PENGEMBANGAN BATERAI LITHIUM ION

UNIVERSITAS SEBELAS MARET

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 BEVs PHEVs
Plug-in
Battery
Hybrid
Electric
Electric
Vehicles
Vehicles
HEVs
Hybrid
Electric
Vehicles

[Link]
Battery Capacity: 53.2 kWh, Range:410.0 kM
BYD focuses mostly on the production of
prismatic LiFePO4 battery cells
Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 “The largest market for
lithium-ion batteries LIB is and
will remain electric vehicles,
mainly cars, from 2020-2030.”
-idtechex Forecast

Image Source: Avicenne Energy

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 Active
Raw Li Ion Battery
Materials
Materials Cell Assembly
Processing

Cell Pack Product

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
[Link]

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 Low Cost High Low Cost
materials Performance Battery

RESEARCH SCOPE

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
SINTESA AKTIF MATERIAL

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 ❑ Nickel-rich cathode material (NCA) (LiNixCoyAlzO2) batteries have superior performance and
lower price compared to commercially established LCO batteries

❑ Develop process of Solid-state and Co-Precipitation using technical grade material

❑ Comparable with commercial material

NCA-Solid State and Co-Precipitation

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
❑ As-prepared NCA samples exhibit a layered -NaFeO2-like hexagonal structure (space group: R_3m).
❑ Highly crystalline peaks are in good agreement JCPDS card no. 87-1562, with no observable impurities phase.
❑ The peak splits of 006/102 and 018/110 could be clearly observed in both samples, hence it could be
concluded that the NCA-PC and NCA-SS have a well-ordered layered structure
❑ All samples have nano-sized to submicron-sized primary particles which agglomerate to form larger spherical
secondary particles.
❑ NCA-SS secondary particles show a smoother morphology and denser sphere compared to NCA-CP particles
due to the morphology of raw materials, especially Ni(OH)2, which also has a spherical shape.
❑ The tapped density of NCA-CP is 1.93 g/cm3, while the tapped density of NCA-SS is 2.17 g/cm3.
Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 ❑ In the formation phase, the coulombic
eficiency of NCA-CP, NCA-SS, and NCA-
Commercial is 69.36%, 69.19%, and
72.97%, respectively.
❑ About 30% capacity loss is attributed to
solid electrolyte interphase (SEI) formation
on both the cathode and anode side. The
dierence of NCA-CP and NCA-SS
coulombic eciency is insignificant;
however, the value is slightly lower than
the commercial NCA.
❑ The initial specific discharge capacity of
NCA-SS and NCA-CP is similar; however,
the value is also slightly lower than the
commercial NCA.

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 ❑ Sample NCA-SS and NCA-CP have a similar rate performance behavior and are relatively comparable to
commercial NCA. Surprisingly, at a higher rate, NCA-SS and NCA-CP are superior compared to commercial
NCA.
❑ NCA-CP and NCA-SS have similar cycling behaviors for 100 cycles at 1 C’ rates and have a capacity
retention of 84.4% and 86.3%, respectively. Overall, the cycle performance of NCA-CP and NCA-SS is
comparable to the commercial NCA.
- Purwanto A., Yudha C.S., Ubaidillah U., Widiyandari H., Ogi T., Haerudin H. Materials Research Express 5, 2018, art no 122001
- Yudha, C.S., Muzayanha, S.U, Widiyandari, H., Iskandar, F., Sutopo, W., Purwanto, A., Energies 12(10), 2019 pages 1886.1-14
 ❑ Simple Equipment
❑ Fast
❑ Continuous
❑ Produce material with good
characteristics

NCA-Flame Spray Pyrolisis

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
❑ After 20 cycles, all samples exhibit good coloumbic efficiencies
❑ NCA9 has the most stable capacity with capacity retention of 89% while NCA3, NCA6
and NCA12 sample capacity retention is 63%, 71% and 76% respectively.

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 ❑ Recycling of Li-Ion battery waste
❑ Fast, efficient and easy processing
❑ High specific discharge capacity of recycled NCA
❑ Reuse for active materials

Muzayanha S.U., Yudha C.S., Nur A., Widiyandari H., Haerudin H., Nilasary H., Fathoni F., Purwanto A., Metals 9, 2019, 615

NCA-Recycling Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 ❑ Low cost of raw materials (technical grade)
❑ High specific capacity of NMC
❑ Comparable with commercial material

NMC-Co Precipitation Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 IMPROVING CATHODE PERFORMANCE
❑ Internal resistance plays important role
❑ Controlling internal resistance enhance battery performance
❑ Densification, additive addition and welding configuration

Purwanto, A.,Jumari, A., Nizam, M., Widiyandari, H., Mohamad, A. A., Materials Research Express Volume 5 Issue 4, April
2018, Art no. 045512
❑Improving zero strain anode material via additive
❑Lifecycle for more than 20 years
❑Fast charging (6 min)
❑High power density (10C)

LTO-ENHANCING BATTERY LIFE CYCLES

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
Proses Assemby Baterai Li-Ion

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
Fasilitas Pilot Plant
❑ Mencampur material
aktif, binder, bahan
konduktif dan bahan
tambahan lain

❑ Untuk bahan anoda dan

katoda

❑ Proses mixing pada

kondisi vaccum
(menghilangkan gas
buble yang akan
mempengaruhi film)

Unit Mixing
❑ Digunakan untuk coating
slurry dari unit mixer

❑ Parameter yang perlu

diperhatikan: temperature,
coating speed, panjang
coating per sell

Unit Coating
❑ Digunakan untuk
memadatkan elektroda

❑ Parameter yang perlu

diperhatikan: roller gap,
speed

Unit Press
❑ Digunakan untuk membuat
jelly roll

❑ Parameter yang perlu

diperhatikan: Ketepatan
feeding, kebersihan dari
debris, kecepatan

Unit Winding
❑ Digunakan untuk mengisi
elektrolit

❑ Parameter yang perlu

diperhatikan: jumlah
elektrolit, kondisi chamber

Unit Pengisian Elektrolit

❑ Formation dan grading
digunakan untuk
mengaktifkan dan memilah
baterai

❑ Parameter yang perlu

diperhatikan: kondisi
parameter formation dan
grading, waktu aging

Unit Formation dan Grading

Aplikasi Baterai Li-Ion
 Motor • Hub motor
Listrik • 350Watt

• LiFePO4
Baterai
• 36V 7,2Ah

Jarak • 45km (Pedal Assist)

tempuh • 30km (full Throotle)

Sepeda Listrik Uns Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
 Unjuk kerja
baterai NMC

Rangkaian baterai NMC 10s2p dan BMS

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
kendaraan listrik Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
[Link]
KESIMPULAN

 Fabrikasi sel baterai lithium terdiri dari penyiapan bahan baku, coating,
calendaring, slitting, electrolyte filling serta formation dan grading.
 Sintesa Material aktif dengan berbagai metode dapat dikembangkan dengan
menggunakan material teknis → Low Cost and High Performance.
 Baterai yang telah dikembangkan telah diaplikasikan pada kendaraan listrik
dan sistem penyimpan energi listrik.
PUI PT TEKNOLOGI PENYIMPANAN ENERGI LISTRIK UNS
 2013- MOLINA Project 2015-Modul/Pack 2017- Pilot Plant

2014-Sel

❑ Pada 2 Januari 2020 ditetapkan PUI Baterai Lithium

UNS (SK Rektor No 27 A/UN27/KP/2020)
❑ Fasilitas: Gedung 3 Lantai di Pusbangis UNS
Purwosari
❑ Alamat: Jalan Slamet Riyadi No.435, Purwosari,
Laweyan, Pajang, Kec. Laweyan, Kota Surakarta, Jawa
Tengah 57146
❑ [Link]

2020- PUI Baterai Lithium

PUI PT TPEL UNS

No Teknologi Sarana dan Prasarana
1 sel, modul dan pack Mini plant sel dengan kapasitas
1500 sel per hari
2 Material aktif, Mini plant material dengan
elektrolit dan kapasitas sampai dengan 10
Separator kg/hari dan alat karakterisasi
material: XRD, PSA, dan EIS
3 Baterai Testing Peralatan charge-discharge
untuk uji kapasitas dan lifetime
4 Monitoring system, Peralatan Pengujian elektronika
safety, dan komunikasi BMS, Safety dan Komunikasi
5 Bangunan PUI Bangunan 3 Lantai (~2000 m2)
yang khusus diperuntukkan
untuk kegiatan PUI Baterai
Lithium
6 Sel coin Satu line peralatan lab untuk
baterai lithium untuk coin cell
7 Charging station 3 charging station terpasang di
FT terhubung PV dan LPPM
terhubung grid

SARANA PRASARANA PUI PT TPEL UNS

TERIMAKASIH