SCPC02 2025
CHEMISTRY MOCK CET – 1 (KEY & SOLUTIONS)
KEY:
61 62 63 64 65 66 67 68 69 70
c b a d d a d a a b
71 72 73 74 75 76 77 78 79 80
b c a a c c a b d c
81 82 83 84 85 86 87 88 89 90
d a b c c b c c c c
91 92 93 94 95 96 97 98 99 100
c c b a a b c d a b
101 102 103 104 105 106 107 108 109 110
c a a a a d b a b a
111 112 113 114 115 116 117 118 119 120
a b a d c b a a d a
SOLUTIONS:
61. Sol: (c)
𝑀1 𝑉1 + 𝑀2 𝑉2 = 𝑀3 𝑉3
⟹ 0.5 × 20 + 0.3 × 30 = 𝑀3 [𝑉1 + 𝑉2]
19
⟹ 10 + 9 = 𝑀3 [20 + 30], ∴ 𝑀3 = = 0.38
50
62. Sol: (b)
1000M
m=
1000𝑑− 𝑀𝑀𝐵
63. Sol: (a)
𝑀1 𝑉1 + 𝑀2 𝑉2 = 𝑀3 𝑉3
1.5 × 480 + 1.2 × 520 720 + 624 1344
𝑀3 = = = = 1.344 M
480 + 520 1000 1000
64. Sol: (d)
toluene (𝑃𝑜 𝑥)𝑡𝑜𝑙𝑢𝑒𝑛𝑒
𝑦𝑡𝑜𝑙𝑢𝑒𝑛𝑒 = =
𝑃𝑡𝑜𝑡𝑎𝑙 (𝑃𝑜 𝑥)𝑡𝑜𝑙𝑢𝑒𝑛𝑒 + (𝑃𝑜 𝑥)𝑏𝑒𝑛𝑧𝑒𝑛𝑒
(Vapour phase)
37 × 0.5 18.5 18.5
⟹ = = = 0.237
37 × 0.5 + 119 × 0.5 18.5 + 59.5 78
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𝑋𝑏𝑒𝑛𝑧𝑒𝑛𝑒 + 𝑋𝑡𝑜𝑙𝑢𝑒𝑛𝑒 = 1
𝑋𝑏𝑒𝑛𝑧𝑒𝑛𝑒 + 0.5 = 1
𝑋𝑏𝑒𝑛𝑧𝑒𝑛𝑒 = 1 – 0.5 = 0.5
65. Sol: (d)
𝑝𝑜 − 𝑝
= 𝑥𝐴
𝑝𝑜
(Solute),
854 − 848.9 𝑛𝐴 𝑊𝐴 × 𝑀𝐵
𝑥𝐴 = = = ;
854 𝑛𝐵 𝑀𝐴 × 𝑊𝐵
𝑊𝐴 = weight of solute, 𝑊𝐵 = molar mass of solute
5.1 2 × 76
⟹ = ;
854 𝑀𝐴 × 100
𝑀𝐵 = molar mass of solvent = 𝐶𝑆2 = 12 + 32 × 2 ⟹ 76g
𝑀𝐴
2 × 76 × 854
(Molar mass = = 253
100 × 5.1
of solute)
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 253
Number of atoms = = = 7.90 ≈ 8
𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠 32
So formula of solute is 𝑋8
66. Sol: (a)
𝑁1 𝑉1 + 𝑁2 𝑉2 100 + 50 150
𝑁𝑚𝑖𝑥𝑡𝑢𝑟𝑒 = ⟹ = ⟹ 1N
𝑉1 + 𝑉2 100 + 50 150
𝑁1 𝑉1 = 1 × 100 = 100
(NaOH)
𝑁2 𝑉2 = 1 × 50 = 50
67. Sol: (d)
PV = nRT
So molarity and normality depends on volume so also depends on temperature. But molality and
mole fraction doesn’t depend on volume so doesn’t depend on temperature.
68. Sol: (a)
Moles moles
Molarity ⟹ , Molality =
𝑉𝑜𝑙𝑢𝑚𝑒 𝑀𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑣𝑒𝑛𝑡(𝑖𝑛 𝑘𝑔)
Moles Moles
1= , 1= ,
𝑉𝑜𝑙𝑢𝑚𝑒 𝑊(𝑘𝑔)
i.e., moles in litre
i.e., moles in 1 kg of solvent solution so is more than molality which is defined for solvent.
69. Sol: (a)
Mole fraction of NaOH
moles of NaOH
⟹
𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑁𝑎𝑂𝐻 + 𝑚𝑙𝑒𝑠 𝑜𝑓 𝑢𝑟𝑒𝑎 + 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝐻2 𝑂
w 20 1
moles of NaOH = = ⟹
𝑀𝑤 40 2
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[NaOH = 23 + 16 + 1 ⟹ 40]
w 15
moles of urea ⟹ ⟹
𝑀𝑤 60
w 215
moles of 𝐻2 O ⟹ ⟹
𝑀𝑤 8
[15 + 20 + x = 250]
urea NaOH 𝐻2 O Total
1
2
Mole fraction of NaOH ⟹ 1 15 215 ⟹ 0.03
+ +
2 60 18
70. Sol: (b)
Molarity includes volume of solution which can change in temperature.
71. Sol: (b)
1 1
𝜒𝑠𝑜𝑙𝑢𝑡𝑒 = = = 0.0177
55.5 + 1 56.5
72. Sol: (c)
Molality depends on temperature as it is independent of volume of the solution.
73. Sol: (a)
98% by weight → 98 g 𝐻2 𝑆𝑂4 in 100 g of solution
(𝐻2 𝑆𝑂4 = 98g)
molar mas
m
d=
𝑉
m 100
V= = cc
𝑑 1.84
w 98 × 1.84 × 1000
M= = = 18.4
𝑀×𝑉 98 × 100
74. Sol: (a)
(5% of cane sugar = 1% of a substance(x)
For isotonic 𝜋1 = 𝜋2 π = CRT
𝑛1 𝑛2
⟹ =
𝑉 𝑉
5 1
⟹ =
342 𝑀𝑤
342
∴ 𝑀𝑤 = = 68.4 g
5
75. Sol: (c)
w
M= ; d = 1.17 g/cc
𝑀𝐵 × 𝑉𝐿
1.17 × 1000
∴ M= = 32.05
36.5 × 1
76. Sol: (c)
Urea dissolved in water forms true solution.
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77. Sol: (a)
Adsorption of a gas on the surface of solid.
78. Sol: (b)
Morality expressed in moles per litre.
79. Sol: (d)
Solubility of a gas depends on nature of gas; temperature; pressure of gas.
80. Sol: (c)
Sugar solution contains free molecules (covalent compound)
81. Sol: (d)
Fraction of solute present in water (volume) changes with temperature.
82. Sol: (a)
w 1000 5 1000
M= × = × = 0.5 M
GMw Vml 40 250
83. Sol: (b)
n 0.006
M= = = 0.06
V lit. 0.1
84. Sol: (c)
M × GMW 2.55 × 98
d= = = 1.25 g. cm−3
10 × % 10 × 20
85. Sol: (c)
M1V1 + M2V2 = M3V3
6 × 250 + 2 × 750 = 2.5 × V3
V3 = 1200 ml
Volume of water to be added = V3 – (V1 + V2)
= 1200 – (250 + 750)
= 200 ml
86. Sol: (b)
No. of moles of solute per kg of solvent, molality is independent of temperature.
87. Sol: (c)
240
M= = 0.4
60 × 10
88. Sol: (c)
No.of moles of solute
M=
Volume of solution in litre
0.5
2=
V lit.
0.5
V= = 0.25 lit. = 250 ml solution.
2
89. Sol: (c)
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18 1000
m= × = 0.2 m
180 500
90. Sol: (c)
Strength (s) of H2SO4 = 98 × 19.8 g/L
S = Eq. wt. × N
S 98 × 19.8
N= = = 39.6 N
eq.wt 49
91. Sol: (c)
No. of moles of solute = 1
Wt. of solvent (H2O) = 1000 g
n 1
xsolute = = = 0.018
n+M 1 + 55.55
92. Sol: (c)
M 1
m= M × GMw = 18×98 = 500
d – ( 1000 ) 1.8 − ( 1000 )
93. Sol: (b)
M 0.01
xGlucose = = = 0.00199
nglu + nwater 0.01 + 5
94. Sol: (a)
Molality is defined as the no. of moles per 1000 gm of solvent
1000
m= = 55.5
18
95. Sol: (a)
500 — 0.2 g. fluorine
106 — ?
106 × 0.2
= 400 ppm
500
96. Sol: (b)
P° − P w M
= ×
P° m W
10 2 78
= ×
750 m 78
m = 150
97. Sol: (c)
P° − P w M
= ×
P° m W
6 18 1
= × = = 0.02
60 90 50
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98. Sol: (d)
∆P = P° × x
∆P = 0.80 × 0.25 = 0.2
99. Sol: (a)
P° − P m
=
P° m + 55.5
76 − 75.6 m
=
76 m + 55.5
m = 0.3
100. Sol: (b)
m
xsolute = 1000
m+
Mw of solvent
m
0.2 = 1000 = 3.2
m + 78
101. Sol: (c)
w1 w2
+
M1 M2
6 2
=
180 M2
M2 = 6
102. Sol: (a)
1000 × xsolute
m=
xsolvent × Msolute
1000 × 0.2
= = 3.2
0.8 × 78
103. Sol: (a)
This is Raoult’s law.
104. Sol: (a)
Al2(SO4)3 furnishes maximum number of ions.
105. Sol: (a)
The interparticle force in between CHCl3 and acetone increases due to H-bonding and thus ∆mixing V
becomes negative.
106. Sol: (d)
C2H5OH show H-bonding as well as polarity both.
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107. Sol: (b)
NaCl furnishes two ions on complete dissociation.
108. Sol: (a)
Minimum freezing point means more number of ions
(a) 0.01 × 2 = 0.02 (b) 0.005 × 1 = 0.005 (c) 0.005 × 3 = 0.015 (d) 0.005 × 2 = 0.01
109. Sol: (b)
𝑜
PEtOH = 𝑃𝐸𝑡𝑂𝐻 × Mole fraction of EtOH in liquid phase
= PT × Mole fraction of EtOH in vapour phase
Thus, mole fraction of EtOH in vapour phase
𝑃′ 4.556
= = = 0.635
𝑃𝑇 4.556 + 2.619
110. Sol: (a)
p = 𝑃𝐵𝑜 χB (B = Benzene acts as solvent)
167
χB = = 0.623
268
χsolute = 1 – χB = 0.377
111. Sol: (a)
𝑃𝐴 °𝜒𝐴 𝑃𝐴 °𝜒2
χ1 = =
𝑃𝑇𝑜𝑡𝑎𝑙 𝑃𝑇𝑜𝑡𝑎𝑙
𝑃𝐴 °𝜒2
∴ PTotal =
𝜒1
112. Sol: (b)
For urea, i = 1, while for BaCl2, i = 3, therefore, the rations of any colligative property for BaCl2 solution
to urea solution is 3.
113. Sol: (a)
i = 1, for non-electrolyte
114. Sol: (d)
Total colligative properties are four.
115. Sol: (c)
Azeotropic mixtures are also known as constant boiling mixtures. They are liquid mixtures which boil
over without any change in the composition. Such mixtures cannot be separated into components by
fractional distillation. They are of two types: maximum boiling azeotropes and minimum boiling
azeotropes.
Maximum boiling azeotropes are formed by solutions having negative deviations. Boiling point is
maximum.
For example,
• Water and HCl
• Water and nitric acid
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• Chloride form and acetone
• Acetic acid and pyridine
Minimum boiling azeotropes are formed by solutions having positive deviations. Boiling point is
minimum. For example,
• Acetic acid and toluene
• Pyridine and water
• Ethanol and benzene
• Water and ethanol
116. Sol: (b). The relative lowering of vapour pressure is equal to the mole fraction of the solute.
117. Sol: (a). The number of moles of the solute present per kilogram of the solvent is known as its
molality.
𝑊𝑠𝑜𝑙𝑢𝑡𝑒 1 𝑊𝑠𝑜𝑙𝑢𝑡𝑒 1
m= × = × × 1000
𝑀𝑤𝑠𝑜𝑙𝑢𝑡𝑒 𝑊𝑠𝑜𝑙𝑣𝑒𝑛𝑡 𝑖𝑛 𝑘𝑔 𝑀𝑤𝑠𝑜𝑙𝑢𝑡𝑒 𝑊𝑠𝑜𝑙𝑣𝑒𝑛𝑡 𝑖𝑛 𝑔
118. Sol: (a). Urea and glucose do not dissociate in solution. Sodium chloride gives two ions and
potassium sulphate gives three ions per formula unit. Therefore, the effective number of particles is
maximum in potassium sulphate, and it shows the maximum depression in freezing point.
119. Sol: (d)
C6H5NH3Cl → C6H5𝑁𝐻3⊕ + Cl⊝
Ca(NO3)2 → Ca2+ + 2𝑁𝑂3⊝
La(NO3)3 → La3+ + 3𝑁𝑂3⊝
Glucose does not dissociate. So it has the minimum number of particles, and therefore, it shows
minimum depression in freezing point. So it has the maximum freezing point.
120. Sol: (a)
𝑃𝑁2 = 5 × 0.8 = 4
Applying Henry’s law, we get
𝑃𝑁2 = KH × 𝜒𝑁2
or 4 = 105 × 𝜒𝑁2
𝜒𝑁2 = 4 × 10−5
𝑛𝑛𝑖𝑡𝑟𝑜𝑔𝑒𝑛
= 4 × 10−5
𝑛𝑛𝑖𝑡𝑟𝑜𝑔𝑒𝑛 + 𝑛𝐻2 𝑂
𝑛𝑛𝑖𝑡𝑟𝑜𝑔𝑒𝑛
or = 4 × 10−5
𝑛𝑛𝑖𝑡𝑟𝑜𝑔𝑒𝑛 + 10
or 𝑛𝑛𝑖𝑡𝑟𝑜𝑔𝑒𝑛 = 4 × 10−4
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