TM
REVISION ASSIGNMENT # 01
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PHYSICA L CHEMISTRY LIQUID SOLUTION
CHEMISTRY
SECTION–I : (i) Only One option correct Type
This section contains 17 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(0)
1. If 'a' is degree of dimerisation of CH3COOH in benzene, then van't Haff factor 'i' for calculation of
colligative properties is.
a a
(A)1 + a (B) 1– (C) 1+ (D) 1 + 2a
2 2
2. How much water will freeze out if 4m ethylene glycol aqueous solution containing 500 gm water is
placed at –10ºC.
(Use : Kf of water = 2 kkg /mole)
(A)100gm (B) 200gm (C) 50gm (D) 250gm
3. If a volatile liquid 'A' is mixed with another volatile liquid 'B' then vapour pressure of solution will be
(A)Greater than vapour pressure of pure 'A' liquid
(B) Less than vapour pressure of pure 'B' liquid.
(C) Greater or less than vapour pressure of pure 'B' liquid
(D)Greater than vapour pressure of pure 'B' liquid
4. Which of the following solutions is expected to show positive deviations from Raoult's law ?
(A)Pyridine – Formic acid (B) Ethanol – Hexane
(C) Acetone – Chloroform (D) Hydrochloric acid – Water
5. Two beakers, one containing 20 ml of a 0.05 M aqueous solution of a non volatile, non electrolyte and
the other, the same volume of 0.03 M aqueous solution of NaCl, are placed side by side in a closed
enclose. What are the volumes in the two beakers when equation is attached ? Volume of the solution
in the first and second beaker are respectively.
(A) 21.8 ml and 18.2 mL (B) 18.2 mL and 21.8 mL
(C) 20 mL and 20 mL (D) 17.1 mL and 22.9 mL
6. An azeotropic solution of two liquids has boiling point lower than either of them when it-
(A) Shows negative deviation from Raoult's law
(B) Shows positive deviation from Raoult's law
(C) Shows no deviation from Raoult's law
(D) Follows henry's law
7. An aqueous solution of a solute AB has normal boiling point of 101.08°C and normal freezing point of
– 1.80°C. Hence, AB
Given : AB is 100% ionised at boiling point of the solution, (Kb / Kf )water = 0.3
(A) is 100% ionised at the freezing point of the solution
(B) behaves as non-electrolyte at the freezing point of the solution
(C) forms dimer at the freezing point of the solution
(D) is dissociated at the freezing point of the solution
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8. An aqueous solution contains 6% and 4 % by weight weak acid (HA) and urea respectively. If depression
13.6
in freezing point º C . Ka of CH3COOH will be [Kf = 1.8 K-Kg/mole] (Molecular wight of HA=
3
60, dsolution = 1gm/ml)
(A) 0.9 (B) 2 × 10–5 (C) 4 × 10–5 (D) 10–5
9. Which among the following aqueous solution have highest boiling point -
(A) 1 molal KCl solution (B) 2 molal glucose
(C) 1 molal Co(NO3)2 solution (D) 1 molal NaCl solution
10. The Henry law constant for dissolution of a gas in aqueous medium is 3 × 102 atm. At what partial pressure
5
of the gas, the molality of gas in aqueous solution will be m.
9
(A) 1 (B) 4 (C) 3 (D) 68
11. A solution of x moles of sucrose in 100 grams of water starts freezing at – 0.2°C. As ice separated the
freezing point goes down to – 0.25°C. How many grams of ice would have separated?
(A) 18 grams (B) 20 grams (C) 25 grams (D) 23 grams
12. Y g of non-volatile organic substance of molecular mass M is dissolved in 250g benzene. Molal elevation
constant of benzene is Kb. Elevations in it's boiling point is given by -
M 4K b Y K bY K bY
(A) K Y (B) (C) (D)
b M 4M M
13. A molecule M associates in a given solvent according to the equation M (M)n. For a certain
concentration of M, the van’t Hoff factor was found to be 0.9 and the fraction of associated molecules
was 0.2. The value of n is :
(A) 28/18 (B) 18/28 (C) 5 (D) 1/5
14. Which among the following aqueous solution have highest boiling point -
(A) 1 molal KCl solution (B) 2 molal glucose
(C) 1 molal Co(NO3)2 solution (D) 1 molal NaCl solution
15. Osmotic pressure of a 4.44% solution of anhydrous CaCl2 was found to be 16.42 atm at 27°C. What is
the degree of dissociation of CaCl2 :
(A) 100% (B) 33% (C) 66% (D) 50%
16. Number of correct statements are-
(i) Azeotrope obey Raoult's law
(ii) Minimum boiling point azeotrope is formed if DHmix < O
(iii) DHvap for ideal aqueous solution containing non-volatile solute is same as DHvap for pure water
(iv) When azeotrope is vapourised, composition of vapour formed is same as solution.
17. At a certain temperature when glucose is dissolved in water lowering in vapour pressure is 0.6 mmHg.
What will be the vapour pressure of glucose solution if molality is 1/18.
(A) 200 mm Hg (B) 300 mm Hg (C) 600 mm Hg (D) 720 mm Hg
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(ii) One or more options correct Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
18. Dry air is slowly passed through three solutions of different concentrations, c1, c2 and c3 ; each containing
(non volatile) NaCl as solute and water as solvent, as shown in the Fig. If the vessel 2 gains weight
and the vessel 3 loses weight, then
Vessel-1 Vessel-2 Vessel-3
ik=k-1 ik=k-2 ik=k-3
(A) c1 > c2 (B) c1 < c2 (C) c1 < c3 (D) c2 > c3
19. For a solution of ethanol and water at room temperature the correct option is/are -
(A) DG is zero (B) DSsystem is positive
(C) DSsurrounding is negative (D) DH is zero
20. Solution among the following is/are showing significant deviation from ideal behaviour.
(A) C6H6 + C6H5CH3 (B) C2H5OH + H2O (C) CHCl3 + CH3COCH3 (D) C5H5N + H2O
21. Which of the following is/are correct
(A) Henry's law is applicable for low soluble gases at high temperatures and low pressure.
(B) All systems that obey's Roult's law must satisfy Henry's law
(C) All systems that obey Henry's law must satisfy Roult's law
(D) In the formation of an ideal solution neither cooling nor heating is observed.
(iii) Paragraph Type
This section contains 2 paragraphs , describing theory, experiment, data etc. 4 questions relate to
one paragraphs with two questions. Each question of a paragraph has only one correct answer among
the four choices (A), (B), (C) and (D). 3(0)
Paragraph for Questions 22 and 23
Addition of non–volatile solute to a solvent always increases the colligative properties such as osmotic
pressure, DTb and DTf . All these colligative properties are directly proportional to molality if solutions
are dilute. The increases in colligative properties on addition of non–volatile solute is due to increases in
number of solute particles.
22. For different aqueous solutions of 0.1 N NaCl, 0.1 M urea, 0.1 N Na2SO4 and 0.1 N Na3PO4 solution
at 27°C. The correct statements are:
(A) The order of osmotic pressure is, NaCl > Na2SO4 > Na3PO4 > urea
(B) The order of osmotic pressure is, Na3PO4 > Na2SO4 > NaCl > urea
(C) The order of DTb is, Na3PO4 > Na2SO4 > NaCl > urea
(D) The order of freezing point is NaCl > Na2SO4 > Na3PO4 > urea
23. 6gm urea is present in 250 ml solution (molar mass of solvent = 10000g/mole) at 27ºC. If S = 0.08
lit-atm/mole-K and density of solution is 1.024 g/ml then which of the following is incorrect-
(A) Osmotic pressure of solution is 9.6 atm
(B) Relative lowering in vapour pressure is 0.8
(C) Elevation in boiling point of solution is 2Kelvin (Kb of solvent = 5K-mole/kg)
(D) If urea is replace by same mass of glucose than solution formed will show higher osmotic
pressure
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Paragraph for Q.24 to Q.25
For ideal liquid -liquid solutions where both component are volatile, Raoult's applies.
Ptotal = PA + PB = XAPAº + XBPBº
The composition of vapour phase can be determined with the help of Dalton's law of partial pressure.
Given vapour pressure of pure A (PºA) = 100 mm Hg
Vapour pressure of pure B (PºB) = 200 mm Hg
Given 2 moles of liquid A & 3 moles of liquid B are mixed to form an ideal solution
24. The vapour pressure of solution will be
(A) 40 mm Hg (B) 80 mm Hg (C) 120 mm Hg (D) 160 mm Hg
25. Which of the following is incorrect -
(A) On increasing temperature vapour pressure of solution will increase
(B) On increasing temperature vapour pressure of A (PA) in solution will increase
(C) On increasing XB vapour pressure of solution will increase
(D) On increasing XA vapour pressure of solution will increase
(iv) Matching List Type
This Section contains 2 multiple choice questions. Each question has matching lists. The codes for
the lists. have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 4(0)
26. Column-I Column-II
(P) Propan-2-ol + 2-methyl propanol (A) Maximum boiling azeotrope
(Q) H2O + HNO3 (B) Raoult's law is obeyed
(R) CS2 + CH3COCH3 (C) Positive deviation from Raoult's law
(S) H2O + HCOOH (D) Fractional distillation column gives
azeotrope from residual liquid
Code :
P Q R S
(A) 2 1, 4 3 1, 4
(B) 2 3 1 4
(C) 1 2 3 4
(D) 1, 4 3 2 1,3
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27. Column-I Column-II
Solution Property
(P) 0.1 molal aq. urea (A) DTb = 0.125ºC
(Q) 0.1 molar NaCl (at 25ºC) (B) p = 4.89 atm
(R) 0.1 mol PhOH added to 1kg benzene(l) (C) Freezing point = 272.8K
(S) 0.1 mol PhOH (Ka = 10–10) added (D) Relative lowering of V.Pr = 0.18 %
to 1 kg H2O
K - Kg K - Kg K - Kg K - Kg
[Given : (Kb)H = 0.5 ] (Kf)C H = 5 ; (Kf)H O = 2 (Kb)C H = 2.5
2O mol 6 6 mol 2 mol 6 6 mol
Code:
P Q R S
(A) 4 3 4 4
(B) 2 3 1 4
(C) 3 2 1 4
(D) 4 3 2 1
SECTION-III : (Integer Value Correct Type)
This section contains 1 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–1)
1. 560 gm, 2m Urea solution when kept at temperature which is 5ºC below its freezing point, then half
of the solvent freezes out. Calculate the weight of solvent freezes out if the same solution is placed at
temperature 15ºC below its freezing point
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
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