AIM- IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -A EXPERIMENT -04
AIM- IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE - A
RESULT - The experimental obscrvation shows the prescnce of Akobolic group -OH
PART-A- PHYSICAL PROPERTIES
Equations -( write on white side of paper)
a. Colour - colouriess
[Link] + (NHLCe (NOk- (CH-OHHCe (NO, (NHNO, b, Odour - order of sprit or wine
c) C;H,0H +CH,CoOH CHCOO CH, + H0 c. Solubility in Water - soluble in water
d. Solubtity in dil HCI - soluble in Dil Hcl
PART- B-CHEMICAL PROPERTIES
Experiment Observation Inference
Imaturation trst- To the given
otganac conpound add alkane
KMnO4 get Compound is
decolouriscd saturated (-)
oylik group- Add |No C02 evolve Carboxylic group
ch of NalHCO, to thhe eisml absent
mesl sarnpie No change Alcohoie e
bseno hosy eroup is
abscnt
Tot for ehcnel -to the gives NO VOILETPPT Phenolic group
ampk add 2- 3 ml ef Neutral Fe% obtained abscnt
dRUa drop apicce of Evolution of Alkoholic group
dned sodium in the given sample. colourless gas OH confim
Conk amneniu: ntrate tcst Add Red PPT |Alcobolic group
drops of ca a nitrate formation OH confirm
Estertesñ- to th I miof give Fruity smell Alcoholic group
nplc add 1ml acetic acid and few OH confir
drops of Con H2S04 and hcat on
walcr bath
RESULT- The cxpcrimental obscrvation shows the prescnce of Alcoholie group - OH
Equations -(writeon white side of paper)
a) CHOH Na -C;[Link] 5 H:
D) CaHOH (NCe (NO (CHOH)Ce (NO (NHa,NO,
c) CHO CHCOO - CHc Hs
ALM -IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -B EXPERIMENT - 05
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -B
RESULT-The experimental observation shows the presence of Phenolic group
Ar-OH confimed PARI- A- PHYSICAL PROPERTIES
a. Colour - colourless
EQUATIONS -(write on white side of paper) [Link]- order of sprit or winc
a) CoH:0H + FeCl - ((CH0) Fel +3HCI
b) N,'Cr c. Solubility in Water soluble in water
Naoy
d. Solubility in dil HCI -soluble in Dil Hcl
Aoni
ehlori
NuN oH +NaCI+H0 PART- B- CHEMICAL PROPERTIES
SN. Esperiment Observation Inference
Uaturation test- add
organic compound
To thealkaline
given KMn04 get Compound is
decolouriscd saturated (-)
KMnO solution
Totforcarboxslic eroun- Add a No C0 evolveCarboxylic group
pinch of NaHCO, to the given sample bsent
Litmus Tst- Puta drop of sample No change is Alcoholic or
on litn and red Ilitmus observed rboxyl group is
absent
Tot for phenol- to the given VOILET PPT IPhenolic group
sample add 2-3 mi of Neutral obtained confirm
FeC3 soln
5. Azo dye test:-Compound +NaNOOrange red dye Phenolic group
+conc. HC and add aniline lconfirmed
RESULT- The experimental observation shows the presence of Phenolic group
Ar-OH confimed
Equations- (write on white side of paper)
a) CaHOH + FeCl -[(CH:O0) «Fel, +3HCI
b) N,' OH
NaOH
N=N OH - NaCi + H,o
(Ocange dye)
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -C EXPERIMENT- 06
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -C
RESULT- The cxpcrimental observation shows the presence of aldehyde group CHO
confirmed. PART-A- PHYSICAL PROPERTIES
EQUATION a. Colour - colourless
2 AgN0H
b. Odour- order of sprit or wine
2 Agie c. Solubility in Water - soluble in water
d. SoBubility in dil HCI- soluble in Dil Hcl
PART- B -CHEMICAL PROPERTIES
SN. Experimnent Observation Inference
Unsaturatios test- To the KMn04 get Compound is
given organic conpound add decolourised saturated (-)
alkaline KMnO4 solution
Litms Test- Put a drop of No change is Alcoholic or
sample on blue litmus and red observed carboxyl group is
llitmus absent
Tet for carborsic groUL- Add No CO2 evolveCarboxylic group
a pinch of NaHCO3 to the given absent
ample
4 Iest for phenol -to the given NO VOILET |Phenolic group
sample add 2- 3 ml of Neutral PPT obtained absent.
FeCl; soBn
5 Tet for carbovi group- Add Orange yellow Carbonyl group may
Iml of sample add 2-3 ml of 2,4 ppt formed be an aldehyde or
DNP (dnitro phenylhvdraz
6. AAÀod Red pot formed rou
Iml oenye
Fehline selut oupAocd eonfnod
mpound & heated on
organje com
water bath
|Added Tollen's reagent tto Silver miror on -CHO group
organic compound and warm it inside wall ofconfirmed
in water bath the test tube
RESULT - The cxpcrimental obscnation shows the prescnce of aldehyde group -CHO
confirmed.
EQUATION
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE - D EXPERIMENT - 07
RESULT- The experimental observation shows the presence of ketonic group AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE - D
>C-O confirmed.
PART-A- PHYSICAL PROPERTIES
EQUATION a. Colour - colourless
b. Odour- order of sprit or wine
c. Solubility in Water - soluble in water
d. Solubility in dil HCI- soluble in Dil Hcl
PART- B-CHEMICAL PROPERTIES
SN. Experiment Observation Inference
. Unsaturtion test- To the given KMnOu Compound is
[Link] add allkaline decoloursedt
so
saturated (-)
I t for carborvlic Eroun- Add a No CO: Carboxylic group
pinch of NaHCO3 to the given evolve absent
sample
Litmus Tet-Put a drop of sample No change isAlcoholic or carboxyl
on blue litmus and red Ilitmus observed group is absent
Test for phenol- to the given INO VOILET Phenolic group
sample add 2- 3 ml of Neutral FeCh PPT obtaincd absent.
soln
Tet for carbonvi eroun- Add I ml Orange Carbonyl group may
of sample add 2-3 ml of 2,4 DNP yellow pp be an aldehyde or
(dinitro phenylhydrazine) formed kelone.
Test for Ketonic group: Added Rod colour Ketonic group
ml sodium nitroprusside solution appcarcd confirmcd
to given organic
Compound & then added NaOH
solution dropwise
7. Add Iml fincly powdered m Violct
dintrobenzene to given organic colour
Olour confirmcd
Compound & then added NOH PPcared
soln.
RESULT- The cxpcrimental obscrvation shows the presence of ketonic group
>C0 confirmed.
ALM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -E EXPERIMENT - 08
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -E
RESULT - The experimental observation shows the prescnce of Carboxy li gruup -C0OH PART- A- PHYSICAL PROPERTIES
Eauntion aH:COOH + Na:CO, CHCOO Na +H;0 +CO a. Colour - colourless
b) C;HOH +CHCOOH CHCOO CH +H0. b, Odour- order of sprit or wine
c. Solubility in Water - soluble in water
d. Solubility in dil HCI - soluble in Dil Hcl
PART- B-CHEMICAL PROPERTIES
SN. Experiment Observation Inference
Unsaturation test- To the given KMnO4 get |Compound is
organic compound add alkaline decolourised saturated (-)
KMnO, solution
Litmus Test-Put a drop of change isAkobolic or
sample on blue litmus and red observed, bluecarbonyl group
Ilitmus itrmus tun red may be present
Iet for carboxylic goup Effervescence with
- Sodium bi carbonate testt evolution of colour
Added a pinch of NaHCO, to less and odourless Carboxylic
small amount of Organic gas which turns group present
compound Iime water milk
b.- Ester test: Addcd cthanol to Plcasant fruity |Carboxylic
organic Compound and then smcll group present
added 2-3 drops of conc. H:SOa
to it and warmed in water bath for
RESULT Crperimental obseration shows the presence of Carboxylic group-COOH.
Eauntions aCHCoOH NaCo, - CHcoO Na +HO +CO;
b) CHsOH +CHcOOH CHCO0 CHs + H:0.