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Functional Group Identification Experiments

The document outlines a series of experiments aimed at identifying functional groups in various samples (A to E). Each experiment details physical properties, chemical tests, observations, and inferences leading to the confirmation of specific functional groups such as alcoholic, phenolic, aldehyde, ketonic, and carboxylic groups. The results indicate the presence of these functional groups based on the reactions observed during the tests.
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0% found this document useful (0 votes)
45 views3 pages

Functional Group Identification Experiments

The document outlines a series of experiments aimed at identifying functional groups in various samples (A to E). Each experiment details physical properties, chemical tests, observations, and inferences leading to the confirmation of specific functional groups such as alcoholic, phenolic, aldehyde, ketonic, and carboxylic groups. The results indicate the presence of these functional groups based on the reactions observed during the tests.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

AIM- IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -A EXPERIMENT -04

AIM- IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE - A


RESULT - The experimental obscrvation shows the prescnce of Akobolic group -OH
PART-A- PHYSICAL PROPERTIES
Equations -( write on white side of paper)
a. Colour - colouriess
[Link] + (NHLCe (NOk- (CH-OHHCe (NO, (NHNO, b, Odour - order of sprit or wine
c) C;H,0H +CH,CoOH CHCOO CH, + H0 c. Solubility in Water - soluble in water
d. Solubtity in dil HCI - soluble in Dil Hcl
PART- B-CHEMICAL PROPERTIES

Experiment Observation Inference


Imaturation trst- To the given
otganac conpound add alkane
KMnO4 get Compound is
decolouriscd saturated (-)

oylik group- Add |No C02 evolve Carboxylic group


ch of NalHCO, to thhe eisml absent

mesl sarnpie No change Alcohoie e


bseno hosy eroup is
abscnt
Tot for ehcnel -to the gives NO VOILETPPT Phenolic group
ampk add 2- 3 ml ef Neutral Fe% obtained abscnt

dRUa drop apicce of Evolution of Alkoholic group


dned sodium in the given sample. colourless gas OH confim

Conk amneniu: ntrate tcst Add Red PPT |Alcobolic group


drops of ca a nitrate formation OH confirm

Estertesñ- to th I miof give Fruity smell Alcoholic group


nplc add 1ml acetic acid and few OH confir
drops of Con H2S04 and hcat on
walcr bath
RESULT- The cxpcrimental obscrvation shows the prescnce of Alcoholie group - OH
Equations -(writeon white side of paper)
a) CHOH Na -C;[Link] 5 H:
D) CaHOH (NCe (NO (CHOH)Ce (NO (NHa,NO,
c) CHO CHCOO - CHc Hs

ALM -IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -B EXPERIMENT - 05


AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -B
RESULT-The experimental observation shows the presence of Phenolic group
Ar-OH confimed PARI- A- PHYSICAL PROPERTIES
a. Colour - colourless
EQUATIONS -(write on white side of paper) [Link]- order of sprit or winc
a) CoH:0H + FeCl - ((CH0) Fel +3HCI
b) N,'Cr c. Solubility in Water soluble in water
Naoy
d. Solubility in dil HCI -soluble in Dil Hcl
Aoni
ehlori
NuN oH +NaCI+H0 PART- B- CHEMICAL PROPERTIES
SN. Esperiment Observation Inference

Uaturation test- add


organic compound
To thealkaline
given KMn04 get Compound is
decolouriscd saturated (-)
KMnO solution
Totforcarboxslic eroun- Add a No C0 evolveCarboxylic group
pinch of NaHCO, to the given sample bsent
Litmus Tst- Puta drop of sample No change is Alcoholic or
on litn and red Ilitmus observed rboxyl group is
absent
Tot for phenol- to the given VOILET PPT IPhenolic group
sample add 2-3 mi of Neutral obtained confirm
FeC3 soln
5. Azo dye test:-Compound +NaNOOrange red dye Phenolic group
+conc. HC and add aniline lconfirmed

RESULT- The experimental observation shows the presence of Phenolic group


Ar-OH confimed
Equations- (write on white side of paper)
a) CaHOH + FeCl -[(CH:O0) «Fel, +3HCI
b) N,' OH
NaOH

N=N OH - NaCi + H,o


(Ocange dye)
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -C EXPERIMENT- 06

AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -C


RESULT- The cxpcrimental observation shows the presence of aldehyde group CHO
confirmed. PART-A- PHYSICAL PROPERTIES
EQUATION a. Colour - colourless
2 AgN0H
b. Odour- order of sprit or wine
2 Agie c. Solubility in Water - soluble in water
d. SoBubility in dil HCI- soluble in Dil Hcl
PART- B -CHEMICAL PROPERTIES
SN. Experimnent Observation Inference

Unsaturatios test- To the KMn04 get Compound is


given organic conpound add decolourised saturated (-)
alkaline KMnO4 solution
Litms Test- Put a drop of No change is Alcoholic or
sample on blue litmus and red observed carboxyl group is
llitmus absent
Tet for carborsic groUL- Add No CO2 evolveCarboxylic group
a pinch of NaHCO3 to the given absent
ample
4 Iest for phenol -to the given NO VOILET |Phenolic group
sample add 2- 3 ml of Neutral PPT obtained absent.
FeCl; soBn
5 Tet for carbovi group- Add Orange yellow Carbonyl group may
Iml of sample add 2-3 ml of 2,4 ppt formed be an aldehyde or
DNP (dnitro phenylhvdraz
6. AAÀod Red pot formed rou
Iml oenye
Fehline selut oupAocd eonfnod
mpound & heated on
organje com
water bath
|Added Tollen's reagent tto Silver miror on -CHO group
organic compound and warm it inside wall ofconfirmed
in water bath the test tube
RESULT - The cxpcrimental obscnation shows the prescnce of aldehyde group -CHO
confirmed.
EQUATION

AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE - D EXPERIMENT - 07


RESULT- The experimental observation shows the presence of ketonic group AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE - D
>C-O confirmed.
PART-A- PHYSICAL PROPERTIES
EQUATION a. Colour - colourless
b. Odour- order of sprit or wine
c. Solubility in Water - soluble in water
d. Solubility in dil HCI- soluble in Dil Hcl
PART- B-CHEMICAL PROPERTIES
SN. Experiment Observation Inference
. Unsaturtion test- To the given KMnOu Compound is
[Link] add allkaline decoloursedt
so
saturated (-)
I t for carborvlic Eroun- Add a No CO: Carboxylic group
pinch of NaHCO3 to the given evolve absent
sample
Litmus Tet-Put a drop of sample No change isAlcoholic or carboxyl
on blue litmus and red Ilitmus observed group is absent
Test for phenol- to the given INO VOILET Phenolic group
sample add 2- 3 ml of Neutral FeCh PPT obtaincd absent.
soln
Tet for carbonvi eroun- Add I ml Orange Carbonyl group may
of sample add 2-3 ml of 2,4 DNP yellow pp be an aldehyde or
(dinitro phenylhydrazine) formed kelone.
Test for Ketonic group: Added Rod colour Ketonic group
ml sodium nitroprusside solution appcarcd confirmcd
to given organic
Compound & then added NaOH
solution dropwise
7. Add Iml fincly powdered m Violct
dintrobenzene to given organic colour
Olour confirmcd
Compound & then added NOH PPcared
soln.
RESULT- The cxpcrimental obscrvation shows the presence of ketonic group
>C0 confirmed.
ALM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -E EXPERIMENT - 08
AIM-IDENTIFY THE FUNCTIONAL GROUP FROM GIVEN SAMPLE -E
RESULT - The experimental observation shows the prescnce of Carboxy li gruup -C0OH PART- A- PHYSICAL PROPERTIES
Eauntion aH:COOH + Na:CO, CHCOO Na +H;0 +CO a. Colour - colourless
b) C;HOH +CHCOOH CHCOO CH +H0. b, Odour- order of sprit or wine
c. Solubility in Water - soluble in water
d. Solubility in dil HCI - soluble in Dil Hcl
PART- B-CHEMICAL PROPERTIES
SN. Experiment Observation Inference
Unsaturation test- To the given KMnO4 get |Compound is
organic compound add alkaline decolourised saturated (-)
KMnO, solution
Litmus Test-Put a drop of change isAkobolic or
sample on blue litmus and red observed, bluecarbonyl group
Ilitmus itrmus tun red may be present
Iet for carboxylic goup Effervescence with
- Sodium bi carbonate testt evolution of colour
Added a pinch of NaHCO, to less and odourless Carboxylic
small amount of Organic gas which turns group present
compound Iime water milk
b.- Ester test: Addcd cthanol to Plcasant fruity |Carboxylic
organic Compound and then smcll group present
added 2-3 drops of conc. H:SOa
to it and warmed in water bath for

RESULT Crperimental obseration shows the presence of Carboxylic group-COOH.


Eauntions aCHCoOH NaCo, - CHcoO Na +HO +CO;
b) CHsOH +CHcOOH CHCO0 CHs + H:0.

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