ALLEN

DIGITAL
JEE (Main + Advanced) : Chemistry

Exercise - I(JEE-Main Pattern)

SECTION-A
Thissection contains TWENTY questions.
Each question has FOUR options (1), (2), (3) and (4). ONLY ONE of these four
options is correct.
For each question, darken the bubble corresponding to the correct option
in the ORS.
For each question, marks willbe awarded in one of the following categories:
Full Marks :+4, if only the bubble corresponding to the correct option is darkened.
Zero Marks :0, if none of the bubbles is darkened.
Negative Marks :-1 in all other cases
1.

Select the correct statement about above compound.

(1) It is having four 2° & four 3° carbons
(2) It is having three 1°, six 2°, three 3° &two 4° carbons
(3) It is having three 1°, three 2° &three 3° carbons
(4) None of these
CIUO01
2, Allthe members of homologous series have same :
(1) general molecular formula and functional group
(2) molecular weight
(3) molecular formula
(4) None of these
CIUO02
3. DOU of the following compound
CN

N
(1) 11 (2) 13 (3) 15 (4) 17
CIUO03
4. How many 1°, 2°, 3°Catoms does 1, 3, 5-Trimethyl cyclohexane have?
(1) 3,6, 0 (2) 3, 4, 2 (3) 0, 3,6 (4)3, 3, 3
CIUO04

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IUPAC Nomenclature and Common Names ALLEN
DIS|TAL

5. The total number of r-bond electrons in the following structure is :

H3C H H H
CH3
H3C
H2C H
CH:

(1)8 (2) 12 (3) 16 (4) 4

CIU005
6. The third member of the family of alkenynes has the molecular formula :
(1) C&Hs (2) CH6 (3) CHa (4) C&H4
CIUO06

7. Findout the incorrect statement about given molecule.

HC= C- CH = CH - CH = CH2
(1) All the carbons in given molecule are not in same plane
(2) IUPAC name is hexa-1,3-dien-5-yne
(3) It has 4 sp² hybrid carbons and 2 sp hybrid carbons
(4)All the carbons in given molecule are in same plane
CIUO07

H-CH,
8. CH3- CH2 - CH2 - ÇH2 - CH - CH - CH2 - CH2 - CH2- CH3
CH3 - C- CH3
CH3

(1)5-(1, 1-Dimethyl Ethyl)-6-Ethyl decane (2) 5-Ethyl-6-(1, 1-Dimethyl Ethyl) decane

(3)6-Ethyl-5-(1, 1-Dimethyl Ethyl) decane (4) 6-(1, 1-Dimethyl Ethyl)-5 Ethyldecane
CIUO08

9. Allthe following IUPACnames are correct except:

(1)1-Chloro-1-ethoxy propane (2) 1-Amino-1-ethoxypropane
(4) 1-Ethoxy-1-propanamine
(3) 1-Ethoxy-2-propanol
CIUO09

10. The IUPACname of rH-CH |- CHCH2 CH3 is :

H3
(2) 3-Methyl-5-cyclohexylpent-1-ene
(1)2-Cyclohexylhex-2-ene
(4)1-Cyclohexyl-3,4-dimethyl-but-1-ene
(3) 1-Cyclohexyl-3-ethylbut-1-ene
CIU010

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 ALLEN JEE(Main + Advanced) : Chemistry
DIGITAL

11. IUPAC name of compound is :

OH
(2) 6-ethyl-4,4-dimethylcyclohex-2enol
(1) S-ethyl-3,3-dimethylcyclohex-en-6-ol
(4) 6-ethyl-4,4-dimethylcyclohexenol
(3) 2-ethyl-4,4-dimethylcyclohex-5-enol
CIUO11
-COOC,Hs
12, The IUPAC name of is :
~CI
(1) 2-Chlorocarbonyl ethylbenzoate (2) 2-Carboxyethyl benzoylchloride
(3) Ethyl-2-chlorobenzoate (4) Ethyl-1-(chlorocarbonyl)benzoate
CIUO12
13. The IUPACnamne of CsHsCH=CH-COOH is :
(1)Cinnamic acid (2) 1-Phenyl-2-carboxy ethane
(3) 3-Phenylprop-2-enoic acid (4) Dihydroxy-3-phenylpropionic acid
CIU013
14. The number of carbon atoms in the principle carbon chain of the given compound is :
CH3 - CH2 CH2- C-COOH
OHCCH,- CH3
(1)7 (2) 5 (3)4 (4)6
CIU014
15. The correct IUPAC name of compound CH3-CH2-C-ÇH-CHO is
0CN
(1)2-Cyano-3-oxopentanal (2) 2-Formyl-3-oxopentanenitrile
(3)2-Cyano-1, 3-pentanedione (4) 1,3-Dioxo-2-cyanopentane
CIU015

16.

what is the IUPAC name of the above compound ?

(1)Cyclo[1.2.2]heptane (2) Bicyclo[1.2.2]heptane
(3) Bicyclo[2.2.1]heptane (4) Cyclo[2.2.1]heptane
CIU016
CH3 CHs
17. The IUPAC name of the compound,
is :

(1) 2,6-Dimethylspiro[4.5] dec-1-ene (2) 2,7-Dimethylspiro[5.4]dec-1-ene

(3) 2,10-Dimethylspiro[4.5]dec-2-ene (4) 2-Methylspiro [5.4]
dec-2-ene CIUO17

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IUPAC Nomenclatureand Common Names ALLEM
DIS|TAL
18. The IUPAC name for
ÇI
NO%

CHa
(1)1-Chloro-2-nitro-4-methylbenzene (2) 1-Chloro-4-methyl-2-nitrobenzene
(3) 2-Chloro-1-nitro-5-methylbenzene (4) m-Nitro-p-chlorotoluene
CIU018
19. What is the correct IUPACname of the following compound?

(1)3-(2-Cyanopropyl)-N-ethyl-N-methylpentanamide
(2) N-Ethyl-3-(2-cyanopropyl)-N-methylpentanamide
(3) N, 3-Diethy-5- cyano-N-methylhexanamide
(4) 5-Cyano-N, 3-diethyl-N-methylhexanamide
CIUO19

20. The compound has been named in IUPAC as

(1)Bicyclo[1.2.1] octane-2, 6-dione (2) Bicyclo[1.2.2]octane-2,6-dione

(3) Bicycdo[2.2.2]octane-2, 6-dione (4) Bicyclo[1.1.1]octane-2, 6-dione
CIU020

SECTION-B

This section will have TEN questions. Candidate can choose to attempt any 5 questions out of these
10 questions. In case if candidate attempts more than 5 questions, first 5 attempted questions will
be considered for marking.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numericalvalue (Answer should be rounded off to the nearest
integer).
Answer toeach question will be evaluated according to the following marking scheme:
Full Marks :+4 If only correct answer is given.
Zero Marks :0If no answer is given.
Negative Marks :-1 For incorrect answer

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 ALLEN JEE(Main + Advanced) : Chemistry
DIGTAL

1. Calculate molecular weight of the lowest alkane containing asequence of 1°, 2°, 3° and4 carbon atom?
CIU021
2, Calculate D.0.U. ?

CIUO22

3.
ÇH3
CH3CH2-¢-ÇH-ÇHCH- CHs
CH3 CH3 CH3
Calculate lowest set of locant?
CIU023
CN

H2N COOMe
4.

COOH
HO

How many functional group are presents ?

CIU024

5.

Number of 1°, 2° ,3° and 4°C present in compound ?

CIU025
6. Isooctane contains 1°,2°,3°,4°Crespectively write answer as sum of all degrees of
carbon?
CIUO26

7 (a) (b)

Total number of carbon in principal carbon chain ?

CIUO27

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IUPAC Nomenclature and Common Names L

8. D.B.E. in Benzoic acid is ?

CIUO28
9. Find the totalnumber of sigma bond' (s) in naphthalene ?
CIUO29
10. Total number of carbon in P.C.C.?

(A) (C)

(D) A (E)

HO CH2 rOH

CIU030

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 ALLEN
DIGI TAL JEE (Main + Advanced) : Chemistry

Exercise - II(EE-Main PYQs)

1, Underlined carbon issp hybridised in [AIEEE-2002|
(4) CH3CH,CN
(1) CH,CH=CH2 (2) CH,CH2-NH2 (3)CH3CONHz
CIU031
2. Which of the following compound has wrong IUPAC name? [AIEEE-2002]
(1)CH,CH,- CH,CO0- CH,CH, (Ethylbutanoate)
(2) CH3-ÇH-CH2--CHO (3-Methylbutanal)
CH3

(3) CH3-ÇH-ÇH-CH3 (2-Methyl-3-butanol)

OH CH:

(4) CH-H-CHz-CH3 (2-Methyl-3-pentanone)

CH3 0
CIUO32
3. The IUPAC name of CH3C0CH(CH3)2 is [AIEEE-2003]
(1) Isopropylmethylketone (2) 2-Methyl-3-butanone
(3) 4-Methylisopropylketone (4) 3-Methyl-2-butanone
CIUO33

4. The IUPACname of the compound is [AIEEE-2004]

HO

(1) 1, 1-Dimethyl-3-cyclohexanol (2) 1, 1-Dimethyl-3-hydroxycyclohexane

(3) 3,3-Dimethyl-1-cyclohexanol (4) 3, 3-Dimethyl-1-hydroxycyclohexane
CIUO34

5. The IUPAC name of the compound is

[AIEEE-2006]
Br

(1) 6-Bromo-2-chlorocyclohexene (2) 3-Bromo-1-chlorocyclohexene

(3) 1-Bromo-3-chlorocyclohexene (4) 2-Bromo-6-chlorocyclohex-1-ene
CIUO35
6. The IUPAC name of is [AIEEE-2007]

(1)1, 1-Diethyl-2, 2-dimethylpentane (2) 4, 4-Dimethyl-5, 5-diethylpentane

(3) 5, 5-Diethyl-4, 4-dimethylpentane (4) 3-Ethyl-4,4-dimethylheptane
CIUO36

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 ALLEN
IUPAC Nomenclature and Common Names DIGITAL

7. The correct decreasing order of priority for the functionalgroups of organic compounds in the
IUPACsystem of nomenclature is [AIEEE-2008]
(1) -co0H, -SO3H, -CONH2, -CHO (2) -sO;H, -COOH, -CONH2, -CHO
(3)-CH0, -COOH, -S0;H, -CONH, (4)-CONH2, -CHO, -S0;H, -COOH
CIUO37
8. The IUPAC name of neopentane is : [AIEEE-2009]
(1)2-Methylpropane (2) 2, 2-Dimethylbutane
(3) 2-Methylbutane (4) 2, 2-Dimethylpropane
CIU038
9. The IUPACname of the compound is: [AIEEE (nline) 2012]

H2C -CH-CH3
(1)1,2-Epoxypropane (2) Propyleneoxide
(3) 1, 2-Oxopropane (4) 1,2-Propoxide
CIUO39
10. The hydrocarbon with seven carbon atoms containing a neopentyl and a vinyl group is :
[JEE (Main) Online 2016]
(1)4,4-Dimethylpentene (2) 2,2-Dimenthyl-3-pentene
(3) Isopropyl-2-butene (4) 2,2-Dimethyl-4-pentene
CIU040
11. The IUPAC name of the following compound is: JEE (Main)Online 2017]

(1) 1-Ethyl-2,2-dimethylcyclohexane (2) 2,2-Dimethyl-1-ethylcyclohexane

(3) 1,1-Dimethyl-1,2-ethylcyclohexane (4) 2-Ethyl-1,1-dimethylcyclohexane
CIU041

12. The IUPAC name of the following compound is : [JEE (Main) Online 2018]

(1)4-Methyl-3-ethylhex-4-ene (2) 4,4-Diethyl-3-methylbut-2-ene

(3) 3-Ethyl-4-methylhex-4-ene (4) 4-Ethyl-3-methylhex-2-ene

CIU042

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 ALLEN
DIG|TAL
JEE (Main + Advanced) : Chemistry
What is the IUPAC nameof the following compound?
[JEE (Main) Online20191
13.
H3C CH3
H

H
H3C Br

(1) 3-Bromo-1, 2-dimethylbut-1-ene

(2) 4-Bromo-3-methylpent-2-ene
(3) 2-Bromo-3-methylpent-3-ene
(4) 3-Bromo-3-methyl-1,2-dimethylprop-1-ene
CIU043
[JEE (Main) Online 2019]
14. The IUPAC name of thefollowing compound is:

CH3-H-H-CH;-COOH

(1)2-Methyl-3-Hydroxypentan-5-oicacid (2) 4,4-Dimethyl-3-hydroxy butanoicacid

(3) 3-Hydroxy-4 -methylpentanoicacid (4) 4-Methyl-3-hydroxypentanoicacid
CIU044
15. The correct IUPAC name ofthe following compound is: [JEE (Main) Online 2019]

CI
CH3
(1) 5-Chloro-4-methyl-1-nitrobenzene (2) 2-Methyl-5-nitro-1-chlorobenzene
(3) 3-Chloro-4-methyl-1-nitrobenzene (4) 2-Chloro-1-methyl-4-nitrobenzene
CIU045
16. The IUPAC name of thefollowing compound is: JEE (Main) Online 2019]
CH:
H3C

FCH
CH,
CH2
(1) 3,5-Dimethyl-4-propylhept-6-en-1-yne
(2) 3-Methyl-4-(3-methylprop-1-enyl)-1-heptyne
(3) 3-Methyl-4-(1-methylprop-2-ynyl)-1-heptene
(4) 3,5-Dimethyl-4-propylhept-1-en-6-yne

CIU046

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IUPACNomenclature and Common Names ALLEN
DIG|TAL

17. The lUPAC name for the following compound is [JEE (Main) 2020]
(1) 2,5-Dimethyl-6-carboxy-hex-3-enal CHO

(2)6-Formyl-2-methyl-hex-3-enoic acid CH3

H3C
(3) 2,5-Dimethyl-5-carboxy-hex-3-enal
(4)2,5-Dimethyl-6-0X0-hex-3-enoic acid COOH

CIU047

18. The IUPACname of the following compound is : CH3

[JEE (Main) 2020]
(1)4-Bromo-2-methylcyclopentanecarboxylicacid C- OH
(2) 5-Bromo-3-methylcyclopentanoicacid
(3) 3-Bromo-5-methylcyclopentanecarboxylicacid
(4) 3-Bromo-5-methylcyclopentanoicacid Br
CIU048

19. The IUPAC name of the following compound is - OH [JEE (Main) 2020]
(1) 3-Amino-4-hydroxymethyl-5-nitrobenzaldehyde NH2
(2)2-Nitro-4-hydroxymethyl-5-aminobenzaldehyde
(3) 4-Amino-2-formyl-5-hydroxymethylnitrobenzene O2N
(4) 5-Amino-4-hydroxymethyl-2-nitrobenzaldehyde HO
CIU049

20. The number of sp² hybridised carbons present in "Aspartame" is

[JEE (Main) 2020]
CIUO50

21. Choose the correct namne for compound given below:

[JEE (Main) 2021]
(1) (4E)-5-Bromo-hex-4-en-2-yne

(2) (2E)-2-Bromo-hex-4-yn-2-ene -Br

(3)(2E)-2-Bromo-hex-2-en-4-yne
(4)(4E)-5-Bromo-hex-2-en-4-yne
CIUO51

[JEE (Main)2022]
22. The correct IUPAC name of the following compound is:

0;N

(2) 4-methyl-5-oxo-2-nitrohept-3-enal
(1)4-methyl-2-nitro-5-oxohept-3-enal
(4) 6-formyl-4-methyl-2-nitrohex-3-enal

(3)4-methyl-6-nitro-3-oxohept-4-enal CIUO52

[Link]. In
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 ALLEN
DIGITAL JEE (Main+ Advanced) :Chemistrv

Exercise - III (EE Advanced Pattern)

SECTION-I
This section contains TEN questions.
Each question has FOUR options (A), (B), (C) and (D), ONLY ONE of these four options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories:
darkened.
Full Marks :+3, If only the bubble corresponding to the correct option is
Zero Marks :0, If none of the bubbles is darkened.
Negative Marks :-1, in all other cases

1 The correct IUPAC name of the compound is

CH3

CH3-CHz-( H-CH= CH2-CH3

CH
CH3-CH2-CH-CH2-CH2-CH2-CH3
(A) 5,6-Diethyl-8-methyldec-6-ene (B) 5,6-Diethyl-3-methyldec-4-ene
(C)6-Butyl-5-ethyl-3-methyloct-4-ene (D) 2,4,5-Triethyl-3-ene
CIU053

2, The IUPAC name of the compound H-C-CH =CH- CH - CH =CH, is

CH, -CH, -CH, -CH,

(A) 4-Butylhexa-2,5-dien-1-al (B) 5-Vinyloct-3-en-1-al
(C) 5-Vinyloct-5-en-8-al (D) 3-Butylhexa-1,4-dien-8-al
CIUO54
3. The IUPAC name of the compound CH3CH =CHCH=CHC=CCH3 is:
(A) Octa-4,6-diene-2-yne (B) Octa-2,4-diene-6-yne
(C)Oct-2-yne-4,6-diene (D) Oct-6-yne-2,4-diene
CIUO55

4. The IUPAC name of H-C-CH2

H¡C=CH-c

(A) 2-Formyl ethanoic propanoic anhydride

(B)2-Oxo-propanoic prop-2-enoic anhydride
(C) Prop-2-enoic-2-formyl propanoicanhydride
(D) 2-Formylethanoic prop-2-enoic anhydride
CIUO56

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 ALLEM
IUPACNomenclature and Common Names
p-CHO
5. The IUPACname of OHC--CHz-CH2-H--CH2-CHO is:

(A)4,4-Di(formylmethyl) butanal (B) 2-(Formylmethyl) butane-1, 4-dicarbaldehyde

(C) Hexane-3-acetal-1, 6-dial (D) 3-(Formylmethyl) hexane-1,6-dial
CIU057
6. IUPAC name will be ÇH2-ÇH-ÇH2
CN N N

(A)1,2,3-Tricyano propane (B)Propane-1,2,3- trinitrile

(C)1,2,3-Cyano propane (D) Propane-1,2,3-tricarbonitrile
CIUO58
7. A
substance containing an equal number of primary, secondary and tertiary carbon atoms is:
(A) Mesityl Oxide (B) Mesitylene (C) Maleic acid (D)Malonic acid
CIUO59

8. Structural formula of isopropyl methanoate is:

(B) H--0-CH,-ÇH-CHs
H3 H:

(C) CHsf-0-CH;-CH, (D) )!H-Ç-0-CH-CH3

H3 H3
CIUO60

9. Which of the following compound is wrongly named?

2-Chloropentanoicacid
(A) CH;CH;CH-ÇHCOOH
I
2-Methylhex-3-enoicacid
(B) CH,C = CCHÇOOH
CH3
(C) CH3CH,CH=CHCOCH3 Hex-3-en-2-one
(D) CH3-ÇHCH2CHzCHO 4-Methylpentanal
H3
CIU061

ÇOOH
10. The IUPAC name of is :
OH
OCH3
(B) 2,3-Dihydroxybenzoicacid
(A) 3-Hydroxy-4-Methoxybenzoicacid (D)4-Carboxybenzene-1,2-diol
(C) 4-Carboxy-2-hydroxyphenol CIUO62

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 ALLEN
OIGITAL JEE (Main + Advanced) : Chemistry
SECTION-II
This section contains FOUR questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four
option(s) is (are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer : toeach question will be evaluated according to the following marking scheme:
Full Marks +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 Ifall the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks If none of the options is chosen (i.e. the question is unanswered).
Negative Marks -2 In all other cases.

11.

I III

Select the correct statement about, I, II & III compounds.

(A) Iis having four 2° &four 3°carbons
(B) IIis having three 1°,six 2°,three 3° &two 4° carbons
(C) IIIis having three 1°, three 2° &three 3° carbons
(D) All are homocyclic compounds
CIU063
12. Which of the following statements is/are wrong ?
(A)CHH2n is the general formula of alkanes.
(B) In homologous series, all members have the same physical properties.
(C) IUPAC means International Union of Physics and Chemistry
(D) Normal butane contains two 1° Catoms and two 2°Catoms,

CIUO64
13. Which of the following statements is/are wrong ?
(A) Aceticacid is the systematic name of vinegar.
(B)neopentane is an unsaturated compound.
(C) Prefixes like n-, iso, sec-, tert, neo-, etc.,, are used in IUPACsystem.
(D) The systematic names of acids are formed by dropping -e of the name of
parent alkane and
adding -oic acid.
CIU065

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IUPAC Nomenclature and Common Names ALLEN
DIGTA

14. Which of the following statements is/are correct ?

(A) The trivial names of organic compounds are called common names.
(B) The systematic names of organic compounds are obtained from the IUPAC system.
(C) The systematic names of alkanes are based on the number of Catoms in the longest continuous
chain ofC atoms.

(D) The maximum number offunctionalgroups must be included in theCatom chain selected even
if it does not satisfy the longest chain rule.
CIU066

SECTION-III
This section contains a paragraph.
Based on each paragraph, there are TWO questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories:
Full Marks +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks In all other cases.
Paragraph for Question Nos. 15 to 16
The analgesic drug ibuprofen A) is chiral and exists in (+) and (-)forms. One enantiomer is
physiologically active, while the other is inactive. The structure of ibuprofen is given below.
COOH

15. The principal functional groupin structure (A) is:

(B) -COOH group (C) Isopropyl (D) Both (A) and (B)
(A) Phenyl
CIUO67

16. The IUPAC name of structure (A) is:

(A) 3-(p-Isobutyl phenyl)propanoic acid (B) 3-(p-Isobutyl phenyl)propanoic acid
(C) 3-(p-sec-Butyl phenyl]propanoic acid (D) 2-(p-sec-Butyl phenyl)propanoic acid
CIUO68

SECTION-IV
This section contains TWO questions.
the lists have choices (A), (B), (C) and (D) out of
Each question has matching lists. The codes for
which 0NLY ONE is correct
of the following categories :
For each question, marks will be awarded in one corresponding
Full Marks +3 If only the bubble to the correct option is darkened.
Zero Marks 0 If none of the bubbles is darkened.
Negative Marks: -1 In all other cases

[Link]. In
[ 237]
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 ALLEN
DIG|TAL JEE (Main+ Advanced) : Chemistry
17. Column -I Column- II

(Common Name) (Structural formula)

!
(A) Acetone (P) CH,= CH C-H

(B) Acetaldehyde () CH3 C CH,

(C) Crotonaldehyde (R) CHs CH = C H - C H

(D) Acrolein (S) CH -C H

(A) A’ R, B>S, C’ P, D’Q (B) A-’QB S, C’P, D’R

(C) A’ P, B’ S, C’QD-’R (D) A’P, B ->QC’RDS
CIU069

18. Column-I Column-II

(Common Name) (Structural formula)
(A) Isooctane (P) CH2ÇH2

CH3
(B) Neopentane (Q) CH3 Ç- CH2 ÇH CH3
CH3 CH3

(C) Ethylidene chloride (Geminal dihalide) (R) CH3 -CH2-CH) CH2 CH2- CH-CH3
CH3
CH:
(D) Ethylene Dichloride (Vicinal dihalide) (S) CH3Ç CH3
CH3

Cl
(T)CH3 - CH
CI

(A) A’P, B ’ S,C’T,D-’Q (B) A’ S, B-’Q, C’T, D’P

(C) A’P,B -’ QC’S,D’T (D) A ’ QB’S, C’T, D’P
CIU070

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JUPAC Nomenclature and Common Names ALLEN
DIOITAL
SECTION-V
This section contains TWO questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value (in decimal notation,truncated/rounded-off
to the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30, if answer is 11.36777...
then both 11.36 and 11,37 will be correct).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks :+3, if ONLY the correct numerical value is entered as answer.
Zero Marks :0, in all other cases.

CH3 CH3
19. CH3-CHz-ÇH-CH-¢-CH3 compound (M)
CH3 CH3
(a) No. of 1° carbon atomns in compound (M) is X
(b) [Link] 2° carbon atoms in compound (M) is Y
(c) No. of 3° carbon atoms in compound (M) is Z
Write answer of part (a),(b) & (c) in the same order and present the three digit number XYZ
as your answer in OMR sheet. for example : If allthese answers are 9 (X=9, Y=9,Z=9 ) then
fill999 in OMR sheet.
CIU071

20. The degree of unsaturation in compound is:

CH3
CH3

CIU072

[Link]. In [239 ]
ALLENDigital
 ALLEN
DIGITAL JEE (Main + Advanced) : Chemistry

Exercise - IV (JEE Advanced PYQs)

1. The IUPAC name of the compound having the formula is: [IIT- 1984]
ÇH3
H3C - - CH = CH,
H3
(A) 3,3,3-trimethyl-1-propene (B) 1,1,1-trimethyl-2-propene
(C) 3,3-dimethyl-1-butene (D) 2,2-dimethyl-3-butene
CIU073
2. The IUPACname of the compound CH2=CH-CH(CH3)2 is : [IIT- 1987]
(A)1,1-dimethyl-2-propene (B) 3-methyl-1-butene
(C) 2-vinyl propane (D)None of the above
CIU074
3. The number of sigma and pi-bonds in 1-butene 3-yne are: [IIT - 1989]
(A)5 sigma and 5 pi (B) 7 sigma and 3 pi
(C) 8sigma and 2 pi (D) 6 sigma and 4 pi
CIU075
4. The IUPACname of CoHsCOCl is [IIT - 2006]
(A) Benzoyl chloride (B) Benzene chloro ketone
(C) Benzene carbonyl chloride (D) Chloro phenyl ketone
CIU076
5. The IUPAC name of the following compound is:
[IIT-2009]
OH

CN
Br

(A)4-Bromo-3-cyanophenol (B) 2-Bromo-5-hydroxybenzonitrile

(B) 2-Cyano-4-hydroxybromobenzene (C)6-Bromo-3-hydroxybenzonitrile
CIU077
6. In allene (CsH4), the type(s) of hybridisation of the carbon atoms is (are)

[IIT - 2012]
(A) sp and sp (B)sp and sp2 (C)only sp2 (D) sp² and sp3
CIU078

[ 240 ] [Link]. In ALLEN Digital

IUPAC Nomenclature and Common Names ALLEN
DIGITAL
7. The IUPAC name(s) of the following compound is(are) :
H;C

[JEE (Advanced) 2017]

(A) 4-Methylchlorobenzene (B) 4-Chlorotoluene
(C) 1-Chloro-4-methylbenzene (D)1-MOethyl-4-chlorobenzene
CIU079
8. Which one of the following structures has the IUPAC name
3-ethynyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid ?
JEE (Advanced) 2020]
OH

(A) CO2H (B) HO>C

OH
QH OH

(C) CCO,H (D) CO;H

CIUO80

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 ALLEN
DIGTAL JEE (Main + Advanced) : Chemistry

ANSWER KEY
Exercise-I((EE Main Pattern)
6 10
Q 1 2 4 5
1 3 1 1 2 1
A 1 2 4
Section-A 19 20
11 12 13 14 15 16 17 18
1 2 4 3
A. 2 3 3 2 2 3
6 7 8 9 10
Q. 1 2 3 44 5
Section-B 19 22
A. 114 19 15 6 16 8 17 5

Exercise - II((EE Main PYQs)

Question 12 4 5 6 8 10
1 4 1 1
Answer 4 3 4 3 2 4
11 12 13 14 15 16 17 18 19 20
Question
4 1 4 9
Answer 4 4 2 3 4 4
Question 21 22
Answer 3 3

Exercise III(EE Advanced Pattern)

Q.1 23 4 5 6 7 8 10
Section-l B D B A
A. B A B D D
Q 11 12 13 14
Section-I|
A. ABCD ABC ABC ABCD
0. 15 16
Section-III
A B D

Q 17 18
Section-IV
A B D

Q. 19 20
Section-V
A. 612 12

Exercise -IV(JEE Advanced PYQs)

Question 2 3 4 5 6
Answer C B B C B B BC D

[242] [Link]. in ALLEN Digital