30-04-2025

7101CJA101021250003 JA

PHYSICS

SECTION - I (i)

1) A half cylinder of radius R and length L >> R is formed by cutting a cylindrical pipe made of an
insulating material along a plane containing its axis. The rectangular base of the half cylinder is
closed by a dielectric plate of length of length L and width 2R. A charge Q on the half cylinder and a
charge q on the dielectric plate are uniformly sprinkled. Electrostatic force between the plate and
the half cylinder is closest to

(A)

(B)

(C)

(D)

2) A point charge Q1 = – Q is fixed at the centre of an insulated disc of mass “M”. The disc rests on a
rough horizontal plane. Another charge Q2 = + Q is fixed vertically above the centre of the disc at a
height of h. After the disc is displaced slightly in the horizontal direction [friction is sufficient to
prevent sliping]. Find the time period of oscillation of disc. Radius of the disk = R

(A)

(B)

(C)

(D)
3) There are two identical point charges Q1 & Q2 and placed at a finite distance away from each
other. An electric field line is emerging from Q2 and its angle of emergence from the line joining two
charges is ‘α’ = 90o. A tangent drawn at this field line at infinity which makes an angle of ‘β’ with the
line joining of two charges and intersect it somewhere between two charges as shown in fig. Find

cosβ.

(A) 1/3
(B) 1/2
(C) 2/3
(D) 1/4

4) A ring of radius R is made out of a thin wire of area of cross section A. The ring has a uniform
charge Q distributed on it. A charge q0 is placed at the centre of the ring. If Y is the young’s modulus
for the material of the ring and ΔR is the change in the radius of the ring then :-

(A)

(B)

(C)

(D)

5) A cylindrical portion of radius 'r' is removed from a solid sphere of radius R and uniform volume
charge density ρ in such a way that the axis of the hollow cylinder coincides with one of the
diameters of the sphere. ('r' is negligible compared to R). Then the electric field intensity at point A

is

(A)

(B)

(C)

(D)
6) A system of two charge particle A and B having charges +q and –q and mass m and 2m
respectively and connected with an ideal massless inextensible string which lies along the axis of a
uniform charged fixed non-conducting ring as shown. If gravity is neglected and ignore the force

between A and B, find the tension in the string at this instant.

(A) Zero

(B)

(C)

(D)

SECTION - I (ii)

1) A non-conducting sphere having a spherical cavity centred at a distance ‘a’ from centre of sphere.
Charge inside the sphere is distributed uniformly with volume density ρ. A particle of mass m having
charge –q is suspended vertically from light non-conducting spring of force constant k. Choose the
correct statement(s). (there is no gravity and initially when –q is suspended, the spring was in

natural length)

Maximum elongation of the spring is

(A)

Maximum elongation of the spring is

(B)

Time period of oscillation is

(C)

Time period of oscillation is

(D)
2)

A charged shell of radius R carries a total charge Q. Given Φ as the flux of electric field through a
closed cylindrical surface of height h, radius r and with its center same as that of the shell. Here,
center of the cylinder is a point on the axis of the cylinder which is equidistant from its top and
bottom surfaces. Which of the following option(s) is/are correct ?
[∈0 is the permittivity of free space]

(A)
If h > 2R and r > R then Φ =

(B)
If and r = then Φ = 0

(C)
If h > 2R and Φ=

If h > 2R and then Φ =

(D)

3) An infinitely long thin non-conducting wire is parallel to the z-axis and carries a uniform line
charge density λ. It pierces a thin non-conducting spherical shell of radius R in such a way that the
arc PQ subtends an angle 120° at the centre O of the spherical shell, as shown in the figure. The
permittivity of free space is e0. Which of the following statements is (are) true ?

(A) The electric flux through the shell is Rλ/ε0.

(B) The z-component of the electric field is zero at all the points on the surface of the shell.
(C) The electric flux through the shell is Rλ/ε0.
(D) The electric field is normal to the surface of the shell at all points.

4) Two non-conducting solid spheres of radii R and 2R, having uniform volume charge densities ρ1
and ρ2 respectively, touch each other. The net electric field at a distance 2R from the centre of the

smaller sphere, along the line joining the centres of the spheres, is zero. The ratio can be

(A) –4

(B)
(C)

(D) 4

5) An oil drop has a charge - 9.6 × 10–19 C and mass 1.6 × 10–15 gm. When allowed to fall, due to air
resistance force it attains a constant velocity. Then if a uniform electric field is to be applied
vertically to make the oil drop ascend up with the same constant speed, which of the following are
correct. (g = 10 ms-2)
(Assume that the magnitude of resistance force is same in both the cases)

(A) The electric field is directed upward

(B) The electric field is directed downward

(C)
The intensity of electric field is

(D)
The intensity of electric field is

6) Two non-conducting spheres of radii R1 and R2 and carrying uniform volume charge densities +ρ
and –ρ, respectively, are placed such that they partially overlap, as shown in the figure. At all points

in the overlapping region :-

(A) the electrostatic field is zero

(B) the electrostatic potential is constant
(C) the electrostatic field is constant in magnitude
(D) the electrostatic field has same direction

SECTION - II

1) Consider a uniformly charged solid sphere of volumetric charge density ‘ρ’. Find force between

two halves of solid sphere. If the answer is then calculate y/x.

2) An insulated plate in the form of a regular triangle ABC with side is uniformly charged with a
surface charge density σ. The electric force on point charge & placed at point ‘D’ located outside the

plane of plate and equidistant from A, B, C [which is equal to ‘a’] is of the form find k.
3) Two hemispherical shell of radius R1 and R2 and having charges Q and 2Q distributed uniformly

respectively are arranged as shown. The force of interaction between two shells is , find n :-

4) A cylinder is uniformly charged on its curved surface with charge density σ = .

Radius of the cylinder is R = 10 cm. Calculate the electric field (in V0/m) at the axis of cylinder, as
shown in the figure. Given : θ2 = 53° & θ1 = 37° "If E is the electric field obtained then mark 10E in

OMR"

5) A particle of mass m and charge q is attached to a light insulating thread of length L. The other
end of the thread is secured at point O. Exactly below point O, there is a small ball having charge Q
fixed on an insulating horizontal surface. The particle remains in equilibrium vertically above the
ball with the string taut. Distance of the ball from point O is L. The minimum value of Q for which

the particle will be in a stable equilibrium for any gentle horizontal push given to it is ,
then n is

6) An infinitely long solid cylinder of radius R has a uniform volume charge density ρ. It has a
spherical cavity of radius R/2 with its centre on the axis of the cylinder, as shown in the figure. The
magnitude of the electric field at the point P, which is at a distance 2R from the axis of the cylinder,

is given by the expression . The value of n is

CHEMISTRY

SECTION - I (i)

1) For 0.1 m aq. solution of given electrolytes, correct order of their increasing order of boiling
point.

(A) CH3COOH < HCOOH < NaCl < Na2SO4

(B) HCl < HCOOH < NaCl < Na2SO4
(C) HCOOH < CH3COOH < NaCl < Na2SO4
(D) Na2SO4 < NaCl < HCOOH < CH3COOH

0 0
2) What is the mole ratio of benzene (PB = 150 torr) and toluene (PT = 50 torr) in vapour phase if the
given solution has a vapour pressure of 120 torr ?

(A) 7 : 1
(B) 7 : 3
(C) 8 : 1
(D) 7 : 8
3) The value of Henry’s law constant for some gases at 293 K is given below. Arrange the gases in
the increasing order of their solubility.
He : 144.97 kbar, H2 : 69.16 kbar,
N2 : 76.48 kbar, O2 : 34.86 kbar

(A) He < N2 < H2 < O2

(B) O2 < H2 < N2 < He
(C) H2 < N2 < O2 < He
(D) He < O2 < N2 < H2

4)

A solution containing 0.1 g of a non-voltatile organic substance P(molecular mass 100) in 100g of
benzene raises the boiling point of benzene by 0.2°C, while a solution containing 0.1 g of another
non-volatile substance Q in the same amount of benzene raises the boiling point of benzene by
0.4°C. What is the ratio of molecular masses of P and Q ?

(A) 1 : 2
(B) 2 : 1
(C) 1 : 4
(D) 4 : 1

5) A solution of x moles of sucrose in 100 grams of water freezes at –0.2ºC. The amount of ice that
will separate out when it is cooled upto –0.25°C is :-

(A) 18 grams
(B) 20 grams
(C) 25 grams
(D) 23 grams

6)

State T(true)/F(false) for following statements regarding given liquid solutions :

(a) Final volume of solutions if

equal volume of compounds are mixed, is in the order:
VI=VII < VIII
(b) ΔSmix for solution I and solution II is positive but for solution III it is zero.
(c) Enthalpy change of mixing is negative for solution II and solution III but positive for solution I.
(A) TFF
(B) FFF
(C) TTF
(D) FTT

SECTION - I (ii)

1) Consider the following system.

Three different aqueous solution each having volume 100 ml are taken and kept in contact as shown.

After sufficient time (Consider temperature

constant & 100% dissociation of strong electrolyte)

(A)
Volume of urea solution will be

(B)
Volume of AlCl3 solution will be
(C) There will be no change in volume of KCl solution.
(D) Volume of both KCl and AlCl3 solutions will increase.

2) Four solutions of various electrolytes are given along with their percent ionization:
(I) 0.1 M NaCl(aq.) (90 % ionized)
(II) 0.05 M CaCl2 (aq.) (80 % ionized)
(III) 0.04 M K3[Fe(CN)6](aq.) (60 % ionized)
(IV) 0.03 M FeCl3 (aq.) (70 % ionized)
Identify correct statement(s) assuming all solutions to be dilute:

(A) Solution (IV) has maximum vapour pressure.

(B) Solution (I) has minimum vapour pressure.
(C) Solution (III) has lowest freezing point.
(D) Solution (I) has highest boiling point.

3) 0.2 moles of A and 0.3 moles of B are taken in separate beakers and enclosed in chamber I.
Another 0.2 moles of A and 0.3 moles of B are mixed in a beaker and enclosed in chamber II. At
equilibrium. Which of the following statement(s) is/are not correct? (A and B are volatile liquids and
they form ideal solution on mixing)

(A) The vapour pressure in chamber I is greater than vapour pressure in chamber II.
(B) The vapour pressure in chamber I is less than vapour pressure in chamber II.
(C) The vapour pressure in both chambers are equal.
(D) The vapour pressure in chamber II can not be determined.

4) In reverse osmosis the flow of solvent across semi permeable membrane occurs
(A) when hydrostatic pressure is greater than osmotic pressure
(B) when hydrostatic pressure is lower than osmotic pressure
(C) from higher concentrated solution to lower concentrated solution
(D) from lower concentrated solution to higher concentrated solution

5) In which of the following pairs of solutions will the values of the van't Hoff factor of solutes be the
same?
(Assume 100% ionization of given salts)

(A) 0.05 M K4 [Fe(CN)6] and 0.10 M FeSO4

(B) and

(C) 0.20 M NaCl and 0.10 M BaCl2

(D) and

6) For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the
mole fraction of M in solution is shown in the following figure. Here XL and XM represent mole
fractions of L and M, respectively, in the solution. The correct statement(s) applicable to this system

is (are):

Attractive intermolecular interaction between L-L in pure liquid L and M-M in pure liquid M are
(A)
stronger than those between L-M when mixed in solution.
The point Z represents vapour pressure of pure liquid M and Raoult’s law is obeyed when
(B)

The point Z represents vapour pressure of pure liquid M and Raoult’s law is obeyed from
(C)

The point Z represents vapour pressure of Pure liquid L and Raoult’s law is obeyed when
(D)

SECTION - II

1) Equal mass of A & B are present in liquid solution then total pressure exerted by vapours is X

torr, Give X/6. [A = 80 gm/mol, B = 120 gm/mol]

2)

Two elements X and Y form two types of molecules like XY3 and XY (both non electrolytic). 1 gm of
XY3 lowers the freezing point by 1°C when dissolved in 100 gram solvent whereas for the same
lowering in freezing point for same amount of solvent 0.5 gram XY is required. The sum of the
atomic masses of X and Y is 5n. Find the value of 'n'. (Given : Kf for solvent is 5K molal–1).

3) 10 g of solute A and 20 g of solute B (both non-ionizable and non-volatile) are dissolved in 500 ml.
of water. The solution has the same osmotic pressure as 6.67 g of A and 30 g of B are dissolved in
the same volume of water at the same temperature. If the simplest ratio of molar masses of A and B

is x/y, then find the value of :

4) In the saturated aqueous solution of PbCl2 the freezing point decreases by °C then ‘D’ is
(Given Ksp of PbCl2 = 4 × 10–6, Kf, water = 2K-kg/mole.

5) The Henry's law constant for the solubility of O2 gas in water at 298 K is 1.0 × 104 atm. The mol
fraction of O2 in air is 0.8. The number of millimoles of O2 from air dissolved in 5 moles of water at
298 K and 5 atm. total pressure is.

6) Two liquids 'A' (Molecular mass = 20) and 'B' (Molecular mass = 40) are partially miscible. When
1 mol of A and 3 mol of B are shaken together and allowed to settle, two layer 'M' and 'N' are formed
as shown in diagram. Layer 'M' contains 0.2 mole fraction of 'A' and layer 'N' contains 0.6 mole

fraction of A. Calculate the ratio of masses of layer M to layer N.

MATHS

SECTION - I (i)

1)

If , then the value of determinant

(A) 65
(B)
(C)

(D) 0

2) If a, b and c are unequal natural numbers, then is equal to

(A) a + b + c
(B) a + b
(C) b + c
(D) 0

3) For the system of linear equations

2x – y + 3z = 5
3x + 2y – z = 7
4x + 5y + αz = β
Which of the following is NOT correct ?

(A) The system has infinitely many solutions for α = –5 and β = 9

(B) The system has a unique solution for and β = 8
(C) The system has infinitely many solutions for α = –6 and β = 9
(D) The system is inconsistent for α = -5 and β = 8

4) If then is equal to :

(A) 28
(B) 212
(C) 220
(D) 216

5) If a, b, & c are nonzero real numbers, then is equal to -

(A) a2b2c2(a + b + c)
(B) abc(a + b + c)2
(C) zero
(D) none of these
6) Let [λ] be the greatest integer less than or equal to λ. The set of all values of λ for which the
system of linear equations x + y + z = 4, 3x + 2y + 5z = 3, 9x + 4y + (28 + [λ])z = [λ] has a solution
is:

(A) ℝ
(B)
(C) [–9, –8)
(D)

SECTION - I (ii)

1) The value of θ lying between and and satisfying the equation

are -

(A)
A=

(B)
A=

(C)

(D)

2) Let a, b, c be the real numbers. The following system of equations in x, y, z

has :

(A) no solution
(B) unique solution
(C) infinitely many solutions
(D) finitely many solutions

3) For any 3 × 3 matrix M, let |M| denote the determinant of M. Let

If Q is a nonsingular matrix of order 3 × 3, then which of the following statements is (are) TRUE ?
(A)

F = PEP and P2 =
(B) |EQ + PFQ–1| = |EQ| + |PFQ–1|
(C) |(EF)3| > |EF|2
(D) Sum of the diagonal entries of P–1EP + F is equal to the sum of diagonal entries of E + P–1FP

4) Let , where θ ≠ (2n + 1) & then which of

following statement is correct

(A) A is skew symmetric matrix

(B) B is skew symmetric matrix
(C) (A + B) is skew symmetric matrix
(D) (A + B) is symmetric matrix

5) Let A be a square matrix with B as its adjoint & C be the adjoint of B. If |A| = 1 then |C–1B + BA| is
equal to -

(A) |A + B|
(B) |B + C|
(C) |A + C|
(D) |A + adjC|

6) Let M be a 3 × 3 invertible matrix with real entries and let I denote the 3 × 3 identity matrix. If
M–1 = adj(adj M), then which of the following statement is/are ALWAYS TRUE?

(A) M = I
(B) det M = 1
(C) M2 = I
(D) (adj M)2 = I

SECTION - II

1)

If then the absolute value of det (A2021 – 2A2020) is :

2)

The set of natural numbers is divided into arrays of rows and columns in the form of matrices as
A1 = (1), A2 =

............ so on. Find the value of

3) Let A and B are two non-singular matrices such that and . If the least value of m

such that is K then find the value of

4) If A is a square matrix of order 2 then (–tr(A2) + (tr(A))2) is (Where |A| ≠ 0)

5)

If the value of , then the value of is

6)

If x, y, z are distinct non zero numbers such that then is

equal to
 ANSWER KEYS

PHYSICS

SECTION - I (i)

Q. 1 2 3 4 5 6
A. D D B D C D

SECTION - I (ii)

Q. 7 8 9 10 11 12
A. A,C A,B,D A,B B,D B,C C,D

SECTION - II

Q. 13 14 15 16 17 18
A. 12.00 8.00 4.00 36.00 32.00 6.00

CHEMISTRY

SECTION - I (i)

Q. 19 20 21 22 23 24
A. A A A B B B

SECTION - I (ii)

Q. 25 26 27 28 29 30
A. B,C A,B,D A,B,D A,C B,D A,D

SECTION - II

Q. 31 32 33 34 35 36
A. 12.00 5.00 2.00 6.00 2.00 9.00

MATHS

SECTION - I (i)

Q. 37 38 39 40 41 42
A. A D C D C A

SECTION - I (ii)

Q. 43 44 45 46 47 48
A. A,B,C,D D A,B,D A,B,C A,B,D B,C,D
 SECTION - II

Q. 49 50 51 52 53 54
A. 9.00 5.00 7.00 2.00 4.00 6.00
 SOLUTIONS

PHYSICS

1)

electric field due to half cylinder on a small area of the plate is as shown. The four points
shown are symmetrically placed. Force due to field will be
But due to symmetry force along the plane will cancel and only force in perpendicular
direction will be left.
The magnitude of force will vary at all the points. So we can add them as:
Taking dQ to be charge on a straight thin strip
element of the half cylinder. E is due to cylinders charge on base of plate of charge density

= (Flux due to cylinder on plate)

So dQ will always sustain a right angle.

Flux due to it will be

& net flux =

∴ Fnet =

2)

x = displacement in x direction

as x is small

3)

flux due to Q2 bounded by tangent line passing through P = (as tangent makes 90O)
Taking the circle as gaussian surface, the net flux through it with solid angle β must be same.
4)
θ is small, then

0
2T sinθ = kq
Putting sinθ = θ we get

T=

Now Y =

∴ ΔR = =

5) Field at A due to the solid sphere without the cylindrical cavity

field at A due to the cylinder of length 2R (which can be assumed to be infinite, since r << R)

∴ net field E = E1 – E2 =

6)

T + qE = 2qE – 2T
T=

T=

T=

7)

Electric field inside cavity is constant and

as its a constant force so time period will not change

and equilibrium position

Kx = qE

This will be amplitude of oscillation

There fore maximum elongation =

8)

For option (A), cylinder encloses the shell, thus option is correct.
For option (B),

Cylinder perfectly enclosed by shell,

Thus ϕ = 0, so option is correct.
For option (C)

=
For option (D) :
Flux enclosed by cylinder

9)
Field due to straight wire is perpendicular to the wire and radially outward.
Hence Ez = 0
Length, PQ = 2R sin 60 = According to Gauss's law

Total flux = =

10)

q1 = ; q2 =
If Enet = 0 at point A then

⇒
⇒
If Enet = 0 at point B then

⇒ ⇒

11) (initially) ∴ mg = fair

(finally) ∴ QE = mg + fair = 2mg

∴ charge is –ve, so electric field 'E' is directed downwards.

& QE = 2 mg

12)
Electric field at point

P= =
= constant in both magnitude and direction at every point of overlap region.
Also, E is non zero so potential is not same at all points.
13)
Electric field is due to all charges (including the right hemisphere)
force on dQ charge = E dQ

This also includes the force due to charges present on the right hemisphere among
themselves. But this force will be internal hence net force will be zero. we will be left with only
the force from the left hemisphere.
dF = Eρ (dA) (dr)

= pressure (p)

Force due to this pressure can be found out by taking projected area.

Fx = p πr2

14)
Force along the plane will cancel each other due to symmetry. It will be only one
perpendicular axis.
Force between q & dq will be:
 {ϕ is flux through the base}

15)

0
F = 2Q

0
F =

0
F =

16)
dq = σ(2πR)(dx)

=
R = x tan θ
0 = (dx)tanθ + x. sec2θ dθ

dE =

=
= –Kσ(2π) sin θ
= –Kσ(2π)(sinθ1 + sin θ2)

= 9 × 109 × × 10-9 × 2π
= 3.6

17) In equilibrium
Now considering the particle in a slightly displaced position.
Equilibrium will be stable if tangential component (along TT) of electrostatic repulsion is
greater than the tangential component of mg

for small displacement,

18) Electric field due to cylinder =

Electric field due to sphere =

[where K = ]
 From principle of superposition.

CHEMISTRY

19) Tb (solution) = Tb (solvent) + i Kb m

20) P = PB°XB + PT° XT

120 = 150(XB) + 50 (1 – XB)
100XB = 70
XB = 0.7

YB = = = 0.875
YT = 1 – 0.875 = 0.125

21) Solubility

22)

ΔTb = Kb× m
for P

0.2 = Kb × × 1000 ........(1)

for Q

0.4 = Kb × × 1000 ........(2)

23)

Ans : → Given : → moles of sucrose = x moles

mass of water (solvent) = 100 g

malality = = 10 x mol/kg
Freezing point = –0.2°C
Depression in freezing point. = ΔTf = 0.2°C
ΔTf = Kf m

Kf = = =
⇒ New temperature = –0.25°C
 = 0.25°C

KF = , mass of solvent left = Wg

moles of sucrose = x moles
= 0.25 = Kf × m

0.25 =

W= = 80 g
Mass of ice separated = initial mass of solvent – mass of solvent left
= 100 – 80 = 20g – .

24)

I. Ethanol + acetone : + ve deviation from Raoult’s law

II. Chloroform + acetone : –ve deviation from Raoult’s law
III. n–Hexane + h–heptane: ideal solution

25) After sufficient time osmotic pressure of all solution will become same.
as T is same i.e. molar concentration should be same, for this ratio of volume should be the
same as that of ratio moles.
Urea : KCl : AlCl3
20 m moles 30 m moles 40 m moles
Total volume (300 ml) should be divided in 2 : 3 : 4

26) (I) i = 1+ (n – 1) α = 1 + (2 – 1) × 0.9 = 1.9

(II) i = 1 + (3 – 1) × 0.8 = 2.6
(III) i = 1 + (4 – 1) × 0.6 = 2.8
(IV) i = 1 + (4 –1) × 0.7 = 3.1
Colligative property = i × concentration
(I) i × concentration = 0.1 × 1.9 = 0.19
(II) i × concentration = 0.5 × 2.6 = 0.13
(III) i × concentration = 0.04 × 2.8 = 0.112
(IV) i × concentration = 0.03 × 3.1 = 0.093

27) In both chamber vapour compositions are same so vapour pressure are equal.

28) In reverse osmosis, solvent molecules flow from higher concentration to lower
concentration.

29)

Question is Asking About :-

 To deter mine which of the following solution have same van't hoff factor.

Concept :-
i = n for (∝ = 100%)
(1) ; i = 5 and FeSO4; i =2
(2) ; i = 5 and FeSO4 (NH4)2 SO4.6H2O n = 1+1+2+1 = 5
(3) NaCl ; i = 2 and BaCl2 ;i = 3
(4) FeSO4 (NH2)SO4;i = 5 and KCl. MgCl2. 6H2O; i = 1+1+1+2 = 5

Hence, option (2) and (4) is correct.

30) From graph it is clear that there is +ve deviation w.r.t.

L. Therefore, option (a) is correct. When , then z will have value equal to (vapour
pressure of pure L). Therefore, option (d) is also correct.

31)

PT =

= 80 × + 40 × = 48 + 24 = 72 torr.

32) = 1gm
= x + 3y
ΔTf = 1°C
kf = 5 K molal–1
Wsolvent = 100g = 0.1 kg
⇒ ΔTf = mKf

⇒ ΔTf =

⇒1=
⇒ x + 3y = 50.....(1)
Wxy= 0.5g
Mxy = x + y

nxy =
ΔTf = 1°C
Kf = 5 k molal–1
Wsolvent = 100g = 0.1 kg
⇒ ΔTf = mKf

⇒ 1=
⇒ x + y = 25 ..........(2)
⇒ from question :- x + y = 5n .........(3)
Also :- x + y = 25.............(2)
⇒ comparing equation (2) & (3) :-
5n = 25
⇒ n = 5 Ans.

33)

34)

PbCl2 ⇌ Pb2+ + 2Cl–

Ksp = 4s3 = 4 × 10–6
s = 10–2 M
ΔTf = ikf.m
i = 3, kf = 2 K. kg/mol

ΔTf = 3 × 2 × 10–2 = 6 × 10–2 =

D=6

35)

0.8 × 5 = 1 × 104 ×
n = 2 × 10–3
= 2 mmol

36) Total moles in layer M = x

Total moles in layer N = y
∴ In layer M Moles of A = 0.2 x
Moles of B = 0.8 x
and
In layer N Moles of A = 0.6 y
Moles of B = 0.4 y
As per question
0.2 x + 0.6 y = 1
 0.8 x + 0.4 y = 3
x = 3.5
y = 0.5
Ratio of masses of layer M to

N = = 9 Ans.

MATHS

37)

38)

39)

For infinitely many solutions

For α = -5 and β = 9

40) Let
A= = K X where K is constant & X is matrix
|A| = K3 |X|

X=
⇒ |X| = 5!6!7!(2)

|X| =
So |A| = 2K2
|adj (adj2A)| = 212|A|4 = 212.24.K8

41)
(R1 → aR1, R2 → bR2, R3 → cR3)

(C3 → C3 + C1)
=0

42)
if [λ] + 9 ≠ 0 then unique solution
if [λ] + 9 = 0 then D1 = D2 = D3 = 0
so infinite solutions
Hence λ can be any real number.
43)
C1 → C1 + C2

⇒
R1 → R1 – R2

⇒
⇒ 2(1 + 2sin4θ) – 2sin4θ = 0
⇒ 1 + sin4θ = 0 ⇒ sin4θ = –1

or

or and

44) Let
Then the system of equations are
X+Y–Z=1
X–Y+Z=1
–X+Y+Z=1

So it has finite solution.

46) (A, B) A is skew symmetric matrix ⇒ A + AT = 0

B = A + A3 + A5 + A7 + A7 + A9 ...(i)
T 3 5 7 9
B = – A – (A ) – (A ) – A – A ...(ii)
B + BT = 0 Þ B is skew symmetric matrix
(C) Let C = A + B ...(i)
T T T
C =A +B
CT = – A – B ...(ii)
(i) + (ii) ⇒ C + CT = 0

47) B = adjA & (adjA)A = |A|I = I

|C–1B + BA| = |C–1B + AB| = |C–1 + A||B| = |C–1 + A||A|n–1 = |C–1 + A|
C = adj(adjA) = |A|n–2 × A = A
⇒ C = A, C–1 = A–1 = adjA = B
⇒ (C–1 + A) = |A + B| = |B + C|
Now adjC = adjA = |A + adjC|

48)

det (M) ≠ 0
M–1 = adj(adj M)
M–1 = det(M).M
M–1M = det(M).M2
I = det(M).M2 …(i)
det(I) = (det(M))5
1 = det(M) …(ii)
From (i) I = M2
(adj M)2 = adj(M2) = adj I = I

49)
⇒ |A| = 1
det (A2021 – 2A2000)
= |A2020 (A – 2I)|

⇒ Absolute value is 9

51) squaring both the sides

Again squarring

Similarly

so

52) ⇒ tr(A) = a + d

tr(A2) = a2 + 2bc + d2
–(a2 + 2bc + d2) + (a + d)2 = –tr(A2) + (tr(A))2
2(– bc + ad) = 2|A|

53)

Clearly 2nd determinant is determinant of cofactor of element in 1st determinant.

Use standard result (where n is the order of the determinant)

54) and

⇒ (x – y)(y – z)(z – x) (8x + 8y + 8z – 6xyz) = 0