SAFETY DATA SHEET

Date of issue/Date of revision 17 December 2023

Version 18.01

Section 1. Identification
Product name : ZR-6320 GRN PAIL
Product code : SPZR6320XXBMB11B
Other means of : Not available.
identification
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Manufacturer : PPG Aerospace PRC-DeSoto

12780 San Fernando Road
Sylmar, CA 91342
Phone: 818 362 6711
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
substance or mixture
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 29.9%
(oral), 32.3% (dermal), 32.3% (inhalation)
GHS label elements
Hazard pictograms :

Signal word : Danger

Hazard statements : Causes damage to organs.
Precautionary statements

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Section 2. Hazards identification

Prevention : Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling.
Response : IF exposed: Call a POISON CENTER or doctor.
Photosensitive agents : In case of accidental eye contact, avoid direct exposure to the
sun or other sources of UV light as severe irritation including burns may result. These
reactions can be delayed – get medical attention if pain, irritation or blistering occurs
after contact. In case of accidental skin contact, avoid direct exposure to the sun or
other sources of UV light as severe irritation including burns may result. These
reactions can be delayed – get medical attention if pain, irritation, rash or blistering
occurs after contact.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Contains isothiazolinones. May cause allergic reaction. Sanding and grinding dusts may
elements be harmful if inhaled. Cannot be made nonpoisonous. May be fatal or cause blindness if
swallowed. Repeated exposure to high vapor concentrations may cause irritation of the
respiratory system and permanent brain and nervous system damage. Inhalation of
vapor/aerosol concentrations above the recommended exposure limits causes
headaches, drowsiness and nausea and may lead to unconsciousness or death. Emits
toxic fumes when heated.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : ZR-6320 GRN PAIL

Ingredient name % CAS number

Paraffin waxes and Hydrocarbon waxes ≥1.0 - ≤5.0 8002-74-2
methanol ≥1.0 - ≤3.5 67-56-1
Caseins ≥1.0 - ≤5.0 9000-71-9

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.

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Section 4. First aid measures

In case of accidental eye contact, avoid direct exposure to the sun or other sources of
UV light as severe irritation including burns may result. These reactions can be delayed
– get medical attention if pain, irritation or blistering occurs after contact.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
In case of accidental skin contact, avoid direct exposure to the sun or other sources of
UV light as severe irritation including burns may result. These reactions can be delayed
– get medical attention if pain, irritation, rash or blistering occurs after contact.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes damage to organs following a single exposure in contact with skin.
Ingestion : Causes damage to organs following a single exposure if swallowed.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. Vapors
from the chemical may accumulate in low or confined areas or travel a considerable distance to a source
of ignition and flash back.

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Section 5. Fire-fighting measures

Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
nitrogen oxides
phosphorus oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use
the material presents a respiratory hazard, use only with adequate ventilation or wear
appropriate respirator. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.

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Section 7. Handling and storage

Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Do not store above the following temperature: 50°C (122°F). Store in accordance with
including any local regulations. Store in original container protected from direct sunlight in a dry, cool
incompatibilities and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Store locked up. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Paraffin waxes and Hydrocarbon waxes ACGIH TLV (United States, 1/2023).
[Paraffin wax fume]
TWA: 2 mg/m³ 8 hours. Form: Fume
methanol ACGIH TLV (United States, 1/2023).
Absorbed through skin.
STEL: 328 mg/m³ 15 minutes.
STEL: 250 ppm 15 minutes.
TWA: 262 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 260 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
Caseins ACGIH TLV (United States).
TWA: 10 mg/m³, (Inhalable fraction) Form:
Dusts and mists
Key to abbreviations
A = Acceptable Maximum Peak S = Potential skin absorption
ACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitization
C = Ceiling Limit SS = Skin sensitization
F = Fume STEL = Short term Exposure limit values
IPEL = Internal Permissible Exposure Limit TD = Total dust
OSHA = Occupational Safety and Health Administration. TLV = Threshold Limit Value
R = Respirable TWA = Time Weighted Average
Z = OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
Consult local authorities for acceptable exposure limits.

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Section 8. Exposure controls/personal protection

Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to national
procedures guidance documents for methods for the determination of hazardous substances will
also be required.

Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
controls local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety glasses with side shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Gloves : polyethylene
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Green.
Odor : Not available.
Odor threshold : Not available.
pH : Not applicable.

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Section 9. Physical and chemical properties

Melting point : Not available.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 93.33°C (200°F)
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flammability : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1.02
Density ( lbs / gal ) : 8.51
Media Result
Solubility(ies) :
cold water Partially soluble

Partition coefficient: n- : Not applicable.

octanol/water
Viscosity : Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
VOC : 156 g/l
% Solid. (w/w) : 33

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Depending on conditions, decomposition products may include the following materials:
products carbon oxides nitrogen oxides phosphorus oxides

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Paraffin waxes and LD50 Oral Rat >5000 mg/kg -
Hydrocarbon waxes
methanol LC50 Inhalation Vapor Rat 64000 ppm 4 hours
LD50 Dermal Rabbit 15800 mg/kg -
LD50 Oral Rat 5600 mg/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Reproductive toxicity
Conclusion/Summary : There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
methanol Category 1 - -
Specific target organ toxicity (repeated exposure)
Not available.

Target organs : Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: gastrointestinal
tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.

Aspiration hazard
Not available.
Information on the likely routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
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Section 11. Toxicological information

Inhalation : No known significant effects or critical hazards.
Skin contact : Causes damage to organs following a single exposure in contact with skin.
Ingestion : Causes damage to organs following a single exposure if swallowed.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. Contains . methanol - Cannot be
made nonpoisonous. May be fatal or cause blindness if swallowed. Contains
isothiazolinones. May cause allergic reaction. Acrylate components of the mixture have
irritating properties. Prolonged or repeated contact with skin or mucous membrane may
result in irritation symptoms, such as redness, blistering, dermatitis etc. May cause
allergic skin reactions with repeated exposure. The inhalation of airborne droplets or
aerosols may cause irritation of the respiratory tract. Ingestion may cause nausea,
weakness and central nervous system effects. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. This takes into account, where known, delayed and
immediate effects and also chronic effects of components from short-term and long-
term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates

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Section 11. Toxicological information

Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
ZR-6320 GRN PAIL 4140.1 11983.3 N/A 119.8 N/A
methanol 100 300 64000 3 N/A

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
methanol Acute LC50 13 mg/l Fresh water Fish 96 hours

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
methanol -0.77 - Low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures

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14. Transport information

DOT IMDG IATA
UN number Not regulated. Not regulated. Not regulated.
UN proper shipping - - -
name
Transport hazard class - - -
(es)
Packing group - - -
Environmental hazards No. No. No.
Marine pollutant Not applicable. Not applicable. Not applicable.
substances

Additional information
DOT : None identified.
IMDG : None identified.
IATA : None identified.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not applicable.

to IMO instruments

Section 15. Regulatory information

United States
United States inventory (TSCA 8b) : All components are active or exempted.
United States - TSCA 5(a)2 - Proposed significant new use rules:
3(2H)-Isothiazolone, 2-methyl- Listed P-96-1250
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
No products were found.

SARA 311/312
Classification : SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
Composition/information on ingredients

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Section 15. Regulatory information

Name % Classification
methanol ≥1.0 - ≤3.5 ACUTE TOXICITY (oral) - Category 3
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 1
SARA 313
Chemical name CAS number Concentration
Supplier notification : methanol 67-56-1 1-5

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
California Prop. 65
WARNING: Reproductive Harm - [Link].

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 2 * Flammability : 1 Physical hazards : 0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Health : 2 Flammability : 1 Instability : 0
Date of previous issue : 8/16/2023
Organization that prepared : EHS
the SDS
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer

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Section 16. Other information

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.

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