Desmopan (TPU)
Product Range - Reference Data
Edition: 2004-09
Introduction
Desmopan is Bayer MaterialScience's trade name
for thermoplastic polyurethanes (TPU).
The Desmopan range of grades has been adapted
to the many special requirements imposed by
Desmopan's broad range of applications. It takes in
eight general-purpose lines, based on different raw
material groups, and three series of specialpurpose Desmopan grades.
Overviews
Nomenclature
Property comparison of the Desmopan
grade series (for preliminary material selection)
Overview of grades (arranged according to
Shore hardness and raw material base)
Short description of grades and reference
value tables
For business and technical questions, such as
prices or general enquiries, please contact:
Bayer MaterialScience AG - Business Unit TPU
Region EMEA&LA
[email protected]Tel. 0049 214 30 81673,
Leverkusen
Region APAC
[email protected]Tel. 00852-28947251,
Hongkong
Region NAFTA
[email protected]Tel. 001-412-777-4810,
Pittsburgh
Page 1 of 22
File No.: KU24001-0410 en
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Desmopan
Technical Information
Nomenclature
ester grades, and a number of 300-series grades.
These products can be recognized from the letters
KA or KU. New developmental products have the
letters DP in front of their code. The nomenclature
for developmental and sales products has otherwise remained the same.
Midway through 2003, we changed the nomenclature for our Desmopan products. These changes
were made in order to give the Desmopan product
range a more transparent structure. Nearly all the
grades have been given a new name, with the exception of the sales products to date (threecharacter code), the full range of impact-modified
DESMOPAN
New Nomenclature
Trade name
Appendix only for aliphatic grades ( weatherable)
Status
Series
Processing
Shore hardness
Suffix to characterize
special properties
Desmopan
DP
89
51D X
W = plasticized
U = UV protected
FR = flame retardant
30 99 A or D
0 = injection molding grades
3 = extrusion grades
4 = blow molding grades
5 = blown film grades
6 = high transparency grades
7 = only for special applications
8 = polymer blends
9 = contains modifier ( GF,)
100 C2 /C4 Ester
200 Ester without hydrolysis stabilizer
300 C4 Ester
400 Special Ester
500 C3 Ether / Ester
600 C3 Ether
700 Carbonate
900 C4 Ether
8000 only applicable for aliphatic grades
( 2nd digit polyol - basis analogous to aromatic grades)
DP = Developmental product
TP = Trial product
Not applicable for sales products
Page 2 of 22
File No.: KU24001-0410 en
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Desmopan
Technical Information
Page 3 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan Product range
Raw material
group
Series
Shore hardness
55 - 64A
Ester
100
200
300
400
Ether/
Ester
C3-Ether
Carbonate
Aliphatics
C4-Ether
500
600
700
W8000
900
5377A
DP 6065A
R - TPU
DP 1060A
DP 8060SGN
DP 3070A
DP 9370A
DP 9370AU
65 - 79A
DP 2784A
DP 3380A
DP 3080A
481
DP 5080A
DP 1485A
DP 2586A
DP 2786A
385
3385A
585
3485A
KU 2-8785 DPS 032
DP 8785 S043
DP 3685AU
487
588
192
DP 2590A
DP 2792A
DP 3491A
392
DP 3690AU
KU 2-8792A
DP 8792 S043
80 - 84A
85 - 89A
90 - 94A
45 - 49D
50 - 54D
Impact
mod. Ester
150
DP 1350D
Desmopan
Technical Information
60 - 64D
KU 2-8795A
DP 8795 S043
DP 3695AU
345
445
KU 2-8798A
DP 8798 S043
453
see Disclaimer for developmental products
786
W DP 89085A
W DP 85085A
KU 2-88586
W DP 85786A
DP 6045D
795U
9385
DP 9585A
DP 9392A
DP 9392AU
W DP 89043D
DP 9395A
DP 9395AU
DP 9095AU
W DP 89051D
955U
DP 9659DU
KU 2-8715
KA 8529
W DP 89056D
DP 9662DU
KA 8377
365
DP 9665DU
KA 8333
KA 8410
KA 8417
372
DP 9873D
DP 3059D
359
DP 3660DU
65 - 69D
70 - 74D
DP 6386A
790
355
356
55 - 59D
DP 9380A
460
DP 3970D
400 / Ester
500 / Ether-Ester
80A - 58D
77A - 92A
Flexibility at low
temperatures
70A - 73D
Resistance to
microbial attack
300 / Ester
++
Fastness to
light (yellowing)
82A - 92A
++
Resistance to
hot air
200 / Ester
Injection molding and extrusion grades with a high
mechanical strength for articles exposed to wear
Properties
Resistance to
hydrolysis
60A - 50D
Resistance to oil
and grease
100 / Ester
Short description
Heat deflection
Shore hardness range
Dynamic
load bearing
capacity
Series
Resistance to
abrasion
Page 4 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Property comparison of the Desmopan grade series
-x
Extrusion- ; injection molding and calandering-grades,
may be used for food contact applications
++
++
Injection molding and extrusion grades, with a high
mechanical strength, improved hydrolysis resistance
and low-temperature flexibility
++
++
-x
Injection molding grades with a low compression set, a
high heat deformation temperature and a good
resistance to grease and oil
++
++
++
++
++
0x
Injection molding and extrusion grades which combine
the advantages of ether and ester grades in an
economical manner
0/+
++
++
++
Desmopan
Technical Information
600 / Ether
65A - 45D
Injection molding and extrusion grades with very good
resistance to hydrolysis and microbes but reduced
mechanical properties
700 / Carbonate
88A - 43D
Injection molding and extrusion grades, resistant to
microbes and hydrolysis, with low swelling in water
+/++1)
++
W8000 / Aliphatics
85A - 56D
Modifier, injection molding and slush molding grades
which do not yellow under the action of UV light
0/+
+/++1)
+ / -1)
++
70A - 73D
Injection molding and extrusion grades with very good
resistance to microbes and hydrolysis; highly flexible at
low temperatures
++
57D - 66D
Special grades for shoe shells and similar applications
with a high rigidity and good low -temperature impact
strength
900 / Ether
impact mod.
Ester
++
++ = very good; + = good; 0 = satisfactory; - = moderate; x = improves with increasing hardness; 1) depending on the grade
-/++1) +/++1)
++
++
++
Series 100 ester grades
Injection molding, extrusion and blow molding grades with a high
mechanical strength. In extrusion applications, there is no crystallization of the melt with grades in this series even when the
extruder has been in service for a long period of time. Used
primarily for articles subject to wear, such as castors, shoe
heels, pneumatic hoses and bellows.
DP 1485A
Shore hardness: 86A / 33D; extrusion and
injection molding grade; suitable for extrusion
blow molding; very broad processing range;
Application: bellows; hoses, unreinforced; profiles; engineering injection moldings
192
Shore hardness: 94A / 42D; injection molding
grade; with high mechanical strength
for articles subject to wear;
Application: shift lever balls; rollers; coupling
elements; shoe heels
150
Shore hardness: 96A / 50D; injection molding
grade; with high mechanical strength
for articles subject to wear
DP 1350D
Shore hardness: 96A / 50D; extrusion grade;
good wear resistance; high melt stability;
Application: pneumatic hoses
Desmopan
DP 1060A
DP 8060SGN
Shore hardness: 60A; injection molding grade;
free from plasticizer; grease and oil resistance;
good wear resistance;
Application: rigid/flexible composites; shoe
soles
Shore hardness: 61A; injection molding grade;
good wear resistance; short cycle times;
Application: shoe soles
Desmopan (TPU)
Typical Properties
Test
Conditions
100 series, Ester grades
Units
Standards
DP 1060A
DP 8060SGN
DP 1485A
192
150
DP 1350D
60
61
86
94
96
96
33
42
50
50
Mechanical properties (23 C/50 % r.h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
MPa
i.A. ISO 527-1,-3
15
22
46
50
50
50
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
850
900
630
520
420
420
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
2,9
15
15
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
15
18
31
31
ISO 868
ISO 868
Compression set
24 h; 70 C
ISO 815
55
36
60
50
50
Compression set
72 h; 23 C
ISO 815
30
11
25
25
25
Abrasion resistance
mm
ISO 4649
60
100
19
30
30
30
Impact resilience
ISO 4662
55
51
46
30
30
30
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
33
78
100
120
120
Flexural modulus
2 mm/min
MPa
ISO 178
130
130
Torsional storage modulus
-20 C
MPa
ISO 6721-2
20
63
280
458
458
Torsional storage modulus
23 C
MPa
ISO 6721-2
10
30
62
62
Torsional storage modulus
70 C
MPa
ISO 6721-2
15
26
26
kg/m
ISO 1183
ISO 3451-1
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
1198
1200
1216
1230
1240
1240
160 - 200
190 - 210
200 - 220
210 - 225
210 - 230
210 -230
20
20
20
20 - 40
20 - 40
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
180 - 200
210 - 230
DP = Developmental product (see disclaimer for developmental products)
Page 5 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 200, ester grades
Desmopan
Blow molding and coating grades, may be used for food contact
applications.
DP 2784A
Shore hardness: 82A / 33D;
base material for batches
Our Ecology Department will be pleased to provide you with
more information on the subject of "Food Contact":
DP 2586A
Shore hardness: 86A / 38D; extrusion and
injection molding grade;
Application: blown film
DP 2786A
Shore hardness: 88A; calender coating grade;
Application: fabric coating
DP 2590A
Shore hardness: 92A; extrusion and injection
molding grade;
Application: blown film
DP 2792A
Shore hardness: 93A / 50D; calender coating
grade;
Application: fabric coating
Bayer MaterialScience AG
Dr. Eduard Haensel
Tel.: +49(0)214/30-72939
Fax: +49(0)214/30-31764
e-mail: [email protected]
Desmopan (TPU)
Typical Properties
Test Conditions
200 series, Ester grades
Units
Standards
DP 2784A
DP 2586A
DP 2786A
DP 2590A
DP 2792A
88
92
93
Mechanical properties (23 C/50 % r.h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
Elongation at break
Stress at 100 % strain
Stress at 300 % strain
ISO 868
82
86
ISO 868
33
38
200 mm/min
MPa
i.A. ISO 527-1,-3
25
45
33
45
43
200 mm/min
i.A. ISO 527-1,-3
500
500
590
500
520
200 mm/min
MPa
i.A. ISO 527-1,-3
4.0
5.6
6,4
10
10
200 mm/min
MPa
i.A. ISO 527-1,-3
10
12
11,2
30
20
52
69
23
17
26
Compression set
24 h; 70 C
ISO 815
Compression set
72 h; 23 C
ISO 815
50
Abrasion resistance
mm
ISO 4649
30
32
86
70
Impact resilience
ISO 4662
45
46
37
29
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
50
71
69
Flexural modulus
2 mm/min
MPa
ISO 178
Thermal properties
Torsional storage modulus
-20 C
MPa
ISO 6721-2
53
37
438
1860
318
Torsional storage modulus
23 C
MPa
ISO 6721-2
13
12
40
74
24
Torsional storage modulus
70 C
MPa
ISO 6721-2
5,2
8,3
19
29
11
kg/m
ISO 1183
1200
1190
1205
1205
1205
ISO 3451-1
190 - 210
210 - 230
190 - 210
210 - 230
190 - 220
20 - 40
20 - 40
20
20
20 - 40
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
195 - 215
190 - 210
DP = Developmental product (see disclaimer for developmental products)
Page 6 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 300, ester grades (1)
DP 3380A
Injection molding and extrusion grades offering a high mechanical strength together with improved hydrolysis resistance and
low-temperature flexibility. Low swelling values in oils, greases
and solvents.
Shore hardness: 80A; extrusion grade;
plasticizer-free;
Application: hoses, reinforced; profiles
385 E
Shore hardness: 85A / 32D; extrusion and
injection molding grade;
Application; hoses, unreinforced; screenpacks;
engineering parts; rigid/flexible composite systems
585
Shore hardness 85A / 32D; injection molding
grade; containing microbicidal agent;
Application: sport shoe soles
3385A
Shore hardness: 85A / 33D; extrusion and
injection molding type; good wear resistance;
short cycle times;
Application: rigid/flexible composite systems;
hoses, unreinforced; profiles; injection molding
engineering parts
This is the series of grades used most frequently for extruded
articles of all types, as well as for highly-stressed structural
parts.
Desmopan
DP 3070A
Shore hardness: 70A; injection molding grade;
plasticizer-free;
Application: engineering injection moldings;
rigid/flexible composite systems
DP 3080A
Shore hardness: 80A; injection molding grade;
plasticizer-free;
Application: rigid/flexible composite systems;
engineering parts
Desmopan (TPU)
Typical Properties
Test
Conditions
300 series, Ester grades (1)
Units
Standards
DP 3070A
DP 3080A
DP 3380A
385 E
70
80
80
85
585
3385A
Mechanical properties (23 C/50 % r.h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
MPa
i.A. ISO 527-1,-3
25
44
44
50
40
50
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
800
600
590
500
550
500
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
2,5
4,5
4,5
6.0
5.0
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
4,6
8,3
8,3
13
12
15
ISO 868
ISO 868
32
85
32
85
33
Compression set
24 h; 70 C
ISO 815
52
42
42
50
55
42
Compression set
72 h; 23 C
ISO 815
24
18
18
25
30
15
Abrasion resistance
mm
ISO 4649
50
20
20
30
25
25
Impact resilience
ISO 4662
47
41
41
42
40
50
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
36
58
58
70
70
70
Flexural modulus
2 mm/min
MPa
ISO 178
17
Thermal properties
68
Torsional storage modulus
-20 C
MPa
ISO 6721-2
11
95
95
32
Torsional storage modulus
23 C
MPa
ISO 6721-2
20
20
12
15
Torsional storage modulus
70 C
MPa
ISO 6721-2
13
13
8,7
9,9
kg/m
ISO 1183
1148
1160
1160
1200
1200
ISO 3451-1
200 - 230
185 - 200
185 - 200
210 - 230
20
20 - 40
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
1200
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
20
20 - 40
175 - 190
200 - 220
210 - 230
20 - 40
190 - 210
20
175 - 205
DP = Developmental product (see disclaimer for developmental products)
Page 7 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 300, ester grades (2)
Injection molding and extrusion grades with high mechanical
strength, improved hydrolysis resistance and low-temperature
flexibility. Low swelling values in oils, greases and solvents.
392
Shore hardness: 92A / 40D; extrusion and
injection molding grade;
Application: cogged belts: profiles; hoses, unreinforced
345
Shore hardness: 95A / 47D; injection molding
grade; with high mechanical strength for articles
subject to wear;
Application: injection molding engineering parts
355
Shore hardness 96A / 56D; injection molding
grade;
Application: injection molding engineering parts
356
Shore hardness: 97A / 55D; injection molding
grade
Application: engineering parts; ski-boot shells;
heel patches
This is the series of grades used most frequently for extruded
articles of all types, as well as for highly-stressed structural
parts.
Desmopan
3485A
Shore hardness: 85A / 33D; extrusion and
injection molding grade; suitable for extrusion
blow molding; with mold release agent; high
melt stability;
Application: bellows; injection molding
engineering parts
DP 3491A
Shore hardness: 92A / 40D; extrusion and
injection molding grade; suitable for extrusion
blow molding; high melt stability;
Application: blow molding; profiles; injection
molding engineering parts
Desmopan (TPU)
Typical Properties
Test
Conditions
300 series, Ester grades (2)
Units
Standards
3485A
DP 3491A
392
345
355
356
Mechanical properties (23 C/50 % r. h.)
shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
MPa
i.A. ISO 527-1,-3
50
50
45
52
60
60
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
500
500
450
450
430
400
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
5.0
8.0
9.0
12
15
19
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
15
20
22
27
35
40
Compression set
24 h; 70 C
ISO 815
42
50
41
42
45
50
Compression set
72 h; 23 C
ISO 815
15
20
25
25
30
30
Abrasion resistance
mm
ISO 4649
25
25
25
30
35
35
Impact resilience
ISO 4662
50
36
33
35
35
35
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
70
100
80
100
130
130
Flexural modulus
2 mm/min
MPa
ISO 178
17
70
150
140
470
ISO 868
85
92
92
95
ISO 868
33
40
40
47
96
56
97
55
Thermal properties
Torsional storage modulus
-20 C
MPa
ISO 6721-2
32
95
115
230
505
Torsional storage modulus
23 C
MPa
ISO 6721-2
12
22
24
47
66
72
Torsional storage modulus
70 C
MPa
ISO 6721-2
8,1
14
15
22
24
29
kg/m
ISO 1183
1200
1200
1210
1220
1200
1250
ISO 3451-1
190 - 210
190 - 210
210 - 230
210 - 235
20 - 40
20 - 40
20 - 40
20 - 40
175 - 205
180 - 210
200-220
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
220 - 235
20 - 40
210 - 235
20 - 40
DP = Developmental product (see disclaimer for developmental products)
Page 8 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 300, ester grades (3)
DP 3059D
Shore hardness: 97A / 59D; injection molding
grade; with mold release agent; excellent wear
resistance; very short cycle times;
Application: heel patches; castors; shoe shells;
injection molding engineering parts
365
Shore hardness: 98A / 65D; injection molding
engineering parts;
Application; injection molding engineering parts;
heel patches; sports shoe soles
372
Shore hardness: 98A / 73D; injection molding
grade;
Application: injection molding engineering parts;
gear socket balls for automotive sector
Injection molding and extrusion grades with high mechanical
strength, improved hydrolysis resistance and low-temperature
flexibility. Low swelling values in oils, greases and solvents.
This is the series of grades used most frequently for extruded
articles of all types, as well as for highly-stressed structural
parts.
Desmopan
359
Shore hardness: 97A / 59D; injection molding
grade; with high mechanical strength for articles
subject to wear;
Application: injection molding engineering parts;
roller tires; shoe heels; ski-boot shells
Desmopan (TPU)
Typical Properties
Test Conditions
300 series, Ester grades (3)
Units
Standards
359
DP 3059D
365
372
Mechanical properties (23 C/50 % r.h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
MPa
Elongation at break
200 mm/min
ISO 868
97
97
98
98
ISO 868
59
59
65
73
i.A. ISO 527-1,-3
50
60
i.A. ISO 527-1,-3
400
50
70
400
250
35
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
20
21
25
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
40
42
40
Compression set
24 h; 70 C
ISO 815
60
60
50
Compression set
72 h; 23 C
ISO 815
30
30
30
Abrasion resistance
mm
ISO 4649
35
18
30
30
Impact resilience
ISO 4662
35
35
40
42
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
160
120
180
220
Flexural modulus
2 mm/min
MPa
ISO 178
180
180
350
650
Torsional storage modulus
-20 C
MPa
ISO 6721-2
555
560
632
1000
Torsional storage modulus
23 C
MPa
ISO 6721-2
105
115
160
354
Torsional storage modulus
70 C
MPa
ISO 6721-2
38
42
52
68
kg/m
ISO 1183
1230
1230
1230
1240
ISO 3451-1
220 - 240
200 - 230
220 - 245
220 - 245
20 - 40
20 - 40
20 - 40
20 - 40
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
Page 9 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 300 ester grades (4)
(sport shoe grades)
The 300 series grades listed below were developed for use in
sport shoe soles. They have UV protection and fulfill the requirements of the leading sport shoe manufacturers. In addition
to this, they are noted for their short cycle times, easy demolding
and very good melt flowability when processed by injection
molding. Long flow paths can thus be achieved with low wall
thicknesses too.
Desmopan (TPU)
Typical Properties
Test Conditions
300 series, Ester grades (4)
Units
Standards
KU 2-8785
DPS 032*
KU 2-8792 A*
KU 2-8795 A*
KU 2-8798 A*
85
91
94
94
53
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
ISO 868
33
36
41
200 mm/min
MPa
i.A. ISO 527-1,-3
50
50
55
65
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
550
500
450
400
ISO 868
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
8.0
10
17
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
15
17
26
39
Compression set
24 h; 70 C
ISO 815
42
50
40
45
Compression set
72 h; 23 C
ISO 815
15
20
20
25
25
Abrasion resistance
mm
ISO 4649
25
27
26
Impact resilience
ISO 4662
50
43
40
36
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
70
90
90
120
Flexural modulus
2 mm/min
MPa
ISO 178
Torsional storage modulus
-20 C
MPa
ISO 6721-2
39
90
157
Torsional storage modulus
23 C
MPa
ISO 6721-2
11
19
27
62
Torsional storage modulus
70 C
MPa
ISO 6721-2
12
16
27
kg/m
ISO 1183
1200
1200
1210
1220
ISO 3451-1
200 - 220
190 - 210
190 - 210
195 - 215
20
20 - 40
20 - 40
20 - 40
100
Thermal properties
390
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
*) see disclaimer for developmental products
Page 10 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 300, ester grades (5)
(sport shoe grades, reduced-wear)
These grades with the additional designation S043 are a further
development of our sport shoe series of grades. In addition to
the familiar good properties, such as UV stabilization, good flowability and short cycle times, these grades are noted for their
considerably improved wear properties. They are used on parts
subject to high wear. For coloring, it should be noted that these
grades have a slightly milky natural color.
Desmopan (TPU)
Typical Properties
Test Conditions
300 series, Ester grades (5)
Units
Standards
ISO 868
DP 8785A
S043
DP 8792A
S043
DP 8795A
S043
DP 8798A
S043
85
91
94
94
53
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
ISO 868
33
40
41
200 mm/min
MPa
i.A. ISO 527-1,-3
45
50
50
65
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
500
500
450
400
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
10
17
39
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
14
17
24
Compression set
24 h; 70 C
ISO 815
42
50
45
45
Compression set
72 h; 23 C
ISO 815
15
20
21
25
15
Abrasion resistance
mm
ISO 4649
18
18
17
Impact resilience
ISO 4662
50
43
40
36
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
70
80
90
120
Flexural modulus
2 mm/min
MPa
ISO 178
374
Thermal properties
Torsional storage modulus
-20 C
MPa
ISO 6721-2
39
115
185
Torsional storage modulus
23 C
MPa
ISO 6721-2
11
19
29
67
Torsional storage modulus
70 C
MPa
ISO 6721-2
12
16
28
kg/m
ISO 1183
1200
1200
1210
1220
ISO 3451-1
190 - 210
190 - 210
190 - 220
200 - 230
20
20
20
25 - 40
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
Page 11 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 300, ester grades (6)
(transparent grades)
All the highly transparent grades listed here are hydrolysisstabilized and have special UV protection. They can be used for
clear, transparent injection moldings with a wall thickness of up
to 6 mm. Hoses, flat film and profiles can be extruded from these
grades.
Desmopan (TPU)
Typical Properties
Test Conditions
300 series, Ester grades (6)
Units
Standards
DP 3685AU
DP 3690AU
DP 3695AU
DP 3660DU
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
Elongation at break
Stress at 100 % strain
Stress at 300 % strain
ISO 868
86
93
96
98
ISO 868
38
40
43
56
200 mm/min
MPa
i.A. ISO 527-1,-3
50
55
59
60
200 mm/min
i.A. ISO 527-1,-3
450
430
425
400
200 mm/min
MPa
i.A. ISO 527-1,-3
12
19
200 mm/min
MPa
i.A. ISO 527-1,-3
13
24
34
40
Compression set
24 h; 70 C
ISO 815
36
Compression set
72 h; 23 C
ISO 815
13
Abrasion resistance
mm
ISO 4649
22
22
20
20
Impact resilience
ISO 4662
32
29
25
31
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
88
95
112
170
Flexural modulus
2 mm/min
MPa
ISO 178
Torsional storage modulus
-20 C
MPa
ISO 6721-2
190
848
1180
2380
Torsional storage modulus
23 C
MPa
ISO 6721-2
13
54
69
267
Torsional storage modulus
70 C
MPa
ISO 6721-2
30
33
77
kg/m
ISO 1183
1197
1211
1218
1229
ISO 3451-1
215 -235
215 - 235
215 - 235
215 - 235
110
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
20
20 - 40
20 - 40
20 - 40
180 - 200
180 - 200
190 - 210
190 - 210
DP = Developmental product (see disclaimer for developmental products)
Page 12 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 400, ester grades
This series offers a number of special properties thanks to the
use of special raw materials and ancillary materials. Compared
with the 100 and 300 series of ester grades, the individual materials display improved:
-
compression set
elasticity
heat resistance
hydrolysis resistance
oil/grease resistance
microbe resistance
487
Shore hardness: 86A / 34D; injection molding
grade; grease and oil resistant; low compression set; high heat resistance; short cycle times;
Application: automotive engineering parts; rollers; seals, membranes; damping elements
445
Shore hardness: 93A / 44D; injection molding
grade; grease and oil resistant;
high heat resistance; low compression set;
Application: automotive engineering parts: injection molding engineering parts
453
Shore hardness: 97A / 52D; injection molding
grade; grease and oil resistant; low compression set; good wear resistance;
Application: injection molding engineering parts;
automotive engineering parts
460
Shore hardness: 97A / 58D; injection molding
grade; grease and oil resistant; low compression set; high heat resistance; high elasticity;
short cycle times;
Application: automotive engineering parts; engineering parts
These injection molding grades are used first and foremost in
functional engineering components for automotive, mechanical
and plant engineering.
Desmopan
481
Shore hardness: 80A / 30D; injection molding
grade; plasticizer-free; grease and oil-resistant;
low compression set; high elasticity;
high heat resistance; easy-release;
Application: rollers; seals; membranes; automotive engineering parts
Desmopan (TPU)
Typical Properties
Test Conditions
400 series, Ester grades
Units
Standards
481
487
445
453
460
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
MPa
i.A. ISO 527-1,-3
30
35
38
38
35
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
600
500
500
475
350
ISO 868
80
86
93
97
97
ISO 868
30
34
44
52
58
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
5.0
6.0
17
21
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
9.0
14
20
29
33
Compression set
24 h; 70 C
ISO 815
35
30
35
27
35
Compression set
72 h; 23 C
ISO 815
22
15
Abrasion resistance
mm
ISO 4649
25
20
25
15
25
32
40
Impact resilience
ISO 4662
48
45
35
30
35
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
45
70
95
180
150
Flexural modulus
2 mm/min
MPa
ISO 178
Torsional storage modulus
-20 C
MPa
ISO 6721-2
17
46
280
448
710
Torsional storage modulus
23 C
MPa
ISO 6721-2
7,2
13
25
53
128
Torsional storage modulus
70 C
MPa
ISO 6721-2
6,7
9,6
16
24
43
kg/m
ISO 1183
1200
1210
1220
1230
1220
ISO 3451-1
225 - 235
230 - 240
210 - 235
220 - 240
235 - 245
20 - 40
20 - 40
20 - 40
20 - 40
20 - 40
170
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
Page 13 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 500, ether/ester grades
Series 600, ether grades
Ether/ester grades that combine the advantages of both classes
of raw material at low cost. These are used in applications subject to mechanical stressing with a simultaneous risk of damage
through micro-organisms. Fields of application include extrusion
coating, seals, technical injection moldings and watch straps.
The grades in the 600 series can be used as a lower-cost solution for applications that require the hydrolysis and microbe
resistance of the 900 series but not such high-level mechanical
properties. Potential applications include fire extinguisher hoses,
shoe soles and rigid/flexible combinations.
Desmopan
Desmopan
5377A
Shore hardness: 77A / 28D; extrusion and
injection molding grade; improved microbe
resistance; improved hydrolysis resistance;
Applications: cable sheathings; fabric coating;
watch straps
DP 6065A
Shore hardness: 66A; injection molding grade;
plasticizer-free; very good hydrolysis and
microbe resistance; very short cycle times;
Application: rigid/flexible composite systems;
shoe soles
DP 5080A
Shore hardness: 80A / 29D; injection molding
grade; improved microbe resistance; improved
hydrolysis resistance;
Application: seals, membranes; rigid/flexible
composite systems
DP 6386A
Shore hardness: 85A; extrusion and injection
molding grade; very good hydrolysis and
microbe resistance; short cycle times;
Application: fire-extinguisher hoses; injection
molding engineering parts; rigid/flexible composite systems
588E
Shore hardness: 88A / 33D; extrusion and
injection molding grade; improved microbe
resistance; improved hydrolysis resistance;
Application: cable sheathings; hoses, unreinforced; roof lining
DP 6045D
Shore hardness: 94A / 45D; injection molding
grade; with special UV stabilizers;
very good resistance to hydrolysis and
microbes; very short cycle times;
Application: injection molding engineering parts;
animal identification tags
Desmopan (TPU)
Typical Properties
Test
Conditions
500 series, Ether/Ester
grades
Units
600 series, C3-Ether grades
Standards
5377A
DP 5080A
588 E
DP 6065A
DP 6386A
DP 6045D
77
80
88
66
85
94
27
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
ISO 868
ISO 868
28
29
33
MPa
i.A. ISO 527-1,-3
26
28
35
17
24
45
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
740
650
600
850
725
391
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
4.0
4.0
6.0
2,7
6,8
13,5
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
7.0
9.0
11
11
23
Compression set
24 h; 70 C
ISO 815
50
50
50
36
37
56
Compression set
72 h; 23 C
ISO 815
20
20
25
16
17
18
90
Abrasion resistance
mm
ISO 4649
80
70
60
150
90
Impact resilience
ISO 4662
45
45
36
50
43
39
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
40
55
55
26
40
50
Flexural modulus
2 mm/min
MPa
ISO 178
Torsional storage modulus
-20 C
MPa
ISO 6721-2
20
20
39
42
455
Torsional storage modulus
23 C
MPa
ISO 6721-2
6,7
7,5
11
15
155
Torsional storage modulus
70 C
MPa
ISO 6721-2
5,1
5,6
7,9
12
91
kg/m
ISO 1183
1140
1140
1150
1084
1117
ISO 3451-1
180 - 200
190 - 210
210 - 230
190 - 210
215 - 230
200 - 220
20 - 40
20 - 40
20 - 40
20 -30
20
20 - 30
170 - 190
18
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
190 - 210
185 - 210
DP = Developmental product (see disclaimer for developmental products)
Page 14 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 700, carbonate grades
Desmopan
The grades in this series have been specially developed for
particular applications and have been successfully used in these
applications for many years. They display good resistance to
microbes and hydrolysis, experience less swelling in water than
ether grades and offer a level of mechanical properties comparable to ester grades.
786 E
Shore hardness: 88A / 33D; extrusion and
injection molding grade; high mechanical
strength; very good hydrolysis and microbe
resistance; good low-temperature flexibility;
Application: fire-extinguisher hoses; films;
profiles; engineering parts
Applications include fire-extinguisher hoses, film, cogged belts,
seals and animal identification tags.
790
Shore hardness: 92A / 40D; extrusion and
injection molding grade; good hydrolysis and
microbe resistance; high mechanical strength;
good low-temperature flexibility;
Application: cogged belts; profiles; injection
molding engineering parts
795 U
Shore hardness: 94A / 43D; injection molding
grade; with special UV stabilizers;
good hydrolysis and microbe resistance;
short cycle times;
Application: animal identification tags
Desmopan (TPU)
Typical Properties
Test Conditions
700 series, Carbonate grades
Units
Standards
786 E
790
795 U
88
92
94
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
ISO 868
33
40
43
200 mm/min
MPa
i.A. ISO 527-1,-3
43
55
46
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
525
450
430
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
7.0
10
14
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
14
25
34
Compression set
24 h; 70 C
ISO 815
55
50
42
Compression set
72 h; 23 C
ISO 815
25
25
22
ISO 868
Abrasion resistance
mm
ISO 4649
40
30
25
Impact resilience
ISO 4662
32
32
32
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
60
85
102
Flexural modulus
2 mm/min
MPa
ISO 178
Torsional storage modulus
-20 C
MPa
ISO 6721-2
120
200
Torsional storage modulus
23 C
MPa
ISO 6721-2
15
22
48
Torsional storage modulus
70 C
MPa
ISO 6721-2
9,3
12
19
kg/m
ISO 1183
1150
1210
1200
ISO 3451-1
210 - 230
210 - 230
210 - 230
20 - 40
20 - 40
20 - 40
190 - 210
200 - 220
72
Thermal properties
450
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
Page 15 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series W8000, aliphatic (1)
W DP 85786A
Shore hardness: 90A; calender-coating grade;
good low-temperature flexibility; high compression set; improved microbe resistance;
improved hydrolysis resistance;
Application: fabric coating
W DP 89085A
Shore hardness: 86A; injection molding grade;
very good hydrolysis and microbe resistance;
good low-temperature flexibility;
high compression set; low wear;
for colored applications in the automotive,
sports and leisure sectors
KU 2-88586*
Shore hardness: 89A; special grade for slush
processes; good low-temperature flexibility;
high compression set; improved microbe resistance; improved hydrolysis resistance
The new Desmopan product line based on an aliphatic isocyanate. In addition to possessing the familiar properties of
TPUs, these products do not yellow under the action of UV light.
They additionally offer a particularly high resilience and "snappiness".
This is why these grades are particularly suitable for colored
applications in automotive engineering and the sport and leisure
sectors.
Desmopan
W DP85085A
Shore hardness: 85A; injection molding grade;
improved microbe resistance;
good low-temperature flexibility;
improved hydrolysis resistance;
Application: automotive interior applications
Desmopan (TPU)
Typical Properties
Test Conditions
W8000 series, Aliphatic grades (1)
Units
Standards
W DP85085A
W DP85786A
KU 2-88586*
W DP 89085A
85
90
89
86
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
Elongation at break
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
6.0
6,3
6.3
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
9.5
9,5
9.5
10
43
43
ISO 868
ISO 868
200 mm/min
MPa
i.A. ISO 527-1,-3
32
26
25
33
200 mm/min
i.A. ISO 527-1,-3
880
850
890
750
Compression set
24 h; 70 C
ISO 815
42
Compression set
72 h; 23 C
ISO 815
18
Abrasion resistance
mm
ISO 4649
28
30
30
31
Impact resilience
ISO 4662
63
62
62
64
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
75
74
74
42
Flexural modulus
2 mm/min
MPa
ISO 178
33
Thermal properties
Torsional storage modulus
-20 C
MPa
ISO 6721-2
62
67
67
Torsional storage modulus
23 C
MPa
ISO 6721-2
22
22
22
150
30
Torsional storage modulus
70 C
MPa
ISO 6721-2
15
15
15
40
kg/m
ISO 1183
1130
1130
1130
1080
ISO 3451-1
180-210
170 - 190
170 - 190
200 - 220
20 - 40
20
20 -40
20 -40
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
*) see disclaimer for developmental products
Page 16 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series W8000, aliphatic (2)
The new Desmopan product line based on an aliphatic isocyanate. In addition to possessing the familiar properties of TPUs,
these products do not yellow under the action of UV light. The
products in the following Table also have very good hydrolysis
and microbe resistance, good low-level flexibility and low wear
values. They additionally offer a particularly high resilience and
"snappiness".
This is why these grades are particularly suitable for colored
applications in automotive engineering and the sport and leisure
sectors.
Desmopan (TPU)
Typical Properties
Test Conditions
W8000 series, Aliphatic grades (2)
Units
Standards
W DP89043D
W DP89051D
W DP89056D
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
MPa
i.A. ISO 527-1,-3
39
48
43
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
717
550
320
ISO 868
95
96
95
ISO 868
43
51
56
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
12
17
20
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
18
23
43
Compression set
24 h; 70 C
ISO 815
41
46
46
Compression set
72 h; 23 C
ISO 815
Abrasion resistance
mm
ISO 4649
11
17
22
Impact resilience
ISO 4662
56
52
51
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
96
142
Flexural modulus
2 mm/min
MPa
ISO 178
80
170
250
Torsional storage modulus
-20 C
MPa
ISO 6721-2
73
152
700
Torsional storage modulus
23 C
MPa
ISO 6721-2
46
77
298
Torsional storage modulus
70 C
MPa
ISO 6721-2
31
52
193
kg/m
ISO 1183
1080
1080
1110
ISO 3451-1
210 - 230
230 - 250
240 - 260
40 - 60
40 - 60
40 - 60
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
Page 17 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 900, ether grades (1)
Products offering very good hydrolysis and microbe resistance.
Their excellent low-temperature flexibility constitutes a further
characteristic feature. The 900 grade series is used inter alia in
applications where good flexibility or impact strength is required
at very low temperatures. Applications include cables, hoses,
profiles, films and shoe shells.
9385
Shore hardness: 86A / 35D; extrusion and
injection molding grade; good low-temperature
flexibility; complies with DIN VDE 0282-10;
Application: cable sheathings; hoses, unreinforced
DP 9585A
Shore hardness: 85A / 34D; extrusion and
injection molding grade; good low-temperature
flexibility;
Application: blown film; fabric coating; cable
sheathings; profiles; engineering parts
DP 9392A
Shore hardness: 92A / 42D; extrusion and
injection molding grade;
good low-temperature flexibility;
Application: hoses, unreinforced; cable sheathings; profiles; engineering parts
DP 9392AU
As for DP 9392A but with special UV stabilizers
DP 9095AU
Shore hardness: 95A / 43D; injection molding
grade; with special UV stabilizers;
good wear resistance, low tendency to warp;
short cycle times;
Application: animal identification tags
Desmopan
DP 9370A
Shore hardness: 70A; extrusion and injection
molding grade; good low-temperature flexibility;
plasticizer-free; high moisture vapor transmission rate;
Application: roof lining; seals, membranes;
films; rigid/flexible composite systems; sport
shoe soles
DP 9370AU
As for DP 9370A but with special UV stabilizers
DP 9380A
Shore hardness: 82A / 31D; extrusion and
injection molding grade; good low-temperature
flexibility; complies with DIN VDE 0282-10;
Application: cable sheathings; hoses, unreinforced
Desmopan (TPU)
Typical Properties
Test
Conditions
900 series, C4-Ether grades (1)
Units
Standards
DP 9370A /
AU
DP 9380A
9385
DP 9585A
DP 9392A /
AU
DP 9095AU
70
82
86
85
92
95
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
200 mm/min
ISO 868
ISO 868
31
35
34
42
43
MPa
i.A. ISO 527-1,-3
25
40
48
40
50
65
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
800
500
600
630
500
370
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
2.4
5.0
6.0
6.0
8,5
18
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
4.3
9.0
13
10
17
30
Compression set
24 h; 70 C
ISO 815
49
42
43
36
40
77
Compression set
72 h; 23 C
ISO 815
22
25
25
28
20
30
Abrasion resistance
mm
ISO 4649
69
20
25
84
20
18
Impact resilience
ISO 4662
63
50
40
45
32
33
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
39
50
65
60
85
129
Flexural modulus
2 mm/min
MPa
ISO 178
275
Thermal properties
Torsional storage modulus
-20 C
MPa
ISO 6721-2
37
14
29
31
104
Torsional storage modulus
23 C
MPa
ISO 6721-2
4,5
8,3
12
12
22
40
Torsional storage modulus
70 C
MPa
ISO 6721-2
3,2
6,3
7,9
7,8
13
19
kg/m
ISO 1183
1060
1110
1120
1110
1150
1149
ISO 3451-1
190 - 210
205 - 225
205 - 225
205 - 225
210 - 230
200 - 220
20 - 40
20 - 40
20 - 40
20 - 40
20 - 40
20
175 - 215
195 - 215
195 - 215
180 - 210
195 - 215
200 - 220
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
Page 18 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Series 900, ether grades (2)
DP 9659DU
Products offering very good hydrolysis and microbe resistance.
Their excellent low-temperature flexibility constitutes a further
characteristic feature. The 900 grade series is used inter alia in
applications where good flexibility or impact strength is required
at very low temperatures. Applications include cables, hoses,
profiles, films and shoe shells.
Shore hardness: 97A / 59D; extrusion and
injection molding grade; with special UV stabilizers; transparent up to 6 mm wall thickness;
Application: ski-boot shells; hoses, unreinforced
DP 9662DU
Shore hardness: 97A / 62D; extrusion and
injection molding grade; with special UV stabilizers; transparent up to 6 mm wall thickness;
Application: ski-boot shells; hoses, unreinforced
DP 9665DU
Shore hardness: 98A / 65D; extrusion and
injection molding grade; with special UV stabilizers; transparent up to 6 mm wall thickness;
Application: ski-boot shells; hoses, unreinforced; pneumatic hoses
KA 8333*
Shore hardness: 98A / 66D; injection molding
grade; very good low-temperature impact
strength;
Application: shoe soles; engineering parts
DP 9873D
Shore hardness: 98A / 73D; injection molding
grade; very good low-temperature impact
strength;
Application: shoe soles; injection molding engineering parts
Desmopan
DP 9395A
Shore hardness: 95A / 46D; extrusion and
injection molding grade;
good low-temperature flexibility;
Application: pneumatic hoses; cable sheathings; profiles, injection molding engineering
parts
DP 9395AU
As for DP 9395A but with special UV stabilizers
955 U
Shore hardness: 97A / 55D; injection molding
grade; with special UV stabilizers; very good
low-temperature impact strength;
Application: ski-boot shells; hoses, unreinforced; injection molding engineering parts
Desmopan (TPU)
Typical Properties
Test
Conditions
900 series, C4-Ether grades (2)
Units
Standards
DP 9395A /
AU
955 U
DP 9659DU
DP 9662DU
DP 9665DU
KA 8333*
DP 9873D
ISO 868
95
97
97
97
98
98
98
73
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
ISO 868
46
55
59
62
65
66
200 mm/min
MPa
i.A. ISO 527-1,-3
50
55
60
55
55
55
55
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
450
400
400
350
350
325
310
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
13
20
22
28
26
29
35
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
27
35
40
49
55
45
50
46
30
Compression set
24 h; 70 C
ISO 815
40
Compression set
72 h; 23 C
ISO 815
22
30
Abrasion resistance
mm
ISO 4649
Impact resilience
ISO 4662
40
20
20
19
38
29
31
40
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
47
45
100
140
89
98
208
150
200
Flexural modulus
2 mm/min
MPa
ISO 178
55
170
180
220
530
910
Torsional storage modulus
-20 C
Torsional storage modulus
23 C
MPa
ISO 6721-2
209
330
1370
1270
1440
530
733
MPa
ISO 6721-2
39
104
267
362
440
233
475
Torsional storage modulus
70 C
MPa
ISO 6721-2
19
32
75
97
110
63
156
kg/m
ISO 1183
1150
1160
1160
1176
1175
1170
1190
ISO 3451-1
210 -230
215 - 235
220 - 235
220 - 235
220 - 235
225 - 235
225 - 235
40 - 60
40 - 60
40 - 60
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
20 - 40
20 - 40
40 - 60
40 - 60
200 - 220
205 - 235
205 - 235
205 - 235
DP = Developmental product (see disclaimer for developmental products)
*) see disclaimer for developmental products
Page 19 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Impact-modified ester grades
Glass fiber reinforced grades
This series of grades was developed primarily for shoe shells
and similar applications. Shoe shells or ski boots produced in
these grades are lightweight and offer a high rigidity and elasticity with a very good low-temperature impact strength. The modi
fied Desmopan grades additionally display a high scratch and
wear resistance.
Injection moldings in glass fiber reinforced Desmopan are
characterized by a low shrinkage and a low coefficient of expansion. The coefficient of expansion in the direction of the glass
fibers is of the same order of magnitude as for aluminum.
Field of application: exterior automotive engineering parts.
Parts in R-TPU display a high heat resistance, good lowtemperature impact strength and sound insulation, good flowability and accurate reproduction of detail.
Molded parts can be printed and painted.
Desmopan (TPU)
Typical Properties
Test
Conditions
Glass fiber
reinforced
grades
Impact modified, Ester grades
Units
Standards
KU 2-8715*
KA 8529*
KA 8377*
KA 8410*
KA 8417*
DP 3970D
96
97
97
98
98
99
Mechanical properties (23 C/50 % r. h.)
Shore hardness,
method A
shore hardness,
method D
Ultimate tensile strength
ISO 868
57
59
62
64
66
70
200 mm/min
MPa
i.A. ISO 527-1,-3
52
60
60
60
54
64
Elongation at break
200 mm/min
i.A. ISO 527-1,-3
470
410
390
380
360
25
Stress at 100 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
18
18
24
26
31
35
37
40
43
45
30
30
ISO 868
Stress at 300 % strain
200 mm/min
MPa
i.A. ISO 527-1,-3
Compression set
24 h; 70 C
ISO 815
Compression set
72 h; 23 C
ISO 815
Abrasion resistance
mm
ISO 4649
25
30
30
Impact resilience
ISO 4662
36
38
38
Tear propagation resistance
500 mm/min
kN/m
ISO 34-1
130
140
160
150
190
Flexural modulus
2 mm/min
MPa
ISO 178
175
240
330
440
510
1700
Torsional storage modulus
-20 C
MPa
ISO 6721-2
542
600
760
824
895
2870
Torsional storage modulus
23 C
MPa
ISO 6721-2
127
157
206
250
311
1450
Torsional storage modulus
70 C
MPa
ISO 6721-2
46
57
64
77
93
765
kg/m
ISO 1183
1170
1200
1200
1200
1180
1376
ISO 3451-1
225 - 240
225 - 240
225 - 240
225 - 240
225 - 240
220 - 245
40 - 60
40 - 60
40 - 60
40 - 60
40 - 60
40 - 80
60
30
Thermal properties
Other properties (23 C)
Density
Glass fiber / glass bead /
filler content
21
Molding conditions
Injection moldingMelt temperature
Injection moldingMold temperature
Extrusion-Melt temperature
DP = Developmental product (see disclaimer for developmental products)
*) see disclaimer for developmental products
Page 20 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information
Pretreatment of the granules
TPU absorbs moisture from the air. The extent and
rate at which this happens depends on the raw
material type, hardness and climate. To ensure
trouble-free processing and avoid any loss of quality, we recommend drying to a moisture content of
0.05 %. If the granules are too moist, blisters or
streaks can occur on the surface of the finished
components. The extrudate is no longer smooth
and glossy but foamy and gassy.
A frequent cause of defects is also the use of undried functional concentrates. These batches
should be separately pre-dried and have a moisture
content 0.05 %. Such levels can be reliably
reached in conventional dry air and circulating air
dryers.
Depending on the hardness, the recommended
drying temperatures are between 80 and 110 C,
with drying times of 1 to 3 hours. Better drying can
be achieved in a shorter time with dry air dryers.
Dried, hot granules should not be left to cool down
in the open air. They must be stored in dry containers that can be re-sealed. The machine hopper
must be kept covered.
Coloring
Apart from a few exceptions, Desmopan is supplied solely in its natural color. This will be somewhere between transparent yellow and opaque
white, depending on the grade in question.
Converters can easily color Desmopan themselves. A simple and reliable means of doing this is
by using pigment masterbatch with Desmopan as
the carrier material.
Pigment masterbatch based on polystyrene or SAN
resin is suitable to a limited extent, while masterbatch based on polyethylene, polypropylene or PVC
is not at all suitable. Desmopan can similarly be
colored with pigments and pastes. The standard
quantities employed (depending on wall thickness
and color density):
Pigment masterbatch
Coloring pastes
Pigments
Page 21 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
1.0 - 4%
0.5 - 1%
0.2 - 0.5%
Particular care should be taken to ensure that the
coloring agents employed are dry. Even the addition of just 1% moist pigment masterbatch can affect the surface and impair demolding behavior.
Food contact
Since there are different provisions governing food
contact in a large number of countries, no general
statement can be made here.
If you have any questions on this subject please
contact:
Bayer MaterialScience AG
Dr. Eduard Haensel
Tel.: +49(0)214/30-72939
Fax: +49(0)214/30-31764
E-Mail: [email protected]
Occupational hygiene and environmental advice
Air extraction
Desmopan can be machined and processed over a
wide temperature range but, as with all natural and
synthetic organic materials, it decomposes as of a
certain temperature. The development of smoke
signifies that decomposition is taking place.
Slow decomposition commences at approximately
240 C, depending on the grade of Desmopan
involved. Further information may be obtained from
our Safety Data Sheets.
We recommend efficient air extraction in all cases.
This is particularly important for extrusion and welding, since, in the latter case in particular, it is impossible to achieve a controlled temperature profile.
Waste disposal
Providing that it is not contaminated with other substances, Desmopan can essentially be dumped on
municipal landfills. It does not constitute a hazard to
water. If the material can no longer be recycled,
then it is feasible and, indeed makes sense, for it to
be incinerated in a waste incineration plant on
account of its high calorific value.
Desmopan
Technical Information
Recycling
Injection molding
Molded parts in Desmopan must be marked in
accordance with DIN/ISO 11469 and ISO 11469
(see TI KU21159).
Sprue and runner waste and other clean waste can
be granulated and re-processed. The quantity of
regrind added to virgin material should always be
selected on the basis of the requirement profile
specified for the parts. This will also show whether it
is possible to use 100 % regrind. Unless the injection moldings are being used for inferior-quality
applications, they must be tested to check that they
meet the specified requirements.
>TPU<
All Desmopan grades can be remelted in a stable
manner and can thus be reprocessed in the course
of recycling (they should be pre-dried as a matter of
principle).
Extrusion
Either process separately or add to injection molding grades.
DP / * This is a develomental product. Further information, including amended or supplementary data on hazards associated with its use,
may be compiled in the future. For this reason no assurances are given as to type conformity, processability, long-term performance characteristics or other production or application parameters. Therefore, the purchaser/user uses the product entirely at his own risk without having
been given any warranty or guarantee and agrees that the supplier shall not be liable for any damages, of whatever nature, arising out of
such use.
Commercialization and continued supply of this material are not assured. Its supply may be discontinued at any time.
This information and our technical advice whether verbal, in writing or by way of trials are given in good faith but without warranty, and
this also applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify the information currently provided - especially that contained in our safety data and technical information sheets - and to test our products as to
their suitability for the intended processes and uses. The application, use and processing of our products and the products manufactured by
you on the basis of our technical advice are beyond our control and, therefore, entirely your own responsibility. Our products are sold in
accordance with the current version of our General Conditions of Sale and Delivery.
Unless specified to the contrary, the values given have been established on standardised test specimens at room temperature. The figures
should be regarded as guide values only and not as binding minimum values. Kindly note that, under certain conditions, the properties can
be affected to a considerable extent by the design of the mold/die, the processing conditions and the coloring.
Publisher: Business Development TPU
Bayer MaterialScience AG,
D-51368 Leverkusen
www.plstics.bayer.com
Page 22 of 22
File No.: KU24001-0410 en
Issue 2004-10-01
Desmopan
Technical Information