Date

|25
Experiment 12

Aim : To present the given inorganic

detect the positive and negative ions in
saltby
qualitative
analysis.

|Reference: Experiment No. 6.1 of Laboratory Manual]

Apparatus Required :

-10 tyt tale

leak
Teat ue ad,hll

[ Dry tests of inorganic salt :

SI. No. Test Observation Inference

+2
1. Colour B ue cloud sotin Cu
m
2 Smell
H+CH60

3. Heat 0.5g of salt

Bue cold outon s Cu t2
in dry test tube
a
Tuwns wthite

4. Flame test

3u od un cld and Cu t2
5. Borax bead test
um aod wn ht

6. Charcoal cavity test

Cobalt Nitrate test

7.

anion :
|B Tests for detection of

Test Observation Inference

S. No.

1. 0.lg salt + dilute H,SO, luoud

on heating

2
46
 RSO heating
b fet
Matr extrNtor
aitixt sium
carate extrt hute HCI
n wt PP

Water
extrt ot alt or sxunn
carbte extra+
(nllsolutin
tie
mes acidic)+
id e ht PPt

Water extraat or sniutn

cartonate extrat +
onentratei
HNO, + amnium molytiate

C] Confirmatery tests of anion : CL

SL No. Test Observation Inference

Aungnt
woled

olsend cngmd
3 Os t Pb (No,), tht ppt

CL
(D)Chemical equations of anion :

H +cce
Pbi
Pblwg), 47
[E]Group tests for detection of eation :

: Original solution (0.S.) = Salt + (Solvent)

Preparation of original solution

Inference
SI. No. Test Observation

Group (0) is alnd

1.
Salt + dilute NaOH uotund
solution. on heating

2 Mo pp Group () is all
0.S. + dilute HCI

3. 0.S. + dilute HCI + on

blackppt olscwd Group () is fuut
passing H,S gas

Group (II1) is als nt

0.S.+ 2-3 drops of

concentrated HNO, + heat

+ 0.2g NH,CI + add no ppt
NH,OH solution in excess

(till it smells of ammonia)

Group (IV)is alsat
5 O.S. + 0.2g NH,Cl +
NH,OH (add till it smells
no Ppt
of ammonia) + on passing

H,S gas

Group (V)is alscr

6. O.S.+ 0.2g NH,CI +
NH,OH (add till it smells
+ 0.5g
Me ppt
of ammonia)

(NH,),CO,

NH,CI + Group (VI) is alot

,
O.S. + 0.2g

smells it
NH,OH(add till
of ammonia) Na,HPO, Ppt
solution

cations :
|FIAnalysis of group

Test
Observation Inference
SI. No.

black pot oschund C

oS + NaoH ppt Cut

48
IGI
Confirmatory tests of

S. No.
Test
cation : Cu 2
Observation Inference
1. OS +
dght blae ppt Cu t2
(u2on olaod Comu
Felc),Reddih
Ppt
bo Cut2
alscwd
42
3 Os + H, s slackpt olswnd Cu

confmd
|H]Chemical equations of cation : Cut

OS + u2 +20H uoH),

OS + H,S 2H +Cus

|I]Result table :

Anion of inorganic Molecular formula and

Cation of inorganic
salt and its name name of inorganic salt
salt and its name

Cu t 2 Cul,2
C Jn Cotechlid

Sign of subject teacher/Lab teacher

49
 Date :

13
Experiment
salt by qualitative
the giveninorganic
Aim : To detect the positive and negative ions present in

analysis.

6.1 of Laboratory Manual]

No.
|Reference: Experiment

Apparatus Required :
Test Tle Tt Tule tnd

hoddu
[ Dry tests of inorganic salt : Inference
Observation
Test
SI. No. Cot2 fe te Fe

Cutaudess r3,NtMolt
1. Colour
|NH
Smell
odoulss
2.

3 Heat 0.5 g of salt

a dry test tube T2

in
Ba
Flame test
4.
test
5.
Borax bead

cavity test
6 Charcoal

Cobalt Nitrate test

7.

of anion :
[B Tests for detection
Observation Inference
Test
SI. No.

salt + dilute H,SO,

0.lg
-|2.
on heating

50
0, 0t
 2. 0.lg salt + 1 mL
Colaualss CL may
concentrated
be fuisnt
H,SO, on heating icth fungnt
oduw alnd
3. Water extract or acidified. sodium

carbonate extract by dilute HCI

+ BaCl,

4 Water extract

carbonate extract +
of salt or sodium
acetic acid/
nowhti ppt Solt
(till solution becomes acidie +
lead acetate

Water extract

carbonate extract
or sodium

+ concentrated 0telau Ppt

|P,lt
HNO, + ammonium molybdate

|C] Confirmatory tests of anion : C L

SI. No. Test Observation Inference

0S + H Clautlns
oaudl conaud
white ppt o

whii pp t

Pbu, oly aued

[D]Chemical equations of anion :

oSt Pbl No). Pb

51
 for detection of cation :
[E]Group tests

Preparation of original solution Original solution (0.S.) = Salt +

(Solvent)

Observation Inference
SI. No. Test

1
Salt + dilute Na0 Loolud Group (0) is alet
solution, on heating

2 O.S. + dilute HCI no ppt Group (I) is aant

Group (I) isalsasH
3 0.S. + dilute HCI + on
e Buck ppt
passing H,S gas

4 O.S. + 2-3 drops of

Group (II) is Qlat
concentrated HN0, + heat Ppt
+ 0.2 g NH,CI + add
NH,OH solution in excess

(till it smells of ammonia)

0.S.+ 0.2g NH,CI + Group (1V) is

let
NH,OH add till smells it

of ammonia) + on passing

H,S gas

0.S. + 0.2g NH,CI + ppt

Group (V) is Aot
NH,OH add till it smells white
of aminonia) + 0.5g
Glyd
(NHJ,C0,
Group (VI) is at
7. 0.S. + 0.2g NH,CI +
NH,OH(add till smells it

of ammonia) + Na,HPO,
solution

cations :
(F] Analysis of group

Test Observation Inference

SI. No.

os t Hso, cdd)ulhile ppt ole

0S+dlu Na0 wtite ppt olsaed
Ba T2
dau pe t Bu 2m
52
 IGI
Confirmatory tests of cation :
SI. No.
Test Inference
Observation

|0S +H,,cdl) Ppt

old
2 OS + dil Noen whte ppt
easo,,

GutoH) ob
o confamd
Batu
0s +kCr
Balrg

[ Chemical equations of cation :

0S +H
1. Datsu,
2 0S +duAoi 20H + Bu t2 BatoH)
Bat t

Result table :

Anion of inorganic Molecular formula and

Cation of inorganic
name salt and its name name of inorganic salt
salt and its

Ba t2 Ball
hlohud Iem 'atum Ctol
bcim Ton

Sign of subjeetteacher/Lab teacher

53
 Date :

14
Experiment
salt by qualitative
inorganic
in the given
ions present
: To detect the positive and negative
Aim

analysis.
Manual]
6.1 of Laboratory
Experiment No.
[Reference:
lea{ l
Tat .lland
:
Apparatus Required

Helde

:
|A]Dry tests of inorganic salt Inference
Observation
SI. No. Test NIZ (o
olscwnd abit
Mo Colaus +
1. Colour

2. Smell

3. Heat 0.5 g of salt

in adry test tube

olsud
4
Flame test

5. Borax bead test Mnt lat

Charcoal cavity test
6.

Cobalt Nitrate test

7.

for detection of anion :

|B)Tests
Test
Observation Inference
SI. No.

1. 0.lg salt + dilute HSO,, Rsoled co,co

on heating

NO, alt
54
 0.lg salt + I mnl. concentrated

H,SO, on heating

Water extract or acidified sodium 2

3
mo oht ppt
carbonate extract by dilute HCI
als t
+ BaCl, olsuud

a
Water extract of salt or sodium

carbonate extract + acetic acid

Pot
(till solution becomes acidic) +
lead acetate osdud

Water or sodium
extract
po
carbonate extract + concentrated

HNO, ammonium molybdate

+
tests of anion:
C] Confirmatory
Inference
Observation
Test
No.
SL.

Pt
OS +Amm onm
obsuud

confud
3
whele Pp t olsuel
OS +Bac,
:
of anion
Chemieal equations
+)401 PM9,
3+12 Mo Oy

0S 1 Bal
 Group tests for detection of cation :
Preparation of
original solution : Original solution (0.S.) = Salt +
(Solvent)

SI. No. Inference

Test Observation

Salt +
solution,
dilute

on
NaOH
heating
Pangnt ml Group (0) is kat
0.S. + dilute HCI mu wthite Ppt Group ()is alst
2.
Group (I1) is &lsnt
3. + +
0.S. dilute HCI on
o blaoh ppt
passing H,S gas

4 0.S. + 2-3 drops of

Group (111) is alt
concentrated HNO, + heat
+ 0.2 g NH,CI + add
NH,OH solution in excess

(till it smellsof ammonia)

is luat
Ppt at
Group (IV)
5. 0.S. + 0.2g NH,CIl + 0 uht
NH,OH (add till it smells

of ammonia) + on passing

H,S gas

Group (V) is alyat

+ 0.2g NH,Cl +
6. 0.S.
NH,OH (add till it smells happt
of ammonia) + 0.5g

7.
(NH),CO,

0.S. + 0.2g NH,CI +

muhitt ppt
Group (VI) is aa
NH,OH(add till it smells
of ammonia) + Na,HPD,
alsd
solution

cations:
|FIAnalysis of group

Test Observation Inference

SI. No.

tostttzstt otitr pptotst

Redetsh B&aun
PPt ohywd

56
 IGI
Confirmatory tests of cation : N,
SI. No.
Test
Observation Inference

Reddih Buoue Ppt

2
'Pug-r Srall Ah
OS
ylaw Ppt one

0acuu

|HChemical equations of cation :

2-0s + Naot NH +O
3. Ds +(

|I Result table :

Cation of inorganic Anion of inorganie

and Molecular formula and
salt its name salt and its name
name of inorganic
salt

PO, NH,) PO
Phoht Ten
cAmmoun hh

Sign ofsubject
teacher/Lab teacher

57
 Date :

Experiment 15

Am : lo detect the positive and neotive ions present in the given inorganic salt by qualitative

analysis.

|Reterence: Experiment No, 6,l of Laboratory Manual|

Apparatus Required :
t Tlul hldltondSnal
aleh
1 Dry tests of inorganic salt :

SL. No. Test Observation Inference

+2 M nt2
1. Colour Coloulas dotution.

2. Smell
Pungntd mell olcwid| c ,coo
(lnngut lte smell alsund muy betus
Heat 0.5 gof salt
s mell olscucNH, ma!
in adry test tube
en
4
Cyt Mnt2 Nt
Flame test
(o t2lsnt
5 Borax bead
as |CUt
test

Saltcclaulas|Nt(o"dl4t
6
Charcoal cavity test

7. Cobalt Nitrate test

IB)Tests for detection of anion :

SL. No. Test

Observation
Inference
0.lg salt + dilute H,SO,.
|Ugoke
1
on heating
C (oo

58
 Coalud Br
2. 0.lg salt + I mL concentrated

H,SO, on heating

3. Water extract or acidified sodium

mo ppt bsuuds 2
carbonate extract by dilute HCI
+ BaCl,

4. Water extract of salt or sodium

carbonate extract + acetic acid
no ppt lcud
(till solution becomes acidic) +
lead acetate

5. Water extract or sodium

Py.
carbonate extract + concentrated
Mo ppt d

HNO, + ammonium molybdate

(C] Confirmatory tests of anion :

Inference
hservation
SL. No. Test

Bwn- el ppt
Fecy

of anion :
Chemical equations

59
|E] Group tests for detection of cation :

Preparation of original solution :Original solution (0.S.) = Salt +

(Selvent
SI. No. Test Observation
Inferenee

1. Salt + dilute NaOH Group (0)is

solution, on heating olund

2. 0.S. + dilute HCI Group ()is alaat

3 0.S. + dilute HCI + on Group (11) is alu

passing H,S gas

4 0.S. + 2-3 drops of Group (III);

isolaent
concentrated HNO,+ heat
g NH,CI + add Ppt
+ 0.2
NH,OH solution in excess
gdansus
(till it smellsof ammonia)

5. 0.S.+ 0.2g NH,CI + Group (IV) o

smells Mo uthite pot is

NH,OH (add till it

of ammonia) + on passing| olsd

H,S gas

6 + NH,CI+ Group (V) is alesa

0.S. 0.2g
mo wbta ppt
NH,OH (add till it smells

of ammonia) + 0.5g

(NH),CO,

7. O.S. + 0.2g NH,CI + Group (VI) is lat

NH,OH(add till it smells

of ammonia) + Na,HPO,
solution

[F]Analysis of group n cations:

SL. No. Test Observation Inference

Ppt
Aent
Roognt)
60
JG] Confirmatory tests of cation :
SI. No. Test
Observation Inference

Rsolduh

Ppt obsd
2.
Pngnt
ihiti ums

olsd

Chemical equations of eation : NH,

l.0S +
2. 0S t NaOH

.5Result table :
+ N 6 2

Cation of inorganic Anion of inorganic Molecular formula and

salt and its name salt and its name name of inorganie salt

Sign of subject teacher/Labteacher

61