18/09/2024 Code-A

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MM : 800 CHEMISTRY XI EQUILIBRIUM Time : 120 Min.

Topics Covered :
CHEMISTRY:
Thermodynamics
Entropy
Equilibrium
Homogeneous Equilibria
Salt hydrolysis and the pH of their Solution
Ionization Constants of Weak Acids and Weak Bases
The pH Scale
Applications of Equilibrium Constant
Factors Affecting Equilibria
Equilibrium in chemical process
pH of Buffer Solutions : Henderson- Hasselbalch Equation
Introduction
Buffer Solution
Solubility Equilibria of Sparingly Soluble Salts
Ionization of Acids and Bases
Physical Equilibrium, Liquid-vapour, solid-Liquid and solid -vapour equilibria
Acids, Bases and Salts
Relationship between Equilibrium constant (K), Reaction Quotient (Q) and Gibbs Energy (G)

CHEMISTRY

1. In the following
reaction at equilibrium 4. For an endothermic reaction the correct graph is
N2 (g) + 3H2 (g) ⇌ 2 NH3 (g); ΔH = –91.8 kJ/mol.
Formation of ammonia is favoured by

(A) Decreasing the concentration of H2

(B) Increasing the pressure (A)
(C) Addition of inert gas at constant pressure
(D) Increasing the temperature

2. What is pH of the resulting solution when equal volumes

of 0.01 M H2SO4 and 0.1 M HCl are mixed? (log 3 =
0.477)
(A) 3.25 (B)
(B) 2.21
(C) 2.98
(D) 1.22
3. Consider the equilibrium constants for the following
reactions
A + 2B ⇌ C; K1
2C ⇌ F2 + 2E; K2 (C)
The equilibrium constant (K) for the reaction
F + E will be
1
A+2 B ⇌ 2
2

(A) K1K2
−
−−
(B) K1 √K2

K1
(C) √K2 (D)

K1

(D) K
2
5. The number of acidic protons in H3PO3 are 12. Consider the following equilibrium constant for a triprotic
acid, H3PO4.
(A) 1
+
H3 P O4 ⇌ H + H2 P O– ; K1
4
(B) 3 + 2–
H2 P O– ⇌ H + HP O ; K2
4 4

(C) 2 2– + 3–
HP O ⇌ H +PO ; K3
4 4

(D) 0 Which of the following is the correct order?

6. At 298 K, pH of a saturated solution of a diacidic base (A) K3 > K2 > K1
X(OH)2 is 11. The solubility product (Ksp) of X(OH)2 is
(B) K1 > K2 > K3
(A) 5.0 × 10–10
(C) K1 > K3 > K2
(B) 7.0 × 10–9
(D) K2 > K1 > K3
(C) 7.0 × 10–8
13. Which among the following is a Lewis acid?
(D) 4.0 × 10–9 (A) BF3
7. Addition of inert gas at constant pressure in equilibrium (B) H2O
2SO2(g) + O2(g) ⇌2SO3(g), will
(C) R-NH2
(A) Decrease the volume of gaseous mixture
(D) NH2
(B) Decrease the total moles of gases
14. If pH of neutral water at 90°C is 5 then the ionic product of
(C) Shift the equilibrium in backward direction water at 90°C is
(D) Increase the partial pressure of SO3 (A) 10–7
8. For an exothermic reaction
(B) 10–10
A2 (g) + B2 (g) ⇌ A2 B2 (g)

Formation of A2B2 will be favoured at (C) 10–12

(A) High temperature and high pressure
(D) 10–14
(B) High temperature and low pressure
15. Among the following, select the salt of highest solubility
(C) Low temperature and low pressure Given [Ksp(NiS) > Ksp(MnS) > Ksp(ZnS) > Ksp(CdS)]
(D) Low temperature and high pressure
(A) NiS
9. pH of 0.01 M HCOONH4 aq. solution changes (B) ZnS
(A) On increasing dilution (C) MnS
(B) On decreasing dilution (D) CdS
(C) On adding NaCl in small amount 16. Sulphanilic acid is
(D) On increasing temperature (A) Arrhenius acid
10. K for triethyl amine is 6.5 × 10–5. Calculate K for (B) Lewis base
b a
triethyl ammonium ion? (C) α-amino acid
(A) 1.47 × 10–9 (D) Both (1) & (2)

(B) 1.54 × 10–10 17. For a diprotic weak acid (H2A) the value of K and Ka1 a2

are 3 × 10–6 and 3 × 10–10 respectively. The pH of its 1M

(C) 1.47 × 10–8 aqueous solution will be
(D) 1.54 × 10–8 (A) 5.55

11. Which of the following would cause forward shift in the (B) 3.74
given reaction? (C) 6.92
N2 (g) + 3H2 (g) ⇌ 2 NH3 (g) ; ΔH = –x kJ (D) 2.76

(A) Increase of temperature 18. At equilibrium PCl5(g) dissociates 50%, then the value of
(P + Kp) is (where P = total pressure at equilibrium)
(B) Decrease of pressure
(C) Addition of inert gas at constant pressure (A) 2P

(D) Addition of HCl gas (B) 4P

(C) P

(D) 4

3
P
19. For which of the following equilibrium, change in volume 26. Among the following combination of solutions, which
has no effect on equilibrium? cannot form acidic buffer?

(A) PCl5(g) ⇌ PCl3(g) + Cl2(g) (A) CH3COOH and NaOH

(B) CaCO3(s) ⇌ CaO(s) + CO2(g) (B) CH3COONa and HCl

(C) H2(g) + I2(g) ⇌ 2 HI(g) (C) CH3COOH and H3PO4

(D) C(s) + CO2(g) ⇌ 2 CO(g) (D) H3PO4 and NaH2PO4

20. The value of KC for the reaction 2A(g) ⇌ B(g) + C(g) is 4 × 27. All of the given species are Lewis acids except
10–2. At a given time the composition of reaction mixture (A) AlCl3
is [A] = [B] = [C] = 4 × 10–2 M. Then, which of the following
statement is correct? (B) BCl3

(A) Rate of forward reaction > rate of backward reaction (C) NH3

(B) Rate of forward reaction < rate of backward reaction (D) SnCl4
(C) Rate of forward reaction = rate of backward reaction 28. For the reversible reaction,
(D) Only forward reaction takes place NH4 HS (s) ⇌ NH3 (g) + H2 S (g) ,
If equilibrium pressure is 11 atm, then Kp will be
21. Conjugate base of H3PO4 is
(A) 121
atm
2

(A) H3PO2 4

(B) 55
atm
2

(B) PO
3−

4
4

(C) 121 atm2

(C) HPO4
2–

(D) H2 PO4
− (D) 121

2
atm
2

22. pH of 600 mL of 0.1 M HCl solution will be 29. 1 L aqueous solution of HCl of pH 3 is diluted with water
so that the pH of solution becomes 5. Volume of water
(A) 1 added to the solution is
(B) 2 (A) 10 L
(C) 3 (B) 100 L
(D) 4 (C) 1000 L
23. Ratio of concentration of acetic acid to sodium acetate (D) 99 L
required to get a buffer solution of pH of 5.76 will be (pKa
30. The conjugate acid of HPO 2−
is
of acetic acid is 4.76) 3

(A) 10 : 1 (A) H3PO4

(B) 1 : 10 (B) H3PO3
(C) 1 : 1
(C) H2 PO3
−

(D) 100 : 1
(D) PO
3−

4
24. On dilution, the pH of a strong acid is increased from 1 to
1.5. The change in [H3O+] of the acid is (given 10–1.5 = 31. If for the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g), KC is 2 ×
0.032)
1010, then the KP for the reaction at the same
(A) 0.068 M temperature T K is
(B) 0.032 M (A) 2 × 1010
(C) 0.028 M
(B) 2 × 1010 RT
(D) 0.018 M
10

(C) 2×10

25. If pKa of an acid is 4 then value of pKb of its conjugate RT

base is RT
(D) 2×10
10

(A) 3
32. For a hypothetical reaction
(B) 4
2A (s) ⇌ B (g) , ΔH > 0
(C) 10 partial pressure of B at equilibrium can be increased by
(D) 13 (A) Adding moles of A
(B) Decreasing the volume of the container
(C) Increasing temperature
(D) Adding catalyst
33. Given below are two statements: One is labelled as 37. Assertion (A) : HCl, HNO and H SO4 are equally
Assertion(A) and the other is labelled as Reason(R). 3 2
strong acids in water.
Assertion(A): For exothermic reactions, HP > HR
Reason (R) : Water is a stronger acid than alcohols.
Reason(R): For exothermic reactions,
Keq
2
> Keq
1
if T2 > T1 . Both assertion (A) and reason (R) are correct
In the light of the above statements, choose the most (A) statements and reason is the correct explanation of
appropriate answer from the options given below: the assertion.

Both Assertion & Reason are true and the reason is Both assertion (A) and reason (R) are correct
(A) (B) statements, but reason is not the correct explanation
the correct explanation of the assertion
of the assertion.
Both Assertion & Reason are true but the reason is
(B) Assertion (A) is correct, but reason (R) is wrong
not the correct explanation of the assertion (C)
statement.
(C) Assertion is true statement but Reason is false
Assertion (A) is wrong, but reason (R) is correct
(D)
(D) Both Assertion and Reason are false statements statement.
34. Equilibrium constant for H(g) ⇌
1
H2(g) + 1
I2(g) is 8. 38. If pH of a saturated solution of M(OH)2 is 10 then the
2 2

Equilibrium constant for H2(g) + I2(g) ⇌ 2HI(g) will be solubility product (Ksp) of M(OH)2 will be

(A) 64 (A) 2 × 10–11

(B) (B) 5 × 10–13

1

64

(C) 1

8
(C) 5 × 10–8

(D) 1 (D) 2 × 10–9

16

35. For a reaction, the variation of equilibrium constant (K) 39. If an aqueous solution at 25ºC has twice as many
○−
with temperature (T) was studied by plotting log K versus OH as pure water, its pOH will be
1/T. The plot obtained is shown in the figure. Hence
(A) 6.7
enthalpy change (ΔH) of the reaction is
(B) 7.3
(C) 7
(D) 6.98

40. Conjugate acid base pair among the following is

(A) H3 PO3 , HPO3

−

(B) −
H2 PO4 , H3 PO3

(C) HPO4
2−
,
3–
PO4

(D) H3 PO4 , HPO

2−

(A) + 2 cal 41. Given below are two statements: one is labelled as
Assertion A and the other is labelled as Reason R:
(B) – 2 cal Assertion: Unit of KP for 2SO3(g) ⇌ 2SO2(g) + O2(g) is
(C) + 4.606 cal atmosphere.
Reason: Atmosphere is SI unit of pressure.
(D) – 4.606 cal In the light of the above statements, choose the correct
36. If solubility of sparingly soluble salt A3Y in water is s answer from the options given below
mol/lit. then the value of its solubility product (Ksp ) is Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
(A) 27s4
Both Assertion & Reason are true but the reason is
(B)
(B) 3s5 not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(C) s3
(D) Both Assertion and Reason are false statements
(D) 3s4
42. The pKa of acetic acid and pKb of ammonium hydroxide
are 4.76 and 4.75 respectively. The pH of resultant
solution made by mixing 100 ml each of 0.1 M acetic acid
and 0.1 M ammonium hydroxide, is
(A) 3
(B) 7.005
(C) 6.5
(D) 14
43. 49. If concentration of F– in saturated solution of CaF is x
Conjugate acid of HPO is
2–

4
2
then solubility product of CaF2 will be
(A) H PO
2
–

(A) x3
(B) H3PO4
(B) 4x3
(C) PO 3–

4 3

(C) x

(D) HPO 2–

3
(D)
3
x

44. For the reaction

N2 (g) + 3H2 (g) ⇌ 2 NH3 (g) + Heat 50. If equal volume of two solution of strong acids having pH
The reaction will proceed in the forward direction on 2 and 3 are mixed then pH of resulting solution is [log
(5.5) = 0.74]
(A) Increasing both temperature and pressure
(A) 2.26
(B) Increasing temperature and decreasing pressure
(B) 2.74
(C) Decreasing both temperature and pressure
(C) 3.2
(D) Decreasing temperature and increasing pressure
(D) 1.2
45. The pH of a 0.25 M aqueous NaCN solution is (Given that
51. Which of the following is not correct expression?
pKb of CN– is 4.80)
(A) pKw = pH + pOH
(A) 8.7
(B) 10.5 (B) Kh =
Kw

Kb
(for NH4CN)

(C) 6.5 [ Salt ]

pH = pKa + log (For buffer of CH3COONa +
(D) 11.3 (C) Acid
[ ]

CH3COOH)
46. Haber-Bosch process for the manufacture of NH3 is
based on the reaction pH = 7 +
1
pK +
1
log C (For salt of weak acid and
(D) 2 a 2

catalyst strong base at 25°C)

N2 (g) + 3H2 (g) ⇌ 2NH3 (g)

ΔrH° = – 44000 Jmol–1 52. Given below are two statements : one is labelled as
Assertion (A) and the other is labelled as Reason (R):
KP = 12.5 atm–2 Assertion (A) : At equilibrium, concentration of reactants
Out of the following information choose the one which is and products become constant.
correct regarding the above reaction? Reason (R) : A catalyst does not alter the equilibrium
constant of a reaction.
The equilibrium constant KP increases with increase In the light of the above statements, choose the correct
(A)
in temperature answer from the options given below:
On adding H2, the equilibrium is shifted to right side Both Assertion & Reason are true and the reason is
(B) (A)
with an increase in entropy the correct explanation of the assertion

At equilibrium 2 Gm (NH3) = Gm (N2) + 3 Gm (H2) Both Assertion & Reason are true but the reason is
(B)
(C) where Gm represents the molar gibbs free energy of not the correct explanation of the assertion
the species enclosed within the brackets (C) Assertion is true statement but Reason is false
The use of catalyst helps increasing the rate of (D) Both Assertion and Reason are false statements
(D) forward reaction more than that of backward reaction
thereby increasing the yield of NH3 53. Which of the following salt undergoes cationic hydrolysis
?
47. Acidic salt(s) among the following is/are (A) NH4Cl
(A) NaH2PO2
(B) NaHCO3
(B) Na2HPO3
(C) NaNO3
(C) Na2HPO4 (D) NaCN
(D) All of these 54. K for a weak acid is 5 × 10–7 and its concentration is 0.2
a
48. The pH of a solution at 25°C that contains 10–10 M M, the pH of the solution will be
hydroxide ions (OH–) is (A) 4.2
(A) 2 (B) 3.5
(B) 10 (C) 5.1
(C) 4 (D) 2.8
(D) 14
55. A : Ionic product of water (Kw) increases with increase of 61.
For a reaction 2A(g) ⇌ B(g), equilibrium
temperature.
R : The degree of ionization of water increases with concentrations of A and B in one litre container
increase of temperature. respectively are 0.01 M and 0.02 M. If the volume of
solution becomes double then
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion (A) Equilibrium will shift in forward direction
Both Assertion & Reason are true but the reason is (B) Equilibrium concentration of B becomes 0.05 M
(B)
not the correct explanation of the assertion
(C) Equilibrium concentration of A remains 0.01 M
(C) Assertion is true statement but Reason is false
(D) Equilibrium constant will be 200 M–1
(D) Both Assertion and Reason are false statements
62. If 1 M weak acid solution HA is 1% ionized then
56. If K of NH is 2 × 10–5, then the K of NH + ion is percentage ionisation of 4M solution of the acid HA will
b 3 a 4
be
(A) 5 × 10–10
(A) 0.1%
(B) 2 × 10–10 (B) 0.2%
(C) 5 × 10–5 (C) 0.5%
(D) 4%
(D) 2 × 10–5
63. If K = 10–12 at a temperature t°C then pH of pure water
57. Solubility of AgCl in water will not change by the addition w
of at t°C is
(A) NaCl (A) 1

(B) AgNO3 (B) 6

(C) NH4OH (C) 7

(D) 12
(D) NaNO3
64. An example of an acidic buffer is
58. A : Solubility of AgI in NaI solution is less than that in pure
water. (A) Formic acid and acetic acid
R : AgI form complex with NaI.
(B) Sodium acetate and sodium chloride
Both Assertion & Reason are true and the reason is (C) Acetic acid and sodium acetate
(A)
the correct explanation of the assertion
(D) Ammonium hydroxide and ammonium cyanide
Both Assertion & Reason are true but the reason is
(B)
not the correct explanation of the assertion 65. The dissociation equilibrium of ammonia can be shown
(C) Assertion is true statement but Reason is false as 2NH3(g) ⇌ N2(g) + 3H2(g). The degree of dissociation
is ‘x’ and is negligible compared to 1. The expression
(D) Both Assertion and Reason are false statements relating the degree of dissociation (x) with equilibrium
constant Kp and total pressure P is
59. The pKa of a weak acid HX and pKb of a weak base BOH
are 4.76 and 4.75 respectively. The pH of the solution of 1

salt BX will be (A) (

16Kp

2
)
4

27P

(A) 8.005
1

(B) 7.32 (B) (

Kp

2
)
4

27P

(C) 7.005 1

(D) 6.008 (C) (

Kp

3
)
4

27P

60. If dissociation constant of a substituted benzoic acid is 1.0 1

× 10–5 then the pH of 10–2 M solution of sodium salt of (D) Kp 4

( )
27P

this acid will be

(A) 7 66. Pair of solutions which cannot form basic buffer, is

(B) 8.5 (A) NH4OH and KOH

(C) 9.4 (B) NH4OH and HCI

(D) 10 (C) NH4OH and (NH4)2SO4

(D) NH4OH and H2SO4

67. For the reversible reaction, 73. For equimolar solution of K2O, K2S and K2Se correct
A2(g) + 2B2(g) ⇌2 AB2(g) + heat. order of pOH is
Formation of AB2(g) will be favoured at
(A) K2O > K2S > K2Se
(A) High pressure and high temperature
(B) K2Se > K2S > K2O
(B) Low pressure and low temperature
(C) K2O > K2Se > K2S
(C) Low pressure and high temperature
(D) High pressure and low temperature (D) K2Se > K2O > K2S

68. Which among the following is a conjugate acid base 74. If solubility of substance is given as 'S' mole L–1 then
pair? which is the incorrect match for corresponding solubility
product?
(A) H2CO3 and CO 2 −

3
Salt Ksp
(B) H O and OH (1) Mg3(PO4)2 108S5
+–
3

(C) H PO and HPO

3 4
2 −

4
(2) MmAn (m + n)Sm+n
(3) Li3Na3(AlF6)2 2916S8

(4) PbCl2 4S3

(D)
(A) (1)
(B) (2)

69. If helium gas is added at constant pressure to the (C) (3)

following reaction at equilibrium (D) (4)
CO(g) + 3H
(g)
2
⇌ C H4 (g) + H2 O(g), then 75. Which of the following can act as Lewis base?

(A) Formation of methane will increase (A) CO

(B) Equilibrium shifts in backward direction (B) H2O
(C) No effect on equilibrium (C) OH–
(D) Activation energy of the reaction will decrease (D) All of these
70. pH of a neutral solution at 360 K is (Kw at 360 K is 3.6 × 76. Which one of the following is the strongest base?
10–13)
(A) H2 PO
Θ

(A) 7
(B) H2 PO
Θ

(B) 7 + log 2 3

(C) 7 – log 6 (C) H2 PO

Θ
4

(D) 7 + log 6 (D) All are equal

71. Which of the following statements is correct? 77. A : Degree of hydrolysis for NH4CN depends on
Kp is less than Kc for 2 NO2 (g) ⇌ 2 NO (g) + O2 (g) at concentration of salt.
(A) R : NH4CN is a salt of weak base and strong acid.
300 K
Partial pressure of O2 in the reaction, Both Assertion & Reason are true and the reason is
(A)
(B) the correct explanation of the assertion
2 Ag O (s) ⇌ 4 Ag (s) + O2 (g) at eq. is (Kp)1/3
2
Both Assertion & Reason are true but the reason is
(B)
The change in pressure will not affect the equilibrium not the correct explanation of the assertion
(C)
constant for PCl (g) ⇌ PCl (g) + Cl (g)
5 3 2
(C) Assertion is true statement but Reason is false
(D) Unit of Kc is mol L–1 for H2 (g) + I2 (g) ⇌ 2 HI(g) (D) Both Assertion and Reason are false statements

72. If for the reactions 78. Equal volumes of three aqueous solutions with pH values
11, 12, 13 are mixed in a vessel at 25°C. The OH– ion
A ⇌ B, Kc = 10, concentration in the mixture is
(A) 3.7 × 10–2 M
B ⇌ C, Kc = 5 and
(B) 4.9 × 10–3 M
C ⇌ D, Kc = 2 then Kc for the reaction A ⇌ D is
(C) 3.7 × 10–4 M
(A) 10
(D) 2.1 × 10–2 M
(B) 20
(C) 50
(D) 100
79. A : Reaction with Keq = 1 can go farthest for completion. 86. A : The solubility product of AgCl changes by the adding
R : If Keq = 1, then ΔGº of reaction is highly negative. AgNO3 in it.
R : AgNO3 supports dissolution of AgCl in aqueous
Both Assertion & Reason are true and the reason is solution.
(A)
the correct explanation of the assertion
Both Assertion & Reason are true and the reason is
Both Assertion & Reason are true but the reason is (A)
(B) the correct explanation of the assertion
not the correct explanation of the assertion
Both Assertion & Reason are true but the reason is
(C) Assertion is true statement but Reason is false (B)
not the correct explanation of the assertion
(D) Both Assertion and Reason are false statements (C) Assertion is true statement but Reason is false
80. Conjugate acid of PO –3 is (D) Both Assertion and Reason are false statements
4
(A) H3PO4 87. If for the reaction
2N OBr (g) ⇌ 2N O (g) + Br2 (g)

(B) H2PO4–
KC = 3 × 106, then the Kp for the reaction at the same
(C) HPO4–2 temperatures will be

(A) 3 × 106(RT)2
(D) HPO3–
RT
(B)
81. At 300 K, H2(g) + Cl2(g) ⇌ 2HCl(g) has an equilibrium
6
3×10

constant, Kc = 4.0 ×1031. At equilibrium, this reaction has

6

(C) 3×10

RT

(A) Very high concentration of HCl as compared to H2 (D) 3 × 106 RT

(B) Very low concentration of HCl as compared to Cl2 88. The pH of 0.01 M aqueous solution of a salt of weak acid
(C) Appreciable concentrations of Cl2 as well as HCl and strong base is (Ka of weak acidic = 10–4)

(D) Appreciable concentrations of H2 as well as HCl (A) 8

82. The minimum concentration of Ag+ ions required in order (B) 7

to initiate the precipitation of AgCl from a solution (C) 4
containing 0.004 mol L–1 of Cl– ion will be [Ksp of AgCl = (D) 9
1.8 × 10–10] 89. Identify the incorrect conjugate acid and conjugate base
of the given species
(A) 4.5 × 10–8 M
Conjugate Conjugate
Species
(B) 2.0 × 10–8 M acid base

(C) 3.8 ×10–7 M (1) NH3 NH–2 NH+4

(D) 4.2 × 10–6 M (2) H2O H3O+ OH–

83. At 27°C, N2O4(g) dissociates 40% into NO2(g) the
equilibrium vapour density of the mixture is (3) HSO–4 H2SO4 SO
2−

(A) 32.85 (4) HCO–3 H2CO3 CO

2−

(B) 40.26
(A) (1)
(C) 46
(B) (2)
(D) 72.41
(C) (3)
84. Which of the following mixture is a buffer solution?
(D) (4)
(A) NaCl + NaOH
90. The pH of resulting solution when equal volume of 0.01 M
(B) HCl + NH4Cl NaOH and 0.1 M CH3COOH are mixed (given pKa
(C) CH3COOH + HCl (CH3COOH) = 4.74 and log3 = 0.477) is

(D) NH4OH + NH4Cl (A) 3.79

85. Lewis base among the following is (B) 6.5

(C) 5.79
(A) CH4
(D) 4.74
(B) AlCl3

(C) B2H6

(D) PH3
91. Equilibrium which will shift in the forward direction on 97. For a reversible homogeneous gas phase reaction
increasing the volume of reaction vessel is a + 3b ⇌ 2c + d , if the concentration of b is tripled, then the

equilibrium constant
(A) PCl3 (g) + Cl2 (g) ⇌ PCl5 (g)

(A) Becomes nine times

(B) CaCO3 (s) ⇌ CaO(s) + CO2 (g)
th

(C) 2HI(g) ⇌ H2 (g) + I2 (g)

(B) Becomes (
1

27
) times

(D) 2NO2 (g) ⇌ N2 O4 (g) (C) Becomes 3 times

92. If the equilibrium constant for the reaction, (D) Remains same
N2(g) + 3H2(g) ⇌ 2NH3(g) is K, then the equilibrium
98. At t°C, K for water is 6.4 × 10–13. The pH of water at t°C
w
constant for the reaction, NH3 (g) ⇌
1

2
N2 (g) +
3

2
H2 (g) is will be
1 (A) 6.91
(A) K
2

(B) 5.90
−
−
(B) √K
(C) 6.09
(C) K2 (D) 5.15

99. The pH of an aqueous solution of 1.5 M of ammonium

1
(D) √K
acetate is (Given : pKa of CH3COOH and pKb of NH4OH
93. The variation of equilibrium constant (K) with temperature both are equal to 4.74 at 25°C)
is represented by
(A) 7

(A) (
d ln K
) = −
ΔH (B) 6
dT RT
P
(C) 9.45
(B) lnK = constant +
ΔH

RT
(D) 9

T2 [Link] on increasing the temperature, a saturated

(C) lnK2 − lnK1 = −
ΔH

R
∫ d(
1

T
) solution
T1

(A) Becomes unsaturated

(D)
ΔH
logK = constant − (B) Becomes supersaturated
T

94. Consider the following statements (C) Remains saturated

(a) HF is stronger acid than H2O (D) Becomes suspension
(b) BF3 is a Lewis acid
(c) Conjugate bases of weak acids are very strong [Link] 40 cm3 of N aOH , 50 cm
M 3 of H N O and 10
M
3
4 5

The correct statements are

cm3 of H C l solutions are mixed and the volume is
M

2
(A) (a) and (b) only made upto 500 mL, the pH of resulting solution is
(B) (b) and (c) only (A) 2
(C) (a) and (c) only (B) 3
(D) (a), (b) and (c) (C) 4
95. Aqueous solution of which salt involves cationic (D) 5
hydrolysis?
[Link] the equilibrium H O (s) ⇌ H O (l)
(A) NaCl 2 2

Which of the following statements is true?

(B) NaCN
(A) Change in pressure doesnot affect the equilibrium
(C) NaOCN
More of ice melts, if pressure on the system is
(B)
(D) NH4NO3 increased

96. If the pH of saturated solution of B(OH)3 at 298 K is 10 More of liquid freezes, if pressure on the system is
(C)
increased
then the solubility product of B(OH)3 in aqueous solution
is Melting point increases on increasing pressure at
(D)
equilibrium
(A) 3 × 10–18
[Link] is the pH of the resulting solution when 100 mL 0.1
(B) 3.3 × 10–17 M CH3COOH is mixed with 50 mL of 0.1 M NaOH
solution? (pKa of CH3COOH = 4.74)
(C) 27 × 10–27
(A) 4.74
(D) 8 × 10–9
(B) 5.04
(C) 4.44
(D) 9.37
[Link] the equilibrium, [Link] of the following solutions will have pH value more
SO3 (g) ⇌ SO2 (g) +
1
O2 (g) than 12?
2
M M

the molar mass at equilibrium was observed to be 60, S1 : 100 ml

10
KOH + 200 ml
10
H N O3

then the degree of dissociation SO3 would be S2 : 50 ml

M
KOH + 100 ml
M
H N O3
10 20

(A) 0.33 S3 : 50 ml
M

5
KOH + 100 ml
M

20
H N O3

(B) 0.66 S4 : 100 ml

M

10
KOH + 900 ml
100
1
H N O3

(C) 0.25 (A) S3

(D) 0.50
(B) S1
105.A : The ionisation of AgCl(s) in water is suppressed on
addition of NaCl. (C) S4
R : Common ion effect decreases the solubilty.
(D) S2
Both Assertion & Reason are true and the reason is
(A) 111. For pure water
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is pH increases and pOH decreases with rise in
(B) (A)
not the correct explanation of the assertion temperature
(C) Assertion is true statement but Reason is false pH decreases and pOH increases with rise in
(B)
temperature
(D) Both Assertion and Reason are false statements
(C) Both pH and pOH increase with rise in temperature
[Link] a catalyst is added to equilibrium then
(D) Both pH and pOH decrease with rise in temperature
Catalyst affects the activation energy of both the
(A)
forward and backward reaction equally 112.A : Oxo acids are those in which the acidic proton is on a
hydroxyl group with an oxo group attached to same atom.
(B) Catalyst changes equilibrium constant R : Carbonic acid is a strong dibasic acid.
(C) Catalyst changes energy of reactant molecules
Both Assertion & Reason are true and the reason is
(A)
(D) Catalyst changes energy of product molecules the correct explanation of the assertion

[Link] of 0.1 M NaOH solution is Both Assertion & Reason are true but the reason is
(B)
not the correct explanation of the assertion
(A) 1
(C) Assertion is true statement but Reason is false
(B) 12
(D) Both Assertion and Reason are false statements
(C) 6
[Link] sparingly soluble salts AB2 and XY have same Ksp.
(D) 13
Compare the solubility of two salts.
[Link] of the following is not a general characteristic of (A) XY is more soluble
equilibria involving physical process?
(B) AB2 is more soluble
(A) All the physical processes stop at equilibrium
All measurable properties of the system remain (C) Both have same solubility
(B)
constant (D) XY is 10 times more soluble than AB2
Equilibrium is possible only in a closed system at a
(C) [Link] aqueous solution of which salt will give
given temperature
highest pH?
(D) At equilibrium ΔG = 0
(A) NH4Cl
[Link] the equilibrium constant of a reaction is 2 × 103 at 25°C
(B) CH3COONa
then the standard Gibbs free energy change for the
reaction will be nearly (C) CH3COONH4
(A) – 2.5R × 298 (D) NaCl
(B) – 7.6R × 298 [Link] of a saturated solution of Mg(OH)2 is 10. The value of
(C) – 7.6R solubility product (Ksp) of Mg(OH)2 is
(D) – 5.1R × 298 (A) 5 × 10–8

(B) 5 × 10–9

(C) 5 × 10–13

(D) 5 × 10–11
[Link] an inert gas is added to the following equilibrium at [Link] combination(s) represent acid base reaction is/are
constant pressure, then
PCl5 (g) ⇌ PCl3 (g) + Cl2 (g)
(A) H2SO4 + CH3COOH

(A) Equilibrium constant (Kp) decreases (B) H2SO4 + HNO3

(B) More amount of PCl5 will be formed (C) CO2 + CaO

(C) More amount of PCl3 will be formed (D) All of these

(D) No effect on equilibrium is observed [Link] a MX3 type salt, if Ksp is solubility product, then
solubility will be
[Link] degree of dissociation of PCl5 is 50% at 400 K and
−−−
1.0 atm pressure for the gaseous reaction (A) √
Ks p

4
PCl (g) ⇌ PCl (g) + Cl (g) . Assuming ideal behaviour
5 3 2

the density of equilibrium gaseous mixture at 400 K and −−−

Ks p
(B) √
1.0 atmosphere will be (Atomic mass of P = 31.0 u) 27

(A) 4.85 g/litre −−−

(C) 3
Ksp
√
27
(B) 5.20 g/litre
−−−
(C) 4.24 g/litre (D) 4
√
Ksp

27

(D) 2.42 g/litre

[Link] of Na3AlF6 will be _____ (in terms of solubility)
[Link] of 0.05 M aqueous solution of weak acid HA (Ka = 4 ×
(A) 4s3
10–4) is
(A) 4.70 (B) 4s4

(B) 2.35 (C) 16s4

(C) 3.39
(D) 27s4
(D) 1.30
[Link] the reaction, PCl3(g) + Cl2(g) ⇌ PCl5(g); the initial
[Link] of the following statements is incorrect?
concentration of PCl3(g) and Cl2(g) are 'a' mol L–1, but
Weaker is the acid, greater is the hydrolysis constant the equilibrium concentration of PCl5(g) is twice than that
(A)
of its salt with strong base
of equilibrium concentration of PCl3(g). The equilibrium
As temperature increases, pH of pure water constant is
(B)
decreases
(A) 6 a
(C) pH is an extensive property
(B) 3 a
(D) On adding NaOH in basic buffer its pOH decreases
(C)
6

[Link] out the incorrect formula a

pH of salt of weak acid and strong base = (D) 3

(A) 1
7+
2
[pKa + log c]
[Link] pH of aqueous solution of ammonium formate is (pKa
Kf
of HCOOH = 3.6 and pKb of NH3 = 4.6)
(B) Keq = at any temperature
Kb
(A) 5.6
No. of moles of acid or (B) 6.5
(C)
Buffer capacity =
base added per litre of buffer
(C) 7.0
Change ​ in pH

(D) 8.5
Ka
(D) Kw =
Kb
= 10
−14
at 298 K [Link] of AgCl will be maximum in
[Link] which can act as an acidic buffer is (A) 1 M NaCl

(A) NaCl + CH3COOH (B) 1 M BaCl2

(B) NaOH + HClO4 (C) 1 M AgNO3

(C) CH3COOH + CH3COONa (D) 1 M NH3

(D) NaClO4 + HClO4 129.A : For a reversible reaction if Q > 1 then reaction always
moves in forward direction.
[Link] is the pH of the resulting solution when 100 mL 0.1 R : Equilibrium constant is independent of temperature.
M CH3COOH is mixed with 50 mL of 0.1 M NaOH
Both Assertion & Reason are true and the reason is
solution? (pKa of CH3COOH = 4.74) (A)
the correct explanation of the assertion
(A) 4.74 Both Assertion & Reason are true but the reason is
(B)
(B) 5.04 not the correct explanation of the assertion

(C) 4.44 (C) Assertion is true statement but Reason is false

(D) 9.37 (D) Both Assertion and Reason are false statements
[Link] solution of which among the following has [Link] buffer capacity of a basic buffer is achieved
highest [H+] ion concentration? when

(A) 0.1 M HCl (A) pOH = pKb + 1

(B) 0.1 M NaOH (B) pOH = pKb – 1

(C) 0.01 M H2SO4 (C) pOH = pKb

(D) 0.01 M Ca(OH)2 (D) pH = pKb + 1

[Link] buffer cannot be obtained by 137.A 0.2 M solution of monoprotic acid is 40% ionised. The
ionization constant of this acid is
(A) 50 ml, 0.1 M KOH + 100 ml, 0.1 M C6H5COOH
(A) 5.33 × 10–2
(B) 100 ml, 0.2 M NaOH + 50 ml, 1 M CH3COOH
(B) 4.7 × 10–4
(C) 500 ml, 1 M KOH + 500 ml, 1 M C6H5COOH

(D) 500 ml, 0.1 M NaOH + 500 ml, 0.5 M CH3COOH (C) 2 × 10–1

[Link] the following reaction at equilibrium (D) 3.23 × 10–2

2NO(g) + O2(g) ⇌ 2NO2(g)
[Link] vapour density of N2O4 at certain temperature is 23.
If helium is introduced at constant pressure then The degree of dissociation of N2O4 is
(A) Formation of NO2 will increase (A) 0.75
(B) Equilibrium constant of the reaction will change (B) 0.56
(C) Dissociation of NO2 will increase (C) 0.89
(D) There is no effect on equilibrium (D) 1
[Link] below are two statements : one is labelled as [Link] 3 COCH3 (g) ⇌ C2 H6 (g) + CO(g)
Assertion (A) and the other is labelled as Reason (R):
If the number of mole of CO(g) at equilibrium is 1
and
Assertion (A) : AlCl3 acts as a Lewis acid. 4

Reason (R) : In AlCl3 molecule central atom has total pressure at equilibrium is 180 mm Hg then KP is
(Initial mole of CH3COCH3 is 1)
incomplete octet.
In the light of the above statements, choose the correct (A) 120 mm Hg
answer from the options given below:
(B) 12 mm Hg
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion (C) 1.2 mm Hg
Both Assertion & Reason are true but the reason is (D) 45 mm Hg
(B)
not the correct explanation of the assertion
[Link] (A) : The reaction 2NO(g) + O2(g) ⇌ 2NO2(g)
(C) Assertion is true statement but Reason is false is favoured in the forward direction with increase of
(D) Both Assertion and Reason are false statements pressure.
Reason (R) : The above reaction is exothermic.
[Link] the pH of aqueous solution of 0.02 M dimethylamine is
Both assertion (A) and reason (R) are correct
12, then Kb of the dimethylamine is
(A) statements and reason is the correct explanation of
(A) 1.5 × 10–3 the assertion.
Both assertion (A) and reason (R) are correct
(B) 1 × 10–2 (B) statements, but reason is not the correct explanation
of the assertion.
(C) 1 × 10–4
Assertion (A) is correct, but reason (R) is wrong
(C)
(D) 0.5 × 10–2 statement.

[Link] equilibrium constant and for the reactions Assertion (A) is wrong, but reason (R) is correct
Kp Kp (D)
1 2
statement.
A ⇌ 2B and C ⇌ D + E respectively are in the ratio of 1 :
12. If the degree of dissociation of A and C is equal then [Link] of a solution obtained by mixing equal volume of two
the ratio of total equilibrium pressure for these equilibria solutions of pH 2 and 3, is approximately equal to (log55
respectively is = 1.74)
(A) 1 : 1 (A) 2.26
(B) 1 : 36 (B) 2.5
(C) 1 : 12 (C) 1.5
(D) 1 : 48 (D) 3.5
[Link] of the following salts will have the lowest pH in 149.A : Ksp is a constant value for any salt, at particular
water? temperature.
(A) NaCl R : Solubility of any salt is constant at a particular
temperature.
(B) CH3COOK
Both assertion (A) and reason (R) are correct
(C) NH4Cl (A) statements and reason is the correct explanation of
the assertion.
(D) CH3COONH4
Both assertion (A) and reason (R) are correct
[Link] 298 K, pH of 0.1 M NaOH is (B) statements, but reason is not the correct explanation
of the assertion.
(A) 13
Assertion (A) is correct, but reason (R) is wrong
(B) 14 (C)
statement.
(C) 1 Assertion (A) is wrong, but reason (R) is correct
(D)
statement.
(D) 2
144.A buffer solution cannot be prepared from a mixture of [Link] the degree of hydrolysis of 0.05 M solution of
sodium acetate at 298 K. (Ka of acetic acid = 1.8 × 10–5)
(A) Sodium acetate and acetic acid in water
(B) Ammonia and ammonium chloride in water (A) 1.04 × 10–4

(C) Sodium acetate and hydrochloric acid in water (B) 2 × 10–6

(D) Aniline and Anilinium ion in water
(C) 1.02 × 10–5
[Link] of the following conditions will shift the equilibrium,
2 A(g) + B(s) ⇄ C(g) + 10 J, in forward direction? (D) 5.5 × 10–10

(A) Adding more B [Link] an exothermic reaction, A (g) + B 2 2 (g) ⇌ A2 B2 (g)

(B) Increasing temperature Formation of A2B2 will be favoured at

(C) Increasing pressure (A) High temperature and high pressure

(D) Adding inert gas at constant pressure (B) High temperature and low pressure

[Link] pH of an aqueous solution, containing 0.1 M (C) Low temperature and low pressure
NaOH at 360 K is (D) Low temperature and high pressure
(A) 13
[Link] solubility of M(OH)2 in 0.20 M NaOH is (Given Ksp
(B) Greater than 13
of M(OH)2 = 4.0 × 10–15)
(C) Less than 7
(A) 10–13 M
(D) Less than 13
(B) 10–15 M
[Link] at which dissociation of pure water at 100ºC is
maximum (Kw = 1.0 × 10–12 at 100°C) is (C) 10–11 M

(A) 7 (D) 10–17 M

(B) 6
[Link] of the following factor will shift the given
(C) 8 equilibrium in forward direction?
+ −
AgCl(s) ⇌ Ag (aq) + Cl (aq)
(D) 5
(A) Addition of aqueous NaCl
[Link] equilibrium constant of a reaction is 10. If the volume
of the reaction flask is halved, then the value of (B) Addition of aqueous NH3
equilibrium constant will be
(C) Addition of aqueous AgNO3
(A) 10
(D) Addition of solid AgCl
(B) 20
(C) 100 [Link] one of the following pairs is not an acidic buffer?

(D) 5 (A) NaHCO3 and H2CO3

(B) NaHSO4 and H2SO4

(C) HCOONa and HCOOH
(D) NaCN and HCN
155.100 mL of 0.1 M H2SO4, 200 mL of 0.1 M HNO3 and 300 162.23 × 10–6 kg of sodium is added to 0.1 L of water. The pH
mL of 0.1 M NaOH are mixed. To this solution another of solution is
1400 mL of 0.1 M NaCl is added. The pH of the final
solution is (A) 2

(A) 2.7 (B) 8

(B) 3.3 (C) 10

(C) 2.3 (D) 12

(D) 11.7 163.100 mL of 0.04 M NaOH is mixed with 400 mL of 0.02 M

HCl solution. The pH of the resultant solution becomes
[Link] of a saturated diacidic base B(OH)2 is 10. The
(A) 4.6
solubility product of B(OH)2 at 25°C is
(B) 2.1
(A) 2 × 10–12
(C) 8.4
(B) 5 × 10–13 (D) 12.4
(C) 5 × 10–11 [Link] 298 K, pH of a saturated solution of a diacidic base
X(OH)2 is 11. The solubility product (Ksp) of X(OH)2 is
(D) 2 × 10–16
(A) 5.0 × 10–10
[Link] among the following is strongest acid?
(B) 7.0 × 10–9
(A) P(OH)3

(B) HOClO3 (C) 7.0 × 10–8

(C) B(OH)3 (D) 4.0 × 10–9

(D) SO(OH)2 [Link] 100 mL solution of pH = 2 is mixed with 100 mL of

solution of pH = 3, then pH of mixture will be
[Link] of inert gas at constant pressure in equilibrium
always causes same effect as of (A) 1.5

(A) Increasing volume (B) 2.26

(B) Increasing temperature (C) 0.39

(C) Increasing concentration (D) 3.5

(D) All of these [Link] value of equilibrium constant for the following
reaction at 300 K at constant pressure is
[Link] salt which undergoes cationic hydrolysis is CaCO3 (s) ⇌ CaO(s) + CO2 (g)

Given: ΔE° = +30 k cal and ΔS° = 100 Cal/K

(A) CH3COONa
(A) e2
(B) (NH4)2SO4
(B) e
(C) CH3COOK
(D) NaCN (C) 1

[Link] a sparingly soluble salt of type A2B3, Ksp and

1
(D) e
2

solubility(s) are related as

[Link] of the following equimolar solution of given salts
(A) Ksp = s5 will show the lowest pH in water?
(A) CH3COONa
(B) Ksp = 108 s5
(B) CH3COONH4
(C) Ksp = 72 s5
(C) NaBr
(D) Ksp = 6 s5 (D) (NH4)2SO4
[Link] the given equilibrium 168.100 ml of 0.2 M HCl is reacted with 400 ml of 0.1 M NaOH
2SO2(g) + O2(g) ⇌ 2SO3(g) + Heat. solution. The pH of the resultant solution becomes
The equilibrium reaction proceeds in forward direction (A) 1.4
when
(B) 12.6
(A) Oxygen is removed
(C) 8.4
(B) Oxygen is added
(D) 10.4
(C) SO3 is added
(D) Temperature is increased
[Link] the correct relation [Link] acid of NH – is
2
(A) ΔG = – 2.303 RT log K
(A) NH3
(B) ∘ 2.303
ΔG = log K
RT
(B) ⊕

NH2

(C) ΔG = – 2.303 RT log

1

K
(C)
⊕

NH4

(D) ΔG° = 2.303 RT log

1

[Link] the volume is kept constant and argon is added to the (D)
following equilibrium PCl (g) ⇌ PCl (g) + Cl (g) , then
5 3 2

equilibrium concentration of
[Link] a weak base, pKb is 4.8. If pOH of the solution of
(A) Cl2 increases weak base and its salt with a strong acid is 5.8, the ratio
of concentration of base to its salt with a strong acid will
(B) PCl5 decreases be
(C) PCl3 doubles (A) 0.1
(D) Cl2 remains unchanged (B) 3

[Link] one of the following condition will favour maximum (C) 6

formation of the product in the reaction at equilibrium (D) 10
−1
A2 ( s) + 2 B ( g) ⇌ C(g), Δr H = +50 kJ mol
2
[Link] the correct expression
(A) High temperature
(A) ΔG = –ΔG° + RT ln K
(B) Low pressure
(B) ΔG = ΔG° – RT ln K
(C) Adding more A2
(C) ΔG = ΔG° + RT ln Q
(D) Adding more C (D) ΔG° = RT ln K
[Link] the equilibrium, N (g) + 3H (g) ⇌ 2N H
2 2 if inert
3 (g),
[Link] the correct relation among the following
gas is added at constant pressure then
(A) ΔG = –RTlnK
(A) Equilibrium will shift towards forward direction
(B) ΔG = ΔG° + 2RTlnK
(B) Equilibrium will remain unaltered
(C) ΔG = ΔG° – RTlnQ
(C) Equilibrium will shift in backward direction
(D) ΔG = ΔG° + RTlnQ
Effect on equilibrium will depend on the type of inert
(D)
gas used [Link] volumes of acidic solutions having pH 3, 4 and 5

[Link] the following reaction at equilibrium, PCl5(g) are mixed. H+ concentration in mixture will be

⇌ PCl3(g) + Cl­2(g), if small amount of helium gas is (A) 1.85 × 10–5 M

added to the above equilibrium at constant volume then
(B) 3.7 × 10–4 M
(A) Dissociation of PCl5 increases
(C) 1.11 × 10–5 M
(B) Formation of PCl5 increases
(D) 1.85 × 10–4 M
(C) Equilibrium constant value increases
(D) There is no effect on equilibrium [Link] of the following set of salts will undergo anionic
hydrolysis only?
[Link] solubility products of two salts AB2 and C2D3 are
(A) NaCl, NH4Cl, CH3COONa, NaCN
same then the relation between solubilities of salt
C2D3(S') and AB2(S) is (B) NH4Cl, KCN, BaCl2, CuSO4

(C) HCOONa, CH3COOK, NaCN, KCN

−−−
(A) S = 27√2S
'

(B) S
'
= 108S
3
(D) NaBr, KI, CH3COONH4, NH4Cl

(C) 5 −−
S = √27S
−−−
'3 [Link] of 0.002 M HNO3 is

(A) 11 + log32
3 −−−−−
(D) S = √27S
'5

(B) 11 – log2
(C) –3 + log2
(D) 11 + log2
[Link] the temperature decreases for exothermic reaction, the 189.A : If we drop some radioactive sugar into saturated
value of equilibrium constant solution of non-radioactive sugar, then after some time
radioactivity is observed both in the solution and in the
(A) Increases
solid sugar.
(B) Decreases R : Equilibrium is dynamic in nature.
(C) Remains same Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
(D) Depends upon the total pressure of the system
Both Assertion & Reason are true but the reason is
[Link] the following homogeneous reaction at (B)
not the correct explanation of the assertion
equilibrium A(aq) + B(aq) ⇌ 2 C(aq). If the equilibrium
(C) Assertion is true statement but Reason is false
concentrations of A, B and C are 1 M, 2 M and 4 M
respectively then standard Gibbs energy change for the (D) Both Assertion and Reason are false statements
reaction at 27°C will be (R = 8.314 JK–1 mol–1) [Link] of the following mixture of solutions can behave as
a buffer solution?
(A) –7.48 × 103 log2 J
(A) 10 mL of 1 M HCl + 10 mL of 1 M NH4OH
(B) –7.48 × 103 ln2 J
(B) 10 mL of 1 M HCl + 10 mL of 0.5 M NH4OH
(C) 7.48 × 103 ln3 J
(C) 10 mL of 0.5 M HCl + 10 mL of 0.5 M NH4OH
(D) 3.25 × 103 ln2 J
(D) 10 mL of 0.5 M HCl + 10 mL of 1 M NH4OH
[Link] the reversible reaction by
PCl5(g) + heat ⇌ PCl3(g) + Cl2(g) [Link] the equilibrium constant for,
N2(g) + 3H2(g) ⇌2NH3(g) is K, then the equilibrium
The equilibrium shifts in forward direction by
(A) Adding catalyst constant for NH3 (g) ⇌
1

2
N2 (g) +
3

2
H2 (g) is

(B) Increasing pressure (A) −

−
√K

(C) Decreasing temperature

(B) K2
(D) Removing Cl2
1
(C)
[Link] one of the following pairs is not an acidic buffer?
√K

(D)
1

(A) NaHCO3 and H2CO3 2

K

(B) NaHSO4 and H2SO4 [Link] standard Gibbs energy change for the conversion of
oxygen to ozone at 300 K is [Given that Kp for the change
(C) HCOONa and HCOOH
3O (g) ⇌ 2O (g) at 300 K is 2.5 × 10
–30 (atm)–1/2 and
2 3
(D) NaCN and HCN
log105 = 0.699]
[Link] which value of equilibrium constant, reaction
(A) 170.08 kJ
proceeds nearly to completion?
(B) 178.28 kJ
(A) K = 0.1
(C) 182.48 kJ
(B) K = 1
(D) 189.38 kJ
(C) K = 10
(D) K = 1000 [Link] ionization constants of three monobasic weak acids 1, 2
and 3 are K1, K2 and K3 respectively, which are related
[Link] of the following is least likely to behave is Lewis as K1 > K2 > K3, then equimolar aqueous solution of
base? which acid has highest pH?
(A) OH– (A) 1
(B) H2O (B) 3

(C) NH3 (C) 2

(D) All are having equal pH
(D) BF3
[Link] will be the pH of solution obtained by mixing 25 ml
[Link] aqueous solution of which compound will of 0.2 M HCl with 25 ml of 0.2 M Ba(OH)2?
have highest pH?
(A) 7
(A) NaNO3
(B) 1
(B) NH4Cl
(C) 13
(C) CaCl2
(D) 14
(D) Na3PO4
[Link] activation energy of a reaction for forward direction is [Link] reaction, N 2 (g) + 3H2 (g) ⇌ 2NH3 (g) is in equilibrium.
greater than backward direction then If the reaction mixture is compressed to 1
rd of the original
3

(A) ΔH = 0 volume then

(B) ΔH < 0 (A) More of ammonia will be formed
(C) ΔH > 0 (B) Ammonia will dissociate back into N2 and H2
(D) ΔH > Ea (forward) (C) Equilibrium constant of the reaction will change
[Link] the following reaction AB(g) ⇌ A(g) + B(g) , AB is (D) There will be no effect on equilibrium
rd dissociated at a total equilibrium pressure of P. P is
1

3 [Link] of the following is a basic buffer?

related to Kp by which one of the following options?
(A) ​
N H4 OH + N H4 N O3

(A) P = Kp
(B) N H4 OH + N H4 C l

(B) P = 8Kp (C) C H3 C OOH + C H3 C OON a

(C) P = 4Kp (D) Both (1) and (2)

(D) P = 3Kp [Link] litre of water contains 10–7 moles of H+ ions.
[Link] solubility of M(OH)2 in 0.20 M NaOH is (Given Ksp Degree of ionisation of water is

of M(OH)2 = 4.0 × 10–15) (A) 1.8 × 10–7 %

(A) 10–13 M (B) 0.8 × 10–9 %

(B) 10–15 M (C) 3.6 × 10–9 %

(C) 10–11 M (D) 3.6 × 10–7 %

(D) 10–17 M