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The document outlines various chemical reactions involving sulphites, carbonates, nitrites, and sulfides, detailing their interactions with acids and other reagents. It describes how to detect the presence of these compounds through specific tests, including the formation of precipitates and color changes. Additionally, it provides flow sheets for conducting these tests systematically.

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7 views2 pages

New DOC Document

The document outlines various chemical reactions involving sulphites, carbonates, nitrites, and sulfides, detailing their interactions with acids and other reagents. It describes how to detect the presence of these compounds through specific tests, including the formation of precipitates and color changes. Additionally, it provides flow sheets for conducting these tests systematically.

Uploaded by

aslamsaira437
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Name: Tafshala Ashraf

Roll No: CHEM63S25S008

NOTLS/EXPLANATIONS:Sulphites reacts with dil.H2SO4 to give SO2


which reacts with K₂Cr₂O7 and
solution becomes green due to formation of Cr₂(SO₄) 3 .
Na₂SO3+H₂SO₄→Na₂SO₄+H₂O+SO₂
K2Cr₂O7+SO₂ →K₂SO₄+Cr₂(SO₄)3+H₂O
CO2 react with lime water,Ca(OH)2 to form insoluble white ppt.CaCO3.
Na₂CO3+H₂SO₄→Na₂SO₄+H₂O+CO₂
CO₂+Ca(OH)₂→CaCO₃+H₂O
8.CO3² in the presence of C₂O42-
-

Carbonates react with dil.H2SO4 to yield CO2 which turns lime water
milky.
Heat the solution to decompose the carbonate completely.Add few
drops of KMnO4 to this warm solution.Decolourization of
KMnO4 indicates the presence of oxalates.
Flow sheet
Mixture+dil.H,SO. →warm
Effervescence in cold,CO,evolyes on heating:CO
Warm solution after the effervescence stops.Add few
drops of KMnO:colour of KMnO,discharged:C.O
9. NO₂in the presence of NO₃
Nitrite can be detected in the presence of nitrate by usual tests like
Ring test but nitrate cannot be
detected in the presence of nitrite.Therefore nitrite is decomposed
by adding sulphamic acid to the acidified
solution of the mixture before performing tests for nitrate.
HNO₄+HO.SO₂NH₂→N₂+H₂SO₄+IO
10.S²in the presence of SO,?
Dissolve the mixture in water or prepare Na2CO3-extract and
neutralize it with dil.H,SO.Divide this
solution into two portions.To one portion add few drops of sodium
nitroprusside solution.A violet red
colouration indicates the presence of S².To the second portion add
dil HCl,solid CdCO,shake vigorously and
filter,yellow ppt.indicate S².Acidify the filtrate with add dil.HCl and
add BaCl₂and bromine water.A white
Ppt.shows the presence of SO,
Flow sheet
Aq.Solution or neutral sodium extract+dil.H₂SO →Divide into two
portions
Solution:S'and SO₃.Add alkaline solution of sodium
nitroruside solution →A violet red colouration:S²
Solution:S²&SO².Add dil.HCl+
CdCl₂(s)→Shake and filter
Yellow ppt:S²
[Filtrate:Add dil.HCl and BaCl₂→white ppt.
so²
[NOTES/EXPLANATIONS
Sulphide gives violet red colouration with sodium nitroprusside
solution.
NaS+Nas[Fe(CN)sNO]→Na.IFe(CN)sNOSI
Acidified solution of sulphide gives white ppt.when treated with solid
CdCO
CdCO+2HC→
CdC₂+H₂O+CO₂
CdCl₂+NaS→
CdS +2NaCl

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