Hydrocarbons

Hydrocarbons DPP-05

CH3
H+
1. CH3—C—CH2CH2CH2OH Alkene
CH3
The major alkene formed in the above reaction will be:-
CH3
H3C CH3
(A) (B) CH3 C CH=CH–CH3
C=C
H3C CH2–CH3
CH3
CH3
(C) CH3 C CH2–CH=CH2 (D) none of the above
CH3

2. The order of reactivity of alcohols with respect to acid catalysed elimination will be :
(a) (CH3)3C–OH (b) CH3CH2CH2CH2OH (c) CH3CH–CH2–CH3
OH
(A) a > b > c (B) a > c > b (C) b > a > c (D) b > c > a

3. Sec. butyl alcohol on dehydration gives the predominant product :-

(A) 2-Butene (B) 1-Butene (C) Isobutene (D) All of the above

4. The ease of dehydrohalogenation with alcoholic KOH in case of chloroethane (I), 2-

chloropropane (II), 2-chloro-2-methylpropane(III) is of the order -
(A) III > II > I (B) I > II > III (C) II > I > III (D) I > III > II

5. The reaction of tert. butyl bromide with sodium methoxide gives :-

(A) isobutane (B) tert. butylmethyl ether
(C) isobutylene (D) sodium tert. butoxide

6. Consider the reaction

H3C CH3
OH
H2SO4
Heat

The alkene formed in major amount is

CH3 CH3 CH3 CH3 CH2
CH3 CH3 CH3
(A) (B) (C) (D)

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OH
H2SO4
7. A

(Major)
Major product A is :

(A) (B) (C) (D)

8. In pyrolysis of ester, _______membered cyclic transition state is formed.

(A) 5 (B) 6 (C) 4 (D) 3

9. In pyrolysis of (tri-alkyl amine oxide)_____ membered cyclic transition state is formed

(A) 5 (B) 6 (C) 4 (D) 3

10. Which of the following reaction doesn't include intramolecular elimination ?

(A) Pyrolysis of xanthate
(B) Pyrolysis of xanthate (tri-alkyl amine oxide)
(C) Pyrolysis of ester
(D) Dehydrohalogenation


11. ⎯⎯ → (major) (Alkene)
The B formed is:
(A) CH3–CH=CH2 (B) CH2=CH2 (C) CH3–CH=CH–CH3 (D) None of these

(i) H O
12. ⎯⎯⎯⎯
(ii) 
2 2
→ Final unsaturated product (major)

Final product will be :

(A) (B) (C) (D) None of these

D CH3

Me
N—Me
13. HO → Product (major)
 
⎯⎯
CH3
major product will be :
D CH3 D CH3 CH3

(A) (B) (C) (D)

CH3 CH3 CH3 CH3

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Conc. H SO
14. CH3–CH2–CH2–CH2–OH ⎯⎯⎯⎯⎯

2 4
→ Y
Product (Y) is :
(A) cis-2-butene (B) trans-2-butene (C) 1-butene (D) Iso-butene

15. The suitable reagent for the dehydration of alcohol is :

(A) Phosphoric acid (B) Sulphuric acid
(C) Alumina (D) All of these

16.

(A) (B) (C) (D)

Cl

17.

(A) (B) (C) (D)

O

18.

Relationship between (A) & (B) are :-

(A) Geometrical isomers (B) Position isomers
(C) diastereomers (D) Identical

19.

(A) (B) (C) (D) Both a & b

20.

(A) (B) (C) (D)

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21.

(A) (B) (C) (D)

22.

(A) (B) (C) (D)

23.

Identify ‘B’ :-

(A)

COOH

(B)
COOH

(C)

(D) None of these

24.

Degree of unsaturation in product B :-

(A) 1
(B) 2
(C) 3
(D) 4

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25.

Degree of unsaturation in product A :-

(A) 1
(B) 2
(C) 3
(D) 4

26.

Correct statement about ‘A’ :-

(A) ‘A’ shows electrophilic addition reaction.
(B) ‘A’ shows electrophilic substitution reaction.
(C) ‘A’ Shows nucleophilic addition reaction.
(D) ‘A’ Shows nucleophilic substitution reaction.

HOOC–H2C COOH
Electrolysis
27. (A)

HOOC–H2C COOH
Identify product A :-
(A)

(B)

(C)
COOH
(D)
COOH


NMe3
HO–
28. A

(Major)
Major product A is :-

(A) (B) (C) (D)

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Θ
OH
29.
+
N
The above compound undergoes elimination on heating can yield which of the following
product (major product) ?

(A)  (B) (C) Me (D) 

N CH2 N N N Me
Me Me :
Me Me Me Me Me Me

30. Kinetic isotopic effect is observed in :-

(A) E1
(B) E2
(C) E1CB
(D) None of these

O
||
PhΘLi CH3—C—CH3
31. Ph3P + CH3CH2 – Br (A) (B)
A & B are respectively

(A) &

(B) Phosphorous ylide & CH3–CH=CH–CH3

(C) Ph3P+ CH
–
CH3 &

(D) Phosphorous ylide & CH3–CH=CH–CH3

32. Phosphorous ylide (A) + (B) ⎯→ PhCH=CH–CH3

(A) & (B) can be for better yield

(A)

(B)

(C)

(D)

33. In Wittig reaction intermediate converts into product through

(A) 5 membered cyclic transition state
(B) 6 membered cyclic transition state
(C) 4 membered cyclic transition state
(D) 7 membered cyclic transition state

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Paragraph of Q. 34 to 36

(A) + (B) ⎯→ (C) + Ph3PO

(C) + HBr ⎯→ (D)(Racemic mixture)
34. Compound (A) is

(A)

(B)

(C)

(D) NOT

35. Compound (C) contains number of ’ – H’.

(A) 3
(B) 4
(C) 5
(D) 2

36. Compound D is
(A) PhCHBrCH(isopropyl)2
(B)

(C)

(D)

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Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Answer B B A A C B D B A D B A B B D
Question 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Answer B A B A B D A C C B B A B B B
Question 31 32 33 34 35 36
Answer C B C B D A

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