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Velocity Constants in Chemical Kinetics

The document contains a practice test for chemical kinetics for JEE and KVPY exams. It includes 15 multiple choice questions testing concepts such as rate constants, reaction orders, activation energy, rate laws, half lives, and parallel reactions. The questions cover topics including temperature dependence of rate constants, determining reaction orders based on rate laws, calculating half lives from decay constants, determining overall reaction rates and energies of activation for multi-step reactions.

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174 views6 pages

Velocity Constants in Chemical Kinetics

The document contains a practice test for chemical kinetics for JEE and KVPY exams. It includes 15 multiple choice questions testing concepts such as rate constants, reaction orders, activation energy, rate laws, half lives, and parallel reactions. The questions cover topics including temperature dependence of rate constants, determining reaction orders based on rate laws, calculating half lives from decay constants, determining overall reaction rates and energies of activation for multi-step reactions.

Uploaded by

Aditya More
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Deodhar Classes

Chemical Kinetics JEE, KVPY


Time :- 30 Min. Total Marks :- 60

1. The velocity constant of a reaction at 290 K was found to be 3.2


x 10-3 . At 300 K it will be

a) 1.28 x 10-2
b) 6.4 x 10-3
c) 9.6 x 10-3
d) 3.2 x 10-4

2. For the reaction 2N2 O5 (g) 4NO2 (g) + O2 (g), if concentration


of NO2 in 100 seconds is increased by 5.2 x 10-3 m. Then rate of
reaction will be

a) 1.3 x 10-5 ms-1


b) 5 x 10-4 ms-1
c) 7.6 x 10-4 ms-1
d) 2 x 10-3 ms-1
e) 2.5 x 10-5 ms-2

3. Decay constant of a reaction is 1.1 x 10-9 / sec, then half life of the
reaction is

a) 1.2 x 108
b) 6.3 x 108
c) 3.3 x 108
d) 2.1 x 108

4. For reaction, A + B products, it is found that the rate of the


reaction is proportional to the concentration of A, but it is
independent of the concentration of B, then
a) The order of the reaction 2 and molecularity 1
b) Molecularity of the reaction is 2 but order is 1
c) Order is 2 and molecularity is 2
d) Order of the reaction is 2 but molecularity is 0

5. In presence of HCl, sucrose gets hydrolysed into glucose and


fructose. The concentration of sucrose was found to reduce from
0.4 M to 0.2 M in 1 hour and 0.1 M in 2 hours. The order of the
reaction is

a) Zero
b) One
c) Two
d) None of these

6. Which one of the following does not represent Arrhenius


equation?

a) K = Ae-E/RT
𝐸
b) Loge K = loge A – 𝑅𝑡
𝐸
c) Log10 K = log10 A – 2.303𝑅𝑇
d) K = AE-RT

7. Energy of activation of a reactant is reduced by

a) Increased temperature
b) Reduced temperature
c) Reduced pressure
d) Increased pressure

8. Rate constant for a reaction H2 + I2 2 HI is 49, then rate


constant for reaction 2HI H2 + I2 is
a) 7
1
b)
49
c) 49
d) 21
e) 63

9. The order of a reaction with rate equals is

a) 2
b) 1
1
c) −2
3
d)
2

10 .The time taken for 90% of a first order reaction to complete is


approximately

a) 1.1 times that of half-life


b) 2.2 times that of half-life
c) 3.3 times that of half-life
d) 4.4 times of half-life

11. Reaction 3CIO─ CIO3- + 2CI- occurs in following two step

Then the rate of given reaction = ….


a) K1[CIO-]2
b) K1[CIO-]
c) K2[CIO2-][CIO-]
d) K2[CIO-]3

12. Which graph show zero activation energy for reaction?

a)

b)

c)

d)
13. The rate law for a reaction between the substances A and B is
given by, rate = K[A]n [B]m . On doubling the concentration of A
and halving the concentration of B, the ratio of the neq rate to
the earlier rate of the reaction will be as

1
a)
2(𝑚+𝑛)
b) (m + n)
c) (n ─ m)
d) 2(n-m)

14. A substance undergoes first order decomposition. The


decomposition follows two parallel first order reaction as

K1 = 1.26 x 10-4 s-1


K1 = 3.8 x 10-5 s-1
The percentage distribution of B and C are a)
75% B and 25% C
b) 80% B and 20% C
c) 60% B and 40% C
d) 76.83% B and 23.17%C

15. A reaction takes place in three steps. The rate constant are
𝐾1𝐾3
K1, K2 and K3. The overall rate constant K = . If E1, E2, and
𝐾2
E3 (energy of activation) are 60,30 and 10 KJ, respectively, the
overall energy of activation is:

a) 40
b) 400
c) 30
d) 60
Question Answer
1 B
2 A
3 B
4 B
5 B
6 D
7 A
8 B
9 B
10 C
11 A
12 C
13 D
14 D
15 A

Type equation here.

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