Eduvision academy

Chemistry Department
Chemistry
Total Questions : 45 Total Marks : 180
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Mole cocept
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Note :
i) All Questions are compulsory
ii) Darken ( ) the appropriate circle(#) of the most correct option/response with black ball point pen.

Some Basic Concepts Of Chemistry

1) The number of O3 molecules in 16 g of ozone is

A) 5 L of N2 gas at STP
approximately.

B) 0.5 g of H2 gas
A) 2 × 1023 B) 3 × 1023

C) 10 g of O2 gas
C) 4 × 1023 D) 6 × 1023

2) The total number of atoms present in 0.1 mole D) 15 L of H2 gas at STP

of sucrose ( C12 H22 O11 ) is :
6) The number of atoms in 0.1 mol of a triatomic
gas is : ( NA = 6.02 × 1023 mol−1 )
A) 6.02 × 1022 B) 2.7 × 1024

A) 3.600 × 1023 B) 1.800 × 1022

C) 6.02 × 1024 D) 2.7 × 1025

3) The number of gram atoms of oxygen present C) 6.026 × 1022 D) 1.806 × 1023
in 0.25 g mole of (COOH)2 2H2 O is :
7) Assuming fully decomposed, the volume of
CO2 released at N.T.P. on heating 9.85 g of
A) 0.125 B) 0.50 C) 1.0 D) 1.5
BaCO3 (atomic mass of Ba = 137) will be
4) A sample of AlF3 contains 3.0 × 1024 F− ions.
The number of formula units of this sample is : A) 0.84 L B) 2.24 L C) 4.06 L D) 1.12 L

8) A compound contains 8% sulphur. The

A) 2.0 × 1024 B) 1.0 × 1024
minimum molecular weight of the compound is
:
C) 5.0 × 1023 D) 9.0 × 1024

5) The maximum number of molecules are present A) 100 B) 200 C) 350 D) 400
in
9) The mass of carbon anode consumed (giving
only carbon dioxide) in the production of 270 kg
of aluminium metal from bauxite by Hall
process is:
 A) 180 kg B) 270 kg C) 540 kg D) 90 kg. A) 2.88 × 10−3

10) An alkaloid contains 17.28% of nitrogen and its

B) 1.66 × 10−3
molecular mass is 162. The number of nitrogen
atoms present in one molecule of alkaloid is :
C) 4.54 × 10−3
A) five B) four C) three D) two
D) 1.66 × 10−2
11) For the formation of 3.65 g of hydrogen chloride
17) Which of the following pairs of substances
gas, what volumes of hydrogen and chlorine
illustrate the law of multiple proportions
gas are required at N.T.P conditions ?

A) CO and CO 2
A) 1.12 L, 1.12 L B) 1.12 L, 2.24 L

B) H2 O and D2 O
C) 3.65 L, 1.83 L D) 1 L ,1 L

12) A sample of phosphorus trichloride (PCl3 ) C) NaCl and NaBr

contains 1.4 moles of the substance. How many
atoms are there in the sample ? D) MgO and Mg(OH)2

A) 4 B) 5.6 18) Caffeine has a molecular weight of 194. If it

contains 28.9% by mass of nitrogen, number of
C) 8.431×1023 D) 3.372 ×1024 atoms of nitrogen in one molecule of caffeine is

13) Which one of the following sets of compounds A) 4 B) 6 C) 2 D) 3

correctly illustrate the law of reciprocal
proportions ? 19) A 400 mg iron capsule contains 100 mg of
ferrous fumarate, (CHCOO)2 Fe. The percentage
A) P2 O3 , PH3, H2 O B) P2 O5 , PH3, H2 O of iron pasent in it is approximately

A) 33 % B) 25%
C) N2 O5 , NH3, H2 O D) N2 O, NH3, H2 O

14) 20.0 kg of N2 (g) and 3.0 kg of H2 (g) are mixed to C) 14% D) 8%

produce NH3 (g). The amount of NH3 (g) formed
is 20) Volume of a gas at STP is 1.12 × 10−7 cc.
Calculate the number of molecules in it
A) 17 kg B) 34 kg C) 20 kg D) 3 kg
A) 3.01 × 1020 B) 3.01 × 1012
15) Number of atoms in 558.6 g Fe (atomic mass of
Fe = 55.86 g mol−1 ) is C) 3.01 × 1023 D) 3.01 × 1024

A) twice that in 60 g carbon 21) The volume occupied by 4.4 g of CO2 at STP is

B) 6.023 × 1022 A) 22.4 L B) 2.24 L

C) half that of 8 g He C) 0.224 L D) 0.1 L

22) The number of water molecules present in a

D) 558.6 × 6.023 × 1023 drop of water (volume 0.0018 ml) at room
temperature is
16) If 1021 molecules are removed from 200 mg of
CO2 then the number of moles of CO2 left is:
 28) 1.5 mol of O2 combine with Mg to form oxide
A) 6.023 × 1019
MgO. The mass of Mg (at. mass 24) that has
combined is
B) 1.084 × 1018
A) 72 g B) 36 g
C) 4.84 × 1017
C) 48 g D) 24 g
D) 6.023 × 1023
29) 100 g CaCO3 reacts with 1litre 1 N HCl. On
23) The numbers of moles of BaCO3 which contain completion of reaction how much weight of
1.5 moles of oxygen atoms is CO2 will be obtain

A) 0.5 B) 1 A) 5.5 g B) 11 g

C) 3 D) 6.02 × 1023 C) 22 g D) 33 g
24) Haemoglobin contains 0.33% of iron by weight. 30) If 1021 molecules are removed from 200mg of
The molecular weight of haemoglobin is CO2 , then the number of moles of CO2 left are
approximately 67200. The number of iron atoms
(At. wt. of Fe = 56) present in one molecule of
A) 2.85 × 10−3 B) 28.8 × 10−3
haemoglobin is
C) 0.288 × 10−3 D) 1.68 × 10−2
A) 6 B) 1 C) 4 D) 2
31) The mass of 112 cm3 of CH4 gas at STP is
25) The percentage of Se in peroxidase anhydrous
enzyme is 0.5% by weight (atomic weight=78.4).
A) 0.16 g B) 0.8 g
Then minimum molecular weight of peroxidase
anhydrous enzyme is
C) 0.08 g D) 1.6 g
A) 1.568 × 104 B) 1.568 × 103 32) Which of the following has maximum number of
molecules ?
C) 15.68 D) 3.136 × 104
A) 1 g of CO2 B) 1 g of N2
26) H2 evolved at STP on complete reaction of 27 g
of Aluminium with excess of aqueous NaOH
would be C) 1 g of H2 D) 1 g of CH4

33) Which of the following weighs the maximum ?

A) 22.4 B) 44.8
A) 2.24 L of CO2 at N.T.P.
C) 67.2 D) 33.6 litres

27) 12g of Mg (at. mass 24) will react completely B) 6.02 × 1023 molecules of CO2
with acid to give
C) 6.02 × 1023 atoms of carbon
A) One mole of H2
D) 10 g of carbon
B) 1/2 mole of H2 34) One mole of CO2 corresponds to :

C) 2/3 mole of O2

D) Both 1/2 mol of H2 and 1/2 mol of O2

 A) 22.4 L at 1 atm and 25◦ C A) 7.0 × 1023 B) 1.0 × 1023

B) 44 g C) 6.0 × 1023 D) 1.4 × 1022

42) The simplest formula of a compound containing

C) 1 g
50% of element X (at. mass 10) and 50% of
element Y (at. mass 20) is :
D) 6.02 × 1023 C−atoms and 6.02 × 1023 Oatoms

35) Which of the following has maximum mass ? A) X2 Y B) XY2 C) X2 Y3 D) XY

43) compound made up of two elements A and B is

A) 25 gram of iodine
found to contain 25%A (at. mass= 12.5) and
75% B (atl mass = 37.5). The simplest formula
B) 2.5 gram atom of oxygen gas of the compound is :

C) 2.5 gram mole of water A) AB B) AB2 C) AB3 D) A3 B2

D) 2.5 gram mole of nitrogen gas 44) The simplest formula of a compound containing
32.5% K, 0.839% H, 26.7% S and 39.9% O is
36) How many molecules of sulphur are present in
12.8 g of sulphur (atomic mass of S = 32) ? A) KHSO4 B) KHSO3

A) 3.01 × 1022 B) 2.408 × 1023 C) K2 SO4 .2H2 O D) KHSO2

C) 6.02 × 1023 D) 0.4 45) A hydrocarbon is composed of75% carbon. The

empirical formula of the compound is
37) Mass of 0.001 mol of benzoic acid (C6 H5 COOH)
is: A) CH2 B) CH3 C) C2 H5 D) CH4

A) 122 g B) 12.2 g C) 0.122 g D) 1220 g

38) The number of atoms of oxygen present in 11.2

L of ozone at N.T.P. are :

A) 3.01 × 1023 B) 6.02 × 1023

C) 9.03 × 1023 D) 1.20 × 1024

39) How many moles of helium gas occupy 22.4 L

at 0◦ C and 1 atm pressure ?

A) 0.11 B) 0.90 C) 1.0 D) 1.11

40) The number of gram molecules of oxygen in

6.02 × 1024 CO molecules is :

A) 10 gram molecules B) 5 gram molecules

C) 1 gram molecule D) 0.5 gram molecule

41) How many formula units are there in a 42 g

sample of (NH4 )2 Cr2 O7 (formula wt.=252) ?
 Answer Sheet

Chemistry : Some Basic Concepts Of Chemistry

Total Questions : 45 Total Marks : 180

1 A 2 B 3 D 4 B 5 D 6 D 7 D 8 D 9 D 10 D 11 A 12 D
13 A 14 A 15 A 16 A 17 A 18 A 19 D 20 B 21 B 22 A 23 A 24 C
25 A 26 D 27 B 28 A 29 C 30 A 31 C 32 C 33 B 34 B 35 D 36 A
37 C 38 C 39 C 40 B 41 B 42 A 43 A 44 B 45 D
 Solution Sheet

Chemistry : Some Basic Concepts Of Chemistry

Total Questions : 45 Total Marks : 180

1) 48 g of O3 contain molecules =6.02 × 1023 8) Let "a" atoms of sulphur be present in the
16 g of O3 contain molecules compound and
6.02 × 1023 y be the weight of the compound
= × 16 = 2 × 1023
48 8% of weight of compound = Weight of sulphur
2) 1 mole of C12 H22 O11 contains atoms in compound
8
= 6.02 × 1023 × 45 y = 32 × a
100
0.1 mole of C12 H22 O11 contains atoms 3200
= 6.02 × 1023 × 45 × 0.1 = 2.7 × 1024 y= a = 400a
8
The minimum molecular weight is the one in
3) 1 mole of (COOH)2 2H2 O contains = 6 gram which a = 1 (i.e. 1 atom of sulphur is present)
atoms of oxygen Hence minimum molecular weight = 400
0.25 mole of (COOH)2 2H2 O contains = 6 x
0.25 =1.5 gram atoms 9) 2Al2 O3 + 3C −→ 3CO2 + 4Al
3 × 12 g 4 × 27 g
4) 3F− are present in one AlF3 formula unit 4 × 27 g of Al are obtained when carbon anode
No. of AlF3 formula units consumed
3.0 × 1024 = 12× 3g
= = 1 × 1024
3 270 g of the Al are obtained when carbon
5 12 × 3
5) (A) × NA anode consumed = × 270 = 90kg
22.4 4 × 27
0.5
(B) × NA
2 10) Amount of N present in 1 mol of alkaloid
10 162 × 17.28
(C) × NA =
32 100
15 No. of N atoms present in 1 molecule
(D) × NA
22.4 162 × 17.28
(D) contains maximum number of atoms. = = 20 approx.
100 × 14
6) No. of molecules in 0.1 mol 11) H2 (g) + Cl2 (g) → 2HCl(g)
= 0.1 × 6.02 × 1023 22.4LatN.T .P. 22.4LatN.T .P. 2×36.5g
No. of atoms = 0.1 × 6.02 × 1023 × 3 To obtain 2 × 36.5 g of HCl H2 required at N.T.P
= 1.806 × 1023 = 22.4 L
To obtain 3.65 g of HCl H2 required at N.T.P.
7) Mol. mass of BaCO3 = 137 + 12 + 3 × 16 = 197 22.4 × 3.65
= = 1.12L
197 g of BaCO3 on heating gives CO2 = 22.4 L 2 × 36.5
9.85 g of BaCO3 on heating give Cl2 required = 1.12 L (same)
22.4 × 9.85
CO2 = 1.12L 12) 1 mol of PCl3 contains = 4× 6.02×1023 atoms
197 1.4 mol of PCl3 will contain = 4 × 6.02×1023 ×
1.4
= 3.372 ×1024 atoms
13) Ratio of number of hydrogen and oxygen
combining with one P is
3 : 1.5 i.e., 2 :1
It is same as in water (2:1)
 Mass g
22) Density= ;1= or g = ml
Volume ml
0.0018ml = 0.0018gm
No. of
weight 0.0018
moles= = = 1 × 10−4
Molecular weight 18
∴ No. of water molecules
=6.023 × 1023 × 1 × 10−4
14) N2 + 3H2 → 2NH3 = 6.023 × 1019 .
28 2×3 34
1 mole of N2 (28 g) combine with 3 moles of 23) ∵ 3 moles of oxygen is that in 1 mole of BaCO3
H2 (6g) ∴ 1.5 moles of oxygen is that in mole of BaCO3
28 1 1
∴ 3 kg of H2 can react with × 3 = 14kg = × 1.5 = = 0.5.
6 3 2
of N2 H2 is limiting reagent.
34
Moles of NH3 formed= × 3 = 17kg
6 24) ∵ 100gm Hb contain = 0.33gm Fe
558.6 67200 × 0.33
15) No. of atoms = = × 6.02 × 1023 ∴ 67200gm Hb = gm Fe
55.86 100
= 10 × 6.02 × 1023 672 × 0.33
No. of atoms in 60 g C = 5 × 6.02 × 1023 atoms gm atom of Fe = = 4.
56
∴ No. of atoms in 558.6 g = twice the no. of
25) 0.5gm Se →100gm peroxidase anhydrous
atoms in 60 g C.
enzyme
16) 6 × 1023 molecules of CO2 = 1 mole 100 × 78.4
78.4gm Se → = 1.568 × 104
1 × 1021 molecules of CO2 0.5
1 Minimum m.w. → molecule at least contain one
= × 1 × 1021 = 1.66 × 10−3 selenium.
6 × 1023
44 g of CO2 = 1 mole 3
26) H2 O + Al +NaOH → NaAlO2 + H2
200 × 10−3 g of CO2 27 gm 2
1 3
= × 200 × 10−3 = 4.54 × 10−3 = × 22.4 = 33.6 L
44 2
Moles of CO2 left = 4.54 × 10−3 - 1.66 × 10−3 =
27) Mg+2 ≡ H2
2.88 × 10−3 12gm 1
n= = mole of H2
18) 100gm caffeine has 28.9gm nitrogen 24gm 2
28.9 1
194gm caffeine has = × 194 = 56.06gm 28) Mg + O2 → MgO
100 1mole 2
56.06 0.5mole
∴ No. of atoms in caffeine = ≈ 4. 0.5 mole of oxygen react with 1 mole of Mg
14 1.5
1.5 mole of oxygen react with = 3 mole
19) Molecular weight of (CHCOO)2 Fe = 170 0.5
Fe present in 100mg of (CHCOO)2 Fe textbf 24 × 3 = 72gm.
56
= × 100mg = 32.9mg 29) CaCO3 + 2HCl → CaCl2 + CO2 +H2 O
170 100g 2N 44 g
This is present in 400mg of capsule 100 g CaCO3 with 2 N HCl gives 44 g CO2
32.9
% of Fe in capsule = × 100 = 8.2. 100 g CaCO3 with 1 N HCl gives 22 g CO2
400
20) ∵ 22400 cc of gas at STP has 6 × 1023 molecules
∴ 1.12 ×10−7 of gas at STP has
6 × 1023 × 1.12 × 10−7
= 0.03 × 1014 = 3 × 1012 .
22400

21) 44g CO2 occupies 22.4L at STP

22.4
4.4g CO2 occupies = × 4.4= 2.24L.
44
30) 200mg of CO2 = 200 × 10−3 = 0.2gm 40) No. of atoms of oxygen in 6.02 × 1024 CO
44gm of CO2 = 6 × 1023 molecules molecules = 6.02 × 1024 (each CO contains 1
6 × 1023 oxygen atom)
0.2gm of CO2 = × 0.2 = 0.0272 × 1023
44 No. of oxygen molecules
= 2.72 × 1021 molecule 6.02 × 1023
Now 1021 molecule are removed. = = 3.01 × 1024
2
So remaining molecules = 2.72 × 1021 − 1021 Gram molecules of oxygen
24
= 1021 (2.72 − 1) =1.72 × 1021 molecules = 3.01×10
6.02×1023
=5
Now, 6.023 × 1023 molecules = 1mole
1.72 × 1021 molecules 41) Formula units of (NH4 )2 Cr2 O7
1 × 1.72 × 1021 6.02 × 1023
= = 0.285 × 10−2 = × 42 = 1.0 × 1023
6.023 × 1023 252
= 2.85 × 10−3 42) Simplest formula = X2 Y
W V W 112
31) n = = ; = ; W = 0.08gm. 43) Simplest formula AB
M 22400 16 22400
34) (B)is correct 44) Formula of compound = KHSO3
(A) is not correct because 1 mole of CO2
corresponds to 22.4 L at N.T.P. only 45) Carbon = 75%
(C) is not correct because 1 mol means mass of Hydrogen = 100 − 75 =25%
1 mole of CO2 i.e. 44 g ∴ Empirical formula = CH4
(D) is not correct because 1 mol of CO2 =
6.02 × 1023 C−atoms and
2 × 6.02 × 1023 O−atoms.
35) Mass in (A) 25 g
(B) 2.5 × 16 = 40 g
(C) 2.5 × 18 = 45 g
(D) 2.5 × 28 = 70 g
36) No. of atoms of sulphur in 12.8 g
6.02 × 1023
= × 12.8
32
One molecule of sulphur contains 8 atoms =
(S8 )
∴ No. of S8 molecules
6.02 × 1023 × 12.8
= × 3.01 × 1022
32 × 8
37) Mass of 1 mol of C6 H5 COOH = 122 g
Mass of 0.001 mol of C6 H5 COOH
= 122× 0.001 = 0.122 g
38) 22.4 L of ozone at N.T.P. = 6.02 × 1023
molecules of O3 = 3 × 6.02 × 1023 atoms of O
11.2 L of ozone at N.T.P
3 × 6.02 × 1023
= × 11.2 = 9.03 × 1023
22.4

39) 1 mole of all gases at N.T.P. occupies 22.4 L.