Liquid Solution DPP-01

1. On increasing temperature, the value of Henry's constant ________

(A) decreases
(B) increases
(C) remains constant
(D) uncertain

w
2. An unknown solution [Molecular wt of solute = 250] is 20% . Molarity of solution is ..
w
[Given density of solution = 1.25 g/mL]
(A) 1 M
(B) 2 M
(C) 3 M
(D) 4 M

3. Which of the following is depend on temperature -

(A) % w/v
(B) % w/w
(C) Molality
(D) Mol fraction

4. The value of Henry’s law constant for some gases at 293 K is given below. Arrange the gases in the
increasing order of their solubility.
He : 144.97 kbar, H2 : 69.16 kbar, N2 : 76.48 kbar, O2 : 34.86 kbar
(A) He < N2 < H2 < O2
(B) O2 < H2 < N2 < He
(C) H2 < N2 < O2 < He
(D) He < O2 < N2 < H2

5. Two beakers A and B containing pure water and aqueous solution are shown. What will be observed
gradually with passage of time ?

(A) Level of water in beaker A becomes lower than that in beaker B

(B) Level of water in beakers A and B remains constant
(C) Level of water in beaker A increases and that in beaker B decreases
(D) Level of both the beakers increases
6. According to Henry law, the solubility of a gas in a given volume of liquid increase with increase in :-
(A) Temperature
(B) Pressure
(C) Both
(D) None

7. Henry's law constant (KH) for methane in benzene at 298 K is 4.5 × 105 mm Hg. If we use the mole fraction
of methane in the solution as a measure of its solubility then calculate the solubility of methane in
benzene at 298 K under 760 mm Hg.
(A) 1.68 × 10–3
(B) 2.72 × 10–4
(C) 3.24 × 10–5
(D) 1.68 × 10–2

8. CO(g) is dissolved in H2O at 30°C and its pressure is 0.020 atm. Henry's law constant for this system is
6.20 × 104 atm. Thus, mole fraction of CO(g) is :-
(A) 1.72 × 10–7
(B) 3.22 × 10–6
(C) 3.22 × 10–5
(D) 3.22 × 10–7

9. A gas 'X' is dissolved in water at 2 bar pressure. Its mole fraction is .02 in solution. The mole fraction of
water when the pressure of gas is doubled at the same temperature.
(A) 0.04
(B) 0.98
(C) 0.96
(D) 0.02

10. The partial pressure ratio PA0 : PB0 for the two volatile liquid A and B are PA0 : PB0 = 1:2 and mole ratio is
XA : XB = 1: 2. What is the mole fraction of A in vapour phase ?
(A) 0.33
(B) 0.25
(C) 0.20
(D) 0.52

11. The vapour pressure of two pure liquids (A) and (B) are 100 and 80 torr respectively. The total pressure
of solution obtained by mixing 2 mole of (A) and 3 mole of (B) would be :-
(A) 120 torr
(B) 36 torr
(C) 88 torr
(D) 180 torr

12. 2 mole each of liquid A and B are dissolved to form an ideal solution. What will be the mole fraction of
B in the vapour phase ?
PA0 = 120 torr and PB0 = 80 torr.
(A) 1/4
(B) 1/2
(C) 3/5
(D) 2/5

13. The Henry law constant for dissolution of a gas in aqueous medium is 3 × 10 2 atm. At what partial
5
pressure of the gas, the molality of gas in aqueous solution will be m.
9
(Answer should be nearest integral value)
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12 13

Answer B A A A A B A D C C C D 3
 Solutions DPP-01

1. Ans. B
KH depends on nature of gas, nature of liquid & temperature.
As temperature increase, KH increases.

2. Ans. A
number of moles of solute
Molarity =
Volume of solution (inL)
20
80  1.25
M = 250 × 1000 = =1M
100 100
1.25

3. Ans. A
Volume term depends on temperature.

4. Ans. A
1
Solubility 
KH
With increase in KH, solubility of gases decreases.

5. Ans. A
Solvent is more volatile than solution (P0 > PSolution)
 Level  more in A than in B

6. Ans. B
Solubility (gas in liquid)  P; with increase in temperature solubility of gases decreases.

7. Ans. A
From Henry's law,
Pgas = KH × Xgas
760 = 4.5 × 105 × Xgas
760
Xgas = = 168.8×10–5 = 1.688 × 10–3
4.5  105

8. Ans. D
Pgas = KH. Xgas
.02 = 6.20 × 104 Xgas
Xgas = 3.22 × 10–7

9. Ans. C
Pgas = KH .Xgas
2 = KH × 0.02 …(i)
4 = KH × Xgas …(ii)
(i) divided by (ii)
2 K H 0.2
= 
4 K H X gas
Xgas = 0.04
Xwater = 0.96
10. Ans. C
PS = PA0 X A + PB0 XB
1 2
PS = PA0  + 2PA0 
3 3
5
PS = PA0
3
1
PA0 
PA PA0 X A 3 = 0.20
YA = = =
PS PS 5 0
PA
3

11. Ans. C
PT = PA0 X A + PB0 XB
2 3
PT =  100 +  80 [Using Raoult's law]
5 5
= 40 + 48
= 88 torr

12. Ans. D
PS = PA0 XA + PB0 XB
= 120 × 2/4 + 80 × 2/4 = 100 torr
PB0 X B 80  2 / 4
YB = = = 0.4 = 2/5
PS 100

13. Ans. 3
Given : → Henry law constant, KH = 3 × 102 atm
5
molality = m means 5 moles of gas in 9 kg solvent (H2O)
9
9000
moles of solvent = 500 moles
18
5 5
mole fraction of gas = = =X
5 + 500 505
According to Henry law :
Pressure, P = KH X
5
P = 3 × 102 × = 2.97 ≈ 3
505
 Liquid Solution DPP-02

1. State T(true)/F(false) for following statements regarding given liquid solutions :

I II III

(a) Final volume of solutions if equal volume of compounds are mixed, is in the order: VI = VII < VIII

(b) ΔSmix for solution I and solution II is positive but for solution III it is zero.

(c) Enthalpy change of mixing is negative for solution II and solution III but positive for solution I.

(A) TFF s

(B) FFF

(C) TTF

(D) FTT

2. The vapour pressure of the solution of two liquids A(P° = 80 mm) and B(P° = 120 mm) is found to be 100

mm when XA = 0.4. The result shows that

(A) Solution exhibits ideal behaviour

(B) Solution shows positive deviation from ideal behaviour

(C) Solution shows negative deviation from ideal behaviour

(D) Attractive intermolecular forces between A–A in pure liquid A and B–B in pure liquid B are stronger than

those between A–B when mixed in solution.

3. Which of the following mixture of solutions cannot form any type of azeotropes ?

(A) HCl + H2O

(B) CH3COCH3 + CHCl3

(C) C2H5Br + C2H5I

(D) C2H5OH + H2O

4. The diagram given below is a vapour pressure-composition diagram for a binary solution of A and B. In
the solution, A–B interactions are –

(A) similar to A–A and B–B interactions

(B) greater than A–A and B–B interactions
(C) smaller than A–A and B–B interactions
(D) unpredictable

5. Which of the following is incorrect for an ideal solution :-

(A) Hmix = 0 and Vmix = 0
(B) Vmix = 0 and Smix > 0
(C) Hmix > 0 and Smix > 0
(D) Gmix < 0 and Smix > 0

6. A binary solution of liquid A and B will show positive deviation from Raoult's law if it fulfils the following
condition :-
(1) PA > PAoXA and PB > PBoXB
(2) The inter molecular force of A–B < A–A, B–B
(3) Hmix is positive
(4) Vmix is negative
(A) 1, 2 and 4 are True
(B) 1, 2 are wrong
(C) 1, 2, 3 are true
(D) 1, 3, 4 are true

7. Total vapour pressure of mixture of 1 mol volatile component A(PAo = 100 mmHg) and 3 mol of volatile
component B (PBo = 60 mmHg) is 75 mm. For such case :-
(A) There is positive deviation from Raoult's law
(B) Boiling point has been lowered
(C) Force of attraction between A and B is smaller than that between A and A or between B and B
(D) All the above statements are correct

8. An azeotropic mixture of two liquid has a boiling point higher than either of them when it:-
(A) show positive deviation from Raoult's law
(B) shows negative deviation from Raoult's law
(C) show ideal behaviour
(D) is saturated
9. Liquids A and B form an ideal solution. A certain solution of A and B contains 25 mole percent of A,
whereas the vapours in the equilibrium with the solution at 298 K contains 50 mole percent of A. The
ratio of vapour pressures of pure A to that of pure B at 298 K, is
(A) 1:1
(B) 3:1
(C) 1:3
(D) 2:1

10. Two liquids A and B have vapour pressure in the ratio PA0 : PB0 = 1 : 3 at a certain temperature. Assume A
and B form an ideal solution and the ratio of mole fractions of A to B in the vapour phase is 4 : 3. Then
the mole fraction of B in the solution at the same temperature is:-
1
(A)
5
2
(B)
3
4
(C)
5
1
(D)
4

11. Two liquids A and B have PA0 and PB0 in the ratio of 1 : 3 and the ratio of number of moles of A and B in
liquid phase are 1 : 3 then mole fraction of 'A' in vapour phase in equilibrium with the solution is equal
to:-
(A) 0.1
(B) 0.2
(C) 0.5
(D) 1.0

12. At 40°C, the vapour pressure (in torr) of methyl alcohol (A) and ethyl alcohol (B) solution is represented
by :
 P0   P0 
Ps = 120 XA + 138 ; where XA is mole fraction of methyl alcohol. The value of lim  B  and lim  A 
XA → 0 X XB → 0 X
 B  A
are :-
(A) 138, 258
(B) 258, 138
(C) 120, 138
(D) 138, 125
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12

Answer B C C C C C D B B A A A
 Solutions DPP-02

1. Ans. B
I. Ethyl ether + acetone : shows positive deviation from Raoult’s law
II. Chloroform + acetone : shows negative deviation from Raoult’s law
III. n–Hexane + h–heptane: ideal solution
For an ideal solution Smix > 0 and Hmix = 0

2. Ans. C
Total vapour pressure at XA = 0.4 [Considering ideal solution].
PT = XAPA° + XBPB°
P = 104 mm.
Psolution < 104 mm of Hg  given solution shows negative deviation.

3. Ans. C
Solution of both compounds forms nearly ideal solution.

4. Ans. C
Above graph shows positive deviation from ideal solution as per Raoult's law. In this A – B interaction is weaker
than A – A and B – B interaction.

5. Ans. C
Hmix = 0, Vmix = 0, Gmix < 0 and Smix > 0 for an ideal solution.

6. Ans. C
For non-ideal solution showing positive deviation
Hmix = + ve; Vmix = positive
A–B < A–A, B–B
PA > PAoXA and PB > PBoXB

7. Ans. D
PAo = 100 mm of Hg; nA = 1 mol
PB = 60 mm of Hg;
o
nB = 3 mol
PS = PA × XA + PB × XB
o o

1 3
PS = 100 × + 60 ×
1+3 1+3
= 25 + 45 = 70
given PS = 75
Hence calculated PS is less than given PS therefore, solution shows positive deviation.
So, all options are correct.

8. Ans. B
The given solution forms maximum boiling azeotrope  it shows negative deviation from Raoult's Law.
9. Ans. B
XA = 0.25, XB = 0.75
YA = 0.5, YB = 0.5
P P0 X
YA = A = A A
PS PS
PB PB0 X B
YB = =
PS PS
YA PA0 X A
=
YB PB0 X B
0.5 PA0  0.25
=
0.5 PB0  0.75
PA0 3
=
PB0 1

10. Ans. A
PA P0 x P0 x
yA =  A A and yB = B B
P P P
y A PA0 x A 4 1 xA
= 0  = 
y B PB x B 3 3 (1 − x A )
4 1
xA = or xB =
5 5

11. Ans. A
1 1 3
xA =  ; xB = ;
1+3 4 4
y A PA0 x A
= 
y B PB0 x B
yA 1 1
= 
(1 − y A ) 3 3
1
 yA =
10

12. Ans. A
Ps = PA0 X A + PB0 XB
Ps = 120 XA + 138
If XA → 0  Ps = PB0 = 138
If XB → 0  XA → 1  Ps = PA0 = 258
 Liquid Solution DPP-03

1. The unit of ebullioscopic constant is _______

(A) K kg mol–1 or K (molality)–1
(B) mol kg K–1 or K–1 (molality)
(C) kg mol–1 K–1 or K–1 (molality)–1
(D) K mol kg–1 or K (molality)

2. When common salt is dissolved in water

(A) Melting Point of the solution increases.
(B) Boiling Point of the solution increases.
(C) Boiling Point of the solution decreases.
(D) Both Melting Point and Boiling Point is decreased.

3. A liquid freeze at 7ºC and boils at 77ºC. If values of K f and Kb of this liquid are 5.6 K-kg/mole and 2.5 K-
kg/mole respectively, then ratio of molar latent heat of fusion (in kJ/mol) to molar latent heat of
vaporisation (in kJ/mol) for the liquid is -
(A) 1 : 1
(B) 7 : 2
(C) 2 : 7
(D) 7 : 3

4. 60 gm urea was dissolved in 1L water. Find amount of water vapourised if temperature of the solution is
raised to 101.5°C.
[Given Kb (water) = 0.5 k kg mol–1, density of water = 1 gm mL–1]
(A) 450 g
(B) 633.33 g
(C) 650 g
(D) 666.67 g

5. A solution containing 0.1 g of a non-voltatile organic substance P(molecular mass 100) in 100g of
benzene raises the boiling point of benzene by 0.2°C, while a solution containing 0.1 g of another non-
volatile substance Q in the same amount of benzene raises the boiling point of benzene by 0.4°C. What
is the ratio of molecular masses of P and Q ?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 4
(D) 4 : 1
6. Vapour pressure of solute containing 6gm non-volatile solute in 180 gm of water is 20 torr. If 1 mole of
water is further added into the solution so that vapour pressure increases by 0.02 torr. Calculate vapour

pressure of pure water.

(A) 20.22 torr

(B) 20.02 torr

(C) 19.78 torr

(D) 19.88 torr

7. At a certain temperature when glucose is dissolved in water lowering in vapour pressure is 0.6 mmHg.

What will be the vapour pressure of glucose solution if molality is 1/18?

(A) 200 mm Hg
(B) 300 mm Hg
(C) 600 mm Hg

(D) 720 mm Hg

8. Elevation of boiling point of 1 molar aqueous glucose solution (density = 1.2 g/ml) is
(A) Kb

(B) 1.20 Kb

(C) 1.02 Kb

(D) 0.98 Kb

9. In three beakers labelled as (A), (B) and (C), 100 mL of water, 100 mL of 1M aqueous solution of glucose

and 100 mL of 0.5 M aqueous solution of urea are taken respectively and kept at same temperature.
Which of the following statements is correct ?

(A) Vapour pressure in all the three beakers is same.

(B) Vapour pressure of beaker B is highest among all.

(C) Vapour pressure of beaker C is highest among all.

(D) Vapour pressure of beaker B is lower than that of C and vapour pressure of beaker C is lower than that of A.

10. In the depression of freezing point experiment, it is found that

(A) The vapour pressure of the solution is less than that of pure solvent

(B) The vapour pressure of the solution more than that of pure solvent
(C) Only solute molecules solidify at the freezing point

(D) solution molecules solidify at the freezing point

11. The value of Kb is given by RTb2/1000 X. In this relation X is :-
(A) Density of solution
(B) H°f of solvent
(C) Latent heat of vaporisation
(D) Enthalpy of vaporisation

12. The freezing point of a 4% aqueous solution of A' is equal to the freezing point of 10% aqueous solution
of B'. If the molecular weight of 'A' is 60 than the molecular weight of B' will be :-
(A) 160
(B) 90
(C) 45
(D) 180

13. Determine the boiling point of a mixture containing 1560 g benzene (molar mass = 78) and 1125 g
chlorobenzene (molar mass = 112.5) using the following graph at atmospheric pressure of 1000 torr :-

(A) 90°
(B) 100°C
(C) 110°C
(D) 120°C
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12 13

Answer A B C D B A C D D A C A B
 Solutions DPP-03

1. Ans. A
Tb
Tb = Kb . m  Kb =
m

2. Ans. B
With the addition of common salt, the colligative properties should increase i.e. F.P. decreases and B.P. increases.

3. Ans. C
Kf T2 H
= f  2v
K b Hf Tb
Hf 2
=
Hb 7

4. Ans. D
Tb = Kb × m
60 100
1.5 = 0.5 × 
60 [Link] solvent
wt. of solvent = 333.33g
So, water present in vapour phase =1000 – 333.33 = 666.67 g

5. Ans. B
Mass of solute (p) = 0.1 g
Molecular mass, (p) = 100 g/mol = Pm
0.1
moles of solute = = 10 moles
100
Mass of solvent = 100 g
10−3 1
Molality =  1000 = = molal
100 100
ΔTb = 0.2°C = Kb m
0.2 0.2
Kb = =
m 1
100
Kb = 20 K. kg/mol

6. Ans. A
P0 − Ps n B solute
=
Ps n A solvent

P0 − 20 6 18
=  ..............(1)
20 M 180
P0 − 20.02 6 18
=  ..............(2)
20.02 M 198
Using (1) and (2)
P0 = 20.22 torr.
7. Ans. C
P m
=  MA
Ps 1000
P  1000 0.6  1000
Ps = = = 600 mm Hg
MA  m 1
18 
18

8. Ans. D
1 molar glucose solution with density of 1.2 g/ml will have molality = 0.98 mol/kg
Tb = Kb.m
Tb = 0.98 Kb

9. Ans. D
Psolution = Ps0 . Xsolvent (Raoult's Law)
Beaker A contains pure solvent, it will have maximum vapour pressure.
As mole fraction of solvent decreases vapour pressure decreases  PA > PC > PB

10. Ans. A
Vapour pressure of solution with non-volatile solute will be less than vapour pressure of pure solvent.

11. Ans. C
RTb2M
Kb =
Hv

12. Ans. A
m1 = m2 ( Tf1 = Tf2 )
4 10
=
96  M1 90  M2
10  96  60
 M2 =
90  4
M2 = 160

13. Ans. B
2 1
PT (at 100°C) = × 1350 + × 300
3 3
= 900 + 100 = 1000 torr
(Given atmospheric pressure)
hence 100°C is boiling point.
 Liquid Solution DPP-04

1. Consider following solutions :

(P) 1M aqueous glucose solution
(Q) 1M aqueous sodium chloride solution
(R) 1M aqueous ammonium phosphate solution
(S) 1M benzoic acid in benzene
Select the INCORRECT statements -
(A) πP = πS
(B) πR > πS
(C) πR > πQ
(D) πQ > πP

2. If 'α' is degree of dimerization of CH3COOH in benzene, then Van't Haff factor 'i' for calculation of
colligative properties is.
(A) 1 + α

(B) 1 –
2

(C) 1 +
2
(D) 1 + 2α

3. When 20 g of naphtholic acid (C11H8O2) is dissolved in 50 g of benzene (Kf = 1.72 K kg mol–1), a freezing
point depression of 2 K is observed. The Van’t Hoff factor (i) is
(A) 0.5
(B) 1
(C) 2
(D) 3

4. A graph of osmotic pressure (π) vs molarity (M) of aqueous solution of NaCl at room temperature is
given below. The slope of the line represents :-

(A) Concentration
(B) Universal gas constant
(C) RT
(D) None of these
5. Which of the following 0.1 M aqueous solutions will have lowest freezing point ?
(A) Potassium sulphate
(B) Sodium chloride
(C) Urea
(D) Glucose

6. Which of the following is CORRECT for the aqueous solutions of the following salts assuming 100%
ionisation.
(A) 0.5 M of MgSO4 & 0.25 M of Na3PO4 are isotonic.
(B) 0.5 M MgSO4 is hypertonic to 0.25 M of Na3PO4
(C) 0.25 M Na3PO4 is hypotonic to 0.5 M MgSO4
(D) 0.25 M of MgSO4 & 0.5 M Na3PO4 are isotonic.

7. Which one of the following aqueous solutions will exhibit highest boiling point?
(A) 0.01M Na2SO4
(B) 0.01M KNO3
(C) 0.015M urea
(D) 0.015M glucose

8. Amongst the following, the solution which shows highest osmotic pressure is
(A) 0.05 M NaCl
(B) 0.10 M BaCl2
(C) 0.05 M FeCl3
(D) 0.05 M Na2SO4

w
9. Which of the following is isotonic with 15% glucose solution (sp. gr = 1.2) :
w
(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea

10. For which of the following aq. solution freezing point is maximum -
(A) 0.1 M urea
(B) 0.1M NaCl
(C) 0.05 M AlCl3
(D) 0.15 M glucose
11. Mark the correct relationship between the boiling points of very dilute solutions of BaCl 2 (t1) and KCl
(t2), having the same molarity
(A) t1 = t2
(B) t1 > t2
(C) t2 > t1
(D) t2 is approximately equal to t1

12. Which solution will show the maximum vapour pressure at 300 K
(A) 1 M C12H22O11
(B) 1 M CH3COOH
(C) 1 M CaCl2
(D) 1 M NaCl

13. Van't Hoff factor for a dilute aqueous solution of HCN is 1.00002. The percent degree of dissociation of
the acid is :-
(A) 2 × 10–5
(B) 2 × 10–4
(C) 2 × 10–3
(D) 2 × 10–2

14. Deci molar solution of potassium ferricyanide K 3[Fe(CN)6] has osmotic pressure of 3.94 atm at 27°C.
Hence percent ionisation of K3[Fe(CN)6] is
(A) 10%
(B) 30%
(C) 40%
(D) 20%

15. Which one of the following aqueous solution will exhibit highest boiling point :-
(A) 0.019 M urea
(B) 0.02 M KNO3
(C) 0.02 M Na2SO4
(D) 0.019 M glucose
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

Answer A B A D A A A B C A B A C D C
 Solutions DPP-04

1. Ans. A
 = iCRT
For glucose, i = 1; P = RT
NaCl, i = 2; Q = 2RT
(NH4)3PO4, i = 4; R = 4RT
Benzoic acid, i = 2; S = 2RT

2. Ans. B
For assoiciation,
1 
i = 1 +  − 1
n 

i = 1+
2

3. Ans. A
ΔTf = i × Kf × m
20
Msolute
2 = i × 1.72 ×
50
1000
20 1000
2 = i × 1.72 × 
172 50
1
i=
2

4. Ans. D
 = iMRT [For NaCl : i = 2]
 = (2RT)M
Slope = 2RT

5. Ans. A
ΔTf = i × m × Kf
Tf  i
⇒ i↑, Tf↑ (depression in freezing point increases means, solution with i = max has lowest freezing point)
(A) K2SO4 i = 3 (assuming 100% ionisation)
(B) NaCl i = 2
(C) Urea i = 1
(D) Glucose i = 1
6. Ans. A
100% ionisation (Assume)
(A) 0.5 of MgSO4 and 0.25 M Na3PO4
π1 = i × C RT π2 = i × C RT
= 2 × 0.5 × RT = 4 × 0.25 RT
π1 = RT π2 = RT
π1 = π2
It is isotonic
Similarly check B, C, D, which is incorrect.

7. Ans. A
Tb = iKbm
Tb – 373 = iKbm
Tb = (373 + iKbm)
 solution having higher 'i' will have highest boiling point.
And Na2SO4 has i = 3 which is highest.

8. Ans. B
 = iCRT
NaCl = 0.1 RT
BaCl2 = 0.3 RT

FeCl3 = 0.15 RT

Na2SO4 = 0.1 RT

 BaCl2 solution has highest boiling point.

9. Ans. C
15  1.2  10
[Glucose] = = 1M
180
glucose = 1 × 1 × RT
NaCl = 2 × 0.5 × RT
NaCl = glucose

10. Ans. A
Urea NaCl AlCl glucose
[C] 0.1M 0.1M 0.05 M 0.15 M
i = assuming 100% ionisation
i 1 2 4 1
[C]net = i × C
[C]net 0.1 0.2 0.2 0.15
ΔTf ∝ [C]net
([C]net = minimum, ΔTf = minimum, freezing point = Maximum)
11. Ans. B
BaCl2 furnishes more ions (i = 3) than KCl (i = 2) and thus shows higher boiling point t1 > t2.

12. Ans. A
P − P
= i . Xsolute
P0
For sucrose; i = 1
Sucrose will give minimum value of P.
P = Po – Ps
Ps = Po – P is maximum.

13. Ans. C
i=1+
 = 0.00002
% = 2 × 10–3

14. Ans. D
 = CRTi
1
3.94 = × 0.0821 × 300 × i
10
i − 1 1.60 − 1
= = = 20%
N −1 4 −1

15. Ans. C
Tb = (Tsolution – Tsolvent)  molarity × i
For urea and glucose, i = 1
for KNO3, i = 2
for Na2SO4, i = 3
Tb will be maximum for Na2SO4  it will exhibit highest boiling point.
 Liquid Solution DPP-05

1. Select the incorrect option.

(A) For solution showing +ve deviation, there is minima in boiling point curve
(B) Boiling Point of aq. solution of 0.1 M, KCl is greater than that of 0.1 M glucose solution
(C) Osmotic pressure is a colligative property
(D) Colligative properties are defined for non-ideal solutions

2. In a solution, if three molecules of solute undergoes association as : 3A A3, then to evaluate degree
of association 'a' the formula will be :-
3(1 − i)
(A)  =
2
i −1
(B)  =
2
3(i − 1)
(C)  =
2
i −1
(D)  =
3

3. An aqueous solution contains 3% and 1.8% by wt. urea and glucose respectively. What is the freezing
point of solution ? (Kf = 1.86°C/m):-
(A) -1.172°C
(B) –2.27°C
(C) –1.5°C
(D) None of these

M
4. solution of potassium ferrocyante K4[Fe(CN)6] is 46% dissociated at 18°C. What will be its osmotic
10
pressure ?
(A) 5.23 atm
(B) 6.78 atm
(C) 3.38 atm
(D) 8.75 atm

5. A certain substance 'A' tetramerises in water to the extent of 80%. A solution of 2.5 g of A in 100 g of
water lowers the freezing point by 0.3ºC. The molar mass of A is :-
(A) 122
(B) 31
(C) 244
(D) 62

6. The freezing point of a 4% aqueous solution of A' is equal to the freezing point of 10% aqueous solution
of B'. If the molecular weight of 'A' is 60 than the molecular weight of B' will be:-
(A) 150
(B) 90
(C) 45
(D) 180
7. X3Y2 (i = 5) when reacted with A2B3 (i = 5) in aqueous solution given brown colour. These are separated
by a semipermeable membrane AB as shown. Due to osmosis there is :-

(A) Brown colour formation in side x

(B) Brown colour formation in side y
(C) Formation in both of sides x and y
(D) No brown colour formation

8. 0.15 g of a solute, dissolved in 15 g of solvent is boiled at a temperature higher by 0.216°C than that of
the pure solvent. The molecular mass of substance (Kb = 2.16) is :-
(A) 1.01
(B) 10
(C) 10.1
(D) 100

9. Two components A and B form an ideal solution. The mole fractions of A and B in ideal solution are X A
and XB while that in vapour phase, these components have their mole fractions as Y A and YB. Then, the
1 1
slope and intercept of plot of vs. will be :-
YA XA
PAo PBo − PAo
(A) ,
PBo PBo
PAo PBo − PAo
(B) ,
PBo PBo
PBo PBo
(C) ,
PAo PBo − PAo
PAo
(D) PAo − PBo ,
PBo

10. Total vapour pressure of mixture of 1 mol X ( PXo = 150 torr) and 2 mol Y( PYo = 300 torr) is 240 torr. In this
case :-
(A) There is a negative deviation from Raoult’s law
(B) There is a positive deviation from Raoult’s law
(C) There is no deviation from Raoult’s law
(D) Cannot be decided

11. pH of a 0.1 M monobasic acid is found to be 2. Hence its osmotic pressure at a given temperature T K is –
(A) 0.1 RT
(B) 0.11 RT
(C) 1.1 RT
(D) 0.01 RT

12. Which one of the following statements is True?

(A) Raoult's law states that the vapour pressure of a component over a solution is proportional to its mole
fraction.
(B) The osmotic pressure () of a dilute solution is given by the equation  = MRT where M is the molarity of
the solution.
(C) The correct order of osmotic pressure for 0.01M aqueous solution of each compound is BaCl 2 > KCl >
CH3COOH > Sucrose
(D) Two sucrose solutions of same molality prepared in different solvents will have the same freezing point
depression
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12

Answer D A A B D A D D B A B ABC
 Solutions DPP-05

1. Ans. D
(A) A positive deviating solution forms minimum boiling azeotrope.
(B) For KCl, i = 2 : for glucose, i = 1
(D) Colligative properties are for ideal solutions.

2. Ans. A
n(1 − i) 3(1 − i)
= ;= ( n = 3)
(n − 1) 2

3. Ans. A
For both glucose and urea, i = 1
 n + n2 
Tf = Kf  1  1000  ;
W
 solvent 
 3 1.8 
 60 + 180 
Tf = 1.86   1000   1.172
 95.2 
T f = Tf = 1.172 C; Tf = –1.172ºC
o o

4. Ans. B
=i×C×R×T .....(1)
K4[Fe(CN)6] 4K+ + [Fe(CN)6]–4
46
i = 1 + (n – 1) = 1 + (5 – 1) × = 1 + 4 × 0.46 = 2.84
100
 = 2.84 × 0.1 × 0.0821 × 291
 = 6.78 atm

5. Ans. D
1– i
=
1
1−
n
1–i
0.8 = ; i = 0.4
1
1–
4
T = iKf × m
w 1000
0.3 = 0.4 × 1.86 × B
mB  w A
2.5  1000
0.3 = 0.4 × 1.86 ×
mB  100
mB = 62

6. Ans. A
TfA = TfB
1000  K b  4 1000  K f  10
=
100  MA 100  MB
10 10
MB =  MA   60 = 150
4 4
7. Ans. D
Brown colour will not appear in any way as semipermeable membrane allows movement of solvent particles but
does not allows solute particles to cross.

8. Ans. D
w  1000
ΔTb = i ×  kb
mW
0.216 1  0.15  1000  2.16
=
10 M  15  100
M = 100

9. Ans. B
PAo X A
YA =
PBo + (PAo − PBo )  A
1 PBo + (PAo − PBo )  A
=
YA PAo X A
1  PBo  1  PAo − PBo 
 =  + 
YA  PAo  X A  PAo 
Y = mX + C

10. Ans. A
(PS)cal. = PAo X A + PBo XB
1 
= .(150) + (300)
3 3
= 50 + 200 = 250
∴ (PS)obs < (PS)cal.
∴ Negative deviation (from Raoult's Law)

11. Ans. B
pH = 2
[H+] = 0.01 M = C = 0.1 × 
 = 0.1
i = 1 –  + n
= 1 – 0.1 + 2 × 0.1
= 1.1
 = i × CRT = 1.1 × 0.1 × RT = 0.11 RT

12. Ans. A,B,C

(A) According to Raoult's law; Ps = P0 . Xsolvent
(B)  = CRT; where C is concentration of solution.
(C)  = iCRT;
For BaCl2, i = 3
KCl, i = 2
CH3COOH, i = 1 to 2 (weak monobasic acid)
sucrose, i = 1
 Solution having higher i will have higher osmotic pressure.
(D) Since solvents are different, they will have different Kf (cryoscopic constant)