)
Q6 3 Q14 (D)
Q7 8 Q15 (C)
Q8 1
Android App | iOS App | PW Website
