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MODI CAREER ACADEMY 12TH NEET

RAJKOT – JAMNAGAR – ISHWARIYA PV+VJ+ISH+MSA+MCA
Std : 12th EM+GM Date : 18/05/25 Sub : CHEMISTRY(052) Time : 2:00 Hours Marks : 360 1

SOLUTION
B 1.The incorrect rule regarding the determination of significant figures is
;FY”S V\FS GSSL SZJF DF8[ GM SIM lGID BM8M K[m
(A) Zeros preceding to first non-zero digit are not significant
5C[,F lAG < X}gI VF\SGL VFU/GF\ X}gI ;FY”S VF\S GYLP
(B) Zeros between two non–zero digits are not significant
A[ lAG X}gI VF\SGL JrR[GF\ X}gIM ;FY”S VF\S GYLP
(C) Zeros at the right end of the number are significant if they are on the right side of decimal point
;\bIFGM HD6L AFH]GF\ X}gIM ;FY”S VF\S K[P HM T[ NXF\X lRgCGL HD6L AFH]V[ CMI TM
(D) All non–zero digits are significant. AWF lAG<X}gI VF\SM ;FY”S VF\S K[P
Sol. –
B 2. Which one of the following compounds has the most acidic nature?
GLR[GFDF\YL SI]\ ;\IMHG ;F{YL JW] V[l;l0S :JEFJ WZFJ[ K[m

(A) (B) (C) (D)

Sol.

D 3. The rate of hydrolysis / hydration of alkene for given molecule is .............

VF5[, V6]VM DF8[ VFÿSLGGF H,LISZ6 DF8[GF NZGM ;FRM @D PPPPPPPPPP
(i) (ii) Ph − CH = CH2 (iii) CH2 = CH2

(A) i > ii > iii (B) ii > iii > i (C) ii > iii > i (D) ii > i > iii
Sol.
B 4. The intermediate during the addition of HCl to propene in presence of peroxide is
5|M5LGDF\ 5[ZMS;F.0GL CFHZLDF\ HCl GF\ pD[Z6DF\ DwI:YL X]\ CMI K[m
+
(A) CH3 − CH − CH2 − Cl (B) CH3 − CH − CH3
+
(C) CH3 − CH2 − CH2 (D) CH3 − CH2 − CH2
Sol.

C 5. Excess of carbon dioxide is passed through 50 mL of 0.5 M calcium hydroxide solution. After the completion of
the reaction, the solution was evaporated to dryness. The solid calcium carbonate was
completely neutralised with 0.1 N hydrochloric acid. The volume of hydrochloric acid required is (Atomic mass
of calcium = 40)
SFA”G 0FIMS;F.0GM JWFZFGM HyYM 50 mL 0.5 M S[lÿXID CF.0=MS;F.0GF\ 2FJ6DF\YL 5;FZ SZJFDF\ VFJ[ K[P 5|l@IF 5}6”
YIF 5KL 2FJ6G[ X]qS AGFJJF AFq5LEJG SZFI K[P WG S[lÿXID SFAM”G[8G]\ 0.1 N CF.0=MS,MZLS V[l;0 ;FY[ ;\5}6”
T8:YLSZ6 SZJFDF\ VFJ[ TM H~ZL CF.0=MS,MlZS V[l;0G]\ SN X]\ CX[m (S[lÿXID 5ZDF6]G]\ N/ = 40)
(A) 300 cm3 (B) 200 cm3 (C) 500 cm3 (D) 400 cm3
Sol.

B 6. Which of the following is dependent on temperature? GLR[GFDF\YL SI]\ TF5DFG 5Z VFWFZLT K[m
(A) Molality sDM,F,L8Lf (B) Molarity sDM,FZL8Lf
(C) Mole fraction sDM, V\Xf (D) Weight percentage sJHG 8SFJFZf
Sol.
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D 7. 2–Bromopentane is heated with EtO− Na + in ethanol. The major product obtained is

2–A|MDM5[g8[GG[ EtO− Na + ;FY[ UZD SZJFYL 5|F%T YTL D]bI GL5H X]\ K[m
(A) 2–Ethoxypentane (2–.YMlS;5[g8[G) (B) Pent–1–ene (5[g8®–1–.G)
(C) Isobutane sVF.;MaI]8[Gf (D) Pent–2–ene (5[g8®–2–.G)
Sol.

A 8. Which element from following is the last element of 5d–transition series?

GLR[GFDF\YL SI] TßJ 5d – ;\@F\lT `F|[6LG]\ K[ÿ,]\ TßJ K[m
(A) Hg (B) Cd (C) Hs (D) Hf
Sol.
D 9. 0.43 g of a metal of valence 2 was dissolved in 50 mL of 0.5 M H2SO4 solution. The unreacted acid required
14.2 mL of 1 M NaOH solution for neutralization. The atomic weight of the metal is
;\IMHSTF 2 WZFJTL 0.43 g WFT]G[ 50 mL 0.5 M H2SO4 GF\ 2FJ6DF\ VMUF/TF\ 5|l@IF SIF” JUZ AFSL ZC[,F V[l;0G]\
T8:YLSZ6 SZJF DF8[ 14.2 mL 1 M NaOH GF\ 2FJ6GL H~Z 50[ TM WFT]G]\ 5ZDFcJLI N/ X]\ CX[m
(A) 56 u (B) 40 u (C) 42 u (D) 24 u
Sol.

C 10. What is the oxidation state of phosphorus in phosphate ion?

OM:O[8 VFIGDF\ OM:OZ;GL VMlS;0[XG VJ:YF X]\ CX[m
(A) –5 (B) +3 (C) +5 (D) +6
Sol.
C 11. Which among the following properties is NOT exhibited by transition elements?
GLR[GFDF\YL SIF U]6WD” ;\@F\lT TßJ ‹FZF NXF”JFI GCLm
(A) These are generally hard. T[ ;FDFgI ZLT[ ;BT K[P
(B) These from alloys with other metals. T[VM AL_ WFT] ;FY[ lD`F|WFT] AGFJ[P
(C) These do not conduct heat. T[VM pqDFG]\ JCG SZ[ GCLP
(D) These are malleable and ductile. T[VMG[ 8L5L XSFI VG[ B[\RLG[ TFZ AGFJL XSFIP
Sol.
C 12.

,
Product (P) is lG5H (P) X]\ K[m

(A) (B) (C) (D)

Sol.
 Page |3

D 13. 2.76 g of silver carbonate on being strongly heated yields a residue weighing
2.76 g l;ÿJZ SFAM”G[8G[ ;BT UZD SZJFYL D/TL VJX[QG]\ JHG X]\ YX[m
(A) 3.54 g (B) 3.0 g (C) 1.36 g (D) 2.16 g
Sol. Silver carbonate on being strongly heated decomposes as
 1
Ag 2CO3 ⎯⎯ → 2 Ag + CO2 + O2
2
276g 216g
276 g of Ag2CO3 gives = 216 g of Ag
Hence 2.76 g of Ag2CO3 will give
2.76  216
= 2.16 g
276
D 14.

Here reagent is VCL\ 5|l@IS X]\ K[m

(A) LiAlH4 (B) NaBH4 (C) Ni/H2 (4) All of these
Sol.

B 15. 6.02 1020 molecules of urea are present in 100 mL of its solution. The concentration of solution is
I]ZLIFGF 100 mL 2FJ6DF\ 6.02 1020 V6] CFHZ K[P 2FJ6GL ;F\2TF PPPPPPPPPPP YX[P
(A) 0.02 M (B) 0.01 M (C) 0.001 M (D) 0.1 M
Sol. Given Number of molecules of urea = 6.02  1020
6.02  1020
Number of moles =
NA
6.02  1020
= 1  10−3 mol
6.02  10 23

Volume of the solution = 100 mL =

100
L = 0 .1 L
1000
Concentration of urea solution
1  10−3
( )
in mol −1 =
0.1
molL−1
−2 −1
1  10 molL =0.01 M
B 16. Calculate the mass percentage of aspirin (C9H8O4)in acetonitrile (CH3CN) when 6.5 g of C9H8O4 is
dissolved in 450 g of (CH3CN).
6.5 g V[l:5lZG (C9H8O4) 450 g (CH3CN) DF\ VMUF/JFDF\ VFJ[4 TM V[l:5lZGGL V[;L8M GF.8=F.,DF\ N/YL 8SFJFZL
U6MP
(A) 14 (B) 1.4 (C) 15 (D) 1.5
Sol.

C 17. The number of Cl− ions in 100 mL of 0.001 M NaCl solution is

0.001 M NaCl 2FJ6GF 100 mL DF\ CFHZ Cl− VFIGGL ;\bIFo
(A) 6.022 1023 (B) 6.022 1020 (C) 6.022 1019 (D) 6.022 1021
Sol.

A 18. 1.2 g of Mg (at. mass 24) will produce MgO equal to

1.2 g Mg (VFlcJI N/ 24) PPPPPPPPPPPPPPP G[ ;D5|DF6 MgO pt5gG SZX[P
(A) 0.05 mol (B) 40 g (C) 40 mg (D) 4 g
 Page |4

Sol.

C 19. Which of the following compounds undergoes nucleophilic substitution reaction most easily?
GLR[GFDF\YL SI]\ ;\IMHG S[g2FG]ZFUL lJ:YF5G 5|l@IF B}A H ;Z/TFYL VF5[ K[m

(A) (B) (C) (D)

Sol.

A 20. Approximately how many mL of 0.2 M HCl are required to react completely with 1 g mixture of Na2CO3 and
NaHCO3 containing equimolar amounts of both?
Na2CO3 VG[ NaHCO3 A\G[ 5NFYM”GF ;DDM,Z HyYM WZFJTF 1 g lD`F|6G[ ;\5}6” 56[ 5|l@IF SZJF DF8[ 0.2 M HCl GF
VFXZ[ S[8,F lDl, GL H~Z 50X[ m
(A) 79 mL (B) 100 mL (C) 158 mL (D) 316 mL
 Page |5

Sol.

B 21. Neopentyl alcohol on treatment with HBr gives lGIM5[g8F., VFÿSMCM, HBr ;FY[ 5|l@IFYL X]\ VF5[ K[m
(A) neopentyl bromide lGIM5[g8F., A|MDF.0
(B) 2- bromo -2- methyl butane 2–A|MDM–2–lDYF.,aI]8[G
(C) 2- methyl -2- butene 2–lDYF.,–2–aI]8LG
(D) 2- methyl -1- butene 2–lDYF.,–1–aI]8LG
Sol.

A 22. What is the change in oxidation number of S in following reaction?

GLR[GL 5|l@IFDF\ S GL VMlS;0[XG VJ:YFDF\ X]\ O[ZOFZ YX[m
H2S + NO3− ⎯⎯
→ H2O + NO + S
(A) –2 to 0 (B) 0 to –2 (C) –2 to +2 (D) 0 to +2
Sol.
D 23.

What is X? X X\] K[m

(A) (B) (C) (D)

Sol.
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C 24. Identify the correct statement: ;\UT lJWFG 5;\N SZMP

(A) Yb 2+ is an oxidant Yb 2+ VMlS;0g8 K[P
(B) Lu 3+ is paramagnetic Lu 3+ VG]]R]\ASLI K[P
(C) CrO is basic CrO A[hLS K[P
(D) Brass in an alloy of Cu, Sn Cu, Sn GL lD`F|WFT] A|F; K[P
Sol.
C 25.

Product (A) and (B) can be distinguished by GL5H (A) VG[ (B) X[GF ‹FZF lJE[NLT SZL XSFIm
(A) Sodium metal ;Ml0ID WFT]
(B) Neutral FeCl3 T8:Y FeCl3
(3) Lucas reagent ÿI]SF; 5|l@IS
(D) Esterification reaction V[:8ZLSZ6 5|l@IF
Sol.

A 26. Which from following elements belongs to the actinoids?

GLR[GFDF\YL SI]\ TßJ V[S8LGM.0®; ;FY[ ;\A\lWT K[m
(A) Cm (B) Pm (C) Tm (D) Sm
Sol.
C 27. Reaction involving anti addition is S. 5|l@IF anti addition NXF”J[ K[m
H+ /H2O
(B) CH3CH = CH 2 ⎯⎯⎯
→ HX
(A) CH2 = CH2 ⎯⎯⎯⎯ →
Hg( OAc ) /H O
(C) CH3CH = CH2 ⎯⎯⎯⎯⎯⎯
2 2 →
NaBH
(D) CH2 = CH2 ⎯⎯⎯⎯⎯ −→
B2H6 /THF
4 H2O2 /OH

Sol.

C 28. What is the general formula of lanthanoid hydroxide? (Consider Ln as any lanthanoid element)
,[gY[GM.0 CF.0=MS;F.0G]\ ;FDFgI ;}+ X]\ K[m (Ln G[ ,[gY[GM.0 TßJ TZLS[ wIFGDF\ ,[J])
(A) Ln ( OH ) (B) Ln ( OH )2 (C) Ln ( OH )3 (D) Ln ( OH )4
Sol.
A 29.

What is C? C X]\ K[m

(A) CH3 − CH3 (B) (C) (D) CH2 = CH2

Sol.
 Page |7

B 30.Which of the following gas readily de–colourises the acidified KMnO4 solution?
GLR[GFDF\YL SIM JFI] V[l;l0S KMnO4 GF\ 2FJ6G[ h05YL Z\UlJlCG SZX[m
(A) CO2 (B) SO2 (C) P2O5 (D) N2O5
Sol. Sulphur dioxide gas readily decolourises the purple colour of acidified KMnO4 solution . In this case KMnO4
acts as an oxidizing agent and sulphur dioxide gas acts as reducing agent
A 31. A gaseous compounds having carbon, hydrogen and oxygen was burnt in the presence of oxygen. After
combustion, 1 volume of the gaseous compound produces 2 volumes of CO2 and 2 volumes of steam.
Determines the molecular formula of the compound, if all the volumes were measured under the same
conditions of pressure and temperature.
SFA”G4 CF.0=MHG VG[ VMlS;HG WZFJT]\ JFI]DI ;\IMHG VMlS;HGGL CFHZLDF\ ;/U[ K[P NCG AFN JFI]DI ;\IMHGGF 1
SN CO2 GF 2 SN VG[ JZF/GF 2 SN AGFJ[ K[P ;\IMHGG]\ VFlcJI ;}+ XMWMP AWF SN ;DFG NAF6 VG[ TF5DFG[ K[P
(A) C2H4O2 (B) C3H6O3 (C) C4H10O3 (D) C5H10O3
Sol.

A 32. Which element from following has half-filled 4f orbital at observed ground state?
GLR[GFDF\YL SI]\ TßJ T[GL WZF VJ:YFDF\ 4f S1S VW” EZFI[, WZFJ[ K[m
(A) Gd (B) Sm (C) Nd (D) Ho
Sol.

D 33. Identify the basic oxide from the following: GLR[GFDF\YL A[hLS VMS;F.0 5;\N SZMP
(A) Cr2 O3 (B) CrO3 (C) V2 O5 (D) V2 O3
Sol.
A 34. A molal solution is one that contains one mole of solute in
V[S DM,, 2FJ6 H[ PPPPPPP DF\ V[S DM, 2FjI WZFJ[ K[P
(A) 1000 g of the solvent 1000 g 2FJS
(B) one litre of the solution V[S l,8Z 2FJ6
(C) 1000 g of the solution 1000 g 2FJ6
(D) 22.4 litres of the solution 22.4 l,8Z 2FJ6
Sol.

C 35. The oxidation number of oxygen is –1 in VMlS;HGGM VMlS;0[XG VF\S PPPPPPPPPPPPPP DF\ (–1) K[P
(A) NO2 (B) PbO2 (C) Na2O2 (D) MnO2
Sol.
C 36. Given the numbers: 161 cm, 0.161 cm, 0.0161 cm. The number of significant figures for the three
numbers are
GLR[ ;\bIF VF5[, K[P 161 cm, 0.161 cm, 0.0161 cm +6 ;\bIF DF8[ VY” ;}RSVF\SGL ;\bIF X]\ CX[m
(A) 3, 4 and 5 respectively VG]@D[ 3, 4 VG[ 5
(B) 3, 3 and 4 respectively VG]@D[ 3, 3 VG[ 4
(C) 3, 3 and 3 respectively VG]@D[ 3, 3 VG[ 3
(D) 3, 4 and 4 respectively VG]@D[ 3, 4 VG[ 4
Sol.
 Page |8

C 37. In a compound C, H and N are present in 9 : 1 : 3. 5 by weight. If molecular weight of compound is 108, the
molecular formula of compound is
;\IMHGDF\ C, H VG[ N V[ JHG ‹FZF 9 : 1 : 3. 5 DF\ NXF”JFI K[P HM ;\IMHGG]\ VFlcJIN/ 108 CMI TM ;\IMHGG]\
VFlcJI ;}+ PPPPPPPPPPPPPP YX[P
(A) C2H6N2 (B) C3H4N (C) C6H8N2 (D) C9H12N3
Sol.

C 38.Equal weights of NaCl and KC1 are dissolved separately in equal volumes of solutions. Molarity of the two
solutions will be :
NaCl VG[ KCl GF ;DFG JHG 2FJ6GF ;DFG SNDF\ V,U ZLT[ 2FjI YFI K[[P A[ 2FJ6GL DM,FZL8LPPPPPPPPP YX[P
(A) Equal ;DFG
(B) That of NaCl will be less than that of KC1 KCl SZTF\ NaCl GL VMKL
(C) That of NaCl will be more than that of KC1 solution
KCl 2FJ6 SZTF\ NaCl GL JW]
(D) That of NaCl will be about half of that of KC1 solution
KCl 2FJ6YL NaCl GL ,UEU V0WL
Sol. When equal weight of different solutes are present in equal volume of solution the molarity is inversely related
to molecular mass of the solute . Mol mass of NaCl is less than KCl . hence molarity of Nacl Solution will be
more
B 39. Which pair of elements from following has half-filled d-orbital in observed electronic configuration?
TßJGL S. HM0 T[GL .,[S8=MGLI ZRGFDF\ d–S1S VW” EZFI[, WZFJ[ K[m
(A) Cu and Mn (B) Mn and Cr (C) Zn and Co (D) Cu and Zn
Sol.
D 40. In which mode of expression, the concentration of a solution remains independent of temperature?
VlEjIlSTGF SIF VY”DF\ 2FJ6GL ;F\2TFV[ TF5DFGYL :JT\+ ZC[ K[m
(A) Molarity sDM,FZL8Lf (B) Normality sGMDF”l,8Lf
(C) Formality sOMDF”l,8Lf (D) Molality sDM,Fl,8Lf
Sol.
D 41. Which of the following statement is correct? GLR[GFDF\YL SI]\ lJWFG ;FR]\ K[m
(A) Decreasing order of density of alkyl halides is RI > RBr > RCl > RF
VFÿSF., C[,F.0GL WGTFGM @D RI > RBr > RCl > RF K[P
(B) The stability order of alkyl halides is RF > RCl > RBr >RI
VFÿSF., C[,F.0GF\ :YFILtJGM @D RF > RCl > RBr >RI K[P
(C) Among isomeric alkyl halides the decrease in boiling point 1° > 2° > 3°
;D38SLI VFÿSF., C[,F.0DF\ ptS,GlA\N]GM ÷TZTM @D 1° > 2° > 3°
(D) All are correct sAWF H ;FRF K[f
Sol.
C 42. Unacceptable name for a compound containing one –OH group attached to benzene nucleus
would be-
A[ghLG S[g2 ;FY[ V[S –OH ;D}C HM0FI[,F ;\IMHGG]\ SI]\ GFD :JLSFZL XSFI GCLm
(A) Carbolic acid sSFAM”l,S V[l;0f (B) Hydroxybenzene sCF.0=MlS; A[ghLGf
(C) Catechol sS[8[SM,f (D) Phenol slOGM,f
Sol.

B 43. Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in
ethanol.
250 mL 0.15 M A[ghM.S V[l;0 (C6H5COOH) G]\ .Y[GM,DF\ 2FJ6 AGFJJF DF8[GM HyYM sJHGf U6MP
(A) 0.45 (B) 0.0045 (C) 0.050 (D) 0.5
Sol.
 Page |9

Q 44. The empirical formula and molecular mass of a compound are CH2O and 180 g respectively. The molecular
formula of the compound will be
;\IMHGG]\ 5|DF6;}+ VG[ VFlcJI N/ VG]@D[ CH2O VG[ 180 g K[P ;\IMHGG]\ VFlcJI ;}+ PPPPPPPPPPP YX[P
(A) C9H18O9 (B) CH2O (C) C6H12O6 (D) C2H4O2
Sol.
D 45. Find molality of a sample of drinking water was found to be severely contaminated with chloroform (CHCl3)
supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):
5LJFGF 5F6LGM V[S GD}GM B}A H BZFA ZLT[ S,MZMOMD” (CHCl3) J0[ ;\N}lQT YI[,M H6FIM K[P H[G[ S[g;ZHgI WFZJFDF\
VFjIM K[P ;\N}Q6G]\ :TZ s5|DF6f 15 ppm (N/YL) H6FI]\ K[ TM T[GL DM,FZL8L U6MP
(A) 0.125 (B) 0.0125 (C) 0.00125 (D) 0.000125
Sol.

D 46. Glycerol has: u,L;ZM, X]\ WZFJ[ K[m

(A) 3 primary alcoholic groups 3 5|FYlDS VFÿSMCM,LS ;D]C
(B) 3 secondary alcoholic groups 3 l2lTIS VFÿSMCM,LS ;D}C
(C) 1 primary alcoholic group and 2 secondary alcoholic groups
1 5|FYlDS VFÿSMCM,LS ;D}C VG[ 2 l2lTIS VFÿSMCM,LS ;D}C
(D) 2 primary alcoholic groups and 1 secondary alcoholic group
2 5|FYlDS VFÿSMCM,LS ;D}C VG[ 1 5|FYlDS VFÿSMCM,LS ;D}C
Sol.

A 47.

“A” is A X]\ K[m

(A) (B) (C) (D)

Sol.

B 48. What is the correct IUPAC naming of F2 HC − CBrClF ?

F2 HC − CBrClF G]]\ ;FR]\ IUPAC GFD X]\ K[m
(A) l–Bromo–l–chloro–1,1,2–trifluoroethane 1–A|MDM–1–S,MZM–1,1,2–8=FIO,MZM.Y[G
(B) l–Bromo–l–chloro–1,2,2–trifluoroethane l–A|MDM–l–S,MZM–1,2,2–8=FIO,MZM.Y[G
(C) 2–Bromo–2–chloro–1,1,2–trifluoroethane 2–A|MDM–2–S,MZM–1,1,2–8=FIO,MZM.Y[G
(D) 2–Bromo–2–chloro–1,1,2–trifluoroethane 2–A|MDM–2–S,MZM–1,1,2–8=FIO,MZM.Y[G
Sol.
 P a g e | 10

A 49. Assertion: When alkyl halide is reacted with AgCN then alkyl isocyanide is formed.
lJWFGo HIFZ[ VFÿSF., C[,F.0 AgCN ;FY[ 5|l@IF SZ[ K[ tIFZ[ VF.;M;FIGF.0 AG[ K[P
Reason: AgCN is a covalent compound and only the site of nitrogen available for the reaction.
SFZ6: AgCN V[S ;C;\IMHS ;\IMHG K[P H[DF\ DF+ GF.8=MHGGL AFH] 5|l@IF DF8[ 5|F%I CMI K[P
(A) Assertion is correct, reason is correct; reason is correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5[ K[P
(B) Assertion is correct, reason is correct; reason is not a correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5T]\ GYLP
(C) Assertion is correct, reason is incorrect. lJWFG ;FR]\ K[4 SFZ6 BM8]\ K[P
(D) Assertion is incorrect, reason is correct. lJWFG BM8]\ K[4 SFZ6 ;FR]\ K[P
Sol.

A 50. In the conversion of Br2 to BrO3− , the oxidation number of Br changes from
Br2 YL BrO3− GF ~5FT\Z6DF\ Br GM VMlS;0[XG VF\S PPPPPPPPPPPP ;]WL AN,FIP
(A) zero to +5 sX}gIYL +5f (B) +1 to +5
(C) zero to –3 sX}gIYL –3f (D) +2 and +5
Sol.
B 51. 1.0 g of Mg is burnt with 0.28 g of O2 in a closed vessel. Which reactant is left in excess and how much?
(Mg = 24)
1.0 g Mg G[ A\W 5F+DF\ 0.28 g O2 ;FY[ NCG SZJFYL SIM 5|l@IS AFSL ZC[X[ VG[ S[8,M AFSL ZC[X[m (Mg = 24)
(A) Mg, 5.8 g (B) Mg, 0.58 g (C) O2, 0.24 g (D) O2, 2.4 g
Sol.

C 52. What volume of oxygen gas (O2) measured at 0 °C and 1 atm, is needed to burn completely 1 L of propane gas
(C3H8) measured under the same conditions?
5|M5[G JFI] (C3H8) GF 1 L GF ;\5}6” NCG DF8[ H~ZL VMlS;HG JFI]G]\ SN (O2) 0 °C VG[ 1 atm NAF6[ S[8,]\ CX[m
(A) 7 L (B) 6 L (C) 5 L (D) 10 L
Sol.
 P a g e | 11

A 53. Which of the following changes involves transfer of 5 electrons?

GLR[GFDF\YL SIF O[ZOFZDF\ 5 .,[S8=MGGM lJlGDI YFI K[m
(A) MnO−4 ⎯⎯
→ Mn 2+ (B) CrO24− ⎯⎯
→ Cr 3+ (C) NO3− ⎯⎯
→ NH+4 (D) Cr2 O72− ⎯⎯
→ 2Cr 3+
Sol.
C 54. Write an IUPAC name of given structure? VF5[, A\WFZ6G]\ IUPAC GFD ,BMP

(A) 3–Methyl pent–3–ene 4–ol 3–lDYF., 5[g8–3–.G –VM,

(B) 2–Methyl 1–hydroxy but–2–en 2–lDYF., 1–CF.0=MS;L aI]8–2–.G
(C) 3–Methyl pent–2–ene 1–ol 3–lDYF., 5[g8–2–.G 1–VM,
(D) None of the above VF5[, 5{SL V[S56 GCL
Sol.
A 55. Cost of sugar (C12H22O11) is ₹ 50 per kg. Calculate its cost per mol.
XS”ZF (C12H22O11) GM BR” ₹ 50 ~l5IF 5|lT kg K[P NZ DM,[ T[GM BR” PPPPPPPPPPPPP YX[P
(A) ₹ 17.1 per mol (B) ₹ 27.1 per mol (C) ₹ 14.1 per mol (D) None of the above
Sol.

A 56. Assertion: The molality of the solution does not change with change in temperature.
lJWFG : 2FJ6GL DM,F,L8L TF5DFGDF\ O[ZOFZ ;FY[ AN,FI GCLP
Reason: The molality is expressed in units of moles per 1000 g of solvent.
SFZ6 : DM,F,L8L V[ DM, 5|lT 1000 g 2FJS V[JF V[SDDF\ NXF”JFI K[P
(A) Assertion is correct, reason is correct; reason is correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5[ K[P
(B) Assertion is correct, reason is correct; reason is not a correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5T]\ GYLP
(C) Assertion is correct, reason is incorrect. lJWFG ;FR]\ K[4 SFZ6 BM8]\ K[P
(D) Assertion is incorrect, reason is correct. lJWFG BM8]\ K[4 SFZ6 ;FR]\ K[P
Sol.

D 57. The transition metal with highest melting point is ;F{YL ÷\RF U,GlA\N] ;FY[GL ;\@F\lT WFT] PPPPPPPPPP K[P
(A) Re (B) Cr (C) Mo (D) W
Sol.
A 58. Silver benzoate reacts with bromine in CCl4 to form
l;ÿJZ A[ghMV[8 CCl4 DF\ A|MDLG ;FY[ 5|l@IF SZLG[ X]\ AGFJ[ K[m

(A) (B) (C) (D)

Sol.
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A 59. Arrange the following in increasing order of the volume (in L) occupied by them at STP
GLR[GFG[ STP V[ T[GF SNGF (L DF\) JWTF @DDF\ UM9JMP
(i) 1.5 moles of CO2 1.5 DM, CO2
(ii) 14 g of N2 14 g N2
21
(iii) 10 molecules of oxygen VMlS;HGGF 1021 V6]
(A) (iii) < (ii) < (i) (B) (i) < (ii) < (iii) (C) (ii) < (i) < (iii) (D) (i) < (iii) < (ii)
Sol.

B 60. Acidification of chromate gives ‘Z’. The oxidation state of chromium in ‘Z’ is
@MD[8G]\ V[l;l0SZ6 ‘Z’ VF5[ K[P @MlDIGGM VMlS;0[XG VF\S ‘Z’ DF\ X]\ CX[m
(A) +3 (B) +6 (C) +7 (D) +2
Sol.
A 61. Select the incorrect option for the following reaction:
GLR[GL 5|l@IF DF8[ SIM lJSÿ5 BM8M K[m

CH3–CH=CH2 + H2O ⎯⎯⎯
H
→
(A) This is an example of Nucleophilic addition reaction (NAR) of alkene
VF VFÿSLGGL S[g2FG]ZFUL IMUXL, 5|l@IFG]\ pNFCZ6 K[P
(B) In the first step, protonation of alkene takes place to form carbocation
5|YD TASSFDF\ VFÿSLGG]\ 5|M8MG[XG Y.G[ SFAM”S[8FIG AG[ K[P
(C) In the second step, Nucleophilic attack of water takes place on carbocation
ALHF TASSFDF\ SFAM”S[8FIG 5Z 5F6LGM S[g2FG]ZFUL C]D,M YFI K[P
(D) In the last step deprotonation takes place to form an alcohol
V\lTD TASSFDF\ lJ5|M8MGLSZ6 Y.G[ VFÿSMCM, AG[ K[P
Sol.
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A 62. Assertion (A): Anisole on reaction with HI gives phenol and CH3I.
lJWFG (A) : V[lG;M, HI ;FY[ 5|l@IF SZLG[ lOGM, VG[ CH3I VF5[ K[P
Reason (R): Phenyl-oxygen bond is stronger than methyl-oxygen bond in anisole and hence is not claved by HI.
SFZ6 (R) : V[lG;M,DF\ lOGF., – VMlS;HG A\W V[ lDYF., – VMlS;HG A\W SZTF DHA}T CMJFYL T[ HI ‹FZF T}8TM
GYLP
(A) Assertion is correct, reason is correct; reason is correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5[ K[P
(B) Assertion is correct, reason is correct; reason is not a correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5T]\ GYLP
(C) Assertion is correct, reason is incorrect. lJWFG ;FR]\ K[4 SFZ6 BM8]\ K[P
(D) Assertion is incorrect, reason is correct. lJWFG BM8]\ K[4 SFZ6 ;FR]\ K[P
Sol.

C 63. Which among the following is the correct order of melting point?
GLR[GF 5{SL SIM U,GlA\N]GM ;FRM @D K[m

(A) (B)

Cl Cl Cl
Cl
(C) > > (D)
Cl
Cl

Sol.

A 64. The correct order of oxidizing power of the given ions is

VF5[, VFIGGF VMlS;0[XG 1DTFGM ;FRM @Do
(A) VO+2  Cr2 O72−  MnO4− (B) VO+2  MnO−4  Cr2 O72−
(C) MnO−4  Cr2 O72−  VO2+ (D) Cr2 O72−  VO2+  MnO4−
Sol.

D 65. In the reaction N2 + 3H2 ⎯⎯

→ 2NH3 , ratio by volume of N2, H2 and NH3 is 1 : 3 : 2. This illustrates law of:
5|l@IF N2 + 3H2 ⎯⎯ → 2NH3 DF\ N2, H2 VG[ NH3 GF SNGM U]6MßFZ 1 : 3 : 2 K[P VF PPPPPPPPP lGID ‹FZF ;DHFJL
XSFIP
(A) definite proportion lG`RLT 5|DF6 (B) multiple proportion U]6S 5|DF6
(C) reciprocal proportion jI:T 5|DF6 (D) gaseous volumes JFI]DI SN
Sol.

C 66. Calculate the mass of urea (NH2CONH2) required in making 5 kg of 0.25 molal aqueous solution.
5 kg 0.25 DM,, I}lZIF (NH2CONH2) G]\ 2FJ6 AGFJJF DF8[ Il}ZIFG]\ N/ U6MP
(A) 100 gm (B) 10 gm (C) 74 gm (D) 50 gm
 P a g e | 14

Sol.

A 67. In a mixture of 1 g H2 and 8 g O2 the mole fraction of hydrogen is

1 g H2 VG[ 8 g O2 GF lD`F|6DF\ CF.0=MHGGF DM, V\X PPPPPPPPPPPPPPPPPP K[P
(A) 0.667 (B) 0.5 (C) 0.33 (D) None of the above
Sol.

D 68. Assertion: When a concentrated solution is diluted by adding more water, molarity of the solution remains
unchanged.
lJWFG : HIFZ[ ;F\2 2FJ6DF\ JW] 5F6L pD[ZL D\N SZJFDF\ VFJ[ TM DM,FZL8LDF\ O[ZOFZ YFI GCLP
Reason: Product of moles of a solute and volume is equal to the molarity.
SFZ6 : 2FjI GF DM, VG[ SNGM U]6FSFZ DM,FZL8LG[ ;DFG K[P
(A) Assertion is correct, reason is correct; reason is correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5[ K[P
(B) Assertion is correct, reason is correct; reason is not a correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5T]\ GYLP
(C) Assertion is correct, reason is incorrect. lJWFG ;FR]\ K[4 SFZ6 BM8]\ K[P
(D) Both Assertion and Reason are false. A\G[ lJWFG VG[ SFZ6 BM8F K[P
Sol.

C 69. (
The number of atoms in 0.2 mole of a triatomic gas is N A = 6.02 1023 mol−1 )
l+-VFlcJI JFI]GF 0.2 DM,DF\ 5ZDF6]GL ;\bIF PPPPPPPPPPP CX[P (N A = 6.02 1023 mol−1 )
(A) 6.026 10 22
(B) 1.806 10 23
(C) 3.600 10 23
(D) 1.800 1022
 P a g e | 15

Sol.

B 70. Which of the following species do not show disproportionation reaction?

GLR[GFDF\YL SI]\ lJQDLSZ6 5|l@IF NXF”J[ GCLm
(A) ClO− (B) ClO−4 (C) ClO−2 (D) ClO3−
Sol.
C 71. The number of d–electrons in Cr3+ ion (Z = 24) is Cr3+ VFIG (Z = 24) DF\ d–.,[S8=MGGL ;\bIF PPPPPP K[P
(A) 6 (B) 4 (C) 3 (D) 8
Sol.
B 72. Which of the following is known as freon 12? GLR[GFDF\YL SM6 lvVMG 12 TZLS[ VM/BFI K[m
(A) CHCl3 (B) CCl2F2 (C) Ph–COCH2Cl (D) Ph–Cl
Sol.
D 73. Which of the following is a secondary alkyl halide? GLR[GFDF\YL SI]\ l2lTIS VFÿSF., C[,F.0 K[m
(1) Isobutyl chloride VF.;MaI]8F., S,MZF.0
(2) Isopentyl chloride VF.;M5[g8F., S,MZF.0
(3) Neopentyl chloride lGIM5[g8F., S,MZF.0
(4) Isopropyl chloride VF.;M5|M5F., S,MZF.0
Sol.

D 74.

B is B X]\ K[m

(A) (B) (C) (D)

Sol.
 P a g e | 16

B 75.Assertion (A): Eu2+ is not a reducing agent. lJWFG (A) : Eu2+ V[ ZL0SXGSTF” GYLP
2+ 7
Reason(R): Eu is 4f which is stable. SFZ6 (R) : Eu2+ V[ 4f7 K[P
(A) Assertion is correct, reason is correct; reason is correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5[ K[P
(B) Assertion is correct, reason is correct; reason is not a correct explanation for assertion.
lJWFG ;FR]\ K[4 SFZ6 ;FR]\ K[4 SFZ6 V[ lJWFGGL ;FRL ;DH}TL VF5T]\ GYLP
(C) Assertion is correct, reason is incorrect. lJWFG ;FR]\ K[4 SFZ6 BM8]\ K[P
(D) Assertion is incorrect, reason is correct. lJWFG BM8]\ K[4 SFZ6 ;FR]\ K[P
Sol. –
C 76. What is the molarity of 0.1N H2SO4 solution ? 0.1 N H2SO4 2FJ6GL DM,FZL8L S[8,L YX[m
(A) 1 M (B) 2 M (C) 0.05 M (D) 3 M
Sol.

A 77. Number of atoms of He in 100 amu of He(atomic wt. of He is 4) are:

100 amu He DF\ He GF 5ZDF6]GL ;\bIF (He G]\ VFlcJI N/ 4) :
(A) 25 (B) 100 (C) 50 (D) 100  6 10−23
Sol.

A 78.Match the following. GLR[GFG[ HM0MP

List I (Substance) List II (Equivalent weight) sT]ÿIEFZf
A. Na 2CO3 M
I.
5
+ M
B. KMnO4 / H II.
3
+ M
C. K2Cr2 O7 / H III.
2
D. KMnO4 / H2O IV. M
6
(M = Formula weight) s;}+N/f
The correct answer is: ;FRM HJFA X]\ K[m
(A) (A – III) ; (B – I); (C – IV) ; (D – II) (B) (A – III) ; (B – IV); (C – I) ; (D – II)
(C) (A – II) ; (B – III); (C – IV) ; (D – I) (D) (A – IV) ; (B – III); (C – IV) ; (D – I)
Sol. –
C 79. Identify the correct statements from the following. GLR[GFDF\YL ;FR]\ lJWFG 5;\N SZMP
I. Brass is an alloy of copper and nickel A|F;V[ SM5Z VG[ lGS,GL lD`F|WFT] K[P
II. Bronze is an alloy of copper and zinc A|MghV[ SM5Z VG[ hL\SGL lD`F|WFT] K[P
III. German silver is an alloy of copper, zinc and nickel
HD”G l;ÿJZ V[ SM5Z4lh\S VG[ lGS,GL lD`F|WFT] K[P
IV. Brass is an alloy of copper and zinc A|F; VG[ SM5Z VG[ hL\SGL lD`F|WFT] K[P
(A) I & II only (B) II & III only (C) III & IV only (D) I & IV only
Sol.
D 80. Phosgene is a common name for OM:_G SMG]\ ;FDFgI GFD K[m
(A) phosphoryl chloride OM:OMZF., S,MZF.0
(B) Thionyl chloride YFIMGL, S,MZF.0
(C) Carbon dioxide and phosphine SFA”G 0FIMS;F.0 VG[ OM:OLG
(D) Carbonyl chloride SFAM”GL, S,MZF.0
Sol.

D 81. The highest number of helium atoms is in lCl,ID 5ZDF6]GL DCßFD ;\bIF PPPPPPPPPPPP DF\ CX[P
(A) 4 u of helium lCl,IDGF 4 u
(B) 4 g of helium lCl,IDGF 4 g
(C) 2.271098 L of helium at STP STP V[ lCl,IDGF 2.271098 L
(D) 8 mol of helium lCl,IDGF 8 mol
 P a g e | 17

Sol.

B 82. Concentrated nitric acid used in laboratory work is 98% nitric acid by mass in aqueous solution. What
should be the approximate molarity of such a sample of the acid if the density of the solution is 1.504 g mL–1?
5|IMUXF/F SFID”F\ J5ZFTM ;F\2 GF.l8=S V[l;0 N/YL 98% GF.8=LS Vl[;0 TZLS[ H,LI 2FJ6DF\ K[P HM 2FJ6
3GTF1.504 g mL–1CMI4 TM V[l;0GF VFJF GD}GFGL DM,FlZ8L ,UEU S[8,L CX[ m
(A) 2.339 (B) 23.39 (C) 0.2339 (D) None of the above
Sol.

C 83. An organic compound contains 80% (by wt.) carbon and remaining percentage of hydrogen. The right option
for the empirical formula of this compound is: [Atomic wt. of C is 12 and of H is 1]
SFA”lGS ;\IMHG JHGGF 80% SFA”G VG[ AFSLGF 8SFJFZ 5|DF6 CF.0=MHGG]\ WZFJ[ K[P VF ;\IMHGGF 5|DF6;}RS ;}+
DF8[GM ;FRM lJSÿ5 5;\N SZMP (C G]\ VFlcJI JHG 12 VG[ H G]\ VFlcJI JHG 1 K[f
(A) CH (B) CH2 (C) CH3 (D) CH4
Sol.
 P a g e | 18

C 84. Predict the product when the given compound reacts with LiAlH4:
GLR[G]\ ;\IMHG LiAlH4 ;FY[ 5|l@IF SZ[ tIFZ[ AGTL GL5HG]\ VG]DFG SZMP

(A) (B)

(C) (D)

Sol.

C 85. Which element from following is NOT considered as transition element on the basis of electronic
configuration?
GLR[GFDF\YL SI]\ TßJ .,[S8=MGLI ZRGFG[ VFWFZ[ ;\@F\lT WFT] SCL XSFI GCLm
(A) Ti (B) V (C) Cd (D) Ag
Sol.
A 86.

,
B is B X]\ K[m

(A) (B) (C) (D)

Sol.

D 87. Which of the following has the largest number of moles? GLR[GFDF\YL X[DF\ DM,GL ;\bIF JW] CX[m
(A) 8 g of oxygen atoms VMlS;HG 5ZDF6]GF 8 gm
(B) 16 g of oxygen gas VMlS;HG JFI]GF 16 gm
(C) 14 g of nitrogen gas (N2) GF.8=MHG JFI]GF 14 gm
(D) All have the same number of moles AWF ;DFG DM, ;\bIF WZFJ[
 P a g e | 19

Sol.
n =
( actual mass)
( molar mass)
w 8 1
( a) n = = = mole
m 16 2
16 1
( b) n = = mole
32 2
14 1
( c) n = = mole
28 2
(d) Thus , a have the same number moles
A 88. What is change in oxidation number of nitrogen when NO3− is converted to NH+4 ion?
HIFZ[ NO3− V[ NH+4 VFIGDF\ O[ZJFI tIFZ[ GF.8=MHGGF VMlS;0[XG VF\SDF\ X]\ O[ZOFZ YFIm
(A) +5 to –3 (B) –3 to +5 (C) +3 to –5 (D) –5 to +3
Sol.

C 89. Which element from following in +2 state exhibits highest magnetic moment?
GLR[GFDF\YL SI]\ TßJ +2 VMlS;0[XG VJ:YFGF ;F{YL JW] R]\ASLI RF@DF+F WZFJ[ K[m
(A) Fe (B) Cr (C) Mn (D) Ni
Sol.

B 90. Which of the following is an allylic alcohol? GLR[ 5{SL SIM V[,F.,LS VFÿSMCM, K[m
(A) (B)

(C) (D) None of the above sVF5[, 5{SL V[S56 GCLf

Sol.