Class: 9th (CO-IIT) JEE – MAIN Date: 14-06-2025

Time: 3 hrs WTM-02_PAPER-A Max. Marks:300M

INITIAL KEY
Mathematics
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans. 1 2 1 3 4 3 2 3 1 4
Q.No. 11 12 13 14 15 16 17 18 19 20
Ans. 3 2 4 4 4 3 2 4 1 2
Q.No. 21 22 23 24 25
Ans. 1 2 0 8 2

Physics
Q.No. 26 27 28 29 30 31 32 33 34 35
Ans. 1 2 2 3 4 3 2 3 2 3
Q.No. 36 37 38 39 40 41 42 43 44 45
Ans. 4 4 1 1 1 2 4 1 3 4
Q.No. 46 47 48 49 50
Ans. 4 2 2 1 2

Chemistry
Q.No. 51 52 53 54 55 56 57 58 59 60
Ans. 1 2 4 3 3 1 2 4 4 1
Q.No. 61 62 63 64 65 66 67 68 69 70
Ans. 3 2 3 3 3 2 3 1 2 3
Q.No. 71 72 73 74 75
Ans. 4.6 84 4 0 5

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MATHEMATICS SOLUTION
1. If  and  are the roots of ax 2  bx   0, then find the roots of the equation
2
ax 2  bx  x  1  c  x  1  0
1
ax 2  bx  x  1  c  x  1  0
2 2
 x   x   x   x 
  b   c  0 , or   b  c  0
 x 1  x 1 x x 1  x 
x x
Now, , are the roots of ax 2  bx  c  0 , then,   and  
1 x 1 x
   
 x  and x  , Hence, , ,are the roots of the Eq. i  .
 1  1  1  1
2. Here, a  1, b  2 m  1 and c  m  5
2
D  b 2  4ac  4 m  1  4 m  5   4 m 2  3m  4  
 D  4 m  4 m  1 and here a  1  0
i  b  0 and D  0 ,  2 m  1  0 and 4 m  4 n  1  0
 m  1and m   , 1   4,   ,
m 
3.   
Let y  x 2  14x  9 / x 2  2x  3 
   
 y x 2  2x  3  x 2  14x  9 ,  x 2y  2xy  3y  x 2  14x  9
 1  y  x 2  2x  7  y   3  3  y   0
Now, we see that the above equation quadratic with x as the variable.
The equation is in the form ax 2  bx  c  0
Now, we know that for real value of x , b 2  4ac  0.
2
 2  7  y    4 1  y   3  3  y   0 ,  y 2  y  20  0 ,   y  4  y  5   0
Hence, we see that the solution of y lies in the range  5,4.
4. a  1, b  b and c  1,   b 2  4ac ,   b 2  4
 0  b 2  4  0 , b   2,2
5. Clearly from given figure
b
a  0,c  0 , Also 0 b 0
2a
So, abc  0 , Also f  1  a  b  c  0, f  3   9a  3b  c  0
1 a b
Clearly f    0    c  a  3b  9c  0
3 9 3
 1  a b
Also f    0    c  0  a  3b  9c  0
 3  9 3
Now verify alternatives.
6.  x2 1  4  x2  3 ,  x2 1 4  x2  0   
  
 x2 1 x2  4  0 ,  1  x2  4

1  x 2  2 ,  1  x  2
x   2, 1  1,2

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7. tan2   2 tan   8 t 2  2t  8
Let y  , y 
tan2   4 tan   5 t 2  4t  5
2
 y  1 t  2 1  2y  t   8  5y   0 , Clearly, D  0
2 2
4 1  2y   4  y  1 8  5y   0 , 1  2y    y  1 8  5y   0
9y 2  17y  9  0 , Clearly, D  0
Thus it is true for all y, Hence, the range =R
Conceptual
8.
9. Conceptual
10. We have, 3x 2  5 x  6  1.
 3x 2  5 x  6  3 ,  x 2  5 x  6  1
2
 x  5 x  6  0 ,   x  2 x  3   0
 x  2, 3 ,  x  
Hence the solution set is  .
11. x   0,3 , f  0   3, f 1  4, f  3  0 ,  f  3  f  0
 y will take all the values from minimum to f  3 . y   4,0
12. Conceptual
13. 1 log 7 1 3
We have, 3 log 3 7  3 3   ,   7  1 3
3
14. 5x  2x  7  0; 5x 2  5x  7x  0  x  15x  7   0
2

15. x 2 3
 5 2 6 x2 3
x2 3  1

We have, 5  2 6     10.  5  2 5   
 2
 x 3
 52 6 
 10.
x2 3 1 1 x 2 3

 52 5  
x2 3
 10.  a 
a

 10, a  5  2 6 
5  2 6 
10  100  4 10  4 6
 a 2  10a  1  0 ,  a    5k  2 6
2 2
x2  3
When a=5+2 6 ,  5  2 6   
 52 6 
 x 2  3  1,  x 2  4 ,  x  2
x2 3 1

When a=5-2 6 ,  5  2 6 x 2  3  5  2 6 ,  5  2 6      
 52 6 
 x 2  3  1 ,  x 2  3  1 ,  x 2  2 ,  x   2
Hence the solution set is 2,  2, 2,2  
16. x 
   0 ,  ii   a  10,   16,   b  9
i  f
k 
x  ax  b  x 2  10x  9; x  1,9
2

17. Since  , ,are the roots of equation x 2  3x  5  0

So,  2  3  5  0 ,  2  3  5  0
 2  3  5 ,  2  3  5
  
Putting in  2  3  7 &  2  3   7 ...............  i  

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5  7, 5  7 , 2 and 2 are the roots.

 The requirede equation is
x 2  4x  4  0
18. 
We know that tan  2 1
8
Irrational roots always occur in conjugational pairs
 
Hence if one root is 1  2 , the other root will be 1  2 , Equation is  
 x   1  2   x   1  2   0  x 2 2x  1  0
19. 2
a  b  x 2  c  a   4 a  b b  c   0  c  a   4ab  4b 2  4ac  4bc  0
2

2 2 2
 c  a   4ac  4b c  a   4b 2  0  c  a   2.  2b c  a    2b   0
2
 c  a  2b   0  c  a  2b  0  c  a  2b
Hence. a,b,c are in A.P
20. loge X  p  a p  x  a = x1 P , similary bq  x 2  b  x 2 q
 1 21
   1 1
Now, log x ab  log x x 2 q  log x x  p 42
 
2p q
21. x x Y Y
log e x  log e Y  a  log e  a   e a , log e y  log e Z  b  log e  b   eb
y y Z Z
Z Z
log e Z  log 3 X  c  log 3 c   ec
X X
b c c a a b a b c   b c a   c a b 
 
 ea  
 eb  ee  , e  e0  1
22. loga x=p  a p  x  a  x 1 p , Similarily bq  x 2  b  x 2 q
 1 2 1
   1 1
Now,log x ab  log x x 1 p x 2 p  log x x  p q 2
 
2p q
23. Conceptual
24. 1 4
let log x4  t  x  4t ,  3
5  4t 1  t
 1  t   4  5  4t  
  3  ,2t 2  3t  1  0, 2t 2  3t  1  0,  2t  1 t  1  0

  5  4t 1  t  
1
t  1 t  x  4 x  2 , A  4  2  6 , B  2m  3 , 3n  4
2
mn 2
2  2 , B  2
Then A+B = 6+2 = 8
25. A.M  G .M
log a log b
log ab  logab  log ba log ab , log a  logba  2 
log b log a
 2 , Min  2

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PHYSICS SOLUTIONS
26. Let volume of the spherical balloon =V
4
V  r 3
3
Since volume changes at a constant rate,
dv d 4 3 4 dr 3 4 dr
 k   r   k ,   k ,  3r 2 k
dt dt  3  3 dt 3 dt
27. 4 dx 4 4 2 4 2
2 x   loge x 2  log e  log e  loge 2  log e
28. m  m2
tan   1
1  m1m2
29.

 
2 2  1
a b  10    6    210  6   1    100  36  60  76
 2
b
 sin   6  sin   6  3 3 3 3
Tan   ,  2  tan 
p  a cos  10  6 cos1 6 7 7
10 
2

30.
 sin  sin 
tan   , tan   ,
P   cos  p  2 cos 
1
p  cos   0 ,1  cos   0 , cos   ,   1
2
31.

     
R  a  b , R  a  b , R 2  a 2  2Ra cos150  b 2
4  b2 , b  2

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32. R R2
R 2  a 2  b2 ,  a b ,  a  b 
2 2
R2 1
2 R b
2
2 R 2  b2 2
 a  b  ,  a  b    ab  b 
2 2 2
R 2  b2
2
 
 a 2  b 2  2ab, a 2  b 2  2 a 2  b 2  2ab  2a 2  2b 2  4ab

a 2 b2
a 2  b 2  4ab  0 , a 2  b 2  4ab ,  4
ab ab
a b
  4
b a
33. A 2  B 2  2 ABCos  C 2
A 2  B 2  2 ABCos  D 2
_________________________________
2 A2  2 B 2  C 2  D 2

 C 2  D 2  2 A2  B 2 
34. R 2  16  9    (1)
R 2  12  16  9  24Cos    (2)
From Equation (1) and (2)
12  24Cos
  60 0
35.

From diagram p  12  12  2
36. 12  12  12  2 cos     120 0
R 2  12  12  2 cos   2  1   1200 
R 3
37. F 2  F12  F22  2F1F2 cos  _____ 1
4F 2  F12  4F22  2F1F2 cos  __  2 
4F 2  F12  F22  2F1F2 cos  ____  3 
F12  4F22  4F1F2 cos    2  F22  2F1F2 cos  , 3F22  6F1F2 cos 
F2
F2  2F1 cos  cos    , 4F 2  F12  2F22
2P1
 F 
4 F12  F22  2F1F2 cos    F12  2F22 , 4 F12  F22  2F1F2  2   F12  2F22
 2F1 
2
F 2 F1 2
3F12  2F22 , 12   , 4F 2  F12  2F22
F2 3 F2 3

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2 2 2F2
 F  2F22 F1 
3 2 3
2
8 2 F 3 F2 3
4F 2  F2 , 2
2
  , F1 : F2  3  2, F2  F 3 2
3 F 2 F 2
 F1F2  F  2  3 2
38. F1  F2 7

F1  F2 3
3F1  3F2  7 F1  7 F2
10F2  4F1
F1 10
  F1 : F2  5 : 2
F2 4
39. R 2  a 2  b 2  2 ab cos 
1 2
cos    
2 3

As magnitudes of a,b and R are same, then the angle between R and a is,
3
40. A  B  4iˆ  3 ˆj  2kˆ
A  B  4 2  32  2 2  29
41.

42. dx dy
 3t 2   1  4t    2 
dt dt
 2 / 1
dy 4t 4
  t
dx 3t 2 3
dy 4
At t  1, 
dx 3
43. dx 2
 t  5t  6
dt
dx
When  0, then t  2 (or ) 3
dt
d 2x
 2  2t  5
dt
d 2x
At t=2,  1
dt 2
d 2x
At t=3,  1
dt 2
 1
44. 
 A ij
n  
A 2
45. y
y  3x  1  1  3 , x   5  3x  y  5  y  3 x  5
3

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m 2  3 , m1  m 2
46. sin  3 3
 ,tan   ,3sin 2  4cos 2
cos  4 4
 2 tan    1  tan    2 tan    1  tan  
 3   4 , 3   4 
 1  tan    1  tan    1  tan    1  tan  
3  9 
6  1
 4 4 16  , 18 16 7 
72 28

9   
1 1  9  
4 25
 4  25 25
16  16   25 
47. Conceptual
48. dy x 2

dx 2
dy
At x  2 , 2
dx
49. 2  2   1  5   25  2  1
50. y 5  32  y  2

CHEMISTRY SOLUTIONS
6 2.5 2 0 4 6 4 4
51. H 2 S2 O7 , Na2 S4 O6 , Na2 S 4 O3,S8 , S O 2 , S O42 , S O32 , HS O4
6 4 2 2 6 4 2 6
H 2 S O5 , H 2 S O3, S C2 , H 2 S , H 2 S O4 , S O2 , H 2 S , H 2 S2 O8
53. In oxidation, there is decrease in oxidation number. Oxidant is a substance which
increases the oxidation number of other substance and Reductant or reducing
agent is a substance which decreases the oxidation number of other substance. In
oxidation, there is increase in oxidation number.
3 o
56. 3CuO  2NH 3  N 2  3H 2O  3Cu

6e 

Loss of 6 electrons for 1mol of N2

57. Here 3 atom of the metal combines with w atoms of N Hence, the formula of the
compound  M 3N 2 Suppose the atomic weight of metal  X . 28g of nitrogen
combines  3 Xg metal From question, 28g nitrogen combines  72g metal
3X  72 , So X  24
Atomic weight for metal =24
c
58. a CN   b NO 3  c H   a  b  NO  a CO 2  H 2O
2
Ion Electron method (Oxidation Half)
33H 2O  CN 23  NO 22  CO22  6H   7e 
3e   4H   NO32  NO 2  2H 2O  reduction half  7
 3CN   7NO3  10NO  3CO2  5H 2O
c
 5  c  10
2
 a ,b,c    3,7,10 

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(Mass of electron=
59. 9.108  10 31 kg .Avogado number = 6.023  1023 
As mass of one electron =9.108  10 31kg , So, 1kg of electrons =1 9.108  1031
1031 1031 23 108
 mol ,  mol ,  mol
9.108  6.022 9.108  6.022 9.108  6.022
60. Balancing according to oxidation number method
61. KClO3 on heating decomposed to give KCl and O2 and the chemical reaction
involved is:
Heat
2KClO3  2KCl  3O2
2mol KCIO3 on heating gives 3 mol oxygen and oxygen being a gas escapes the
reaction mixture .The loss in weight is equal to the weight of oxygen evolved.
245g K ClO3 will give 96. Oxygen. Molar mass of KClO3  122.5 g mol 
96
Percent loss in weight   100  39.18%
245
62. AB2C3 :  6  2  1  3  2  2 AB2C2 :  6  2  1  2  2  0
ABC3 :  6   1  3  2  1 ABC2 : 2  6   1  2  2  7
65. 3Ca OH 2  2H 3PO4  Ca3  PO4   H 2O 
3mole 2moles
1mole 1mole
 Ca OH 2 is limiting reagent
1
number of moles of Ca 3  PO4 2 formed = moles
3
28
66. N 2O 3 , % N   100  36.8%
76
67. 18g H 2O contains 2gH
 0.72g H 2O contains 0.08g H , 44g CO2,contains 12g C
0.84 0.08
C : H  : ,  0.07 : 0.08  7 : 8
12 1
 Empirical formula =C7H 8
 
68. 4Nn 0 
8e
4Zn 2   oxidation  N 5 
8e
N 3   reduction 
Insert these coefficients in the reaction equation
4Zn  NO3  H   4Zn 2  NH 4  H 2O
Place required coefficients for molecules that do not participate in the redox
process. Since the oxygen atoms on the reactants side are 3, we multiply the water
molecule coefficient by 3. To equate the hydrogen atoms on the sides, we multiply
the reactant hydrogen ion by 10.
4Zn  NO3  10H   4Zn 2  NH 4  3H 2O
69. Identify the limiting reagent.
We have:
K 2SO4 : 0.7 moles,  BaCl 2 : 0.9 moles
Since the ratio is 1:1 the reactant with the smaller number of moles will be the
limiting reagent. Here

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K 2SO4 :  0.7 moles  is less than BaCl2  0.9 moles  , so K 2SO4 is the limiting
reagent.
Calculate the moles of BaSO4 precipitated.
From the stiochiometry. 1 mole of K 2SO4 gives 1 mole of BaSO4.
So, 0.7moles of K 2SO4 0.7moles of BaSO4.
Final Answer
0.7 moles of BaSO4 will precipitated
 y y
73. C x H y  g    x   O2  g   H 2O l  , V 6V 
 4 2   Vx  4V

 y  y
 x  4 , since 1 V O 2  6  VC x H y ,  V  x    6V ,   x    6
 4  4
y
 4   6,  y  8
4
74. In amalgams metals will has 'zero' oxidation states.

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