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Engineering Chemistry Course Overview

The document outlines the Engineering Chemistry course for the second semester, detailing course objectives, outcomes, and content across five units covering water treatment, polymers, lubricants, corrosion, and spectroscopy. It includes a lab component with practical experiments related to the theoretical concepts taught. Textbooks and reference materials are also provided for further study.

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0% found this document useful (0 votes)
206 views4 pages

Engineering Chemistry Course Overview

The document outlines the Engineering Chemistry course for the second semester, detailing course objectives, outcomes, and content across five units covering water treatment, polymers, lubricants, corrosion, and spectroscopy. It includes a lab component with practical experiments related to the theoretical concepts taught. Textbooks and reference materials are also provided for further study.

Uploaded by

gdrivee515
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SCHOOL OF ENGINEERING

&TECHNOLOGY

SECOND SEMESTER

Course Code: L T P C
Engineering Chemistry
3 0 0 3
Total Teaching: 45 Hours
COURSE OBJECTIVES
 The objective of the Chemistry is to acquaint the students with the basic phenomenon/concepts of
chemistry, the student faces during course of their study in the industry and Engineering field.
 To rationalize periodic properties such as ionization potential, electro-negativity and oxidation states.
 To understand polymerization and spectroscopic techniques.
COURSE OUTCOMES
Student shall be able to:
 The student will able to understand the new developments and breakthroughs efficiently in
engineering and technology.
 Define various water treatment methods for domestic and industrial applications.
 Apply the knowledge of lubricants for protection of different metals from Corrosion

UNIT I
Water Treatment and Organic Reactions: Water quality parameters: Physical, Chemical &
Biological significance, Hardness of water, disadvantages of using hard water in boilers: Scale,
sludge formation, disadvantages, prevention, treatment: Internal conditioning, phosphate, carbon
and carbonate conditioning methods, External: Zeolite, ion exchange methods, desalination,
reverse osmosis and domestic water treatment. Introduction to reactions involving substitution,
addition, elimination, oxidation, reduction, cyclization and ring openings. Synthesis of a
commonly used drug molecule

UNIT II
Polymers and Reinforced Plastics: Polymers, Types, Polymerization, Addition and
condensation polymerization, mechanism, Plastics, classification- preparation, properties and
uses of PVC, Teflon, Polyurethane, Nylon 6:6, PET, Bakelite, and Epoxy resin, Compounding of
Plastics- Compression molding, Injection molding, Composites, definition, types of Polymer
matrix composites, FRP Carbon and Glass applications.

UNIT III
Lubricants and Refractories: Lubricants: Classification solid, semi solid, liquid, emulsion-
properties, selection of lubricants for different purposes, Refractories, Classification-( acidic,
basic and neutral), Properties (refractoriness, refractoriness under load, porosity, dimensional
stability, thermal spalling), manufacture of alumina, magnesite and Zirconia bricks, Abrasives,
Natural abrasives, (Quartz, corundum, emery, garnet, diamond), Artificial abrasives (silicon
carbide, boron carbide)

UNIT IV
Corrosion and Its Control: Corrosion: Basic concepts, mechanism of chemical,
electrochemical corrosion, Types of Electrochemical corrosion, galvanic corrosion, differential
aeration corrosion, pitting corrosion, stress corrosion, factors influencing corrosion. Corrosion
SCHOOL OF ENGINEERING
&TECHNOLOGY

control: Cathodic protection, sacrificial anodic method, corrosion inhibitors. Protective coatings:
surface preparation for metallic coatings, electro plating (copper plating) and electroless plating
(Nickel plating), Galvanizing and Tinning.

UNIT V
Spectroscopic techniques and applications: Principles of spectroscopy and selection rules,
UV-visible spectroscopy, infrared spectroscopy, atomic absorption spectroscopy and flame
photometry. Fluorescence and its applications in [Link] and rotational
spectroscopy of diatomic [Link] magnetic resonance and magnetic
resonance imaging, surface characterization techniques. Diffraction and scattering

Text Books:
1. Dara S.S, “A Text book of Engineering Chemistry”, 10th ed., New Delhi, [Link]&
Company Ltd, 2003.
2. Jain P.C and Monika Jain, “Engineering Chemistry”, New Delhi, Danpat Rai publishing
company (P) Ltd, 2010

Reference Books:
1. Manisha Agrawal, “Engineering Chemistry”.
2. B. H. Mahan, “University Chemistry”.
3. M. J. Sienko and R. A. Plane, “Chemistry: Principles and Applications”.
4. C N. Banwell, “Fundamentals of Molecular Spectroscopy”.
5. B. L. Tembe, Kamaluddin and M. S. Krishnan, “Engineering Chemistry”, NPTEL Web
Book.
6. Physical Chemistry, by P. W. Atkins
7. Organic Chemistry: Structure and Function by K. P. C. Volhardt and N. E. Schore, 5th
Edition
8. J.C. Kuriacose and J. Rajaram ,Chemistry in Engineering and Technology, New Delhi, Tata
McGraw Hills (P) Ltd.
SCHOOL OF ENGINEERING
&TECHNOLOGY

SECOND SEMESTER

Course Code: L T P C
Engineering Chemistry Lab
0 0 2 1
Total Teaching: 30 Hours
COURSE OBJECTIVES
 To apply the concepts of chemistry and develop analytical skills for applications in
engineering.
 To define various water treatment methods for domestic and industrial applications.
 To demonstrate basic techniques used in chemistry laboratory for small/large scale water
analyses/purification.
COURSE OUTCOMES
Student shall be able to:
 Estimate rate constants of reactions from concentration of reactants/products as a function of
time.
 Measure molecular/system properties such as surface tension, viscosity, conductance of
solutions, redox potentials, chloride content of water, etc.

List of Experiments: (Choice of 10-12 experiments from the following):


1. Estimation of total, permanent and temporary hardness by EDTA method
2. Conduct metric titration - determination of strength of an acid
3. pH titration (acid and base)
4. Estimation of alkalinity of water sample & Estimation of acidity of water sample
5. Determination of dissolved oxygen in a water sample by Digital DO meter
6. Determination of Na / K in water sample by Flame photometry (Demonstration)
7. Determination of surface tension and viscosity.
8. Thin layer chromatography.
9. Ion exchange column for removal of hardness of water.
10. Determination of chloride content of water.
11. Colligative properties using freezing point depression.
12. Determination of the rate constant of a reaction.
13. Determination of cell constant and conductance of solutions.
14. Potentiometry - determination of redox potentials and emfs.
15. Synthesis of a polymer/drug.
16. Saponification/acid value of an oil.
17. Chemical analysis of a salt.
18. Chemical oscillations- Iodine clock reaction.
19. Determination of the partition coefficient of a substance between two immiscible liquids.
20. Adsorption of acetic acid by charcoal.
SCHOOL OF ENGINEERING
&TECHNOLOGY

Note: Experiments can be expanded and revised by course instructor based on course
curriculum.

Text Books:
1. Dara S.S, “A Text book of Engineering Chemistry”, 10th ed., New Delhi, [Link]&
Company Ltd, 2003.
2. Jain P.C and Monika Jain, “Engineering Chemistry”, New Delhi, Danpat Rai publishing
company (P) Ltd, 2010

Reference Books:
1. Manisha Agrawal, “Engineering Chemistry”.
2. B. H. Mahan, “University Chemistry”.
3. M. J. Sienko and R. A. Plane, “Chemistry: Principles and Applications”.
4. C N. Banwell, “Fundamentals of Molecular Spectroscopy”.
5. B. L. Tembe, Kamaluddin and M. S. Krishnan, “Engineering Chemistry”, NPTEL Web
Book.
6. Physical Chemistry, by P. W. Atkins.
7. Organic Chemistry: Structure and Function by K. P. C. Volhardt and N. E. Schore, 5th
Edition.
8. J.C. Kuriacose and J. Rajaram ,Chemistry in Engineering and Technology, New Delhi,
Tata McGraw Hills (P) Ltd.

Common questions

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Spectroscopic techniques such as fluorescence and nuclear magnetic resonance (NMR) have advanced medical applications substantially. Fluorescence is used in medical diagnostics to track biomolecules and diagnose diseases through tagging specific molecules with fluorescent dyes. NMR, including MRI, provides detailed images of soft tissues based on the magnetic properties of atomic nuclei, revolutionizing non-invasive imaging in healthcare to diagnose and monitor diseases. These technologies help in early diagnosis and treatment, significantly impacting patient outcomes .

Internal conditioning methods work by adding chemicals such as phosphates, carbon, and carbonate to prevent scale and sludge inside the boiler itself, altering the chemical composition of the water to prevent deposits from forming. External methods like ion exchange and reverse osmosis involve treating the water before it enters the boiler, removing minerals and impurities through exchanging ions or filtering through semi-permeable membranes to reduce hardness and improve water quality .

The manufacture of alumina refractories involves raw material preparation, forming, drying, and firing processes. Initially, high-purity alumina is processed to remove impurities. Then, it's formed into shapes and sizes depending on its intended use. The shaped alumina is dried to remove moisture and increase strength. Finally, it undergoes firing at high temperatures to achieve the desired densification and mechanical properties. These steps ensure the refractory has high thermal stability, resistance to thermal shock, and maintains structural integrity in high-temperature applications .

The main types of corrosion mechanisms include chemical and electrochemical corrosion. Chemical corrosion involves direct chemical reactions between the metal and surrounding gases or liquids, while electrochemical corrosion involves an electrochemical reaction where an anode and cathode form on the material's surface. Factors influencing these processes include the environment (moisture, oxygen, temperature), the nature of the material (composition, structure), and external stresses such as mechanical or thermal stresses .

Electroplating uses an electrical current to deposit a coating onto a substrate, allowing for controlled thickness and uniform coatings but requires an external power source and conductive substrate. In contrast, electroless plating uses a chemical reduction process that doesn't need an electrical source, allowing for uniform deposition on complex shapes and non-conductive materials. However, electroless plating may have issues with less control over thickness and uniformity compared to electroplating. Both methods provide corrosion resistance through the barrier protection of the plated layer .

UV-visible spectroscopy is based on the absorption of ultraviolet and visible light by molecules, causing electronic transitions, and is often used to determine the concentration of dissolved substances. In contrast, infrared spectroscopy focuses on the absorption of infrared radiation, causing molecular vibrations and is used to identify functional groups and molecular structures. In engineering chemistry, UV-visible spectroscopy is typically used for quantitative analysis, while infrared spectroscopy is used for qualitative analysis of complex mixtures .

Lubricants can minimize friction and wear on metal surfaces by providing a protective film, which reduces direct exposure to corrosive environments. The selection of lubricants depends on their properties such as viscosity and thermal stability. In industrial settings, using the correct lubricant helps to create a barrier that prevents moisture and other corrosive agents from coming into contact with metal surfaces, thereby inhibiting corrosion .

Nylon 6:6 is produced via condensation polymerization, where monomers with functional groups react to form long chains, releasing small molecules like water. This results in strong fibers with high melting points, making it suitable for textiles and engineering materials. Bakelite, on the other hand, is produced through addition polymerization where phenol and formaldehyde react, resulting in a highly cross-linked polymer with high thermal and electrical resistance, used in electrical insulators and plasticware. These processes determine the polymer structure, influencing their mechanical and thermal properties and therefore their applications .

Desalination and reverse osmosis technologies address clean water challenges by removing dissolved salts and impurities, essential for producing potable water from seawater or brackish sources. Desalination typically involves thermal processes or membrane techniques like reverse osmosis, which uses high pressure to force water through semi-permeable membranes, retaining contaminants while allowing pure water to pass through. Both processes play critical roles in areas with limited freshwater resources and in industries requiring water with specific qualities for production and processing .

Ion exchange methods for water hardness removal replace calcium and magnesium ions in hard water with sodium or hydrogen ions, effectively reducing scale formation. Environmentally, this process is significant as it leads to less environmental pollution compared to chemical methods like lime softening. Industrially, it prevents scale build-up in boilers and heat exchangers, improving energy efficiency and reducing maintenance costs and downtime. However, disposal of spent resins and high sodium content in water discharge are potential environmental concerns that require management .

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