Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Super60 & All GTA-02 Date: 25-04-2021
Time: 09.00Am to 12.00 2019_P1 Max.Marks:180

KEY SHEET
PHYSICS

1 A 2 B 3 B 4 A 5 ACD 6 ABC
7 ABD 8 BD 9 ABD 10 AD 11 BD 12 ACD
13 9 14 2 15 2 16 4 17 1 18 5

CHEMISTRY

19 C 20 C 21 B 22 A 23 ABC 24 AB
25 AC 26 ABCD 27 ABCD 28 CD 29 ABC 30 AB
31 2 32 6 33 4 34 6 35 1 36 2

MATHEMATICS

37 A 38 A 39 C 40 D 41 BCD 42 BCD
43 AC 44 AC 45 AC 46 AB 47 D 48 AD
49 24 50 3 51 3.4 52 3 53 2.4 54 1
Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
SOLUTIONS
PHYSICS
1. Path y  x 2  x
 Vy  2xVx  Vx
 a y  2Vx2  2xa x  a x
at 1, 0  , Vy  Vx  2
ay  4  ax

as a.v  0

a x  a y  0  a  2 2m / s 2
V  t /RC V  t / LC
2. ic  e  e
R R
 Rt
V  V
iL  1  e L  
R  R

1  et / LC

1
iC  i L will be at e  t/ LC

2
 t  LC l n  2 
 RCl n 2
3. Equivalent system
K
K eff 
12
12m
T  2
K
Dia
1mm
4. diameter 2r = 2mm   35   2.35mm
100
Length l  9.45cm
 curved surface area s  2rl   3.14  0.235  9.45
 6.98cm 2
dv V2
5. 
dt R
dv dt
 2 
V R
1 1 t
  0
V V R
0
V
V
V
1 0 t
R
dV v2
V 
dS R
dV dS
 
V R
 V  V0 e  S/R
6. TA  4.25   A

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Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
TB  4.70   B
given  B  2 A
1
 TB  TA
4
And TB  TA  1.50
 TB  0.50, TA  2.00
A  2.25eV
 B  4.20eV
7.  i  a 2
a 2 a
 
2 a 2
V2,1 i iR  0
P2
8. Given  const

 P 2 V  const, PT  const
1
 P2 P02  P  P0 / 2,T  2 T0
2
9. We can find no slipping between A and m
 a B  2m / s 2 , a A  B  3m / s 2
From B = 4 N , from A = 6 N
A and B will collide after t :
1
8   2  3 t 2  t 2  16
2
 t  4 sec
10. Let q1 & q 2  5Q
Also  q1  2Q    Q2  Q  2
 q1  2q 2  4Q
 q1  2Q, q 2  3Q
11. let ‘  ’ is angle made by the ray with X-axis at a part ( x,y ) then
1
 cos   1sin 900  cos  

2  1
 tan    e y/2a
1
dy y
  2a  e  y/ 2a day  dx
dx e
 x  2a  e  y/2a  1  x  2a 1  e  y/2a 
 at x  a, y  2a ln 2
12. dia
1 3
Collision  x  Vx  10   2m / s
3 5
1 4
Collision  y  Vy  10   4m / s
2 5
 VA  2m / s, VB  VC  2 5m / s

Sec: Sr. Super60 & All Page 3

Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
 string impulse  0.5  2  1N.S
Gmm 1 Gm
13. Total energy E    m
R 2 2R
Gmm Gmm
  
4  2a
 R
3 
4
 2a  R   max  rmax
3
rmax  9km
It wont loose contact with the surface of planet
y 1.6 1011 4
14. C   104
 2500 5
C  8000m / s
8000
f AC   odd    odd  20KHz
0.40
8000 20
f CD   int    int  KHz
0.20 3
8000 20
f DB   odd    odd  KHz
20 3
Fund .conb = 20KHz
dv V2
15. Given  2
dt R
dv V 2
V  2
ds R
dv 2
   ds
V R
 V  V0 e 2s/R
R /2
R d  2
16. i  2   B0 t  r2rdr   B0 R 3
2 dt  0  24
2
BR
E 0
12
 320  2   320  2 
17. f1    80, f 2    80
 320   320 
4  80
   f 2  f1   1per sec
  320
18. as mg  Fbybottom  Fcurved surface  0
1 3 3
 R 2 R. 3
g.j  3
gRR 2 j
3 4R 4R
g 3g g
 j  j   j  5jN
4 4 2
F  5N

Sec: Sr. Super60 & All Page 4

Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
CHEMISTRY
Zno  2 HCl  ZnCl2  2 H 2O
19.
Al2O3  6 HCl  2 AlCl3  3H 2O
ZnCl2  4 NH 4OH   Zn  NH 3 2  Cl2  4 H 2O
so lub le
AlCl3  3NH 4OH  Al  OH 3  3NH 4Cl
Inso lub le
0
20. Graph II is below graph I of formation Fe2O3 up to 850 C and graph III is below the
graph I of formation of Fe2O3 after 850 C .
0

21. Conceptual
CH3 CH3 CH3

22. Since E is NC it means C is N2+ Cl and D is OH

Reimer Tie reaction takes place ortho position to the OH.

23. double chain silicate.
24. Conceptual
25.
O O O
C H
51. C H C H
OD
OD + OD

CH2 OD O O
C O CH 2 O
C O D
+ deuterium
+
exchange

26. Conceptual
27. Conceptual
28. Conceptual
29. Critical pressure, Pc = a/27b2
Critical temperature, Tc = 8a/27Rb
Critical volume, Vc = 3b
Critical parameter of two gases :
A B
3
Pc  1.277  10 Pc  1.9793  103
Vc  0.0954 Vc  0.1278
8 1.360 8 3.592
Tc   Tc  
27R 0.0318 27R 0.0426
 (Pc )B  (Pc )A; (Vc )B  (Vc )A; (Tc )B  (Tc )A

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Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s

 PCl    PCl  
30. Solid Pcl5 has  4   6 

 PBr    Br  
Solid PBr5 has  4   

ClO3  aq   H 2O  l   ClO4  aq  2H   aq  2e

31.

2 H   ClO3  aq  2e  ClO2  aq  H 2O  l 

2ClO3  aq  ClO2  aq   ClO4  aq 

o
Ecell  0.33  0.36  0.33V
0.059
E  Eo  log Q
n

At equilibrium, E=0, n=2, Q=K

0.059
0  0.03  log K
2

log K  1
1
K
10
xx 1
K 2

 0.1  2 x 10
x  0.019
32.
XeF6 H2O OH -
HF+XeO3 XeO64-+Xe+H2O+O2
(explosive)
33. Bi 2S3 (s) 
2Bi3+ + 3S2–
Ksp= [Bi3+]2[S2–]3
If [Bi3+] = 0.1 M, then [S2–] required will be
1 × 10–56 = (10–1)2 × [S2–]3
[S2–] = 1 × 10–18
[H  ]2 [S2 ]
H2S = 2H+ + S2–, Ka = [H 2S]
10 22
 104
So, [H+]2= 1018
[H+] = 10–2, x = 2
For, Na2CO3 no. = 1
So, 20 × y × 1 = 4000 × 10–2
Sec: Sr. Super60 & All Page 6
Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
y =2
So, x + y = 4
34. i = 1.25
1 1

n 1   n  1
original mole fraction =
1.25 1

1.25   n  1 5
Now
6.25 = 1.25 + (n – 1)
n=6
35. A  Product is of order 1
B  Product is of order 0
1+0=1
CH 2  CH  CH 2CH  CH 2 W 
36.

MATHEMATICS
37. Solving the line and the plane A=  3x 2 5
3 16 
The image of 3 i  k in the plane is B   ,
  ,7
 5 5 
  
AB is parallel to 9i  13j  5k
e12  e2 2  1
cos  
38. e1e2
39. Let S =  h, k  be the focus
x cos   y sin   2 be the directrix
P1  1, 0  , P2   1, 0 
2 2
 h  1  k 2   cos   2 
2 2
 h  1  k 2   cos   2 
Adding h 2  k 2  1  4  cos 2 
subtracting h  2 cos 
h2 k 2
Eliminating '  ' ,  1
4 3
40.  Equation of normal at P(1, 1) is ay + x = a + 1
1
 slope of normal at (1, 1) = -
a
 slope at tangent at (1, 1) = a …… (i)
dy
Also given y
dx
dy
  ky
dx
dy
 k  a from eq.i 
dx 1, 1

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Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
dy
 then  ay
dx
dy
  adx
y
 In | y | ax  c
 It is passing through (1, 1), then c = -a
Or In|y| = a(x – 1)
| y | e  
a x1

x1  tan  , then x  tan   

41. 2  6  ….
 n
xn 1  tan      xn  xn  6 , n  1
 6 
74 3
If x1  2 , x2  5 3  8 , x3 
3 34
1
x4   , x5  
2 3  0

2 2 3 1
1
(A) x2020  x4   (B) x2021  x5  0
2

1 1 1
(D) 2022  2    3033
n
(C) x100  x4      x100   
2 n 1 3  2
y

-4 0 1


42.
f 1  x    x  1 x  4   x 2  3 x  6 
f 11  x    2 x  3  x 2  3 x  1  0
3 3  5
x ,
2 2
x1 , x2  4,1 in which f x is decreasing
   
43. A lies on 3x  y  3 and x  y  1
A  Z1   1, 0 
B  Z2  is foot of perpendicular of (5, 0) on 3x  y  3  0  B  Z2    2, 3 
C  Z3  = centre of the circle = (5, 0)
 Area of ABC  2 3
1
Slope of line perpendicular to AB  
3
Sec: Sr. Super60 & All Page 8
Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
1
Equation of line y   x
3
x y
  
3 1
Z  3 i 
1
44. We have 7
7
3 1 4
1 
1 2 3  7    5   0,    , 7 
7 
6 5 

45. f 1    0  b  2
f l 1    f 1 1    a  4
C) ax 2  bx  a  4 x 2  2 x  4  4 has 4 solutions
D) Area of triangle is 1 square unit
17
4

4 4 4
46. P  A  , P  B   , P C  
8 8 8
2 1 1
8
 
P  A  B  , P A  , P A 
B 2 C 2
 
P A  B C  0
47. Let W = player with white die wins
Ri
= red dice shows i, i=1, 2,……., 6
P  w    P  Ri  P  w 
 Ri 
2 6 5 4 3 2 1 1 1
=            
15  6 6 6 6 6   3 6  2
48. Differentiating two times,
f  2 x   1 2 x2  6 x
 f  x   3 x2  x 
49. Variable plane is lx  my  nz  p  (1)
1 P3 P3
 4  24
6 lmn lmn

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Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s
r x1 y1 z1
If f  x1 , y1 , z1  is foot of  of (0, 0, 0) to ---(1), Then  
l m n
x12 y12 z 2 x 2  y12  z12
   1  1
lx1 my1 nz1 P
p x12  y12  z12 p x12  y12  z12 p x12  y12  z12
  ,  , 
l x1 m y1 n z1
3

multiplying,
x 1
2
 y12  z12 

p3
 24
x1 y1 z1 lmn
50. Centre =  2, 2  , radius=3
 circle passes through  2, 1 ,  2,5  and touches y  5
 1 2 x 
51.  Sin 1  x 2   2, 1, 0,1
 Range of g  x   0,1, 2,3
f  g  x    0, x  R  f  0   0, f  3  0
7 
a  , 2
5 
3 a c
52.    a  9, c  15, b  12 ( a, b, c are in A.P)
1 3 5
 54
r  3
s 18
53. f  0  2
x
f  x    e x  e x  cos x   f  t  dt
0

f l
 x  f  x  e x
e x
 cos x   e  e  sin x
x x

Solving: ye x     e  1 cos x   e  1 sin x  dx

2x 2x

e2 x 2
  2 cos x  sin x  2sin x  cos x    cos x  sin x  
5 5
 3cos x  sin x   2 
y  ex  e x  cos x  sin x  
5  5 
8 6 2
Max of cos x  sin x  is 2.4
5 5 5
1 1
1
n tan t dt
an n n 1
54. Sol: 1) lim  lim 1
n  b n  1 1
 n sin t dt
n
n n 1
 n 
tan 1  
= lim  n 1   1
n   n  2
sin 1  
 n 1
gl  x
2) f l  x   3
1   g  x 

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Sri Chaitanya IIT Academy 25-04-2021_Sr.Super60 & All_Jee-Adv(2019-P1)_GTA-02_Key & Sol’s

=
1  sin  cos x     sin x 
2

3
1   g  x

 2   1  g   2   0 
fl 
1
1 dy  tan 1  xy   tan 1 x
3) f  x   0      lim f  x   1
1  x2 y 2  x 0 x x 0

Sec: Sr. Super60 & All Page 11